EA201791287A1 - Способ фишера-тропша, проводимый с применением активированного восстановлением катализатора на основе кобальта - Google Patents

Способ фишера-тропша, проводимый с применением активированного восстановлением катализатора на основе кобальта

Info

Publication number
EA201791287A1
EA201791287A1 EA201791287A EA201791287A EA201791287A1 EA 201791287 A1 EA201791287 A1 EA 201791287A1 EA 201791287 A EA201791287 A EA 201791287A EA 201791287 A EA201791287 A EA 201791287A EA 201791287 A1 EA201791287 A1 EA 201791287A1
Authority
EA
Eurasian Patent Office
Prior art keywords
cobalt
carbon monoxide
hydrogen
catalyst
activated
Prior art date
Application number
EA201791287A
Other languages
English (en)
Other versions
EA036743B1 (ru
Inventor
Юэн Фергюсон
Мануэль Охеда-Пинеда
Александер Патерсон
Маттью Джеймс Уэллс
Original Assignee
Бп П.Л.К.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Бп П.Л.К. filed Critical Бп П.Л.К.
Publication of EA201791287A1 publication Critical patent/EA201791287A1/ru
Publication of EA036743B1 publication Critical patent/EA036743B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/703—Activation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

В заявке описан способ превращения сырья, содержащего смесь водорода и монооксида углерода, в углеводороды, где водород и монооксид углерода содержатся в сырье в объемном отношении, составляющем от 1:9 до 9:1, способ включает стадии: предварительной обработки каталитической композиции, содержащей подложку из диоксида титана и оксидное соединение кобальта или соединение кобальта, разлагающееся с образованием оксидного соединения кобальта, в течение промежутка времени, составляющего от 1 до 50 ч, содержащим водород потоком, содержащим менее 10% монооксида углерода в пересчете на объем монооксида углерода и водорода, с получением активированного восстановлением катализатора; и введения во взаимодействие сырья с активированным восстановлением катализатором при повышенной температуре и при атмосферном или повышенном давлении; где стадию предварительной обработки каталитической композиции проводят при температуре, находящейся в диапазоне, составляющем от 200 до менее 300ºС, предпочтительно от 220 до 280ºС, более предпочтительно от 250 до 270ºС.
EA201791287A 2014-12-12 2015-12-02 Способ фишера-тропша, проводимый с применением активированного восстановлением катализатора на основе кобальта EA036743B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP14197760 2014-12-12
PCT/EP2015/078422 WO2016091697A1 (en) 2014-12-12 2015-12-02 Fischer-tropsch process using reductively-activated cobalt catalyst

Publications (2)

Publication Number Publication Date
EA201791287A1 true EA201791287A1 (ru) 2017-12-29
EA036743B1 EA036743B1 (ru) 2020-12-16

Family

ID=52358535

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201791287A EA036743B1 (ru) 2014-12-12 2015-12-02 Способ фишера-тропша, проводимый с применением активированного восстановлением катализатора на основе кобальта

Country Status (11)

Country Link
US (1) US20180037825A1 (ru)
EP (1) EP3230408B1 (ru)
JP (1) JP6774411B2 (ru)
CN (1) CN107406775B (ru)
AU (1) AU2015359691B2 (ru)
BR (1) BR112017012497A2 (ru)
CA (1) CA2970558C (ru)
EA (1) EA036743B1 (ru)
ES (1) ES2788715T3 (ru)
WO (1) WO2016091697A1 (ru)
ZA (1) ZA201703872B (ru)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112021005608A2 (pt) * 2018-09-28 2021-06-22 Bp P.L.C. processo de fischer-tropsch
WO2021139898A1 (en) * 2020-01-10 2021-07-15 Bp P.L.C. Process for producing a fischer-tropsch synthesis catalyst and fischer-tropsch start-up process

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4595703A (en) * 1984-06-29 1986-06-17 Exxon Research And Engineering Co. Preparation of hydrocarbons from synthesis gas
CA1312066C (en) * 1986-10-03 1992-12-29 William C. Behrmann Surface supported particulate metal compound catalysts, their use in hydrocarbon synthesis reactions and their preparation
EP0833807B1 (en) * 1995-06-16 2004-04-14 Shell Internationale Researchmaatschappij B.V. Catalyst and process for the preparation of hydrocarbons
CA2316844C (en) * 1997-12-30 2007-10-30 Shell Internationale Research Maatschappij B.V. Cobalt based fisher-tropsch catalyst
GB0222240D0 (en) 2002-09-25 2002-10-30 Ici Plc Cobalt catalysts
EP2367630A1 (en) * 2008-12-18 2011-09-28 Shell Internationale Research Maatschappij B.V. Regeneration of a fischer tropsch catalyst by oxidating it and treating it with a mixture of ammonium carbonate, ammonium hydroxide and water
CN102863306B (zh) * 2011-07-04 2015-04-01 中国石油化工股份有限公司 一种浆态床费托合成方法

Also Published As

Publication number Publication date
CN107406775A (zh) 2017-11-28
BR112017012497A2 (pt) 2018-04-24
ZA201703872B (en) 2020-01-29
ES2788715T3 (es) 2020-10-22
EP3230408A1 (en) 2017-10-18
AU2015359691A8 (en) 2017-07-13
JP2018504477A (ja) 2018-02-15
US20180037825A1 (en) 2018-02-08
CA2970558A1 (en) 2016-06-16
CN107406775B (zh) 2020-10-16
JP6774411B2 (ja) 2020-10-21
CA2970558C (en) 2023-01-03
EP3230408B1 (en) 2020-02-05
AU2015359691B2 (en) 2020-11-19
WO2016091697A1 (en) 2016-06-16
AU2015359691A1 (en) 2017-06-29
EA036743B1 (ru) 2020-12-16

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