DK3372580T3 - Fremgangsmåde til fremstilling af 1-h-pyrrolidin-2,4-dion-derivater - Google Patents
Fremgangsmåde til fremstilling af 1-h-pyrrolidin-2,4-dion-derivater Download PDFInfo
- Publication number
- DK3372580T3 DK3372580T3 DK18162778.7T DK18162778T DK3372580T3 DK 3372580 T3 DK3372580 T3 DK 3372580T3 DK 18162778 T DK18162778 T DK 18162778T DK 3372580 T3 DK3372580 T3 DK 3372580T3
- Authority
- DK
- Denmark
- Prior art keywords
- pyrrolidine
- preparing
- procedure
- dion derivatives
- dion
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D207/00—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D207/02—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D207/30—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members
- C07D207/34—Heterocyclic compounds containing five-membered rings not condensed with other rings, with one nitrogen atom as the only ring hetero atom with only hydrogen or carbon atoms directly attached to the ring nitrogen atom having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D207/36—Oxygen or sulfur atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C235/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms
- C07C235/70—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups and doubly-bound oxygen atoms bound to the same carbon skeleton
- C07C235/72—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups and doubly-bound oxygen atoms bound to the same carbon skeleton with the carbon atoms of the carboxamide groups bound to acyclic carbon atoms
- C07C235/74—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups and doubly-bound oxygen atoms bound to the same carbon skeleton with the carbon atoms of the carboxamide groups bound to acyclic carbon atoms of a saturated carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C255/00—Carboxylic acid nitriles
- C07C255/45—Carboxylic acid nitriles having cyano groups bound to carbon atoms of rings other than six-membered aromatic rings
- C07C255/46—Carboxylic acid nitriles having cyano groups bound to carbon atoms of rings other than six-membered aromatic rings to carbon atoms of non-condensed rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/02—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom condensed with one carbocyclic ring
- C07D209/54—Spiro-condensed
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/04—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members
- C07D307/18—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having no double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D307/22—Nitrogen atoms not forming part of a nitro radical
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D317/00—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms
- C07D317/08—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3
- C07D317/72—Heterocyclic compounds containing five-membered rings having two oxygen atoms as the only ring hetero atoms having the hetero atoms in positions 1 and 3 spiro-condensed with carbocyclic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D405/00—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom
- C07D405/02—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings
- C07D405/06—Heterocyclic compounds containing both one or more hetero rings having oxygen atoms as the only ring hetero atoms, and one or more rings having nitrogen as the only ring hetero atom containing two hetero rings linked by a carbon chain containing only aliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D491/00—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
- C07D491/02—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
- C07D491/10—Spiro-condensed systems
- C07D491/107—Spiro-condensed systems with only one oxygen atom as ring hetero atom in the oxygen-containing ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D491/00—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
- C07D491/02—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
- C07D491/10—Spiro-condensed systems
- C07D491/113—Spiro-condensed systems with two or more oxygen atoms as ring hetero atoms in the oxygen-containing ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
- Pyrrole Compounds (AREA)
- Indole Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
- Nitrogen Condensed Heterocyclic Rings (AREA)
- Pyrane Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161435910P | 2011-01-25 | 2011-01-25 | |
| EP11152069 | 2011-01-25 | ||
| EP12700832.4A EP2668158B1 (de) | 2011-01-25 | 2012-01-20 | Verfahren zur herstellung von 1-h-pyrrolidin-2,4-dion-derivaten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK3372580T3 true DK3372580T3 (da) | 2020-10-12 |
Family
ID=43827830
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK12700832.4T DK2668158T3 (da) | 2011-01-25 | 2012-01-20 | Fremgangsmåde til fremstilling af 1 -h-pyrrolidin-2,4-dion-derivater |
| DK18162778.7T DK3372580T3 (da) | 2011-01-25 | 2012-01-20 | Fremgangsmåde til fremstilling af 1-h-pyrrolidin-2,4-dion-derivater |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK12700832.4T DK2668158T3 (da) | 2011-01-25 | 2012-01-20 | Fremgangsmåde til fremstilling af 1 -h-pyrrolidin-2,4-dion-derivater |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US8859782B2 (da) |
| EP (2) | EP3372580B1 (da) |
| JP (1) | JP5951642B2 (da) |
| KR (2) | KR101841320B1 (da) |
| CN (2) | CN106905215B (da) |
| BR (1) | BR112013018973A2 (da) |
| DK (2) | DK2668158T3 (da) |
| ES (1) | ES2689149T3 (da) |
| IL (2) | IL227590B (da) |
| MX (2) | MX2013008361A (da) |
| TW (1) | TWI545112B (da) |
| WO (1) | WO2012101047A1 (da) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6886458B2 (ja) * | 2015-10-06 | 2021-06-16 | バイエル・クロップサイエンス・アクチェンゲゼルシャフト | 新規なアルキニル置換された３−フェニルピロリジン−２，４−ジオン類および除草剤としてのそれらの使用 |
| CN107468690B (zh) | 2017-08-11 | 2020-01-31 | 北京卓凯生物技术有限公司 | 4-氧-烷基化特特拉姆酸类化合物及其制备方法与应用 |
| CN107353239B (zh) | 2017-08-11 | 2019-06-18 | 北京卓凯生物技术有限公司 | 4-氧-烷基化特特拉姆酸类化合物及其制备方法 |
| WO2019110613A1 (en) | 2017-12-05 | 2019-06-13 | Syngenta Participations Ag | Chemical process for the synthesis of herbicidal pyrazolidinedione compounds |
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| DE3625460A1 (de) * | 1986-07-28 | 1988-02-04 | Bayer Ag | N-(2-cyan-2-oximinoacetyl)-aminonitrile |
| DE4107394A1 (de) | 1990-05-10 | 1991-11-14 | Bayer Ag | 1-h-3-aryl-pyrrolidin-2,4-dion-derivate |
| DE4121365A1 (de) | 1991-06-28 | 1993-01-14 | Bayer Ag | Substituierte 1-h-3-aryl-pyrrolidin-2,4-dion-derivate |
| DE4223015A1 (de) | 1992-07-13 | 1994-01-20 | Bayer Ag | Substituierte 3-Benzoyl-pyrrolidin-2,4-dion-Derivate |
| DE4236400A1 (de) | 1992-10-28 | 1994-05-05 | Bayer Ag | N-Phenylacetaminonitrile |
| AU666040B2 (en) | 1992-10-28 | 1996-01-25 | Bayer Aktiengesellschaft | Substituted 1-H-3-aryl-pyrrolidine-2,4-dione derivatives |
| DE4306257A1 (de) | 1993-03-01 | 1994-09-08 | Bayer Ag | Substituierte 1-H-3-Phenyl-5-cycloalkylpyrrolidin-2,4-dione, ihre Herstellung und ihre Verwendung |
| DE4306259A1 (de) | 1993-03-01 | 1994-09-08 | Bayer Ag | Dialkyl-1-H-3-(2,4-dimethylphenyl)-pyrrolidin-2,4-dione, ihre Herstellung und ihre Verwendung |
| ES2130431T3 (es) | 1993-07-05 | 1999-07-01 | Bayer Ag | Aril-cetoenolheterociclos substituidos. |
| BR9407218A (pt) | 1993-08-05 | 1996-09-17 | Bayer Ag | Derivados de 4-carbamoil-pirrolin-2-ona e derivados de 4-carbamoil-dihidrofuran-2-ona substituídos e uso dos mesmos como pesticidas |
| DE4409044A1 (de) * | 1993-08-05 | 1995-02-09 | Bayer Ag | Substituierte 4-Carbamoyl-pyrrolin-2-on und -dihydrofuran-2-on-Derivate |
| DE4425617A1 (de) | 1994-01-28 | 1995-08-03 | Bayer Ag | 1-H-3-Aryl-pyrrolidin-2,4-dion-Derivate |
| DE4431730A1 (de) | 1994-02-09 | 1995-08-10 | Bayer Ag | Substituierte 1H-3-Aryl-pyrrolidin-2,4-dion-Derivate |
| ES2190786T3 (es) | 1994-04-05 | 2003-08-16 | Bayer Cropscience Ag | 1-h-3-aril-pirrolidin-2,4-dionas alcoxi-alquil-substituidas como herbicidas y pesticidas. |
| HUP9800031A3 (en) | 1995-02-13 | 1998-06-29 | Bayer Ag | 2-phenyl-substituted heterocyclic ketoenols, intermediates, preparation and use thereof, pesticide and herbicide compositions containing these compounds as active ingredients |
| DE19515690A1 (de) * | 1995-04-28 | 1996-10-31 | Bayer Ag | Tetron- und Tetramsäure-Derivate |
| WO1996035664A1 (de) | 1995-05-09 | 1996-11-14 | Bayer Aktiengesellschaft | Alkyl-dihalogenphenylsubstituierte ketoenole als schädlingsbekämpfungsmittel und herbizide |
| BR9609250B1 (pt) | 1995-06-28 | 2011-08-23 | 2,4,5-fenilcetoenóis trissubstituìdos, processo para sua preparação, composições para controle de pestes e herbicidas, uso das referidas composições e método para controle de pestes. | |
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| DE19749720A1 (de) | 1997-11-11 | 1999-05-12 | Bayer Ag | Neue substituierte Phenylketoenole |
| DE19808261A1 (de) | 1998-02-27 | 1999-10-28 | Bayer Ag | Arylphenylsubstituierte cyclische Ketoenole |
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| DE10139465A1 (de) | 2001-08-10 | 2003-02-20 | Bayer Cropscience Ag | Selektive Herbizide auf Basis von substituierten, cayclischen Ketoenolen und Safenern |
| DE10201239A1 (de) | 2002-01-15 | 2003-07-24 | Bayer Cropscience Ag | Fungizide biphenylsubstituierte cyclische Ketoenole |
| JP2005516973A (ja) | 2002-01-22 | 2005-06-09 | シンジェンタ パーティシペーションズ アクチェンゲゼルシャフト | 除草剤として有用なフェニル置換ヘテロ環化合物 |
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| DE10239479A1 (de) | 2002-08-28 | 2004-03-04 | Bayer Cropscience Ag | Substituierte spirocyclische Ketoenole |
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| DE10311300A1 (de) | 2003-03-14 | 2004-09-23 | Bayer Cropscience Ag | 2,4,6-Phenylsubstituierte cyclische Ketoenole |
| DE10326386A1 (de) | 2003-06-12 | 2004-12-30 | Bayer Cropscience Ag | N-Heterocyclyl-phenylsubstituierte cyclische Ketoenole |
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| DE10354628A1 (de) | 2003-11-22 | 2005-06-16 | Bayer Cropscience Ag | 2-Ethyl-4,6-dimethyl-phenyl-substituierte Tetramsäure-Derivate |
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| DE102004001433A1 (de) | 2004-01-09 | 2005-08-18 | Bayer Cropscience Ag | cis-Alkoxyspiro-substituierte Tetramsäure-Derivate |
| DE102004014620A1 (de) | 2004-03-25 | 2005-10-06 | Bayer Cropscience Ag | 2,4,6-phenylsubstituierte cyclische Ketoenole |
| TW200538461A (en) * | 2004-04-07 | 2005-12-01 | Syngenta Participations Ag | Avermectin and avermectin monosaccharide substituted in the 4"-and 4'-position respectively |
| DE102004030753A1 (de) | 2004-06-25 | 2006-01-19 | Bayer Cropscience Ag | 3'-Alkoxy spirocyclische Tetram- und Tretronsäuren |
| DE102004044827A1 (de) | 2004-09-16 | 2006-03-23 | Bayer Cropscience Ag | Jod-phenylsubstituierte cyclische Ketoenole |
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| DE102005008021A1 (de) | 2005-02-22 | 2006-08-24 | Bayer Cropscience Ag | Spiroketal-substituierte cyclische Ketoenole |
| TW200740755A (en) * | 2005-07-13 | 2007-11-01 | Bayer Cropscience Sa | Dihalogenation of N,O-disubstituted hydroxypyridones and their uses |
| DE102005051325A1 (de) | 2005-10-27 | 2007-05-03 | Bayer Cropscience Ag | Alkoxyalkyl spirocyclische Tetram- und Tetronsäuren |
| DE102005059892A1 (de) | 2005-12-15 | 2007-06-28 | Bayer Cropscience Ag | Alkylthio-spirocyclische Tetramsäuren |
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| DE102006007882A1 (de) | 2006-02-21 | 2007-08-30 | Bayer Cropscience Ag | Cycloalkyl-phenylsubstituierte cyclische Ketoenole |
| DE102006018828A1 (de) | 2006-04-22 | 2007-10-25 | Bayer Cropscience Ag | Alkoxyalkyl-substituierte cyclische Ketoenole |
| DE102006025874A1 (de) | 2006-06-02 | 2007-12-06 | Bayer Cropscience Ag | Alkoxyalkyl-substituierte cyclische Ketoenole |
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| DE102006057036A1 (de) | 2006-12-04 | 2008-06-05 | Bayer Cropscience Ag | Biphenylsubstituierte spirocyclische Ketoenole |
| DE102006057037A1 (de) | 2006-12-04 | 2008-06-05 | Bayer Cropscience Ag | cis-Alkoxyspirocyclische biphenylsubstituierte Tetramsäure-Derivate |
| WO2008128058A1 (en) | 2007-04-13 | 2008-10-23 | The Trustees Of The University Of Pennsylvania | New gallium bisaminothiolate complexes for myocardial imaging |
| EP1992614A1 (de) | 2007-05-16 | 2008-11-19 | Bayer CropScience Aktiengesellschaft | 3-(2-Alkoxy-phenyl)-substituierte Tetramate |
| EP2020413A1 (de) | 2007-08-02 | 2009-02-04 | Bayer CropScience AG | Oxaspirocyclische-spiro-substituierte Tetram- und Tetronsäure-Derivate |
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| GB0720126D0 (en) | 2007-10-15 | 2007-11-28 | Syngenta Participations Ag | Chemical compounds |
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| GB0820344D0 (en) | 2008-11-06 | 2008-12-17 | Syngenta Ltd | Herbicidal compositions |
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| AU2010223535B2 (en) | 2009-03-11 | 2015-09-10 | Bayer Intellectual Property Gmbh | Halogenalkylmethylenoxy-phenyl-substituted ketoenols |
| WO2010113831A1 (ja) | 2009-03-31 | 2010-10-07 | 東レ株式会社 | 発光素子材料前駆体およびその製造方法 |
| GB0921343D0 (en) | 2009-12-04 | 2010-01-20 | Syngenta Participations Ag | Chemical compounds |
| ES2700996T3 (es) | 2010-02-10 | 2019-02-20 | Bayer Cropscience Ag | Cetoenoles cíclicos sustituidos con bifenilo |
| ES2545113T3 (es) | 2010-02-10 | 2015-09-08 | Bayer Intellectual Property Gmbh | Derivados de ácido tetrámico sustituidos de manera espiroheterocíclica |
| DE102010008643A1 (de) | 2010-02-15 | 2011-08-18 | Bayer Schering Pharma Aktiengesellschaft, 13353 | Zyklische Ketoenole zur Therapie |
| DE102010008642A1 (de) | 2010-02-15 | 2011-08-18 | Bayer Schering Pharma Aktiengesellschaft, 13353 | Zyklische Ketoenole zur Therapie |
| DE102010008644A1 (de) | 2010-02-15 | 2011-08-18 | Bayer Schering Pharma Aktiengesellschaft, 13353 | Zyklische Ketoenole zur Therapie |
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2012
- 2012-01-20 DK DK12700832.4T patent/DK2668158T3/da active
- 2012-01-20 TW TW101102391A patent/TWI545112B/zh active
- 2012-01-20 EP EP18162778.7A patent/EP3372580B1/de active Active
- 2012-01-20 JP JP2013549824A patent/JP5951642B2/ja active Active
- 2012-01-20 ES ES12700832.4T patent/ES2689149T3/es active Active
- 2012-01-20 WO PCT/EP2012/050840 patent/WO2012101047A1/de active Application Filing
- 2012-01-20 BR BR112013018973A patent/BR112013018973A2/pt not_active Application Discontinuation
- 2012-01-20 KR KR1020137022290A patent/KR101841320B1/ko active IP Right Grant
- 2012-01-20 KR KR1020177027120A patent/KR101813849B1/ko active IP Right Grant
- 2012-01-20 MX MX2013008361A patent/MX2013008361A/es active IP Right Grant
- 2012-01-20 CN CN201611177332.2A patent/CN106905215B/zh active Active
- 2012-01-20 MX MX2015013868A patent/MX343856B/es unknown
- 2012-01-20 EP EP12700832.4A patent/EP2668158B1/de active Active
- 2012-01-20 DK DK18162778.7T patent/DK3372580T3/da active
- 2012-01-20 CN CN2012800145809A patent/CN103459370A/zh active Pending
- 2012-01-25 US US13/358,348 patent/US8859782B2/en active Active
-
2013
- 2013-07-22 IL IL227590A patent/IL227590B/en active IP Right Grant
-
2014
- 2014-08-29 US US14/472,754 patent/US9272997B2/en active Active
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2016
- 2016-11-02 IL IL248698A patent/IL248698B/en active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| MX2013008361A (es) | 2013-08-27 |
| KR101841320B1 (ko) | 2018-03-22 |
| EP3372580A1 (de) | 2018-09-12 |
| EP2668158A1 (de) | 2013-12-04 |
| TWI545112B (zh) | 2016-08-11 |
| US8859782B2 (en) | 2014-10-14 |
| ES2689149T3 (es) | 2018-11-08 |
| US20140371468A1 (en) | 2014-12-18 |
| KR20170115625A (ko) | 2017-10-17 |
| DK2668158T3 (da) | 2018-10-15 |
| TW201309640A (zh) | 2013-03-01 |
| CN103459370A (zh) | 2013-12-18 |
| BR112013018973A2 (pt) | 2017-09-19 |
| US20120190865A1 (en) | 2012-07-26 |
| KR20140009319A (ko) | 2014-01-22 |
| KR101813849B1 (ko) | 2017-12-29 |
| IL248698B (en) | 2018-10-31 |
| JP2014504595A (ja) | 2014-02-24 |
| MX343856B (es) | 2016-11-25 |
| WO2012101047A1 (de) | 2012-08-02 |
| CN106905215B (zh) | 2021-10-01 |
| US9272997B2 (en) | 2016-03-01 |
| IL227590B (en) | 2018-01-31 |
| EP3372580B1 (de) | 2020-07-22 |
| IL248698A0 (en) | 2016-12-29 |
| CN106905215A (zh) | 2017-06-30 |
| JP5951642B2 (ja) | 2016-07-13 |
| IL227590A0 (en) | 2013-09-30 |
| EP2668158B1 (de) | 2018-06-27 |
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