EP0023333B1 - Wäscheweichspülmittel - Google Patents

Wäscheweichspülmittel Download PDF

Info

Publication number
EP0023333B1
EP0023333B1 EP80104268A EP80104268A EP0023333B1 EP 0023333 B1 EP0023333 B1 EP 0023333B1 EP 80104268 A EP80104268 A EP 80104268A EP 80104268 A EP80104268 A EP 80104268A EP 0023333 B1 EP0023333 B1 EP 0023333B1
Authority
EP
European Patent Office
Prior art keywords
methyl
weight
formula
alkyl
carbon atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP80104268A
Other languages
English (en)
French (fr)
Other versions
EP0023333A1 (de
Inventor
Karl-Heinz Dr. Keil
Adolf Dr. May
Hans-Walter Dr. Bücking
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG filed Critical Hoechst AG
Priority to AT80104268T priority Critical patent/ATE1756T1/de
Publication of EP0023333A1 publication Critical patent/EP0023333A1/de
Application granted granted Critical
Publication of EP0023333B1 publication Critical patent/EP0023333B1/de
Expired legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/47—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds
    • D06M13/473—Compounds containing quaternary nitrogen atoms derived from heterocyclic compounds having five-membered heterocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/46—Compounds containing quaternary nitrogen atoms
    • D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/06—Ether- or thioether carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/34—Derivatives of acids of phosphorus
    • C11D1/345—Phosphates or phosphites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D06M2101/08—Esters or ethers of cellulose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/10—Animal fibres
    • D06M2101/12—Keratin fibres or silk
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
    • D06M2101/28—Acrylonitrile; Methacrylonitrile
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/34—Polyamides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions

Definitions

  • washed textiles especially those made from cellulose fibers, have an unpleasant hardening after drying. This is particularly the case when the laundry is done in the washing machine.
  • This undesirable hardening of the handle can be eliminated by treating the textiles after washing in a rinsing bath with cationic substances which contain at least two long-chain aliphatic residues in the molecule.
  • the water-dispersible dialkyldimethylammonium salts have been introduced for this purpose.
  • these products have the disadvantage that the treated tissue becomes hydrophobic when overdosed and the rewettability is thereby delayed.
  • the invention thus relates to fabric softeners in the form of an aqueous solution or dispersion which comprise 3 to 15, preferably 4 to 7% by weight of one or more compounds of the formulas III where R, alkyl or alkenyl with 10-30 carbon atoms, preferably 8-14 carbon atoms, R 2 alkyl with 1-4 carbon atoms, preferably methyl, R 3 methyl or hydrogen and A is an anion such as Cl (-) , Br (-) , CH 3 OSO 3 (-) or (CH 3 O) 2 PO 2 (-) means 0.1-3, preferably 0.5-1.5% by weight of a glycerol ether derivative of the formula IV where R 4 can be alkyl or alkenyl having 4-20 carbon atoms, preferably 8-16 carbon atoms, cyclohexyl or aryl optionally substituted by al
  • the glycerol ether derivatives of the formula IV are known from DE-A 1 256 640 and GB-A 1 370 916.
  • This combination of compounds I and 111 with a compound of formula IV gives any textile materials, especially those made from natural or regenerated cellulose, wool, cellulose acetate, triacetate, polyamide, polyacrylonitrile, polyester, polypropylene, a pleasant and soft feel.
  • the use as a laundry aftertreatment for terry cloth and underwear made of cotton is particularly advantageous.
  • These fabric softeners are produced by simply mixing or dispersing the individual components in water.
  • These fabric softeners according to the invention can either contain only one compound of the formulas I to III or they contain a mixture of two or more compounds of these formulas I to III within the stated limits. If a mixture of two or more compounds of the formula I to III is present, their mixing ratio with one another is completely uncritical and can take on any value.
  • the fabric softener according to the invention can also contain other substances and auxiliaries which are either already mixed in the concentrate of the fabric softener or added separately to the ready-to-use, diluted fabric softener.
  • auxiliaries which have already been used in fabric softeners, e.g. cationic or nonionic surface-active substances, electrolytes, acidifying agents, organic complexing agents, optical brightening agents or solubilizers as well as colors and fragrances. They serve to additionally influence the handle of the goods or other properties of the textiles to be treated or to adjust the viscosity, to regulate the pH or to increase the stability at low temperatures.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Description

  • Es ist bekannt, daß gewaschene Textilien, besonders solche aus Cellulosefasern, nach dem Trocknen eine unangenehme Verhärtung aufweisen. Dies tritt insbesondere dann ein, wenn die Wäsche im Waschautomaten erfolgt. Diese unerwünschte Griffverhärtung kann man dadurch beseitigen, daß man die Textilien nach der Wäsche in einem Spülbad mit kationischen Substanzen behandeit, die mindestens zwei langkettige aliphatische Reste im Molekül enthalten. In der Praxis haben sich für diesen Zweck besonders die in Wasser dispergierbaren Dialkyldimethylammoniumsalze eingeführt. Diese Produkte haben jedoch den Nachteil, daß bei Überdosierung das behandelte Gewebe hydrophob und dadurch die Wiederbenetzbarkeit verzögert wird.
  • Es wurde nun gefunden, daß man diese Schwierigkeiten beseitigen kann, wenn man die als Wäscheweichspülmittel dienenden quaternären Ammoniumverbindungen mit einem Glycerinäther-Derivat kombiniert. Gegenstand der Erfindung sind somit Wäscheweichspülmittel in Form einer wässrigen Lösung oder Dispersion, die 3 bis 15, vorzugsweise 4 bis 7 Gew.-% einer oder mehrerer Verbindungen der Formeln bis III
    Figure imgb0001
    Figure imgb0002
    Figure imgb0003
    wobei R, Alkyl oder Alkenyl mit 10-30 Kohlenstoffatomen, vorzugsweise 8-14 Kohlenstoffatomen, R2 Alkyl mit 1-4 Kohlenstoffatomen, vorzugsweise Methyl, R3 Methyl oder Wasserstoff und A ein Anion wie z.B. Cl(-), Br(-), CH3OSO3 (-) oder (CH3O)2PO2 (-) bedeutet, 0,1-3, vorzugsweise 0,5-1,5 Gew.-% eines Glycerinäther-Derivats der Formel IV
    Figure imgb0004
    wobei R4 Alkyl oder Alkenyl mit 4-20 Kohlenstoffatomen, vorzugsweise 8-16 Kohlenstoffatomen, Cyclohexyl oder gegebenenfalls durch Alkylgruppen substituiertes Aryl, vorzugsweise C7-C14-Alkylphenyl sein kann, x und y Wasserstoff oder Methyl, wobei x und y jedoch nicht gleichzeitig Methyl bedeuten, n eine ganze Zahl von 0-20 vorzugsweise 0-5, Z eine Gruppe der Formel ―(CH2)mCOOMe, -SO3Me oder ―PO3Me2, m eine ganze Zahl von 0 bis 3 und Me ein Alkalimetall- oder Ammoniumion bedeutet, sowie gegebenenfalls weitere übliche Hilfs- und Zusatzstoffe enthalten.
  • Die Glycerinäther-Derivate der Formel IV sind aus der DE-A 1 256 640 und der GB-A 1 370 916 bekannt.
  • Diese Kombination der Verbindungen I, und 111 mit einer Verbindung der Formel IV verleiht beliebigen Textilmaterialien, besonders solchen aus natürlicher oder regenerierter Cellulose, Wolle, Cellulose-acetat, -triacetat, Polyamid, Polyacrylnitril, Polyester, Polypropylen einen angenehmen und weichen Griff. Besonders vorteilhaft ist der Einsatz als Wäschenachbehandlungsmittel für Frottee- und Leibwäsche aus Baumwolle. Die Herstellung dieser Wäscheweichspülmittel erfolgt durch einfaches Vermischen oder Dispergieren der Einzelkomponenten in Wasser. Diese Wäscheweichspülmittel gemäß der Erfindung können entweder nur jeweils eine Verbindung der Formeln I bis 111 enthalten oder aber sie enthalten ein Gemisch aus zwei oder mehr Verbindungen dieser Formeln I bis III innerhalb der angegebenen Grenzen. Liegt ein Gemisch aus zwei oder mehr Verbindungen der Formel I bis III vor, so ist deren Mischungsverhältnis untereinander völlig unkritisch und kann jeden beliebigen Wert annehmen.
  • Darüberhinaus können die erfindungsgemäßen Wäscheweichspülmittel noch weitere Substanzen und Hilfsmittel enthalten, die entweder schon im Konzentrat des Wäscheweichspülmittels zugemischt oder dem gebrauchsfertigen, verdünnten Wäscheweichspülmittel gesondert zugesetzt werden. Hierbei handelt es sich um Substanzen oder Hilfsmittel, die man bereits in Wäscheweichspülmitteln eingesetzt hat, wie z.B. kationische oder nichtionische oberflächenaktive Substanzen, Elektrolyte, Absäuerungsmittel, organische Komplexbildner, optische Aufhellungsmittel oder Lösungsvermittler sowie Farb- und Duftstoffe. Sie dienen zur zusätzlichen Beeinflussung des Warengriffs oder sonstiger Eigenschaften der zu behandelnden Textilien oder zur Viskositätseinstellung, zur pH-Regulierung oder zur Erhöhung der Kältestabilität.
  • Die Anwendung dieser Wäscheweichspülmittel erfolgt wie üblich, indem man sie im Anschluß an die Textilwäsche in das letzte Spülwasser gibt. Das so behandelte Textilmaterial wird dann getrocknet, wobei die Wiederbenetzbarkeit des Textilmaterials wesentlich verbessert ist im Vergleich zu handelsüblichen Mitteln.
  • In den folgenden Beispielen sind einige erfindungsgemäße Wäscheweichspülmittel beschrieben. Prozentangaben sind in allen Fällen Gewichtsprozente. Die Herstellung dieser Wäscheweichspülmittel erfolgt in allen Fällen durch einfaches Verrühren in der Wärme von wässrigen Lösungen der einzelnen Komponenten bei Beispiel 1 und in der Kälte bei Beispiel 2 und 3.
    • Beispiel 1
  • Figure imgb0005
    • Beispiel 2
  • Figure imgb0006
    • Beispiel 3
  • Figure imgb0007
    • Beispiel 4
  • Figure imgb0008
  • Diese Wäscheweichspülmittel wurden auf ihren Einfluß auf die Wiederbenetzbarkeit nach der Steighöhenmethode (DIN 53 924) geprüft.
  • Dabei werden glatte Baumwollgewebe mit den erfindungsgemäßen Mischungen behandelt. Zum Vergleich wurde ein handelsüblicher Weichmacher hinzugezogen (Beispiel 4). Nach dieser Prüfmethode wurden für die Mischungen der Beispiele 1-4 die in der nachfolgenden Tabelle aufgeführten Ergebnisse erhalten. Die Steighöhe nicht ausgerüsteter Gewebe wird dabei mit 100 % bezeichnet.
    Figure imgb0009
  • Die Ergebnisse zeigen, daß die erfindungsgemäßen Wäscheweichspülmittelkombinationen im Vergleich mit einem handelsüblichen Produkt ein verbessertes Saugvermögen aufweisen.

Claims (2)

1. Wäscheweichspülmittel in Form einer wäßrigen Lösung oder Dispersion, die 3 bis 15 Gew.-% einer oder mehrerer Verbindungen der Formeln I bis III
Figure imgb0010
Figure imgb0011
Figure imgb0012
wobei R1 Alkyl oder Alkenyl mit 10-30 Kohlenstoffatomen, R2 Alkyl mit 1-4 Kohlenstoffatomen, vorzugsweise Methyl, R3 Methyl oder Wasserstoff und A ein Anion wie z.B. Cl(-), Br(-), CH3OSO3 (-) oder (CH3O)2PO2 (-) bedeutet, 0,1-3 Gew.-% eines Glycerinäther-Derivats der Formel IV
Figure imgb0013
wobei R4 Alkyl oder Alkenyl mit 4-20 Kohlenstoffatomen, Cyclohexyl oder gegebenenfalls durch Alkylgruppen substituiertes Aryl sein kann, x und y Wasserstoff oder Methyl, wobei x und y jedoch nicht gleichzeitig Methyl bedeuten, n eine ganze Zahl von 0-20, Z eine Gruppe der Formel ―(CH2)mCOOMe, ―SO3Me oder ―PO3Me2, m eine Zahl von 0 bis 3 und Me ein Alkalimetall oder Ammoniumion bedeutet, sowie gegebenenfalls weitere übliche Hilfs- und Zusatzstoffe enthalten.
2. Wäscheweichspülmittel nach Anspruch 1 enthaltend 4 bis 7 Gew.-% einer oder mehrerer Verbindungen der Formel I, oder III und 0,5 bis 1,5 Gew.-% eines Glycerinäther-Derivats der Formel IV.
EP80104268A 1979-07-25 1980-07-19 Wäscheweichspülmittel Expired EP0023333B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT80104268T ATE1756T1 (de) 1979-07-25 1980-07-19 Waescheweichspuelmittel.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19792930111 DE2930111A1 (de) 1979-07-25 1979-07-25 Waescheweichspuelmittel
DE2930111 1979-07-25

Publications (2)

Publication Number Publication Date
EP0023333A1 EP0023333A1 (de) 1981-02-04
EP0023333B1 true EP0023333B1 (de) 1982-11-03

Family

ID=6076716

Family Applications (1)

Application Number Title Priority Date Filing Date
EP80104268A Expired EP0023333B1 (de) 1979-07-25 1980-07-19 Wäscheweichspülmittel

Country Status (7)

Country Link
US (1) US4399043A (de)
EP (1) EP0023333B1 (de)
JP (1) JPS5620678A (de)
AT (1) ATE1756T1 (de)
BR (1) BR8004658A (de)
CA (1) CA1154207A (de)
DE (2) DE2930111A1 (de)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3271812D1 (en) * 1981-03-07 1986-07-31 Procter & Gamble Textile treatment compositions and preparation thereof
US4497716A (en) * 1982-12-23 1985-02-05 Lever Brothers Company Fabric softening composition
DE3416472A1 (de) * 1984-05-04 1985-11-07 Hoechst Ag, 6230 Frankfurt Weichmacher enthaltende waschmittel
GB8414944D0 (en) * 1984-06-12 1984-07-18 Ici Plc Fabric conditioners
JPS6110046A (ja) * 1984-06-23 1986-01-17 新日本製鐵株式会社 粒状スラグの脱水促進処理方法及び処理剤
GB8430301D0 (en) * 1984-11-30 1985-01-09 Swan Thomas & Co Ltd Compositions of matter for fabric softeners
US4622173A (en) * 1984-12-31 1986-11-11 Colgate-Palmolive Co. Non-aqueous liquid laundry detergents containing three surfactants including a polycarboxylic acid ester of a non-ionic
AU614636B2 (en) * 1988-07-21 1991-09-05 Ciba Specialty Chemicals Holding Inc. Corrosion inhibition
US5176850A (en) * 1988-07-21 1993-01-05 Ciba-Geigy Corporation Substituted glycerol compounds
DE19651447C1 (de) * 1996-12-11 1997-10-02 Henkel Kgaa Mittel für die Avivage von Textil- und Keratinfasern und Verwendung von Hydroxycarbonsäureestern zur Herstellung von Avivagemitteln
DE19708133C1 (de) * 1997-02-28 1997-12-11 Henkel Kgaa Mittel für die Avivage von Textil- und Keratinfasern sowie die Verwendung von Hydroxycarbonsäureestern zur Herstellung von Avivagemitteln

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1256640B (de) 1965-08-04 1967-12-21 Bayer Ag Verfahren zur Herstellung grenzflaechenaktiver Verbindungen
US3607765A (en) * 1968-11-29 1971-09-21 Colgate Polmolive Co Detergent softener compositions
FR2102537A5 (de) 1970-08-07 1972-04-07 Ugine Kuhlmann
US3997453A (en) * 1974-02-11 1976-12-14 Colgate-Palmolive Company Softener dispersion
NL7714317A (nl) * 1976-12-31 1978-07-04 Hoechst Ag Avivagemiddel en werkwijze voor het aviveren van textielmateriaal.
GB1596791A (en) * 1977-02-15 1981-08-26 Unilever Ltd Deodorant detergent composition

Also Published As

Publication number Publication date
JPS5620678A (en) 1981-02-26
EP0023333A1 (de) 1981-02-04
US4399043A (en) 1983-08-16
BR8004658A (pt) 1981-02-10
DE2930111A1 (de) 1981-02-12
CA1154207A (en) 1983-09-27
DE3061036D1 (en) 1982-12-09
ATE1756T1 (de) 1982-11-15

Similar Documents

Publication Publication Date Title
EP0082457B1 (de) Konzentrierte Wäscheweichspülmittel
EP0043547B1 (de) Wäscheweichspülmittelkonzentrat
EP0082456B1 (de) Konzentrierte Vormischungen von Wäscheweichspülmitteln
EP0023334B1 (de) Wäscheweichspülmittel
EP0691396A2 (de) Wäscheweichspülmittelkonzentrate
EP0413249B1 (de) Wäscheweichspülmittel
EP0085933B1 (de) Konzentrierte Wäscheweichspülmittel
DE2164742A1 (de) Fluessiges waeschenachbehandlungsmittel
DE3046352A1 (de) Grenzflaechenaktive quaternaere ammoniumverbindungen und deren verwendung zum behandeln von textil- und cellulosematerialien
DE2210087B2 (de) Imidazoliniumsalze und diese enthaltende Textüweichmachungsmittel
EP0023333B1 (de) Wäscheweichspülmittel
DE1195265B (de) Verfahren zur antistatischen, weichmachenden und baktericiden Ausruestung von Geweben
DE1619043B2 (de) Mittel zum weichmachen von textilien und gleichzeitigem vermitteln einer guten saugfaehigkeit
EP0094655B2 (de) Konzentrierte Wäscheweichspülmittel
DE2163003B2 (de) Weichmachungsmittel für Textilien
EP0022555B1 (de) Wäscheweichspülmittel
DE1935499A1 (de) Avivagemittel
DE3730444C2 (de)
DE1769718A1 (de) Weichmachungsmittel fuer Textilien
DE1901194B2 (de) Detergens-verträgliches wäßriges Weichmachungsmittel und dessen Verwendung zum Weichmachen von Geweben während des Waschens oder während des Spülens
DE2226934A1 (de) Quaternaere ammoniumverbindungen und ihre verwendung zur oberflaechenbehandlung
DE3135013A1 (de) "waescheweichspuelmittel"
DE1619182B2 (de) Verfahren zum weichmachen von textilien
DE2243806B2 (de) Waessriges mittel zum weichmachen von textilgut
DE1619081C3 (de) Avivagemittel für Textilien

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Designated state(s): AT BE CH DE FR GB IT NL SE

17P Request for examination filed

Effective date: 19810624

ITF It: translation for a ep patent filed

Owner name: ING. C. GREGORJ S.P.A.

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Designated state(s): AT BE CH DE FR GB IT NL SE

REF Corresponds to:

Ref document number: 1756

Country of ref document: AT

Date of ref document: 19821115

Kind code of ref document: T

REF Corresponds to:

Ref document number: 3061036

Country of ref document: DE

Date of ref document: 19821209

ET Fr: translation filed
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 19830615

Year of fee payment: 4

Ref country code: CH

Payment date: 19830615

Year of fee payment: 4

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 19830616

Year of fee payment: 4

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: AT

Payment date: 19830623

Year of fee payment: 4

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 19830630

Year of fee payment: 4

Ref country code: BE

Payment date: 19830630

Year of fee payment: 4

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 19830815

Year of fee payment: 4

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Effective date: 19840719

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Effective date: 19840720

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Effective date: 19840731

Ref country code: CH

Effective date: 19840731

Ref country code: BE

Effective date: 19840731

BERE Be: lapsed

Owner name: HOECHST A.G.

Effective date: 19840719

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Effective date: 19850201

GBPC Gb: european patent ceased through non-payment of renewal fee
NLV4 Nl: lapsed or anulled due to non-payment of the annual fee
PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 19850329

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Effective date: 19850402

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Effective date: 19881118

EUG Se: european patent has lapsed

Ref document number: 80104268.0

Effective date: 19850612

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT