EA201690609A1 - Половолоконная мембрана из асимметрично модифицированного углеродного молекулярного сита с повышенной проницаемостью - Google Patents
Половолоконная мембрана из асимметрично модифицированного углеродного молекулярного сита с повышенной проницаемостьюInfo
- Publication number
- EA201690609A1 EA201690609A1 EA201690609A EA201690609A EA201690609A1 EA 201690609 A1 EA201690609 A1 EA 201690609A1 EA 201690609 A EA201690609 A EA 201690609A EA 201690609 A EA201690609 A EA 201690609A EA 201690609 A1 EA201690609 A1 EA 201690609A1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- fiber membrane
- asymmetrically modified
- hollow fiber
- carbon molecular
- modified carbon
- Prior art date
Links
- 239000012528 membrane Substances 0.000 title abstract 5
- 239000000835 fiber Substances 0.000 title abstract 3
- 150000001721 carbon Chemical class 0.000 title abstract 2
- 239000012510 hollow fiber Substances 0.000 abstract 4
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 230000035699 permeability Effects 0.000 abstract 2
- 239000002243 precursor Substances 0.000 abstract 2
- 238000000926 separation method Methods 0.000 abstract 2
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000002808 molecular sieve Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000000197 pyrolysis Methods 0.000 abstract 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/021—Carbon
- B01D71/0211—Graphene or derivates thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0067—Inorganic membrane manufacture by carbonisation or pyrolysis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/08—Hollow fibre membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/021—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/021—Carbon
- B01D71/0212—Carbon nanotubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/12—Specific ratios of components used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/022—Asymmetric membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/022—Asymmetric membranes
- B01D2325/0231—Dense layers being placed on the outer side of the cross-section
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/022—Asymmetric membranes
- B01D2325/0232—Dense layer on both outer sides of the membrane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/022—Asymmetric membranes
- B01D2325/0233—Asymmetric membranes with clearly distinguishable layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/20—Specific permeability or cut-off range
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/22—Thermal or heat-resistance properties
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/20—Capture or disposal of greenhouse gases of methane
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Materials Engineering (AREA)
- Nanotechnology (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Inorganic Fibers (AREA)
- Carbon And Carbon Compounds (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
Abstract
Данное изобретение относится к половолоконной мембране из асимметрично модифицированного углеродного молекулярного сита (CMS) с улучшенными эксплуатационными свойствами разделения газов, а также к способу получения половолоконной мембраны из асимметрично модифицированного CMS с улучшенными эксплуатационными свойствами разделения газов. Способ включает обработку полимерного волокна-предшественника перед пиролизом раствором, содержащим модифицирующий агент. Концентрация модифицирующего агента в растворе может быть выбрана таким образом, чтобы получить половолоконную мембрану из асимметрично модифицированного CMS с нужной комбинацией свойств газовой проницаемости и селективности. Затем обработанное волокно-предшественник подвергают пиролизу с формированием половолоконной мембраны из асимметрично модифицированного CMS с улучшенной газовой проницаемостью.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201361884548P | 2013-09-30 | 2013-09-30 | |
PCT/US2014/058329 WO2015048754A1 (en) | 2013-09-30 | 2014-09-30 | Asymmetric modified carbon molecular sieve hollow fiber membranes having improved permeance |
Publications (2)
Publication Number | Publication Date |
---|---|
EA201690609A1 true EA201690609A1 (ru) | 2017-01-30 |
EA034734B1 EA034734B1 (ru) | 2020-03-13 |
Family
ID=52740770
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EA201690609A EA034734B1 (ru) | 2013-09-30 | 2014-09-30 | Половолоконная мембрана из асимметрично модифицированного углеродного молекулярного сита с повышенной проницаемостью, способ ее получения и способ получения полимера |
Country Status (12)
Country | Link |
---|---|
US (3) | US9815030B2 (ru) |
EP (2) | EP3862073A1 (ru) |
JP (1) | JP6487910B2 (ru) |
KR (1) | KR102130876B1 (ru) |
CN (2) | CN105792917B (ru) |
AU (2) | AU2014324439B2 (ru) |
BR (1) | BR112016007089A2 (ru) |
EA (1) | EA034734B1 (ru) |
ES (1) | ES2886525T3 (ru) |
MY (1) | MY177312A (ru) |
SA (1) | SA516370840B1 (ru) |
WO (1) | WO2015048754A1 (ru) |
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US10352833B2 (en) * | 2015-07-22 | 2019-07-16 | The Florida International University Board Of Trustees | Microextraction capsules and method of making |
EP3328965B1 (en) | 2015-07-28 | 2019-04-24 | Shell International Research Maatschappij B.V. | Process for preparing a paraffin product |
WO2017105836A1 (en) | 2015-12-17 | 2017-06-22 | Dow Global Technologies Llc | Method of making carbon molecular sieve membranes |
WO2017172800A1 (en) | 2016-03-28 | 2017-10-05 | Board Of Regents, The University Of Texas System | Low-temperature pyrolysis of organic acid salts providing graphene rich carbons |
US11471824B2 (en) * | 2016-04-29 | 2022-10-18 | Dow Global Technologies Llc | Transition metal containing carbon molecular sieve membranes and method to make them |
CN109937084B (zh) * | 2016-11-10 | 2022-05-24 | 陶氏环球技术有限责任公司 | 改进的制备碳分子筛中空纤维膜的方法 |
BR112019016289B1 (pt) * | 2017-02-10 | 2023-11-14 | Georgia Tech Research Corporation | Processo para separar componentes gasosos utilizando membranas de peneira molecular de carbono |
JP2020518446A (ja) | 2017-05-04 | 2020-06-25 | サウジ アラビアン オイル カンパニー | 架橋ポリマー膜およびその製造方法 |
US20190030491A1 (en) * | 2017-07-25 | 2019-01-31 | Georgia Tech Research Corporation | Methods for preparing carbon molecular sieve hollow fiber membranes for gas separation |
CN111093804A (zh) | 2017-08-14 | 2020-05-01 | 陶氏环球技术有限责任公司 | 改进的制备碳分子筛中空纤维隔膜的方法 |
WO2019036192A1 (en) * | 2017-08-15 | 2019-02-21 | Georgia Tech Research Corporation | METHODS FOR REGENERATING OLD MEMBRANES OF CARBON MOLECULAR SIEVE |
KR101950107B1 (ko) * | 2017-09-05 | 2019-02-19 | 한양대학교 에리카산학협력단 | 중공 섬유 복합체의 제조 방법 |
CA3079195A1 (en) * | 2017-10-30 | 2019-05-09 | Dow Global Technologies Llc | Carbon molecular sieve membranes containing a group 13 metal and method to make them |
CN108993400A (zh) * | 2018-09-14 | 2018-12-14 | 河南环宇石化装备科技股份有限公司 | 一种分离氮气-甲烷的高效吸附剂的制备方法 |
CN114340764B (zh) * | 2019-05-01 | 2024-03-05 | 阿卜杜拉国王科技大学 | 杂化无机氧化物-碳分子筛膜 |
CN110508165A (zh) * | 2019-08-09 | 2019-11-29 | 大连理工大学 | 天然气提浓氦气多孔碳纳米球混合基质复合膜及其制备方法 |
KR102104426B1 (ko) | 2019-12-03 | 2020-04-24 | 주식회사 이피엠 | 고분자 수지의 함침성이 우수한 복합 중공사막 제조방법과 이에 의해 제조된 복합 중공사막 |
EP4164983A1 (en) | 2020-06-10 | 2023-04-19 | Shell Internationale Research Maatschappij B.V. | Method for the production of hydrogen |
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US20020102674A1 (en) * | 1987-05-20 | 2002-08-01 | David M Anderson | Stabilized microporous materials |
US5234471A (en) | 1992-02-04 | 1993-08-10 | E. I. Du Pont De Nemours And Company | Polyimide gas separation membranes for carbon dioxide enrichment |
CN1099310C (zh) * | 1998-04-16 | 2003-01-22 | 中国科学院大连化学物理研究所 | 一种聚酰亚胺不对称中空纤维膜的制备方法 |
JP4081956B2 (ja) * | 1999-03-05 | 2008-04-30 | 宇部興産株式会社 | 部分炭素化された非対称性中空糸分離膜とその製法およびガス分離方法 |
US6299669B1 (en) | 1999-11-10 | 2001-10-09 | The University Of Texas System | Process for CO2/natural gas separation |
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JP2002355538A (ja) | 2001-05-30 | 2002-12-10 | Asahi Medical Co Ltd | 炭素繊維中空糸膜用セルロース中空糸膜およびその製造方法 |
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CA2640545A1 (en) * | 2008-05-19 | 2009-11-19 | Industry-University Cooperation Foundation, Hanyang University | Polyimides dope composition, preparation method of hollow fiber using the same and hollow fiber prepared therefrom |
MX2010012599A (es) * | 2008-05-19 | 2011-04-26 | Iucf Hyu | Fibra hueca, composicion de solucion con aditivo para formar una fibra hueca y metodo para fabricar una fibrra hueca usando la misma. |
US8561812B2 (en) * | 2009-03-27 | 2013-10-22 | Uop Llc | Blend polymer membranes comprising thermally rearranged polymers derived from aromatic polyimides containing ortho-positioned functional groups |
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EP2683473A1 (en) * | 2011-03-07 | 2014-01-15 | Georgia Tech Research Corporation | Polyimide-based carbon molecular sieve membrane for ethylene/ethane separations |
CN104125855B (zh) * | 2011-12-20 | 2017-05-17 | 佐治亚科技研究公司 | 高性能碳分子筛中空纤维膜的多孔形态的稳定化 |
-
2014
- 2014-09-30 WO PCT/US2014/058329 patent/WO2015048754A1/en active Application Filing
- 2014-09-30 KR KR1020167010843A patent/KR102130876B1/ko active IP Right Grant
- 2014-09-30 CN CN201480065382.4A patent/CN105792917B/zh active Active
- 2014-09-30 BR BR112016007089A patent/BR112016007089A2/pt not_active Application Discontinuation
- 2014-09-30 EP EP21165676.4A patent/EP3862073A1/en active Pending
- 2014-09-30 ES ES14848035T patent/ES2886525T3/es active Active
- 2014-09-30 MY MYPI2016000556A patent/MY177312A/en unknown
- 2014-09-30 EA EA201690609A patent/EA034734B1/ru not_active IP Right Cessation
- 2014-09-30 JP JP2016518689A patent/JP6487910B2/ja active Active
- 2014-09-30 CN CN201910863990.4A patent/CN110694495B/zh active Active
- 2014-09-30 EP EP14848035.3A patent/EP3052222B1/en active Active
- 2014-09-30 US US14/501,884 patent/US9815030B2/en active Active
- 2014-09-30 AU AU2014324439A patent/AU2014324439B2/en active Active
-
2016
- 2016-03-30 SA SA516370840A patent/SA516370840B1/ar unknown
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2017
- 2017-11-14 US US15/812,025 patent/US11123693B2/en active Active
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2018
- 2018-01-24 AU AU2018200567A patent/AU2018200567B2/en active Active
-
2021
- 2021-08-20 US US17/407,465 patent/US11992814B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
CN105792917B (zh) | 2019-10-11 |
CN105792917A (zh) | 2016-07-20 |
US11123693B2 (en) | 2021-09-21 |
AU2014324439B2 (en) | 2017-10-26 |
CN110694495A (zh) | 2020-01-17 |
KR20160070087A (ko) | 2016-06-17 |
WO2015048754A1 (en) | 2015-04-02 |
US20210379538A1 (en) | 2021-12-09 |
CN110694495B (zh) | 2022-09-16 |
JP2016539782A (ja) | 2016-12-22 |
EA034734B1 (ru) | 2020-03-13 |
US9815030B2 (en) | 2017-11-14 |
EP3052222B1 (en) | 2021-05-12 |
AU2018200567A1 (en) | 2018-02-15 |
ES2886525T3 (es) | 2021-12-20 |
BR112016007089A2 (pt) | 2020-05-12 |
US11992814B2 (en) | 2024-05-28 |
US20180071691A1 (en) | 2018-03-15 |
AU2018200567B2 (en) | 2020-04-02 |
KR102130876B1 (ko) | 2020-07-09 |
US20150094445A1 (en) | 2015-04-02 |
MY177312A (en) | 2020-09-11 |
JP6487910B2 (ja) | 2019-03-20 |
EP3862073A1 (en) | 2021-08-11 |
SA516370840B1 (ar) | 2018-09-26 |
EP3052222A1 (en) | 2016-08-10 |
EP3052222A4 (en) | 2017-06-07 |
AU2014324439A1 (en) | 2016-04-21 |
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