EP0153849B1 - Hot rolling method - Google Patents

Hot rolling method Download PDF

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Publication number
EP0153849B1
EP0153849B1 EP85301178A EP85301178A EP0153849B1 EP 0153849 B1 EP0153849 B1 EP 0153849B1 EP 85301178 A EP85301178 A EP 85301178A EP 85301178 A EP85301178 A EP 85301178A EP 0153849 B1 EP0153849 B1 EP 0153849B1
Authority
EP
European Patent Office
Prior art keywords
work rolls
strips
rolled
rolling
rolls
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP85301178A
Other languages
German (de)
French (fr)
Other versions
EP0153849A2 (en
EP0153849A3 (en
Inventor
Itaru Hishinuma
Akio Adachi
Ko Toyoshima
Yoji Utashiro
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
Kawasaki Steel Corp
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Priority claimed from JP59037478A external-priority patent/JPS6114002A/en
Priority claimed from JP59107553A external-priority patent/JPS60250806A/en
Priority claimed from JP59204147A external-priority patent/JPS6182907A/en
Priority claimed from JP59211503A external-priority patent/JPS6192702A/en
Application filed by Kawasaki Steel Corp filed Critical Kawasaki Steel Corp
Publication of EP0153849A2 publication Critical patent/EP0153849A2/en
Publication of EP0153849A3 publication Critical patent/EP0153849A3/en
Application granted granted Critical
Publication of EP0153849B1 publication Critical patent/EP0153849B1/en
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D7/00Modifying the physical properties of iron or steel by deformation
    • C21D7/13Modifying the physical properties of iron or steel by deformation by hot working
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B37/00Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
    • B21B37/28Control of flatness or profile during rolling of strip, sheets or plates
    • B21B37/42Control of flatness or profile during rolling of strip, sheets or plates using a combination of roll bending and axial shifting of the rolls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/22Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
    • B21B1/24Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process
    • B21B1/28Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process by cold-rolling, e.g. Steckel cold mill
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B31/00Rolling stand structures; Mounting, adjusting, or interchanging rolls, roll mountings, or stand frames
    • B21B31/16Adjusting or positioning rolls
    • B21B31/18Adjusting or positioning rolls by moving rolls axially
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/22Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length
    • B21B1/24Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process
    • B21B1/26Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling plates, strips, bands or sheets of indefinite length in a continuous or semi-continuous process by hot-rolling, e.g. Steckel hot mill
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B27/00Rolls, roll alloys or roll fabrication; Lubricating, cooling or heating rolls while in use
    • B21B27/02Shape or construction of rolls
    • B21B27/021Rolls for sheets or strips
    • B21B2027/022Rolls having tapered ends
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B2269/00Roll bending or shifting
    • B21B2269/02Roll bending; vertical bending of rolls
    • B21B2269/04Work roll bending
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B2269/00Roll bending or shifting
    • B21B2269/12Axial shifting the rolls
    • B21B2269/14Work rolls

Definitions

  • This invention relates to a hot rolling method for avoiding edge build-up and edge drop of rolled strips or plates and is concerned with such a method involving preventing local wear of the work rolls of rolling mills, such as four or six high mills, whilst simultaneously controlling the profiles of the steel strips or plates.
  • a taper end roll rolling method is effective to prevent edge drops with the aid of work rolls of particular geometrical shapes, for example, as disclosed in JP-A-54 024 256.
  • both ends of each of the work rolls include tapered portions in order to prevent the edges of the strips becoming thinner.
  • a work roll shift method is effective for profile controlling as disclosed in JP-A-55 077 903.
  • a pair of work rolls is used wherein each has a tapered portion and the rolls are arranged one above the other with the tapered portions on opposite sides of the rolling path.
  • the work rolls are shifted in the axial direction, before rolling, in accordance with the width of the strips to be rolled.
  • the work rolls 1 progressively wear to form tracks or traces 2 for the strips whose edge portions 2b usually wear deeper than the centre portions 2a as shown in Fig.1.
  • the rolled strip 3 has a sectional profile including at its edges irregular protrusions or ridges p and p' which are referred to as "edge build-up" as shown in Fig.2. It is clearly evident that such an edge build-up causes the greatest difficulty for profile controlling of the strips and for roll-change-free rolling which is rolling with a pair of work rolls over a wide range of sizes of strips or plates to be rolled without changing the rolls. The same holds true when using taper end rolls.
  • a hot rolling method using a hot finishing mill including a pair of axially adjustable work rolls each having a tapered portion at one end of its barrel and arranged one above the other with the tapered portions being on opposite sides of the rolling path and being so axially adjusted as to locate each edge of strip material to be rolled in a roll gap zone determined by the respective tapered portion of one of the work rolls characterised in that , during the course of rolling a sequence of discrete lengths of strip material, each of substantially the same width, in the interval between succeeding lengths said work rolls are cyclically axially displaced relative to each other within a range of displacement such that said edges of the material remain within the roll gap zone delimited by said tapered portions thereby preventing edge build-ups of the material, whereby the upper limit of the cyclical values of the distance from an edge of the material to the transition point between said tapered portion of the work roll nearest to said edge of the material and the central portion of the roll is variably set so as to decrease as the thermal expansion of
  • the amplitude of displacement of the work rolls lies between a maximum where the shapes of the material at the exit side of the work rolls do not exceed a limit value and a minimum where the profile controlling performance of the work rolls for the material is still maintained.
  • the work rolls are finely displaced and simultaneously a bending action is applied to the work rolls in a manner so as to eliminate the bending action on the work rolls caused by the material being rolled by the work rolls.
  • stepwise variation in the displacement of the work rolls per unit number of rolled material is effected during the rolling cycle.
  • the stepwise variation is made smaller in the first half of the rolling cycle and is made larger in the latter half of the cycle.
  • a pair of work rolls 1' which are so called “taper end rolls” each having a taper ground end 4' at one end of a roll barrel 4.
  • the rolls are arranged one above the other with the taper ground ends on opposite sides of the rolling path so as to locate both edges of strips or plates 3 to be rolled in roll gap zones determined by the respective taper ends 4'.
  • E L values to be determined by limit values depending on the shape of the strips determined by the roll stand, where E L is the distance from an edge of the strip to the starting point of the taper ground end, while relief E H of the strip 3 at its edge relative to the taper ground end 4' is constant.
  • the amplitude of displacement of the work rolls is such that the work rolls are displaced to an excessive extent beyond the effective E L value, the shape of the rolled strip at the exit side of the rolls exceeds its limit value making it impossible to carry out the rolling.
  • the profile controlling performance of the work rolls is incapable of controlling crown formation on the rolled strips.
  • the inventors further investigated the effective E L value to achieve a hot rolling method capable of preventing edge build-up of the rolled strips or plates so as to enable profile controlling and roll-change-free rolling to the effected.
  • Fig.4 illustrates the most displaced position of the work rolls when the E L value shown in Fig.3 is increased to its maximum but not exceeding the limit value determined by the shape of the strips at the exit side of the rolls.
  • Fig.5 shows the least displaced position of the work rolls when the E L value is decreased to its minimum but the rolls still maintain their profile controlling performance.
  • Reference numeral 5 denotes back up rolls.
  • Figs.8a, 8b and 8c illustrate one example of variation in sectional profile of strips at the exit side having thicknesses of 2.0 mm and widths of 1,040 mm according to Japanese Industrial Standards (JIS) SPHC continuously rolled by a taper end roll rolling method with a constant E L of 200 mm.
  • JIS Japanese Industrial Standards
  • the profiles were not greatly varied when the tenth strip had been rolled.
  • the twentieth strip had been rolled, remarkable edge build-ups p and p' occurred to maximum heights of as much as 20 ⁇ which made it impossible to continue rolling strips having the same width.
  • Figs.9a-9d illustrate the variation in sectional profile of strips similar to those of Figs.8a-8c and continuously rolled with the work rolls being cyclically shifted by 20 mm per two strips with EL values of 200-100 mm Even after forty-six strips having the same width had been rolled, no perceptible edge build-ups could be recognised.
  • This latter hot rolling method can equalise or mitigate local wear in tracks or traces in the work rolls for strips having the same width.
  • it can effectively maintain sufficient profile controlling effect for preventing edge drops, thereby simultaneously making compatible roll-change-free rolling and profile controlling of the strips.
  • FIG.11a illustrates work rolls 1' positioned at the maximum E L value but not exceeding the limit value determined by the shape of the strips at the exit side of the work rolls.
  • the bending action is applied to the work rolls in such a manner as to eliminate or cancel the bending action acting upon the work rolls as a result of the strip being rolled by the work rolls.
  • One preferred method of applying such a bending action to the work rolls is to apply loads to both journals of the work rolls in transverse directions substantially perpendicular to the axes of the work rolls.
  • the crowns are substantially constant for successive rolled strips.
  • this technique is very advantageous for effecting profile controlling of strips so as to make the crowns of the strips substantially constant and simultaneously allowing roll-change-free rolling (i.e. rolling of a wide range of widths of strip without changing the work rolls).
  • Fig.12 illustrates sectional profiles of successive strips (JIS) SPHC having thicknesses of 2.0 mm and widths of 1,040 mm with a constant E L value of 200 mm according to the prior art.
  • the twentieth strip included remarkable edge build-ups 5' having a height of 20 ⁇ . It was clearly impossible to continue further rolling with the same width strips.
  • Fig.13 illustrates sectional profiles of strips (JIS) SPHC having thicknesses of 2.0 mm and widths of 1,040 mm rolled with an E L value of 100-200 mm.
  • the work rolls were finely cyclically displaced so as to reduce the E L value by 20 mm per two rolled strips without applying any bending action on the work rolls. After fifty strips having the same widths had been rolled, no edge build-up occurred. However, the crowns varied greatly and were larger than those in Fig.12.
  • Fig.14 illustrates sectional profiles of strips (JIS) SPHC having thicknesses of 2.0 mm and widths of 1,040 mm rolled with an E L value of 100-200 mm.
  • the work rolls were finely displaced so as to reduce the E L value by 20 mm per two rolled strips and were subjected to an increasing bending action of 0 to 200 tons per chock as the E L value decreased.
  • This technique can effectively suppress edge build-up on rolled strips or plates without detrimentally affecting the crowns of the strips so as to eliminate the disadvantages in conventional roll-change-free rolling, whereby hot rolling with high accuracy as to thickness can be accomplished.
  • the work rolls 1' When hot rolling is carried out as shown in Figs.11a and 11b, the work rolls 1' will thermally expand from the configuration shown in Fig.15a to that shown in Fig.15b. If the rolling is continued with a constant E L value which is set in an initial rolling stage with less thermal expansion, the centre zones of the rolled strips are rolled to an excessive extent in comparison with the edge zones of the strips to form waves therein, which make it difficult to pass through the work rolls. This is caused by the increased influence of the effect which decreases the crown of the rolled strips.
  • the upper limit of the E L value is determined at a value corresponding to the limit value causing the above mentioned waves in the centre zones of the rolled strips and the E L value is successively reduced depending upon the thermal expansion of the work rolls to determine an effective variable E L value as shown in a line l in Fig.16.
  • the thermal expansion of the work rolls corresponding to the numbers of the rolled strips is preferably measured with actual rolling conditions to previously determine the data of the thermal expansion, on the basis of which the E L values of the rolls are previously determined.
  • the thermal expansion may be experimentally determined with the aid of theoretical thermodynamic equations.
  • variable E L value shown in broken line l is slightly shifted, as shown in curve P in Fig.17 so as to equalise or mitigate the wear of the work rolls to achieve a decrease in the crown and stability of rolled strips.
  • the upper limit value of the E L value is determined with the aid of the pattern or curve P shown in Fig.17.
  • the profiles of the rolled strips are not detrimentally affected by the thermal expansion of the rolls, and the irregular wear in the rolls is equalised or mitigated as the rolling cycle proceeds.
  • the irregular wear would otherwise occur in tracks in the rolls for the strips as shown in Figs.18a and 18b. This effect is particularly remarkable in the case of rolling in an order from wider strips to narrower strips.
  • Figs. 19 and 20a and 20b illustrate results of the rolling according to the invention wherein strips of (JIS) SPHC having thicknesses of 2.0-2.6 mm and widths of 750-950 mm were rolled by means of six roll stands of a finishing mill with E L values of 100-300 mm decreasing depending upon the thermal expansion of the rolls.
  • Fig.19 shows the E L values set in the cycle and the crowns ⁇ of the rolled strips.
  • the plotted crowns are thicknesses at the centres of the rolled strips minus the thicknesses at locations 25 mm inwardly spaced from the edges of the strips.
  • the crowns of the rolled strips were reduced to 35 ⁇ on an average.
  • profiles of the rolled strips became stable as shown in Fig.20a to prevent defective profiles due to irregular wear of the rolls as shown in Fig.20b.
  • thermal crown of the rolls, or the crown of the rolls due to their thermal expansion, which would detrimentally affect the crowns of the rolled strips. It has been known that the variation in crown of the rolls depends not only upon the periods of rolling allowed by each pair of work rolls, the actual rolling time, the water-cooling conditions, and the like, but also on the kind of steel to be rolled, the size of the strips to be rolled, and the like. Moreover, it is known that the phenomenon of crown increase is different in the first and second halves of the rolling cycle.
  • the shift pattern of work rolls are non-variably determined without considering the kind of steel, the period of rolling allowed by one pair of work rolls, and the first and latter halves of the rolling cycle, irregularities in the crowns of the rolled strips unavoidably occur throughout the rolling cycle due to the differences in the increase of the thermal crown of the rolls in their lengthwise directions.
  • the difference ⁇ S in roll diameter between the centre and the edges of the strips to be rolled in the first half of the rolling is relatively small, the crown of the strips becomes large.
  • the difference ⁇ S becomes larger and reduces the crown of the strips, but there is a tendency for the rolled strips to form waves in their centres resulting in defective strips.
  • Fig.21 illustrates the displacement of the work rolls 1' relative to the centre O of the path of the strips or plates.
  • the "shifting distance" of the rolls is defined by the distance x from the centre O of the path of the strips to the centres of the barrels of the work rolls on both the drive and the operation side.
  • the shifting distance x of the rolls is stepwise increased per a predetermined number of rolled strips until the shifting distance x becomes a maximum, for example, 100 mm and thereafter is stepwise decreased per the predetermined number of the strips.
  • a "shift pitch" is defined by the stepwise increase or decrease of the shifting distance of the rolls per unit number of rolled strips or plates in the repetition of the above displacing operations or cyclic roll displacement.
  • the shift pitch should be set at a small value so as to enlarge the thermal crown in the area corresponding to the width of the strips, thereby mitigating the crown of the rolled strips.
  • the profile of the thermal crown varies usually as shown in Fig.24.
  • the thermal crown or difference in roll diameter between the centres and edges of the strips depends upon the number of rolled strips or coils. This relationship is shown in Fig.25 wherein the rolling is effected with the constant shift pitch 40 mm/2 coil according to the procedure in connection with Fig.22.
  • the difference ⁇ S in roll diameter between the centres and edges varies greatly in the first and latter halves of rolling.
  • it is effective for mitigating the crown of the rolled strips to control the difference ⁇ S in the thermal crown in the first and latter halves of the rolling cycle as explained hereinafter.
  • the shift pitch is made smaller to enlarge the difference ⁇ S in the first half of the cycle generally exhibiting small differences ⁇ S, and the shift pitch is made larger to suppress the difference ⁇ S to a small value in the latter half of the cycle, thereby stabilising the difference ⁇ S throughout the rolling cycle.
  • Fig.26 illustrates the difference ⁇ S dependent upon a variable shift pitch shown in a solid line and a constant shift pitch in a broken line.
  • the difference ⁇ S is stabilised as shown in the solid line in Fig.26.
  • the crowns of the rolled strips can be mitigated and irregularities in the crowns of the rolled strips can be reduced throughout the cycle only by providing work rolls with initial curves.
  • the crown of the rolled strip can be effectively reduced.
  • the crown of the rolls becomes larger in an earlier period in the initial half of the rolling so as to reduce the crown of the rolled strips, and becomes constant in the latter half of the rolling so as not to produce defective rolled strips and to reduce the crown of the rolled strips.
  • the roll initial curve should be changed every time the period of rolling or the kind of steel is changed.
  • the difference ⁇ S can be varied by changing the shift pitch. In this manner, this technique can be applied for compensating for the difference in ⁇ S. Accordingly, this embodiment has the advantages of enlarging the use of range of the rolls and of improving the grinding efficiency by unifying the initial curves for several kinds of steel.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Metal Rolling (AREA)
  • Reduction Rolling/Reduction Stand/Operation Of Reduction Machine (AREA)
  • Control Of Metal Rolling (AREA)

Description

  • This invention relates to a hot rolling method for avoiding edge build-up and edge drop of rolled strips or plates and is concerned with such a method involving preventing local wear of the work rolls of rolling mills, such as four or six high mills, whilst simultaneously controlling the profiles of the steel strips or plates.
  • Recently, it has been required to improve the accuracy in thickness of steel strips or plates rolled by rolling mills in order to improve the yield rate of the steel. To meet this requirement, various profile controlling methods have been proposed. Among them, a taper end roll rolling method is effective to prevent edge drops with the aid of work rolls of particular geometrical shapes, for example, as disclosed in JP-A-54 024 256. In accordance with this document both ends of each of the work rolls include tapered portions in order to prevent the edges of the strips becoming thinner.
  • In this case, the effect of profile controlling tends to decrease with change in the width of the steel strips or plates. To avoid this, a work roll shift method is effective for profile controlling as disclosed in JP-A-55 077 903. In accordance with this document a pair of work rolls is used wherein each has a tapered portion and the rolls are arranged one above the other with the tapered portions on opposite sides of the rolling path. The work rolls are shifted in the axial direction, before rolling, in accordance with the width of the strips to be rolled.
  • Referring to Figures 1 and 2 of the accompanying drawings, as the number of rolled strips having the same width increases during hot finish rolling, the work rolls 1 progressively wear to form tracks or traces 2 for the strips whose edge portions 2b usually wear deeper than the centre portions 2a as shown in Fig.1. As a result, the rolled strip 3 has a sectional profile including at its edges irregular protrusions or ridges p and p' which are referred to as "edge build-up" as shown in Fig.2. It is clearly evident that such an edge build-up causes the greatest difficulty for profile controlling of the strips and for roll-change-free rolling which is rolling with a pair of work rolls over a wide range of sizes of strips or plates to be rolled without changing the rolls. The same holds true when using taper end rolls.
  • It is an object of the invention to provide an improved hot rolling method capable of preventing edge build-up caused by uneven wear of the work rolls forming tracks for the strips or plates and making it possible to effect profile controlling so as to enable roll-change free rolling to be carried out.
  • It is a further object of the invention to provide a hot rolling method with work rolls being displaced in a roll shift pattern determined in consideration of the thermal expansion of the rolls in addition to the equalisation or mitigation of roll wear to reduce crown formation on the rolled strips and to stabilise the profiles of the rolled strips.
  • According to the present invention, there is provided a hot rolling method using a hot finishing mill including a pair of axially adjustable work rolls each having a tapered portion at one end of its barrel and arranged one above the other with the tapered portions being on opposite sides of the rolling path and being so axially adjusted as to locate each edge of strip material to be rolled in a roll gap zone determined by the respective tapered portion of one of the work rolls characterised in that, during the course of rolling a sequence of discrete lengths of strip material, each of substantially the same width, in the interval between succeeding lengths said work rolls are cyclically axially displaced relative to each other within a range of displacement such that said edges of the material remain within the roll gap zone delimited by said tapered portions thereby preventing edge build-ups of the material, whereby the upper limit of the cyclical values of the distance from an edge of the material to the transition point between said tapered portion of the work roll nearest to said edge of the material and the central portion of the roll is variably set so as to decrease as the thermal expansion of the work rolls increases.
  • In carrying out the invention, the amplitude of displacement of the work rolls lies between a maximum where the shapes of the material at the exit side of the work rolls do not exceed a limit value and a minimum where the profile controlling performance of the work rolls for the material is still maintained.
  • It is another object of the invention to provide a hot rolling method capable of effectively suppressing edge build-ups without causing the formation of crowns on the strips which would tend to occur as a consequence of fine displacement of the work rolls, thereby enabling roll-change-free rolling to be effected by displacing the taper end work rolls.
  • To achieve this object, according to preferred embodiment of the invention the work rolls are finely displaced and simultaneously a bending action is applied to the work rolls in a manner so as to eliminate the bending action on the work rolls caused by the material being rolled by the work rolls.
  • It is a still more specific object of the invention to provide a hot rolling method capable of effectively reducing crown formation on rolled strips through-out a rolling cycle by simply setting suitable initial crowns on the work rolls without causing irregularities in the crowns of the rolled strips which would unavoidably be caused by variation in the kind of steel, the period of rolling allowed by one pair of work rolls, and the thermal crowns of the work rolls due to heat.
  • To this end, according to a still further particular embodiment of the invention stepwise variation in the displacement of the work rolls per unit number of rolled material is effected during the rolling cycle.
  • Preferably, the stepwise variation is made smaller in the first half of the rolling cycle and is made larger in the latter half of the cycle.
  • For a better understanding of the invention and to show how the same may be carried into effect, reference will now be made, by way of example, to the accompanying drawings, in which:-
    • Fig.1 is a schematic view of work rolls illustrating their wear;
    • Fig.2 is an explanatory view of a profile of a rolled strip including edge build-ups;
    • Fig.3a is a sectional view illustrating rolling of a strip by taper end work rolls;
    • Fig.3b is a graph showing an effective EL zone;
    • Fig.4 is an explanatory elevation illustrating a rolling condition with the maximum EL;
    • Fig.5 is an explanatory elevation showing a rolling condition with the minimum EL;
    • Fig.6 is a partial sectional view of a work roll illustrating deep wear;
    • Fig.7 is a partial sectional view of a work roll illustrating the equalised or mitigated wear therein;
    • Fig.8 illustrates profiles of strips rolled in the prior art method;
    • Fig.9 illustrates profiles of strips rolled according to another method;
    • Fig.10a is a graph illustrating the uniform crowns of strips rolled with a bending action applied to the work rolls;
    • Fig.10b is a graph illustrating the variation in crown of strips rolled without a bending action exerted upon the work rolls;
    • Figs.11a and 11b are schematic views for explaining the application of a bending action to the work rolls;
    • Fig.12 illustrates profiles of strips rolled with a constant EL value of 200 mm;
    • Fig.13 illustrates profiles of strips rolled with variable EL value with work rolls subjected to fine cyclic shifting;
    • Fig.14 illustrates profiles of strips rolled according to Fig. 13 but with the application of bending action to the work rolls;
    • Figs.15a and 15b are elevations of a work roll for explaining thermal expansion;
    • Fig.16 is a graph for explaining how to determine the EL value in consideration of the thermal expansion of the work rolls;
    • Fig.17 is a graph for explaining the shift of the EL value in consideration of mitigation of wear of the rolls;
    • Figs.18a and 18b are schematic views illustrating irregular wear in a roll;
    • Fig.19 is a graph illustrating the reduced crown of rolled strips resulting from EL values;
    • Fig.20a is a profile of a strip rolled in consideration of thermal expansion according to the invention;
    • Fig.20b is a profile of a rolled strip including defective edges caused by irregular wear of the work rolls;
    • Fig.21 is a schematic view for explaining the displacement distance of the rolls;
    • Fig.22 illustrates various shift pitch patterns of work rolls for carrying out rolling;
    • Fig.23 is a graph illustrating the comparison of the difference Δ S in roll diameters with respect to respective shift pitches;
    • Fig.24 is a graph illustrating the difference Δ S dependent upon the numbers of rolled strips;
    • Fig.25 is a graph illustrating the relationship between the difference ΔS and the numbers of rolled strips;
    • Fig.26 is a graph illustrating the effect of variation in shift pitch on the difference ΔS;
    • Fig.27 is a graph illustrating shift pitch patterns used in actual rolling according to an embodiment of the invention; and
    • Fig.28 is a graph illustrating the suppression of the difference ΔS resulting from the shift pitch patterns shown in Fig.27.
  • Referring to Figure 3a, there is shown a pair of work rolls 1' which are so called "taper end rolls" each having a taper ground end 4' at one end of a roll barrel 4. The rolls are arranged one above the other with the taper ground ends on opposite sides of the rolling path so as to locate both edges of strips or plates 3 to be rolled in roll gap zones determined by the respective taper ends 4'. During profile controlling using such work rolls, the inventors found effective EL values to be determined by limit values depending on the shape of the strips determined by the roll stand, where EL is the distance from an edge of the strip to the starting point of the taper ground end, while relief EH of the strip 3 at its edge relative to the taper ground end 4' is constant.
  • If the amplitude of displacement of the work rolls is such that the work rolls are displaced to an excessive extent beyond the effective EL value, the shape of the rolled strip at the exit side of the rolls exceeds its limit value making it impossible to carry out the rolling. On the other hand, if the work rolls are displaced to a too small extent beyond the opposite limit of the effective EL value, the profile controlling performance of the work rolls is incapable of controlling crown formation on the rolled strips.
  • The inventors further investigated the effective EL value to achieve a hot rolling method capable of preventing edge build-up of the rolled strips or plates so as to enable profile controlling and roll-change-free rolling to the effected.
  • One method of rolling using a four high mill will be explained hereinafter. Fig.4 illustrates the most displaced position of the work rolls when the EL value shown in Fig.3 is increased to its maximum but not exceeding the limit value determined by the shape of the strips at the exit side of the rolls. Fig.5 shows the least displaced position of the work rolls when the EL value is decreased to its minimum but the rolls still maintain their profile controlling performance. Reference numeral 5 denotes back up rolls.
  • In the event that the work rolls 1' are cyclically displaced so as to permit EL to be within the range of the effective EL values from Fig.4 to Fig.5, local wear 2b'' in the track or trace 2' for the strips can be equalised or mitigated in the axial direction of the work roll even after the number of rolled strips has increased as shown in Fig.7 ,instead of being in the form of a deep local wear 2b' in the case of a constant EL value as shown in Fig.6.
  • In order to clarify this further, Figs.8a, 8b and 8c illustrate one example of variation in sectional profile of strips at the exit side having thicknesses of 2.0 mm and widths of 1,040 mm according to Japanese Industrial Standards (JIS) SPHC continuously rolled by a taper end roll rolling method with a constant EL of 200 mm. As can be seen from these drawings, the profiles were not greatly varied when the tenth strip had been rolled. However, when the twentieth strip had been rolled, remarkable edge build-ups p and p' occurred to maximum heights of as much as 20 µ which made it impossible to continue rolling strips having the same width.
  • Figs.9a-9d illustrate the variation in sectional profile of strips similar to those of Figs.8a-8c and continuously rolled with the work rolls being cyclically shifted by 20 mm per two strips with EL values of 200-100 mm Even after forty-six strips having the same width had been rolled, no perceptible edge build-ups could be recognised.
  • As can be seen from the above description, This latter hot rolling method can equalise or mitigate local wear in tracks or traces in the work rolls for strips having the same width. Thus it can effectively maintain sufficient profile controlling effect for preventing edge drops, thereby simultaneously making compatible roll-change-free rolling and profile controlling of the strips.
  • In carrying out such a method, when the work rolls are finely displaced within a range corresponding to the effective EL value, the crown of the rolled strips becomes larger as shown in Fig.10b. In other words, the crowns of the strips rolled by the work rolls as they are finely displaced within the range of effective EL values vary over a fairly wide range.
  • Another technique can be used to solve this problem. Fig.11a illustrates work rolls 1' positioned at the maximum EL value but not exceeding the limit value determined by the shape of the strips at the exit side of the work rolls. When the work rolls 1' are being displaced to make the EL value smaller, according to this technique an increasing bending action is applied to the work rolls as shown by reference numeral 6 in Fig.11b compatible with the reduced value of the EL value but still maintaining their profile controlling performance, in which position the work rolls are subjected to the maximum bending action.
  • In this case, the bending action is applied to the work rolls in such a manner as to eliminate or cancel the bending action acting upon the work rolls as a result of the strip being rolled by the work rolls. One preferred method of applying such a bending action to the work rolls is to apply loads to both journals of the work rolls in transverse directions substantially perpendicular to the axes of the work rolls.
  • As shown in Fig.10a, according to this technique, the crowns are substantially constant for successive rolled strips. In this manner, this technique is very advantageous for effecting profile controlling of strips so as to make the crowns of the strips substantially constant and simultaneously allowing roll-change-free rolling (i.e. rolling of a wide range of widths of strip without changing the work rolls).
  • Fig.12 illustrates sectional profiles of successive strips (JIS) SPHC having thicknesses of 2.0 mm and widths of 1,040 mm with a constant EL value of 200 mm according to the prior art. The twentieth strip included remarkable edge build-ups 5' having a height of 20 µ. It was clearly impossible to continue further rolling with the same width strips.
  • Fig.13 illustrates sectional profiles of strips (JIS) SPHC having thicknesses of 2.0 mm and widths of 1,040 mm rolled with an EL value of 100-200 mm. The work rolls were finely cyclically displaced so as to reduce the EL value by 20 mm per two rolled strips without applying any bending action on the work rolls. After fifty strips having the same widths had been rolled, no edge build-up occurred. However, the crowns varied greatly and were larger than those in Fig.12.
  • Fig.14 illustrates sectional profiles of strips (JIS) SPHC having thicknesses of 2.0 mm and widths of 1,040 mm rolled with an EL value of 100-200 mm. The work rolls were finely displaced so as to reduce the EL value by 20 mm per two rolled strips and were subjected to an increasing bending action of 0 to 200 tons per chock as the EL value decreased.
  • In this case, after fifty strips had been rolled, no edge build-up occurred and the crowns of the rolled strips were substantially constant. Thus rolled strips having good sectional profiles throughout the rolling cycle were obtained.
  • This technique can effectively suppress edge build-up on rolled strips or plates without detrimentally affecting the crowns of the strips so as to eliminate the disadvantages in conventional roll-change-free rolling, whereby hot rolling with high accuracy as to thickness can be accomplished.
  • A rolling method in accordance with the invention will now be explained hereinafter, which method takes into consideration the thermal expansion of the rolls.
  • When hot rolling is carried out as shown in Figs.11a and 11b, the work rolls 1' will thermally expand from the configuration shown in Fig.15a to that shown in Fig.15b. If the rolling is continued with a constant EL value which is set in an initial rolling stage with less thermal expansion, the centre zones of the rolled strips are rolled to an excessive extent in comparison with the edge zones of the strips to form waves therein, which make it difficult to pass through the work rolls. This is caused by the increased influence of the effect which decreases the crown of the rolled strips.
  • In order to avoid this, according to the invention, the upper limit of the EL value is determined at a value corresponding to the limit value causing the above mentioned waves in the centre zones of the rolled strips and the EL value is successively reduced depending upon the thermal expansion of the work rolls to determine an effective variable EL value as shown in a line ℓ in Fig.16.
  • The thermal expansion of the work rolls corresponding to the numbers of the rolled strips is preferably measured with actual rolling conditions to previously determine the data of the thermal expansion, on the basis of which the EL values of the rolls are previously determined. The thermal expansion may be experimentally determined with the aid of theoretical thermodynamic equations.
  • In this case, moreover, the variable EL value shown in broken line ℓ is slightly shifted, as shown in curve P in Fig.17 so as to equalise or mitigate the wear of the work rolls to achieve a decrease in the crown and stability of rolled strips.
  • The upper limit value of the EL value is determined with the aid of the pattern or curve P shown in Fig.17. In this manner, the profiles of the rolled strips are not detrimentally affected by the thermal expansion of the rolls, and the irregular wear in the rolls is equalised or mitigated as the rolling cycle proceeds. The irregular wear would otherwise occur in tracks in the rolls for the strips as shown in Figs.18a and 18b. This effect is particularly remarkable in the case of rolling in an order from wider strips to narrower strips.
  • Figs. 19 and 20a and 20b illustrate results of the rolling according to the invention wherein strips of (JIS) SPHC having thicknesses of 2.0-2.6 mm and widths of 750-950 mm were rolled by means of six roll stands of a finishing mill with EL values of 100-300 mm decreasing depending upon the thermal expansion of the rolls. Three of the stands F3, F4 and F5 included taper end rolls. In these examples, the work rolls were finely displaced by 20 mm per two rolled strips.
  • Fig.19 shows the EL values set in the cycle and the crowns µ of the rolled strips. The plotted crowns are thicknesses at the centres of the rolled strips minus the thicknesses at locations 25 mm inwardly spaced from the edges of the strips. As can be seen from Fig.19, the crowns of the rolled strips were reduced to 35 µ on an average. Furthermore, by finely displacing the work rolls, profiles of the rolled strips became stable as shown in Fig.20a to prevent defective profiles due to irregular wear of the rolls as shown in Fig.20b.
  • As can be seen from the above it is important to take into consideration the so called "thermal crown" of the rolls, or the crown of the rolls due to their thermal expansion, which would detrimentally affect the crowns of the rolled strips. It has been known that the variation in crown of the rolls depends not only upon the periods of rolling allowed by each pair of work rolls, the actual rolling time, the water-cooling conditions, and the like, but also on the kind of steel to be rolled, the size of the strips to be rolled, and the like. Moreover, it is known that the phenomenon of crown increase is different in the first and second halves of the rolling cycle.
  • As a result of various investigations and experiments on rolling with displaced work rolls by the inventors, it has been found that the distribution of the thermal crown along the roll barrel varies with the pattern of displacement of the work rolls, or the profile of the thermal crowns depends upon the shift pattern of the work rolls.
  • By utilising these findings, the inventors reduced the crown of rolled strips with the aid of variation in shift pitch in the rolling cycles.
  • If the shift pattern of work rolls are non-variably determined without considering the kind of steel, the period of rolling allowed by one pair of work rolls, and the first and latter halves of the rolling cycle, irregularities in the crowns of the rolled strips unavoidably occur throughout the rolling cycle due to the differences in the increase of the thermal crown of the rolls in their lengthwise directions. In this case, when the difference ΔS in roll diameter between the centre and the edges of the strips to be rolled in the first half of the rolling is relatively small, the crown of the strips becomes large. On the other hand, in the latter half of the rolling, the difference ΔS becomes larger and reduces the crown of the strips, but there is a tendency for the rolled strips to form waves in their centres resulting in defective strips.
  • This results from the fact that, although the larger crown of the work rolls is effective to reduce the crown of the rolled strips, the initial crown of the work rolls has to be small in order to avoid defective rolled strips having waves at the centres in the latter half of the rolling with the result that the crown of the rolled strips is too large in the initial half of the rolling and therefore irregularities in the crown of the rolled strips become larger throughout the rolling cycle.
  • Fig.21 illustrates the displacement of the work rolls 1' relative to the centre O of the path of the strips or plates. The "shifting distance" of the rolls is defined by the distance x from the centre O of the path of the strips to the centres of the barrels of the work rolls on both the drive and the operation side.
  • The shifting distance x of the rolls is stepwise increased per a predetermined number of rolled strips until the shifting distance x becomes a maximum, for example, 100 mm and thereafter is stepwise decreased per the predetermined number of the strips. A "shift pitch" is defined by the stepwise increase or decrease of the shifting distance of the rolls per unit number of rolled strips or plates in the repetition of the above displacing operations or cyclic roll displacement.
  • In rolling for obtaining (JIS) SPCC strips having thicknesses of 2.3 mm and widths of 935 mm, the roll displacing operation was simultaneously applied to three roll stands F3, F4 and F5 of a finishing mill having six roll stands with constant shift pitches 20 mm/2 coil, 40 mm/2 coil and 60 mm/2 coil in a cyclic system as shown in Fig.22. Fig.23 illustrates the results of the rolling.
  • It is clear from Fig.23 that the larger the shift pitch and the shorter the period, the gentler is the profile of the thermal crown and the smaller is the difference ΔS in roll diameter corresponding to the centres and edges of the rolled strips.
  • Therefore with the kind of strips capable of making the thermal crown relatively small, for example, steel strips to be rolled at relatively lower temperatures, the shift pitch should be set at a small value so as to enlarge the thermal crown in the area corresponding to the width of the strips, thereby mitigating the crown of the rolled strips.
  • As the number of rolled strips increases, the profile of the thermal crown varies usually as shown in Fig.24. The thermal crown or difference in roll diameter between the centres and edges of the strips depends upon the number of rolled strips or coils. This relationship is shown in Fig.25 wherein the rolling is effected with the constant shift pitch 40 mm/2 coil according to the procedure in connection with Fig.22.
  • As can be seen from Fig.25, the difference ΔS in roll diameter between the centres and edges varies greatly in the first and latter halves of rolling. In rolling with the work rolls being cyclically displaced, it is effective for mitigating the crown of the rolled strips to control the difference ΔS in the thermal crown in the first and latter halves of the rolling cycle as explained hereinafter.
  • Namely , the shift pitch is made smaller to enlarge the difference ΔS in the first half of the cycle generally exhibiting small differences ΔS, and the shift pitch is made larger to suppress the difference ΔS to a small value in the latter half of the cycle, thereby stabilising the difference ΔS throughout the rolling cycle.,
  • Fig.26 illustrates the difference ΔS dependent upon a variable shift pitch shown in a solid line and a constant shift pitch in a broken line. The difference ΔS is stabilised as shown in the solid line in Fig.26. The crowns of the rolled strips can be mitigated and irregularities in the crowns of the rolled strips can be reduced throughout the cycle only by providing work rolls with initial curves.
  • In order to obtain strips of (JIS) SPCC having thicknesses of 2.3 mm and widths of 935 mm by the use of a finishing mill having six roll stands, work roll displacement rolling was effected with the work rolls of the F3, F4 and F5 stands being cyclically shifted, while the shift pitches were varied in the first and latter halves of the rolling cycle. The results are shown in Fig.27. Fig.28 illustrates the variation of the difference ΔS. Table 1 below shows a comparison of rolled strips produced with a constant shift pitch with those produced in the above manner according to the invention in respect of the values x of the crowns of the rolled strips and the irregularities δ of the crowns. Table 1
    Crown x of rolled strips Irregularity δ of Crown
    Prior art 48 µ 17.8
    Invention 35 µ 8.2
  • According to this embodiment, as the difference ΔS increases rapidly in the initial half of the rolling cycle, the crown of the rolled strip can be effectively reduced. Particularly, the crown of the rolls becomes larger in an earlier period in the initial half of the rolling so as to reduce the crown of the rolled strips, and becomes constant in the latter half of the rolling so as not to produce defective rolled strips and to reduce the crown of the rolled strips.
  • Moreover, as the thermal crown is stabilised in the earlier period of the rolling cycle, it is possible to enlarge the convex curves of the initial crowns of the work rolls without any risk of disturbance in configuration of the rolled strips and further it is possible to reduce the crown of the rolled strips. In the prior art, such large curves of initial crowns would cause waves in the rolled strips during the latter rolling of the cycle.
  • As to the difference in thermal crown and hence in ΔS due to the period of rolling allowed by one pair of work rolls in the prior art, the roll initial curve should be changed every time the period of rolling or the kind of steel is changed. In contrast herewith, according to the invention the difference ΔS can be varied by changing the shift pitch. In this manner, this technique can be applied for compensating for the difference in ΔS. Accordingly, this embodiment has the advantages of enlarging the use of range of the rolls and of improving the grinding efficiency by unifying the initial curves for several kinds of steel.

Claims (5)

  1. A hot rolling method using a hot finishing mill including a pair of axially adjustable work rolls (1') each having a tapered portion (4') at one end of its barrel (4) and arranged one above the other with the tapered portions (4') being on opposite sides of the rolling path and being so axially adjustable as to locate each edge of strip material (3) to be rolled in a roll gap zone determined by the respective tapered portion (4') of one of the work rolls characterised in that, during the course of rolling a sequence of discrete lengths of strip material, each of substantially the same width, in the interval between succeeding lengths said work rolls (1') are cyclically axially displaced relative to each other within a range of displacement such that said edges of the material remain within the roll gap zone delimited by said tapered portions thereby preventing edge build-ups of the material, whereby the upper limit of the cyclical values of the distance (EL) from an edge of the material to the transition point between said tapered portion of the work roll nearest to said edge of the material and the central portion of the roll is variably set so as to decrease as the thermal expansion of the work rolls increases.
  2. A hot rolling method as claimed in claim 1 wherein said work rolls (1') are subjected to a fine displacement and simultaneously a bending action is applied to said work rolls to eliminate the bending action, acting upon the work rolls, caused by the material being rolled by said work rolls.
  3. A hot rolling method as claimed in claim 2, wherein said bending action applied to said work rolls (1') is progressively increased as the distance (EL) from an edge of the material to the starting point of said tapered portion nearest to said edge of the material is decreased.
  4. A hot rolling method as claimed in any one of claims 1 to 3, wherein the axial displacement of said work rolls (1') per unit number of rolled material is varied stepwise during the rolling cycle.
  5. A hot rolling method as claimed in claim 4, wherein said stepwise variation is relatively small in the first half of the rolling cycle and relatively large in the latter half of the rolling cycle.
EP85301178A 1984-02-29 1985-02-22 Hot rolling method Expired - Lifetime EP0153849B1 (en)

Applications Claiming Priority (8)

Application Number Priority Date Filing Date Title
JP37478/84 1984-02-29
JP59037478A JPS6114002A (en) 1984-02-29 1984-02-29 Hot rolling method
JP59107553A JPS60250806A (en) 1984-05-29 1984-05-29 Hot rolling method
JP107553/84 1984-05-29
JP204147/84 1984-10-01
JP59204147A JPS6182907A (en) 1984-10-01 1984-10-01 Hot rolling method
JP59211503A JPS6192702A (en) 1984-10-11 1984-10-11 Hot rolling method
JP211503/84 1984-10-11

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EP0153849A2 EP0153849A2 (en) 1985-09-04
EP0153849A3 EP0153849A3 (en) 1986-02-12
EP0153849B1 true EP0153849B1 (en) 1992-01-15

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1228818B2 (en) 2001-02-05 2015-09-09 Hitachi Ltd. Rolling method for strip rolling mill and strip rolling equipment
US11059083B2 (en) * 2016-06-15 2021-07-13 Arvedi Steel Engineering S.P.A. Mill rolls capable of rolling long kilometers for ESP production line

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DE3785778D1 (en) * 1986-03-03 1993-06-17 Schloemann Siemag Ag ROLLING MILLS.
DE3620197A1 (en) * 1986-06-16 1987-12-17 Schloemann Siemag Ag ROLLING MILL FOR PRODUCING A ROLLING GOOD, ESPECIALLY A ROLLING STRIP
DE3638331C2 (en) * 1986-11-10 1995-07-13 Schloemann Siemag Ag Roll stand for rolling flat material with a pair of axially displaceable work rolls
GB8630797D0 (en) * 1986-12-23 1987-02-04 Davy Mckee Sheffield Rolling of metal strip
CA1286897C (en) * 1987-01-09 1991-07-30 Mitsuhiro Ikeda Method for rolling metal sheets
JP2616917B2 (en) * 1987-01-24 1997-06-04 株式会社日立製作所 Rolling method by roll shift rolling mill
GB8822669D0 (en) * 1988-09-27 1988-11-02 Davy Mckee Sheffield Rolling of metal workpieces
DE4105079A1 (en) * 1990-03-26 1991-10-02 Schloemann Siemag Ag Grinding device for maintaining roll at predetermined contour - with grinding disc on support which allows radial and parallel movement with respect to work roll
DE4309986A1 (en) * 1993-03-29 1994-10-06 Schloemann Siemag Ag Method and device for rolling a rolled strip

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DE200426C (en) *
EP0049798A2 (en) * 1980-10-15 1982-04-21 Sms Schloemann-Siemag Aktiengesellschaft Rolling mill

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JPS517635B2 (en) * 1971-12-10 1976-03-09
JPS5581009A (en) * 1978-12-14 1980-06-18 Nippon Steel Corp Skin-pass rolling shape control method of cold rolled hoop after continuous annealing and equipment thereof
JPS59110401A (en) * 1982-12-14 1984-06-26 Ishikawajima Harima Heavy Ind Co Ltd Rolling method

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DE200426C (en) *
EP0049798A2 (en) * 1980-10-15 1982-04-21 Sms Schloemann-Siemag Aktiengesellschaft Rolling mill

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1228818B2 (en) 2001-02-05 2015-09-09 Hitachi Ltd. Rolling method for strip rolling mill and strip rolling equipment
US11059083B2 (en) * 2016-06-15 2021-07-13 Arvedi Steel Engineering S.P.A. Mill rolls capable of rolling long kilometers for ESP production line

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KR900009128B1 (en) 1990-12-22
CA1261654A (en) 1989-09-26
KR850007092A (en) 1985-10-30
AU566417B2 (en) 1987-10-22
EP0153849A2 (en) 1985-09-04
AU3911085A (en) 1985-09-05
EP0153849A3 (en) 1986-02-12
DE3585164D1 (en) 1992-02-27

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