EP0171351B1 - Device for cooling a hot product gas - Google Patents
Device for cooling a hot product gas Download PDFInfo
- Publication number
- EP0171351B1 EP0171351B1 EP85730082A EP85730082A EP0171351B1 EP 0171351 B1 EP0171351 B1 EP 0171351B1 EP 85730082 A EP85730082 A EP 85730082A EP 85730082 A EP85730082 A EP 85730082A EP 0171351 B1 EP0171351 B1 EP 0171351B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- product gas
- gas
- cooling
- insert
- wall
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28C—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA COME INTO DIRECT CONTACT WITHOUT CHEMICAL INTERACTION
- F28C3/00—Other direct-contact heat-exchange apparatus
- F28C3/02—Other direct-contact heat-exchange apparatus the heat-exchange media both being gases or vapours
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/82—Gas withdrawal means
- C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/04—Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D17/00—Arrangements for using waste heat; Arrangements for using, or disposing of, waste gases
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F19/00—Preventing the formation of deposits or corrosion, e.g. by using filters or scrapers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28F—DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
- F28F2265/00—Safety or protection arrangements; Arrangements for preventing malfunction
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S48/00—Gas: heating and illuminating
- Y10S48/02—Slagging producer
Definitions
- the invention relates to a device for cooling a hot product gas which contains sticky particles which lose their tackiness on cooling, consisting of a tubular zone in which the product gas is cooled directly by cooling gas and a gas wall being formed in the wall of the tubular zone, which prevents contact of the product gas with the wall.
- Such a device is known from US-PS-2 971 830.
- a particle-free protective gas is fed in near the inlet of the tubular zone in such a way that a protective gas layer is formed on the wall of this zone, which prevents contact of the wall with the hot product gas, the protective gas being at the same time a cooling gas.
- the cooling gas is fed in through an annular insert with a tangentially directed speed component, and through inlets arranged in the radial direction, which lie above the outlets in the annular zone.
- the outlets are arranged at equal intervals around the circumference of the tubular insert somewhat above its lower end, so that there is an annular region not acted upon by the cooling gas in the direction of flow at the beginning of the critical zone mentioned.
- the cooling gas is not only blown in countercurrent to the product gas, but is directed around the lower end of an insert, it flows seamlessly through the tubular zone from the lowest end of the insert over the entire endangered length of the wall of the tubular zone.
- This shows a wall section 1 of a carburetor, in which the product gas is generated.
- the wall section 1 merges into an outlet connection 2, which forms the tubular zone through which the product gas flows upward out of the gasifier.
- the product gas entrains particulate substances which are sticky due to the high temperature of the product gas and which only lose their tack after the product gas has cooled.
- the temperature of the product gas is still so high that there is a risk that the entrained particles, when they hit a solid wall, get caught on it.
- annular insert 3 within the outlet nozzle 2, which forms a gap 4 between itself and the inner wall of the outlet nozzle 2.
- this gap 4 is equidistantly distributed over the circumference of the outlet nozzle 2, one or more inlet opening (s) 5 for a cooling gas, which at the same time form a contact between the product gas and the inner wall of the outlet nozzle 2 or the insert 3 preventing gas wall is used.
- the inlet opening (s) 5 can be connected, for example, to a ring line which is guided around the outlet connection 2.
- the cooling gas flowing down through the gap 4 prevents the product gas from entering the gap 4 and thus clogging of this gap by the particles contained in the product gas.
- the cooling gas is directed around the lower end of the insert 3 by the product gas flowing upwards, so that it flows upwards again on the inner surface of the insert 3 parallel to the latter. It forms a continuous gas wall, which prevents the product gas from touching the insert 3.
- the sticky particles entrained in the product gas can therefore not reach the inner wall of the insert 3 and attach to it.
- the cooling gas simultaneously causes cooling of the product gas during the passage through the insert 3, so that the product gas has cooled down at the upper outlet of the insert 3 to such an extent that the particles in it have lost their stickiness.
- This cooling effect is supported in that the insert 3 itself is cooled. It contains for this purpose, for example, cooling channels running in its interior through which water or another suitable cooling medium flows.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Combustion & Propulsion (AREA)
- General Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Thermal Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
- Sampling And Sample Adjustment (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
- Electrophonic Musical Instruments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Die Bonding (AREA)
- Jigs For Machine Tools (AREA)
- Butt Welding And Welding Of Specific Article (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Abstract
Description
Die Erfindung betrifft eine Vorrichtung zum Abkühlen eines heißen Produktgases, das klebrige Teilchen enthält, die ihre Klebrigkeit beim Abkühlen verlieren, bestehend aus einer rohrförmigen Zone in der das Produktgas durch Kühlgas direkt gekühlt wird und wobei in der Wand der röhrenförmigen Zone eine Gaswand gebildet wird, die einen Kontakt des Produktgases mit der Wand verhindert.The invention relates to a device for cooling a hot product gas which contains sticky particles which lose their tackiness on cooling, consisting of a tubular zone in which the product gas is cooled directly by cooling gas and a gas wall being formed in the wall of the tubular zone, which prevents contact of the product gas with the wall.
Eine derartige Vorrichtung ist aus der US-PS-2 971 830 bekannt. Bei dieser Vorrichtung wird nahe am Einlaß der röhrenförmigen Zone ein teilchenfreies Schutzgas auf solche Weise eingespeist, daß dan der Wand dieser Zone eine schützende Gasschicht gebildet wird, die einen Kontakt der Wand mit dem heißen Produktgas verhindert, wobei das Schutzgas gleichzeitig ein Kühlgas ist. Zur Bildung der schützenden Gasschicht wird das Kühlgas durch einen ringförmigen Einsatz mit eienr tangential gerichteten Geschwindigkeitskomponente eingespeist, und durch in radialer Richtung angeordnete Einlässe, die oberhlab der Auslässe in der ringförmigen Zone liegen, zugeführt. Die Auslässe sind in gleichen Abständen um den Umfang des röhrenförmigen Einsatzes etwas oberhalb seines unteren Endes angeordnet, so daß sich ein vom Kühlgas nicht beaufschlagter Ringbereich in Strömungsrichtung am Anfang der genannten kritischen Zone ergibt.Such a device is known from US-PS-2 971 830. In this device, a particle-free protective gas is fed in near the inlet of the tubular zone in such a way that a protective gas layer is formed on the wall of this zone, which prevents contact of the wall with the hot product gas, the protective gas being at the same time a cooling gas. To form the protective gas layer, the cooling gas is fed in through an annular insert with a tangentially directed speed component, and through inlets arranged in the radial direction, which lie above the outlets in the annular zone. The outlets are arranged at equal intervals around the circumference of the tubular insert somewhat above its lower end, so that there is an annular region not acted upon by the cooling gas in the direction of flow at the beginning of the critical zone mentioned.
Bei dieser bekannten Vorrichtung ist der Einfluß auf die Strömung des Kühlgases in der röhrenförmigen Zone durch die Ausströmrichtung beim Eintritt in diese Zone gegeben. Eine durchgehende schützende Gaswand über den gesamten Umfang der röhrenförmigen Zone schient daher nicht immer gewährleistet. Die Vorrichtung ist außerdem relativ aufwendig, da der ringförmige Einsatz genau eingepaßt werden muß und zum Aufbau der schützenden Gaswand der kritische Bereich unterhalb der Austrittsöffnungen des Kühlgases nicht beiträgt.In this known device, the influence on the flow of the cooling gas in the tubular zone is given by the outflow direction when entering this zone. A continuous protective gas wall over the entire circumference of the tubular zone therefore does not always appear to be guaranteed. The device is also relatively expensive, since the annular insert must be precisely fitted and the critical area below the outlet openings of the cooling gas does not contribute to the construction of the protective gas wall.
Es ist daher die Aufgabe der vorliegenden Erfindung, eine Vorrichtung der anfangs genannten Art zu schaffen, bei der eine über die ganze Länge der röhrenförmigen Zone wirksame schützende Gaswand zur Vermeidung eines Kontaktes zwischen dem die klebrigen Teilchen enthaltenden Produktgas und einer festen Wand gebildet wird und die im Aufbau einfach ist.It is therefore the object of the present invention to provide a device of the type mentioned at the beginning, in which a protective gas wall which is effective over the entire length of the tubular zone is formed to avoid contact between the product gas containing the sticky particles and a solid wall and which is simple to set up.
Diese Aufgabe wird erfindungsgemäß durch die im Kennzeichen des Anspruchs 1 angegebenen Merkmale gelöst.This object is achieved by the features specified in the characterizing part of claim 1.
Dadurch, daß das Kühlgas nicht nur im Gegenstrom zum Produktgas eingeblasen wird, sondern um das untere Ende eines Einsatzes herumgelenkt wird, durchströmt es lückenlos die röhrenförmige Zone vom untersten Ende des Einsatzes über die gesamte gefährdete Länge der Wand der röhrenförmigen Zone.Because the cooling gas is not only blown in countercurrent to the product gas, but is directed around the lower end of an insert, it flows seamlessly through the tubular zone from the lowest end of the insert over the entire endangered length of the wall of the tubular zone.
Die Erfindung wird im folgenden anhand eines in der Figur dargestellten Ausführungsbeispieles näher erläutert. Diese zeigt einen Wandabschnitt 1 eines Vergasers, in dem das Produktgas erzeugt wird Der Wandabschnitt 1 geht über in einen Auslaßstutzen 2, der die röhrenförmige Zone bildet, durch die das Produktgas nach oben aus dem Vergaser ausströmt. Das Produktgas führt klerbei teilchenförmige Stoffe mit sich, die aufgrund der hohen Temperatur des Produktgases klebrig sind und erst nach einer Abkühlung des Produktgases ihre Klebrigkeit verlieren. Am unteren Teil des Auslaßstutzens 2 ist jedoch die Temperatur des Produktgases noch so hoch, daß die Gefahr besteht, daß die mitgeführten Teilchen, wenn sie auf eine feste Wand treffen, an dieser hängen bleiben. Da hierdurch der freie Durchmesser des Auslaßstutzens 2 verengt wird oder dieser sogar ganz geschlossen werden kann, ist es erforderlich, das Produktgas so zu leiten, daß es in diesem Zustand nicht in Berührung mit der Innenwand des Auslaßstutzens oder einer anderen festen Wand im Bereich der röhrenförmigen Zone gelangt. Gleichzeitig müssen Maßnahmen vorgesehen werden, um das Produktgas innerhalb der röhrenförmigen Zone zoweit abzukühlen, daß an deren Auslaßende die mitgeführten Teilchen ihre Klebrigkeit verloren haben. Dies wird durch die dargestellte Vorrichtung erreicht.The invention is explained below with reference to an embodiment shown in the figure. This shows a wall section 1 of a carburetor, in which the product gas is generated. The wall section 1 merges into an outlet connection 2, which forms the tubular zone through which the product gas flows upward out of the gasifier. The product gas entrains particulate substances which are sticky due to the high temperature of the product gas and which only lose their tack after the product gas has cooled. At the lower part of the outlet port 2, however, the temperature of the product gas is still so high that there is a risk that the entrained particles, when they hit a solid wall, get caught on it. Since this narrows the free diameter of the outlet nozzle 2 or it can even be closed completely, it is necessary to direct the product gas so that it does not come into contact with the inner wall of the outlet nozzle or any other solid wall in the region of the tubular in this state Zone arrives. At the same time, measures must be taken to cool the product gas within the tubular zone to such an extent that the entrained particles have lost their stickiness at the outlet end thereof. This is achieved by the device shown.
Innerhalb des Auslaßstutzens 2 befindet sich ein ringförmiger Einsatz 3, der zwischen sich und der Innenwand des Auslaßstutzens 2 einen Spalt 4 bildet. Am oberen Ende dieses Spaltes 4 befindet sich in gleichen Abständen über den Umfang des Auslaßstutzens 2 verteilt eine oder mehrere Einlaßöffnung(en) 5 für ein Kühlgas, das zugleich zur Bildung der eine Berührung zwischen dem Produktgas und der Innenwand des Auslaßstutzens 2 bzw. dem Einsatz 3 verhindernden Gaswand verwendet wird. Die Einlaßöffnung(en) 5 können beispielsweise mit einer um den Auslaßstutzen 2 herumgeführten Ringleitung verbunden sein.There is an
Das durch den Spalt 4 herabströmende Kühlgas verhindert einen Eintritt des Produktgases in den Spalt 4 und damit eine Verstopfung dieses Spaltes durch die im Produktgas enthaltenen Teilchen. Gleichzeitig wird das Kühlgas durch das nach oben strömende Produktgas um das untere Ende des Einssatzes 3 herumgelenkt, so daß es an der Innenfläche des Einsatzes 3 parallel zu dieser wieder nach oben strömt. Es bildet hierbei eine durchgehende Gaswand, die eine Berührung des Produktgases mit dem Einsatz 3 verhindert. Die im Produktgas mitgeführten klebrigen Teilchen können somit nicht zur Innenwand des Einsatzes 3 gelangen und sich an dieser anlagern. Das Kühlgas bewirkt gleichzeitig während des Durchganges durch den Einsatz 3 eine Kühlung des Produktgases, so daß am oberen Ausgang des Einsatzes 3 das Produktgas soweit abgekühlt ist, daß die Teilchen in diesem ihre Klebrigkeit verloren haben.The cooling gas flowing down through the
Diese Kühlwirkung wird dadurch unterstützt, daß der Einsatz 3 selbst gekühlt wird. Er enthält hierzu beispielsweise in seinem Innern verlaufende Kühlkanäle, durch die Wasser oder ein anderes geeignetes Kühlmedium strömt.This cooling effect is supported in that the
Claims (3)
characterized in that in the tubular zone at least in part an annular insert (3) is provided for the passage of the product gas so as to form a gap (4) between the wall of the tubular zone (2) and the insert, through which the cooling gas is blasted countercurrently to the product gas and diverted around the bottom end of the insert (3).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT85730082T ATE44162T1 (en) | 1984-07-18 | 1985-06-11 | DEVICE FOR COOLING A HOT PRODUCT GAS. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3427088 | 1984-07-18 | ||
DE3427088A DE3427088C2 (en) | 1984-07-18 | 1984-07-18 | Device for cooling a hot product gas |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0171351A1 EP0171351A1 (en) | 1986-02-12 |
EP0171351B1 true EP0171351B1 (en) | 1989-06-21 |
Family
ID=6241326
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP85730082A Expired EP0171351B1 (en) | 1984-07-18 | 1985-06-11 | Device for cooling a hot product gas |
Country Status (14)
Country | Link |
---|---|
US (1) | US4874037A (en) |
EP (1) | EP0171351B1 (en) |
JP (1) | JPS6183878A (en) |
KR (1) | KR940001781B1 (en) |
AT (1) | ATE44162T1 (en) |
AU (1) | AU581897B2 (en) |
BR (1) | BR8503406A (en) |
CA (1) | CA1274086A (en) |
CS (1) | CS255888B2 (en) |
DD (1) | DD237544A5 (en) |
DE (2) | DE3427088C2 (en) |
IN (1) | IN164913B (en) |
SU (1) | SU1384205A3 (en) |
ZA (1) | ZA854610B (en) |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB8711359D0 (en) * | 1987-05-14 | 1987-06-17 | Shell Int Research | Cooling hot produced gas |
US4859213A (en) * | 1988-06-20 | 1989-08-22 | Shell Oil Company | Interchangeable quench gas injection ring |
DE3844347A1 (en) * | 1988-12-30 | 1990-07-05 | Krupp Koppers Gmbh | METHOD AND RADIATION COOLER FOR RADIATION COOLING A PRODUCT GAS FLOW LEAVING FROM THE GASIFICATION REACTOR |
FI93056C (en) * | 1991-07-23 | 1995-02-10 | Ahlstroem Oy | Method and apparatus for feeding process or flue gases into a gas cooler |
DE4340156A1 (en) * | 1993-11-25 | 1995-06-01 | Krupp Koppers Gmbh | Method and device for cooling partial oxidation raw gas |
JP2544584B2 (en) * | 1994-04-11 | 1996-10-16 | 株式会社日立製作所 | Coal gasifier and method of using coal gasifier |
ES2121132T3 (en) * | 1994-10-28 | 1998-11-16 | Krupp Uhde Gmbh | INSTALLATION FOR PRESSURE GASIFICATION OF FUELS FINALLY DIVIDED IN THE COURSE OF GENERATING A PRODUCT GAS. |
US6675880B2 (en) * | 1996-03-29 | 2004-01-13 | Mitsui Engineering And Shipbuilding Company Limited | Air heater for recovering a heat of exhaust gas |
DE19910927A1 (en) * | 1999-03-12 | 2000-09-14 | Kloeckner Humboldt Wedag | Method and device for cooling a hot gas stream in a mixing chamber |
EP1128151A1 (en) * | 2000-02-23 | 2001-08-29 | OKR Cleaning | Cleaning installation for removing soot |
DE60106313T2 (en) | 2000-02-23 | 2006-02-23 | Okr Cleaning | Cleaning system for removing soot |
DE102007020145A1 (en) * | 2006-05-23 | 2007-11-29 | Bayer Materialscience Ag | Apparatus for cooling gases (quench) to form a corrosive condensate |
JP6016729B2 (en) * | 2013-08-02 | 2016-10-26 | 東邦チタニウム株式会社 | Metal powder manufacturing method and manufacturing apparatus |
JP6362219B2 (en) * | 2015-03-09 | 2018-07-25 | 太平洋セメント株式会社 | Gas cooling method and apparatus |
CN110538480A (en) * | 2019-09-25 | 2019-12-06 | 上海电气集团股份有限公司 | condensing system and condensing method |
Family Cites Families (28)
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DE1165618B (en) * | 1959-08-05 | 1964-03-19 | Schoppe Fritz | Device for quenching hot gases |
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FR1430185A (en) * | 1964-12-23 | 1966-03-04 | Swirl slot combustion hearth | |
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SE8304273D0 (en) * | 1983-08-04 | 1983-08-04 | Skf Steel Eng Ab | SET AND DEVICE FOR HEATING A GAS WITH ANOTHER GAS |
US4703793A (en) * | 1986-06-13 | 1987-11-03 | Sante Fe Braun Inc. | Minimizing coke buildup in transfer line heat exchangers |
-
1984
- 1984-07-18 DE DE3427088A patent/DE3427088C2/en not_active Expired
-
1985
- 1985-06-11 DE DE8585730082T patent/DE3571145D1/en not_active Expired
- 1985-06-11 EP EP85730082A patent/EP0171351B1/en not_active Expired
- 1985-06-11 AT AT85730082T patent/ATE44162T1/en not_active IP Right Cessation
- 1985-06-19 AU AU43840/85A patent/AU581897B2/en not_active Ceased
- 1985-06-19 ZA ZA854610A patent/ZA854610B/en unknown
- 1985-06-25 IN IN475/CAL/85A patent/IN164913B/en unknown
- 1985-06-27 JP JP60139206A patent/JPS6183878A/en active Granted
- 1985-07-10 SU SU853920677A patent/SU1384205A3/en active
- 1985-07-11 CS CS855175A patent/CS255888B2/en not_active IP Right Cessation
- 1985-07-17 CA CA000486942A patent/CA1274086A/en not_active Expired - Fee Related
- 1985-07-17 DD DD85278695A patent/DD237544A5/en not_active IP Right Cessation
- 1985-07-17 BR BR8503406A patent/BR8503406A/en not_active IP Right Cessation
- 1985-07-18 US US06/756,294 patent/US4874037A/en not_active Expired - Lifetime
- 1985-07-18 KR KR1019850005122A patent/KR940001781B1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
CS255888B2 (en) | 1988-03-15 |
JPH0474635B2 (en) | 1992-11-26 |
KR940001781B1 (en) | 1994-03-05 |
SU1384205A3 (en) | 1988-03-23 |
KR860001333A (en) | 1986-02-26 |
ATE44162T1 (en) | 1989-07-15 |
US4874037A (en) | 1989-10-17 |
DD237544A5 (en) | 1986-07-16 |
JPS6183878A (en) | 1986-04-28 |
AU581897B2 (en) | 1989-03-09 |
CA1274086A (en) | 1990-09-18 |
ZA854610B (en) | 1986-02-26 |
CS517585A2 (en) | 1987-07-16 |
EP0171351A1 (en) | 1986-02-12 |
AU4384085A (en) | 1986-01-23 |
DE3571145D1 (en) | 1989-07-27 |
BR8503406A (en) | 1986-04-08 |
DE3427088C2 (en) | 1987-05-07 |
IN164913B (en) | 1989-07-08 |
DE3427088A1 (en) | 1986-01-30 |
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