DK2883632T3 - Metallisk skumlegeme med kontrolleret kornstørrelse på overfladen, fremgangsmåde til produktion og brug heraf - Google Patents
Metallisk skumlegeme med kontrolleret kornstørrelse på overfladen, fremgangsmåde til produktion og brug heraf Download PDFInfo
- Publication number
- DK2883632T3 DK2883632T3 DK13196540.2T DK13196540T DK2883632T3 DK 2883632 T3 DK2883632 T3 DK 2883632T3 DK 13196540 T DK13196540 T DK 13196540T DK 2883632 T3 DK2883632 T3 DK 2883632T3
- Authority
- DK
- Denmark
- Prior art keywords
- metal
- metallic
- foam body
- foam
- metallic foam
- Prior art date
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- 239000006262 metallic foam Substances 0.000 title claims description 80
- 238000000034 method Methods 0.000 title claims description 33
- 238000004519 manufacturing process Methods 0.000 title claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 57
- 239000002184 metal Substances 0.000 claims description 57
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 40
- 239000006260 foam Substances 0.000 claims description 35
- 238000000151 deposition Methods 0.000 claims description 29
- 239000000758 substrate Substances 0.000 claims description 27
- 229910052709 silver Inorganic materials 0.000 claims description 23
- 229920005830 Polyurethane Foam Polymers 0.000 claims description 18
- 229920000620 organic polymer Polymers 0.000 claims description 18
- 239000011496 polyurethane foam Substances 0.000 claims description 18
- 239000004332 silver Substances 0.000 claims description 18
- 238000009713 electroplating Methods 0.000 claims description 16
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 15
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 14
- 239000003054 catalyst Substances 0.000 claims description 14
- 229910052759 nickel Inorganic materials 0.000 claims description 12
- 229910045601 alloy Inorganic materials 0.000 claims description 9
- 239000000956 alloy Substances 0.000 claims description 9
- 239000004814 polyurethane Substances 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 7
- 238000005229 chemical vapour deposition Methods 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 229910052802 copper Inorganic materials 0.000 claims description 4
- 238000005240 physical vapour deposition Methods 0.000 claims description 4
- -1 polyethylene Polymers 0.000 claims description 4
- 239000002243 precursor Substances 0.000 claims description 4
- 238000010521 absorption reaction Methods 0.000 claims description 3
- 238000001311 chemical methods and process Methods 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 238000001179 sorption measurement Methods 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 238000010304 firing Methods 0.000 claims 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 18
- 230000008021 deposition Effects 0.000 description 18
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 16
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 239000011148 porous material Substances 0.000 description 6
- 210000004027 cell Anatomy 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229920002635 polyurethane Polymers 0.000 description 5
- 238000012546 transfer Methods 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000001419 dependent effect Effects 0.000 description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 3
- 229910052737 gold Inorganic materials 0.000 description 3
- 239000010931 gold Substances 0.000 description 3
- 239000013528 metallic particle Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000004544 sputter deposition Methods 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 239000010937 tungsten Substances 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 238000001493 electron microscopy Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000004848 polyfunctional curative Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 230000005465 channeling Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000006261 foam material Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 238000007327 hydrogenolysis reaction Methods 0.000 description 1
- 238000003384 imaging method Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000006317 isomerization reaction Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000010808 liquid waste Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000005932 reductive alkylation reaction Methods 0.000 description 1
- 238000006268 reductive amination reaction Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 238000007613 slurry method Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000009718 spray deposition Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/11—Making porous workpieces or articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/11—Making porous workpieces or articles
- B22F3/1121—Making porous workpieces or articles by using decomposable, meltable or sublimatable fillers
- B22F3/1137—Making porous workpieces or articles by using decomposable, meltable or sublimatable fillers by coating porous removable preforms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F7/00—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F7/00—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
- B22F7/002—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of porous nature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
- B32B15/018—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of a noble metal or a noble metal alloy
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/043—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/046—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of foam
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/08—Alloys with open or closed pores
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/0005—Separation of the coating from the substrate
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/04—Coating on selected surface areas, e.g. using masks
- C23C14/046—Coating cavities or hollow spaces, e.g. interior of tubes; Infiltration of porous substrates
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/20—Metallic material, boron or silicon on organic substrates
- C23C14/205—Metallic material, boron or silicon on organic substrates by cathodic sputtering
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/58—After-treatment
- C23C14/5846—Reactive treatment
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/58—After-treatment
- C23C14/5873—Removal of material
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D1/00—Electroforming
- C25D1/08—Perforated or foraminous objects, e.g. sieves
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/46—Electroplating: Baths therefor from solutions of silver
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/10—Electroplating with more than one layer of the same or of different metals
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/34—Pretreatment of metallic surfaces to be electroplated
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/60—Electroplating characterised by the structure or texture of the layers
- C25D5/615—Microstructure of the layers, e.g. mixed structure
- C25D5/617—Crystalline layers
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/60—Electroplating characterised by the structure or texture of the layers
- C25D5/623—Porosity of the layers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Crystallography & Structural Chemistry (AREA)
- Electroplating Methods And Accessories (AREA)
- Cell Electrode Carriers And Collectors (AREA)
- Laminated Bodies (AREA)
- Catalysts (AREA)
Claims (9)
1. Metallisk skumlegeme, bestående af (a) et metallisk skumlegemesubstrat fremstillet af mindst ét metal eller én metallegering A, og (b) et lag af et metal eller en metallegering B på i det mindste en del af overfladen af det metalliske skumlegemesubstrat (a), hvor A og B adskiller sig fra hinanden ved metallets eller metallegeringens komstørrelse, der kan opnås ved en fremgangsmåde bestående af følgende trin: (i) tilvejebringelse af en porøs organisk polymerskum, (ii) afsætning af mindst ét metal eller én metallegering A på den porøse organiske polymerskum, (iii) afbrænding af den porøse organiske polymerskum til opnåelse af det metalliske skumlegemesubstrat (a), og (iv) afsætning ved hjælp af galvanisering af det metalliske lag (b) af et metal eller en metallegering B på i det mindste en del af overfladen af det metalliske skumlegeme 00, hvor trin (ii) består af følgende trin: (111) afsætning af et første metallisk lag indeholdende et metal eller en metallegering Al ved hjælp af en kemisk eller fysisk dampafsætningsmetode, og (112) afsætning af et andet metallisk lag indeholdende et metal eller en metallegering A2 ved hjælp af galvanisering, hvor Al og A2 er identiske eller adskiller sig, og hvor Al er valgt fra en gruppe bestående af Ni, Cr, Co, Cu, Ag og en hvilken som helst legering heraf, og hvor A2 og B er sølv.
2. Metallisk skumlegeme ifølge krav 1, hvor den gennemsnitlige tykkelse af det første metalliske lag er fra 0,1 til 3 pm, og den gennemsnitlige tykkelse af det andet metalliske lag er fra 5 til 50 pm.
3. Metallisk skumlegeme ifølge krav 1 eller 2, hvor det porøse organiske polymerskum er valgt fra gruppen bestående af polyurethan (PU)-skum, polyethylenskum og polypropylenskum.
4. Metallisk skumlegeme ifølge hvilket som helst af kravene 1 til 3, hvor den gennemsnitlige tykkelse af lag (b) af metallet eller metallegeringen B er fra 5 til 200 gm.
5. Metallisk skumlegeme ifølge hvilket som helst af kravene 1 til 4, hvor laget (b) af metallet eller metallegeringen B findes på hele overfladen af det metalliske skumlegemesubstrat (a).
6. Fremgangsmåde til produktion af et metallisk skumlegeme, hvor det metalliske skumlegeme består af (a) et metallisk skumlegemesubstrat fremstillet af mindst ét metal eller én metallegering A, og (b) et lag af et metal eller en metallegering B på i det mindste en del af overfladen af det metalliske skumlegemesubstrat (a), hvor A og B adskiller sig fra hinanden ved metallets eller metallegeringens komstørrelse, bestående af følgende trin: (i) tilvejebringelse af en porøs organisk polymerskum, (ii) afsætning af i det mindste et første metal eller en metallegering A på den porøse organiske polymerskum, (iii) afbrænding af den porøse organiske polymerskum til opnåelse af det metalliske skumlegemesubstrat (a), og (iv) afsætning ved hjælp af galvanisering af det metalliske lag (b) af metallet eller metallegeringen B på i det mindste en del af overfladen af det metalliske skumlegemesubstrat (a), hvor trin (ii) består af følgende trin: (111) afsætning af et første metallisk lag indeholdende et metal eller en metallegering Al ved hjælp af en kemisk eller fysisk dampafsætningsmetode, og (112) afsætning af et andet metallisk lag indeholdende et metal eller en metallegering A2 ved hjælp af galvanisering, hvor Al og A2 er identiske eller adskiller sig, og hvor Al er valgt fra en gruppe bestående af Ni, Cr, Co, Cu, Ag og en hvilken som helst legering heraf, og hvor A2 og B er sølv.
7. Fremgangsmåde ifølge krav 6, bestående af følgende trin: (il) tilvejebringelse af en porøs polyurethanskum, (ii3) afsætning af Ag i et lag med en tykkelse på 5 til 50 pm på polyurethanskummet, og (iiil) afbrænding af polyurethanskummet ved en temperatur i området fra 300 til 850°C med henblik på at opnå det metalliske skumlegemesubstrat (a), og (ivl) afsætning af Ag i et lag med en tykkelse af 1 til 200 pm ved hjælp af galvanisering på det metalliske skumlegemesubstrat (a) opnået ved trin (iiil).
8. Brug af det metalliske skumlegeme ifølge hvilket som helst af kravene 1 til 5 i en fysisk adsorptions- eller absorptionsproces eller i en kemisk proces.
9. Brug ifølge krav 8, hvor det metalliske skumlegeme ifølge hvilket som helst af kravene 1 til 5 bruges som en prækursor til en katalysator eller en katalysator i en fremgangsmåde til produktion af formaldehyd ved oxidering af metanol.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13196540.2A EP2883632B1 (en) | 2013-12-10 | 2013-12-10 | Metallic foam body with controlled grain size on its surface, process for its production and use thereof |
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| DK2883632T3 true DK2883632T3 (da) | 2017-10-16 |
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| EP (1) | EP2883632B1 (da) |
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| DK (1) | DK2883632T3 (da) |
| ES (1) | ES2638091T3 (da) |
| RU (1) | RU2652674C2 (da) |
| WO (1) | WO2015086703A1 (da) |
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| EP2883632B1 (en) * | 2013-12-10 | 2017-07-05 | Alantum Europe GmbH | Metallic foam body with controlled grain size on its surface, process for its production and use thereof |
| US9863045B2 (en) * | 2015-03-24 | 2018-01-09 | Council Of Scientific & Industrial Research | Electrochemical process for the preparation of lead foam |
| CN104975309B (zh) * | 2015-06-12 | 2017-07-07 | 东南大学 | 一种开孔泡沫铜孔径调控方法 |
| DE202015103789U1 (de) * | 2015-07-17 | 2015-07-31 | Abb Technology Ag | Oberflächentemperaturfühler |
| CN106245072B (zh) * | 2016-08-25 | 2018-03-02 | 山东清大银光金属海绵新材料有限责任公司 | 孔隙率/成分双梯度的海绵结构型铜硒合金的制备方法 |
| CN106224077A (zh) * | 2016-08-29 | 2016-12-14 | 江苏嘉和热***股份有限公司 | 一种汽车散热器芯体 |
| EP3354337B1 (de) * | 2017-01-31 | 2021-04-14 | Alantum Europe GmbH | Verfahren zum herstellen eines metallschaumpellets, metallschaumpellet, katalysatorfüllung und statischer mischer |
| EP3585515A1 (de) | 2017-02-24 | 2020-01-01 | Basf Se | Silber-katalysatorsystem mit verringertem druckabfall zur oxidativen dehydrierung von alkoholen |
| DE102017216569A1 (de) * | 2017-09-19 | 2019-03-21 | Alantum Europe Gmbh | Verfahren zur Herstellung eines offenporösen Formkörpers, der mit einem Metall gebildet ist und einen mit dem Verfahren hergestellten Formkörper |
| KR102191613B1 (ko) * | 2017-09-15 | 2020-12-15 | 주식회사 엘지화학 | 복합재 |
| DE102017216566A1 (de) * | 2017-09-19 | 2019-03-21 | Alantum Europe Gmbh | Verfahren zur Herstellung eines offenporösen Formkörpers mit modifizierter Oberfläche, der mit einem Metall gebildet ist und einen mit dem Verfahren hergestellten Formkörper |
| WO2019106879A1 (ja) * | 2017-11-29 | 2019-06-06 | 住友電気工業株式会社 | 金属多孔体、燃料電池及び金属多孔体の製造方法 |
| CN108070839B (zh) * | 2017-12-18 | 2020-01-17 | 常德力元新材料有限责任公司 | 一种泡沫镍铬合金的连续制备方法 |
| CN110066935B (zh) * | 2018-01-23 | 2020-05-12 | 清华大学 | 泡沫金属制备装置及制备方法 |
| CN108300969B (zh) * | 2018-03-14 | 2020-02-25 | 河南科技大学 | 一种低电阻泡沫金属的制备方法 |
| EP3539657A1 (en) | 2018-03-14 | 2019-09-18 | Basf Se | Improved catalysts comprising silver based intermetallic compounds |
| DE102018212110A1 (de) * | 2018-07-20 | 2020-01-23 | Alantum Europe Gmbh | Offenporiger Metallkörper mit einer Oxidschicht und Verfahren zu dessen Herstellung |
| EP3797901B1 (de) | 2019-09-25 | 2021-09-08 | Evonik Operations GmbH | Metallschaumkörper und verfahren zu seiner herstellung |
| WO2021058704A1 (de) * | 2019-09-25 | 2021-04-01 | Evonik Operations Gmbh | Metallschaumkörper und verfahren zu ihrer herstellung sowie deren verwendung als katalysator |
| PL3817852T3 (pl) | 2019-09-25 | 2022-08-01 | Evonik Operations Gmbh | Reaktor katalityczny |
| CN115323316B (zh) * | 2022-08-16 | 2023-05-23 | 沈伟 | 一种泡沫镍铬合金及其制备方法 |
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| NL7607390A (nl) * | 1975-07-09 | 1977-01-11 | Montedison Spa | Werkwijze voor de vervaardiging van metallische en/of metaalkeramische en/of keramische spons. |
| US5640669A (en) * | 1995-01-12 | 1997-06-17 | Sumitomo Electric Industries, Ltd. | Process for preparing metallic porous body, electrode substrate for battery and process for preparing the same |
| JPH08225866A (ja) * | 1995-02-22 | 1996-09-03 | Sumitomo Electric Ind Ltd | 三次元網状構造金属多孔体およびその製造方法 |
| RU2188880C2 (ru) * | 2000-05-11 | 2002-09-10 | Открытое акционерное общество "Новосибирский завод химконцентратов" | Способ получения металлической пены |
| RU2003125636A (ru) * | 2001-01-16 | 2005-02-27 | Агс Тарон Инвестментс Инк. (Ca) Агс Тарон Инвестментс Инк. (Ca) | Способ получения металлической пены или металлокомпозитных объектов с улучшенными прочностными, термическими и звукопоглощающими совйствами |
| EP1477578A1 (en) * | 2003-05-15 | 2004-11-17 | Efoam S.A. | Method for producing a metal coated heavy metal foam |
| US20060034722A1 (en) * | 2004-08-10 | 2006-02-16 | Pan-Ting Hsueh | Sintered porous frame and its producing method |
| WO2006111837A2 (fr) * | 2005-04-21 | 2006-10-26 | Pillet, Michel | Procede de fabrication de mousse de metal |
| US20090081444A1 (en) * | 2005-05-30 | 2009-03-26 | Markus Kattannek | Porous metal foam body |
| CN100372808C (zh) * | 2006-04-18 | 2008-03-05 | 中国建筑材料科学研究院大石桥镁砖厂 | 含锆镁砖制造方法 |
| KR100803214B1 (ko) * | 2006-06-28 | 2008-02-14 | 삼성전자주식회사 | 유기막을 채용한 전사필름 및 이를 이용한 금속막 형성방법 |
| US20080081007A1 (en) * | 2006-09-29 | 2008-04-03 | Mott Corporation, A Corporation Of The State Of Connecticut | Sinter bonded porous metallic coatings |
| CN101855072A (zh) * | 2007-09-11 | 2010-10-06 | 格拉弗技术国际控股有限公司 | 被涂覆的碳泡沫制品 |
| US9005420B2 (en) * | 2007-12-20 | 2015-04-14 | Integran Technologies Inc. | Variable property electrodepositing of metallic structures |
| US9758891B2 (en) * | 2008-07-07 | 2017-09-12 | Modumetal, Inc. | Low stress property modulated materials and methods of their preparation |
| JP5574761B2 (ja) * | 2009-04-17 | 2014-08-20 | 国立大学法人山形大学 | 被覆銀超微粒子とその製造方法 |
| JP2012033423A (ja) * | 2010-08-02 | 2012-02-16 | Sumitomo Electric Ind Ltd | 金属多孔体およびその製造方法、それを用いた電池 |
| JP2012082483A (ja) * | 2010-10-13 | 2012-04-26 | Sumitomo Electric Ind Ltd | 金属多孔体とその製造方法、および溶融塩電池 |
| EP2650393A4 (en) * | 2010-12-08 | 2015-02-25 | Sumitomo Electric Industries | POROUS METALLIC BODY HAVING HIGH CORROSION RESISTANCE AND METHOD FOR MANUFACTURING THE SAME |
| JP5691107B2 (ja) * | 2011-01-17 | 2015-04-01 | 富山住友電工株式会社 | 高耐食性を有する金属多孔体及びその製造方法 |
| EP3216522A1 (en) * | 2013-02-06 | 2017-09-13 | Alantum Europe GmbH | Surface modified metallic foam body, process for its production and use thereof |
| EP2883632B1 (en) * | 2013-12-10 | 2017-07-05 | Alantum Europe GmbH | Metallic foam body with controlled grain size on its surface, process for its production and use thereof |
-
2013
- 2013-12-10 EP EP13196540.2A patent/EP2883632B1/en active Active
- 2013-12-10 DK DK13196540.2T patent/DK2883632T3/da active
- 2013-12-10 ES ES13196540.2T patent/ES2638091T3/es active Active
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2014
- 2014-07-14 CN CN201410334584.6A patent/CN104691046B/zh active Active
- 2014-12-10 RU RU2016127840A patent/RU2652674C2/ru active
- 2014-12-10 CN CN201480066062.0A patent/CN105848811A/zh active Pending
- 2014-12-10 US US15/038,958 patent/US20170167041A1/en not_active Abandoned
- 2014-12-10 WO PCT/EP2014/077276 patent/WO2015086703A1/en active Application Filing
- 2014-12-10 KR KR1020187012008A patent/KR102099169B1/ko active IP Right Grant
- 2014-12-10 KR KR1020167015516A patent/KR20160096096A/ko active Application Filing
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Also Published As
| Publication number | Publication date |
|---|---|
| ES2638091T3 (es) | 2017-10-18 |
| EP2883632B1 (en) | 2017-07-05 |
| WO2015086703A1 (en) | 2015-06-18 |
| US20210010146A1 (en) | 2021-01-14 |
| EP2883632A1 (en) | 2015-06-17 |
| KR20160096096A (ko) | 2016-08-12 |
| KR102099169B1 (ko) | 2020-04-09 |
| RU2652674C2 (ru) | 2018-04-28 |
| CN104691046B (zh) | 2017-12-22 |
| CN104691046A (zh) | 2015-06-10 |
| US20170167041A1 (en) | 2017-06-15 |
| CN105848811A (zh) | 2016-08-10 |
| KR20180045073A (ko) | 2018-05-03 |
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