DK3009456T3 - Ethylencopolymer til geomembrananvendelser - Google Patents
Ethylencopolymer til geomembrananvendelser Download PDFInfo
- Publication number
- DK3009456T3 DK3009456T3 DK14188837.0T DK14188837T DK3009456T3 DK 3009456 T3 DK3009456 T3 DK 3009456T3 DK 14188837 T DK14188837 T DK 14188837T DK 3009456 T3 DK3009456 T3 DK 3009456T3
- Authority
- DK
- Denmark
- Prior art keywords
- ethylene copolymer
- polyethylene fraction
- range
- iso
- flow rate
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
- B29C48/08—Flat, e.g. panels flexible, e.g. films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/12—Melt flow index or melt flow ratio
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/18—Bulk density
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/19—Shear ratio or shear ratio index
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/14—Gas barrier composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/02—Ziegler natta catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Laminated Bodies (AREA)
Claims (14)
1. Ethylencopolymer (PE-C) omfattende mindst (a) en første polyethylenfraktion (PE-F1), hvilken fraktion er en ethylenho-mopolymer, (b) en anden polyethylenfraktion (PE-F2), hvilken fraktion er en ethylencopolymer af ethylen og 1-buten, hvor (c) ethylencopolymeren (PE-C) har en smelte-flow rate MFR21 (190 °C; 21,6 kg), målt i henhold til ISO 1133, i området 2,0 til 60 g/10 min; (d) den første polyethylenfraktion (PE-F1) har en smelte-flow rate MFR2 (190 °C; 2,16 kg), målt i henhold til ISO 1133, i området 200 til 500 g/10 min; (e) ethylencopolymeren (PE-C) har en densitet målt i henhold til ISO 1 183 / 1 872-2 B i området 0,919 til 0,954 g/cm3; og (f) ethylencopolymeren (PE-C) opfylder uligheden (Ila) 500 < ^”2(PEF1) < 1000 (Ila) MFR 5{PEC) v ' hvor MFR2(PF1) er smelte-flow rate MFR2 (190 °C; 2,16 kg), målt i henhold til ISO 1133, af den første polyethylenfraktion (PE-F1); MFR5(PEC) er smelte-flow rate MFR5 (190 °C; 5 kg), målt i henhold til ISO 1133, af ethylencopolymeren (PE-C).
2. Ethylencopolymer (PE-C) ifølge krav 1, hvor den første polyethylenfraktion (PE-F1) har en densitet, målt i henhold til ISO 1 183 / 1 872-2 B, på mere end 0,965 g/cm3.
3. Ethylencopolymer (PE-C) ifølge krav 1 eller 2, hvor ethylencopolymeren (PE-C) har en densitet, målt i henhold til ISO 1 183 / 1 872-2 B, i området 0,935 til 0,943 g/cm3.
4. Ethylencopolymer (PE-C) ifølge et hvilket som helst af de foregående krav, hvor (a) vægtforholdet mellem den første polyethylenfraktion (PE-F1) og den anden polyethylenfraktion (PE-F2) er lig med eller under 1,0, fortrinsvis i området 3,5/9,0 til 4,0/5,0; og/eller (b) mængden af den første polyethylenfraktion (PE-F1) er i området 30 til lig med eller under 45 vægt-%, og mængden af den anden polyethylenfraktion (PE-F2) er i området lig med eller under 55 til 70 vægt-%, baseret på den samlede mængde af ethylencopolymeren (PE-C).
5. Ethylencopolymer (PE-C) ifølge et hvilket som helst af de foregående krav, hvor ethylencopolymeren (PE-C) har (a) en molekylvægtfordeling (Mw/Mn) i området 15 til 45; og/eller (b) et shear thinning-indeks SHI(2,7/210), som er forholdet af viskositeten ved et komplekst modul på 2,7 kPa og på 210 kPa på mindst 20,0; og/eller (c) et polydispersitetsindeks (PDI) på mindst 1,7.
6. Ethylencopolymer (PE-C) ifølge et hvilket som helst af de foregående krav, hvor ethylencopolymeren (PE-C) har et flow rate-forhold (FFR; MFR2i/MFR5) på mindst 11, hvor MFR5 er smelte-flow rate MFR5 (190 °C; 5 kg) målt i henhold til ISO 1133.
7. Ethylencopolymer (PE-C) ifølge et hvilket som helst af de foregående krav, hvor den anden polyethylenfraktion (PE-F2) har en densitet i området 0,912 til 0,935 g/cm3.
8. Ethylencopolymer (PE-C) ifølge et hvilket som helst af de foregående krav, hvor ethylencopolymeren (PE-C) opfylder uligheden (I) AfFR2(PEFl) MFR21(PEC) “ 5‘° hvor MFR2(PF1) er smelte-flow rate MFR2 (190 °C; 2,16 kg) målt i henhold til ISO 1133, af den første polyethylenfraktion (PE-F1): MFR21(PEC) er smelte-flow rate MFR2i (190 °C; 21,6 kg), målt i henhold til ISO 1133, af ethylencopolymeren (PE-C).
9. Ethylencopolymer (PE-C) ifølge et hvilket som helst af de foregående krav, hvor ethylencopolymeren (PE-C) har en nominel belastning ved brud på mindst 700 %.
10. Geomembran omfattende en ethylencopolymer (PE-C) ifølge et hvilket som helst af de foregående krav.
11. Geomembran ifølge krav 10, hvor mindst ét lag af geomembranen omfatter, fortrinsvis omfatter med mindst 90 vægt-% baseret på den samlede vægt af laget, ethylencopolymeren (PE-C) ifølge et hvilket som helst af de foregående krav 1 til 10.
12. Geomembran ifølge krav 10 eller 11, hvor geomembranen er fremstillet ved ekstrudering.
13. Fremgangsmåde til fremstilling af en ethylencopolymer (PE-C) ifølge et hvilket som helst af de foregående krav 1 til 9, hvor fremgangsmåden er en sekventiel polymerisationsproces omfattende mindst to reaktorer, der er serieforbundet, hvor der i den første reaktor (1. R), fortrinsvis en loop-reaktor (LR), fremstilles den første polyethylenfraktion (PE-F1), og der i den efterfølgende anden reaktor (2. R), fortrinsvis i gas-fase-reaktoren (GPR), fremstilles den anden polyethylenfraktion (PE-F2) i nærvær af den første polyethylenfraktion (PE-F1).
14. Fremgangsmåde ifølge krav 13, hvor polymerisationen finder sted i nærvær af en Ziegler-Natta-katalysator.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP14188837.0A EP3009456B1 (en) | 2014-10-14 | 2014-10-14 | Ethylene copolymer for geomembrane applications |
Publications (1)
Publication Number | Publication Date |
---|---|
DK3009456T3 true DK3009456T3 (da) | 2017-07-31 |
Family
ID=51703025
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DK14188837.0T DK3009456T3 (da) | 2014-10-14 | 2014-10-14 | Ethylencopolymer til geomembrananvendelser |
Country Status (8)
Country | Link |
---|---|
EP (2) | EP3009456B1 (da) |
KR (1) | KR101867249B1 (da) |
CN (1) | CN107108918B (da) |
CL (1) | CL2017000870A1 (da) |
DK (1) | DK3009456T3 (da) |
PE (1) | PE20171545A1 (da) |
SA (1) | SA517381309B1 (da) |
WO (1) | WO2016058968A1 (da) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109415544B (zh) * | 2016-05-31 | 2022-07-05 | 博里利斯股份公司 | 聚合物组合物以及用于生产该聚合物组合物的方法 |
WO2023217750A1 (en) * | 2022-05-12 | 2023-11-16 | Borealis Ag | Polyethylene copolymer for a film layer |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FI86867C (fi) | 1990-12-28 | 1992-10-26 | Neste Oy | Flerstegsprocess foer framstaellning av polyeten |
FI942949A0 (fi) | 1994-06-20 | 1994-06-20 | Borealis Polymers Oy | Prokatalysator foer producering av etenpolymerer och foerfarande foer framstaellning daerav |
FI101546B1 (fi) * | 1994-12-16 | 1998-07-15 | Borealis Polymers Oy | Polyeteenikompositio |
WO1997003139A1 (en) * | 1995-07-10 | 1997-01-30 | Borealis Polymers Oy | Coating composition |
US5767034A (en) | 1996-05-31 | 1998-06-16 | Intevep, S.A. | Olefin polymerization catalyst with additive comprising aluminum-silicon composition, calixarene derivatives or cyclodextrin derivatives |
US5736237A (en) | 1996-11-25 | 1998-04-07 | Union Carbide Chemicals & Plastics Technology Corporation | Geomembranes |
FI111372B (fi) | 1998-04-06 | 2003-07-15 | Borealis Polymers Oy | Olefiinien polymerointiin tarkoitettu katalyyttikomponentti, sen valmistus ja käyttö |
GB0001914D0 (en) | 2000-01-27 | 2000-03-22 | Borealis Polymers Oy | Catalyst |
US6953828B2 (en) * | 2001-10-15 | 2005-10-11 | Exxonmobil Chemical Patents, Inc. | Polymeric membrane compositions |
ATE478114T1 (de) | 2002-06-20 | 2010-09-15 | Borealis Tech Oy | Atmende filme |
EP1674504A1 (en) | 2004-12-22 | 2006-06-28 | Total Petrochemicals Research Feluy | Geo-membrane applications |
EP2172510A1 (en) * | 2008-10-01 | 2010-04-07 | Dow Global Technologies Inc. | Barrier films and method for making and using the same |
-
2014
- 2014-10-14 EP EP14188837.0A patent/EP3009456B1/en active Active
- 2014-10-14 DK DK14188837.0T patent/DK3009456T3/da active
-
2015
- 2015-10-12 PE PE2017000704A patent/PE20171545A1/es unknown
- 2015-10-12 WO PCT/EP2015/073508 patent/WO2016058968A1/en active Application Filing
- 2015-10-12 EP EP15775744.4A patent/EP3207065B1/en active Active
- 2015-10-12 KR KR1020177012242A patent/KR101867249B1/ko active IP Right Grant
- 2015-10-12 CN CN201580054017.8A patent/CN107108918B/zh active Active
-
2017
- 2017-04-10 CL CL2017000870A patent/CL2017000870A1/es unknown
- 2017-04-12 SA SA517381309A patent/SA517381309B1/ar unknown
Also Published As
Publication number | Publication date |
---|---|
EP3207065A1 (en) | 2017-08-23 |
WO2016058968A1 (en) | 2016-04-21 |
CN107108918A (zh) | 2017-08-29 |
SA517381309B1 (ar) | 2022-04-28 |
CN107108918B (zh) | 2020-07-03 |
EP3009456B1 (en) | 2017-06-21 |
EP3009456A1 (en) | 2016-04-20 |
CL2017000870A1 (es) | 2018-02-09 |
KR20170067821A (ko) | 2017-06-16 |
KR101867249B1 (ko) | 2018-06-12 |
EP3207065B1 (en) | 2019-09-18 |
PE20171545A1 (es) | 2017-10-27 |
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