Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
  • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
  • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
  • B41M5/0041—Digital printing on surfaces other than ordinary paper
  • B41M5/0064—Digital printing on surfaces other than ordinary paper on plastics, horn, rubber, or other organic polymers
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
  • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
  • B41M1/00—Inking and printing with a printer's forme
  • B41M1/14—Multicolour printing
  • B41M1/18—Printing one ink over another
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
  • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
  • B41M1/00—Inking and printing with a printer's forme
  • B41M1/26—Printing on other surfaces than ordinary paper
  • B41M1/30—Printing on other surfaces than ordinary paper on organic plastics, horn or similar materials
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
  • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
  • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
  • B41M5/0011—Pre-treatment or treatment during printing of the recording material, e.g. heating, irradiating
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
  • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
  • B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
  • B41M7/0027—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using protective coatings or layers by lamination or by fusion of the coatings or layers

Definitions

• the present invention is concerned with a method of printing the surfaces of synthetic polymer materials.
• Silk screen printing has the disadvantages that it is difficult to obtain accurate registration and fine definition
• transfer printing has the disadvantage that a different pigment is required for each colour required in the final printed design: for a multi-coloured design, many pigments, for example, up to 16 different pigments, may be required. For each different pigment, a separate printing roller is required and the use of such a large number of printing rollers causes severe difficulties in obtaining colour registration.
• a method of printing a coloured printed design on a polymer body in which the printed design penetrates into the surface of said polymer body such that it cannot be erased by solvent action or mechanical abrasion without destruction of said surface.
• the method according to the invention may be a four-colour printing process, which involves making four colour-separation negatives from the desired design by means of colour filters (the four colours being, for example, magenta, yellow, cyan and black), preparing corresponding printing plates from each of the colour-separation negatives and printing on the polymer surface using each of the resulting printing plates, in succession and in register, using an appropriate ink for each printing plate.
• colour filters the four colours being, for example, magenta, yellow, cyan and black
• printing plates as used herein includes other printing surfaces, such as printing rollers.
• colour separation is carried out as if for the known four-colour printing of paper, it is generally necessary to modify the colour and/or composition of the inks used; an appropriate combination of inks can generally be arrived at empirically, but this is generally less satisfactory than preparing colour separation negatives specific to the surface to be printed.
• the or each printing plate used in the method according to the invention is preferably gravure, lithographic or flexographic; the or each printing plate may be prepared by a generally conventional process, such as screening.
• the polymer which is printed according to the invention may be in any suitable physical form, such as in the form of a 3-dimensional moulded article or in laminar form (such as a film, sheet, coating or textile fabric).
• the polymer when it is in the form of a film, sheet or moulded article, it may be made of a thermoplastic polymer, such as a polyester, nylon, polypropylene, polystyrene (including high impact polystyrene), an acrylic polymer, a polycarbonate,polyvinyl chloride, a cellulosic polymer, or a thermoset polymer such as an alkyd, an unsaturated polyester, an epoxy resin, a phenoplast or an aminoplast.
• the polymer may, when in the form of a moulded article, contain conventional reinforcement, such as, for example, glass fibres.
• Such polymers may also be used in the method according to the invention in the form of a coating on, for example, wood, hardboard, chipboard, laminated plastics, metals (such as etched metals or anodised aluminium) or ceramics.
• the polymer When the polymer is in the form of a coating, it may have been applied, for example, by spraying (e.g. electrostatic spraying) or curtain coating; the coating may be a stoved coating.
• spraying e.g. electrostatic spraying
• curtain coating When the substrate is a ceramic article (such as a ceramic tile),curtain coating is preferred, whereas when the substrate is a metal, electrostatic spraying is preferred.
• the polymer printed according to the present invention is a textile
• it may be, for example, of polyamide, polyester, and acrylic polymer, or polypropylene.
• the polymer when the article being printed is a textile, then the polymer may comprise a natural polymer, in addition to, or instead of, a synthetic polymer. Examples of such natural polymers include wool and cotton textiles.
• Such textiles may, for example, be in the form of woven fabric, knitted fabric, or even open mesh net.
• the coloured inks used in the method according to the invention preferably comprise dyes or pigments in an oil or resin base; solvent free inks are sometimes preferred.
• suitable inks are available commercially from Coates Brothers under the designation Lithotex 137 17/220. Such inks have good colourfastness and are resistant to washing, perspiration, dry cleaning, rubbing and gas-fading.
• the other surface thereof is subjected to elevated temperature and pressure before or during application of the printed design (for example, by means of a heated press plate).
• the elevated temperature employed is preferably from 100 to 220°, more preferably 110 to 180°C. Higher temperatures in the above ranges can be employed when the polymer is relatively thermally stable (such as a polyurethane) or in the form of a coating on a thermally stable backing (such as PVC or a polyurethane on a thermally stable fabric backing).
• the pressure employed may be from 1 to 400 psi. preferably from 50 to 200 psi. Lower pressures are generally employed for thinner polymer substrates and higher pressures for thicker substrates. For example, a pressure as low as 1 psi can be used when printing a very thin PVC film, such as one having a thickness as low as 12, or where low gloss is wanted.
• the polymer substrate can be laminated to another polymer layer at the same time as the printing process according to the invention is carried out.
• the printing may be carried out by a transfer process as an alternative to the four-colour process described above.
• a glossy finish can be applied to the print by the use of a glossy transfer -paper and/or by the use of glazing rollers.
• the plasticiser should not be such as to allow too much migration of dye away from areas to be printed. Accordingly, when the polymer is PVC, it desirably is not plasticised by means of styrene-butadiene copolymer.
• a polymer body which is printed according to the invention may act as a support for the printed design, the printed body being bonded to an article it is wished to decorate, either with the printed design on the polymer surface facing the article to be decorated (in which case the polymer would, of course, be transparent) or with another surface adhered to the final substrate.
• the method according to the invention results in printing, not just on the surface, but penetration of dyes into the layer adjacent the surface, making the resulting printed designs more permanent than those obtained in prior processes (that is, the printed design cannot be erased by solvent action or mechanical abrasion without destruction of the polymer surface).
• One surface of unsupported PVC film was heated by a heated press plate at 110°C for a dwell time of 80 seconds and a pressure of 200 psi, and the other surface thereof was printed by a four-colour printing process. Excellent colour reproduction and print clarity was obtained.
• Example 1 was repeated using a dwell time of 50 seconds and a pressure of 100 psi, the printing being lithographic using two colours. Good colour reproduction and print clarity was obtained.
• One surface of unsupported PVC film was heated by a heated press plate at 110°C for a dwell time of 40 seconds and a pressure of 100 psi, and the other surface thereof was gravure printed in three colours to form a checked pattern. Excellent colour reproduction and print clarity was obtained.
• One surface of unsupported PVC film was heated by a heated press plate at 150°C for a dwell time of 30 seconds and a pressure of 100 psi.
• the other surface was screen printed in multiple colours; excellent colour reproduction and print clarity were obtained.
• Example 1 was repeated. using a temperature of 160°C and a dwell time of 40 seconds; similar results were obtained.
• PVC coated cotton fabric was pressed on the cotton surface by means of a press plate at110°C for 50 seconds and 40 seconds, respectively, using a pressure of 100 psi.
• the other surface was then printed as in Example 1; similar results were obtained.

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• Printing Methods (AREA)

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Publications (1)

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ID=10538727

Family Applications (1)

Country Status (4)

Cited By (9)

Citations (10)

• 1983
  • 1983-02-28 GB GB8305497A patent/GB8305497D0/en active Pending
• 1984
  • 1984-02-28 WO PCT/GB1984/000064 patent/WO1984003257A1/fr unknown
  • 1984-02-28 AU AU25797/84A patent/AU2579784A/en not_active Abandoned
  • 1984-02-28 EP EP84301290A patent/EP0121323A1/fr not_active Withdrawn

Patent Citations (10)

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