EA200100360A1 - METHOD OF DESULPTION - Google Patents

METHOD OF DESULPTION

Info

Publication number
EA200100360A1
EA200100360A1 EA200100360A EA200100360A EA200100360A1 EA 200100360 A1 EA200100360 A1 EA 200100360A1 EA 200100360 A EA200100360 A EA 200100360A EA 200100360 A EA200100360 A EA 200100360A EA 200100360 A1 EA200100360 A1 EA 200100360A1
Authority
EA
Eurasian Patent Office
Prior art keywords
radiation
sulfur
desulfurized
reaction
substance
Prior art date
Application number
EA200100360A
Other languages
Russian (ru)
Other versions
EA003072B1 (en
Inventor
Джеймс К. Жанблан
Original Assignee
Джеймс К. Жанблан
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Джеймс К. Жанблан filed Critical Джеймс К. Жанблан
Publication of EA200100360A1 publication Critical patent/EA200100360A1/en
Publication of EA003072B1 publication Critical patent/EA003072B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/12—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen with oxygen-generating compounds, e.g. per-compounds, chromic acid, chromates
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
    • C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
    • C10G27/14—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen with ozone-containing gases
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G32/00—Refining of hydrocarbon oils by electric or magnetic means, by irradiation, or by using microorganisms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00—Treating solid fuels to improve their combustion
    • C10L9/02—Treating solid fuels to improve their combustion by chemical means
    • C10L9/06—Treating solid fuels to improve their combustion by chemical means by oxidation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Gas Separation By Absorption (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)
  • Treating Waste Gases (AREA)

Abstract

Серосодержащие углеродистые вещества десульфурируют при реакции со смесью окислителя и кислородсодержащего растворителя, такого как диэтиловый эфир, в щелочных условиях при температуре, предпочтительно изменяющейся от температуры окружающей среды приблизительно до 250°F (121°C), и предпочтительном давлении примерно от 1 атмосферы до 2 атмосфер. Использование излучения, такого как рентгеновское излучение, инфракрасное, видимое, микроволновое или ультрафиолетовое, альфа, бета или гамма излучение, другое атомное излучение, происходящее из радиоактивного вещества, или ультразвука - способствует десульфурации. Продуктами реакции являются десульфированное углеродсодержащее вещество, содержание серы в котором составляет (например) менее, чем около 1%, и отделенные соединения серы.Международная заявка была опубликована вместе с отчетом о международном поиске.Sulfur-containing carbonaceous substances are desulfurized by reaction with a mixture of an oxidizing agent and an oxygen-containing solvent, such as diethyl ether, under basic conditions at a temperature preferably ranging from ambient temperature to about 250 ° F (121 ° C) and a preferred pressure from about 1 atmosphere to 2 atmospheres. The use of radiation, such as X-rays, infrared, visible, microwave or ultraviolet, alpha, beta or gamma radiation, other atomic radiation originating from a radioactive substance, or ultrasound - contributes to desulfurization. The reaction products are a desulfurized carbon-containing substance, the sulfur content of which is (for example) less than about 1%, and the separated sulfur compounds. The international application was published along with an international search report.

EA200100360A 1998-09-16 1999-09-16 Desulfurization process EA003072B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10057698P 1998-09-16 1998-09-16
PCT/US1999/021478 WO2000015734A1 (en) 1998-09-16 1999-09-16 Desulfurization process

Publications (2)

Publication Number Publication Date
EA200100360A1 true EA200100360A1 (en) 2001-10-22
EA003072B1 EA003072B1 (en) 2002-12-26

Family

ID=22280457

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200100360A EA003072B1 (en) 1998-09-16 1999-09-16 Desulfurization process

Country Status (8)

Country Link
EP (1) EP1115812A1 (en)
JP (1) JP2002524651A (en)
AU (1) AU762639B2 (en)
BR (1) BR9913755A (en)
CA (1) CA2344339A1 (en)
EA (1) EA003072B1 (en)
ID (1) ID29461A (en)
WO (1) WO2000015734A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2708629C1 (en) * 2019-05-30 2019-12-10 Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский Томский государственный университет" (ТГУ, НИ ТГУ) Desulfurization method of heavy oil product using microwave radiation

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US6402939B1 (en) * 2000-09-28 2002-06-11 Sulphco, Inc. Oxidative desulfurization of fossil fuels with ultrasound
US6500219B1 (en) 2001-03-19 2002-12-31 Sulphco, Inc. Continuous process for oxidative desulfurization of fossil fuels with ultrasound and products thereof
US7871512B2 (en) 2001-05-10 2011-01-18 Petrosonics, Llc Treatment of crude oil fractions, fossil fuels, and products thereof
US7081196B2 (en) 2001-05-10 2006-07-25 Mark Cullen Treatment of crude oil fractions, fossil fuels, and products thereof with sonic energy
US6827844B2 (en) * 2002-10-23 2004-12-07 Sulphco, Inc. Ultrasound-assisted desulfurization of fossil fuels in the presence of dialkyl ethers
US7393513B2 (en) 2003-06-02 2008-07-01 S&B Engineers And Constructors, Ltd. System and process for treating sulfur
MXPA06006664A (en) * 2003-12-12 2007-02-21 Coaltek Corp A pre-burning, dry process methodology and systems for enhancing solid fuel properties.
DE102004044687A1 (en) * 2004-09-15 2006-03-30 Baerlocher Gmbh Process for the preparation of metal carboxylates
AU2005318152B2 (en) * 2004-12-23 2011-10-13 Solvay (Societe Anonyme) Process for the manufacture of 1,2-dichloroethane
US20060180500A1 (en) * 2005-02-15 2006-08-17 Sulphco, Inc., A Corporation Of The State Of Nevada Upgrading of petroleum by combined ultrasound and microwave treatments
US7744749B2 (en) 2005-09-08 2010-06-29 Saudi Arabian Oil Company Diesel oil desulfurization by oxidation and extraction
US8715489B2 (en) 2005-09-08 2014-05-06 Saudi Arabian Oil Company Process for oxidative conversion of organosulfur compounds in liquid hydrocarbon mixtures
US8585788B2 (en) 2006-03-31 2013-11-19 Coaltek, Inc. Methods and systems for processing solid fuel
US8585786B2 (en) 2006-03-31 2013-11-19 Coaltek, Inc. Methods and systems for briquetting solid fuel
US20110189049A1 (en) 2008-05-09 2011-08-04 Martin Beaulieu Method for treating odors
US8597472B2 (en) * 2008-10-28 2013-12-03 Xyleco, Inc. Processing materials
UA117022C2 (en) * 2008-12-19 2018-06-11 Ксілеко, Інк. METHOD OF BIOMASS PROCESSING
WO2010118530A1 (en) 2009-04-14 2010-10-21 Uniboard Canada Inc Process for reducing the content of water soluble volatile organic compounds in a gas
US8926825B2 (en) 2010-03-19 2015-01-06 Mark Cullen Process for removing sulfur from hydrocarbon streams using hydrotreatment, fractionation and oxidation
US20120138449A1 (en) * 2012-02-12 2012-06-07 King Abdulaziz City for Science and Technology (KACST) Method of removing sulfur from crude oil and diesel using ionizing radiation
WO2013123308A1 (en) * 2012-02-15 2013-08-22 Arizona Board Of Regents, A Body Corporate Of The State Of Arizona Acting For And On Behalf Of Arizona State University Multifunctional materials and composites
CN103623774A (en) * 2012-08-21 2014-03-12 华南理工大学 Method for preparing modified activated carbon used for fuel oil desulphurization
CN104342202B (en) * 2013-08-06 2016-08-10 中国石油大学(北京) A kind of Lube basic oil material feedstocks deacidifying device and method
CN116873874A (en) 2017-04-18 2023-10-13 突破技术有限责任公司 Sulfur production
CN107022394A (en) * 2017-06-08 2017-08-08 重庆科技学院 A kind of method that organic sulfur is removed in sulphur coal
CN106995736A (en) * 2017-06-08 2017-08-01 重庆科技学院 Coal desulfurization before combustion method
CN107177396A (en) * 2017-06-29 2017-09-19 广东固特超声股份有限公司 Energy-collecting ultrasonic ripple desulfurizer
RU2677462C1 (en) * 2017-12-07 2019-01-17 Федеральное государственное бюджетное образовательное учреждение высшего образования "Московский государственный университет имени М.В. Ломоносова" (МГУ) Method of oil-protection of raw oil by hydrogen peroxide with identification of oxidation products
CN108998060B (en) * 2018-08-23 2021-06-08 中石化（洛阳）科技有限公司 Novel process for producing low-sulfur coke
CN109266418A (en) * 2018-09-30 2019-01-25 青岛大学 A method of arsenic in coal being leached under ultraviolet light using flue gas

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US3964994A (en) * 1969-11-28 1976-06-22 Marathon Oil Company H2 O2 -containing micellar dispersions
US4097244A (en) * 1976-12-13 1978-06-27 Atlantic Richfield Company Process for removing sulfur from coal
US4152120A (en) * 1978-02-06 1979-05-01 General Electric Company Coal desulfurization using alkali metal or alkaline earth compounds and electromagnetic irradiation
US4391608A (en) * 1980-03-31 1983-07-05 Dondelewski Michael A Process for the beneficiation of carbonous materials with the aid of ultrasound

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2708629C1 (en) * 2019-05-30 2019-12-10 Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский Томский государственный университет" (ТГУ, НИ ТГУ) Desulfurization method of heavy oil product using microwave radiation

Also Published As

Publication number Publication date
AU762639B2 (en) 2003-07-03
AU6252799A (en) 2000-04-03
EP1115812A1 (en) 2001-07-18
WO2000015734A1 (en) 2000-03-23
CA2344339A1 (en) 2000-03-23
ID29461A (en) 2001-08-30
BR9913755A (en) 2001-06-05
JP2002524651A (en) 2002-08-06
EA003072B1 (en) 2002-12-26
WO2000015734A9 (en) 2000-08-17

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Legal Events

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MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ KG TJ TM

MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): BY

MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): MD

MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): KZ RU