DK2585216T3 - Pi-allylpalladium- og pi-allylnickel-komplekser til anvendelse som katalysatorer i carbon-carbon- og carbon-nitrogen-koblingsreaktioner - Google Patents
Pi-allylpalladium- og pi-allylnickel-komplekser til anvendelse som katalysatorer i carbon-carbon- og carbon-nitrogen-koblingsreaktioner Download PDFInfo
- Publication number
- DK2585216T3 DK2585216T3 DK11728654.2T DK11728654T DK2585216T3 DK 2585216 T3 DK2585216 T3 DK 2585216T3 DK 11728654 T DK11728654 T DK 11728654T DK 2585216 T3 DK2585216 T3 DK 2585216T3
- Authority
- DK
- Denmark
- Prior art keywords
- carbon
- allylnickel
- catalysts
- coupling reactions
- complexes used
- Prior art date
Links
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 title 2
- CKUAXEQHGKSLHN-UHFFFAOYSA-N [C].[N] Chemical compound [C].[N] CKUAXEQHGKSLHN-UHFFFAOYSA-N 0.000 title 1
- CREMABGTGYGIQB-UHFFFAOYSA-N carbon carbon Chemical compound C.C CREMABGTGYGIQB-UHFFFAOYSA-N 0.000 title 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 title 1
- 239000003054 catalyst Substances 0.000 title 1
- 238000005859 coupling reaction Methods 0.000 title 1
- 229910052763 palladium Inorganic materials 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2286—Alkynes, e.g. acetylides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2291—Olefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2282—Unsaturated compounds used as ligands
- B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
- C07F15/006—Palladium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/04—Nickel compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
- B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
- B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
- B01J2231/4211—Suzuki-type, i.e. RY + R'B(OR)2, in which R, R' are optionally substituted alkyl, alkenyl, aryl, acyl and Y is the leaving group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
- B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
- B01J2231/4211—Suzuki-type, i.e. RY + R'B(OR)2, in which R, R' are optionally substituted alkyl, alkenyl, aryl, acyl and Y is the leaving group
- B01J2231/4227—Suzuki-type, i.e. RY + R'B(OR)2, in which R, R' are optionally substituted alkyl, alkenyl, aryl, acyl and Y is the leaving group with Y= Cl
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
- B01J2231/4205—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type
- B01J2231/4272—C-C cross-coupling, e.g. metal catalyzed or Friedel-Crafts type via enolates or aza-analogues, added as such or made in-situ, e.g. ArY + R2C=C(OM)Z -> ArR2C-C(O)Z, in which R is H or alkyl, M is Na, K or SiMe3, Y is the leaving group, Z is Ar or OR' and R' is alkyl
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/40—Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
- B01J2231/42—Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
- B01J2231/4277—C-X Cross-coupling, e.g. nucleophilic aromatic amination, alkoxylation or analogues
- B01J2231/4283—C-X Cross-coupling, e.g. nucleophilic aromatic amination, alkoxylation or analogues using N nucleophiles, e.g. Buchwald-Hartwig amination
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0202—Polynuclearity
- B01J2531/0205—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0286—Complexes comprising ligands or other components characterized by their function
- B01J2531/0288—Sterically demanding or shielding ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/847—Nickel
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US35774410P | 2010-06-23 | 2010-06-23 | |
PCT/GB2011/051171 WO2011161451A1 (en) | 2010-06-23 | 2011-06-22 | Complexes |
Publications (1)
Publication Number | Publication Date |
---|---|
DK2585216T3 true DK2585216T3 (da) | 2020-02-03 |
Family
ID=44532941
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DK11728654.2T DK2585216T3 (da) | 2010-06-23 | 2011-06-22 | Pi-allylpalladium- og pi-allylnickel-komplekser til anvendelse som katalysatorer i carbon-carbon- og carbon-nitrogen-koblingsreaktioner |
Country Status (8)
Country | Link |
---|---|
US (2) | US10167305B2 (da) |
EP (2) | EP2585216B1 (da) |
CN (1) | CN103037969B (da) |
DK (1) | DK2585216T3 (da) |
ES (1) | ES2769386T3 (da) |
PL (1) | PL2585216T3 (da) |
PT (1) | PT2585216T (da) |
WO (1) | WO2011161451A1 (da) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011161451A1 (en) * | 2010-06-23 | 2011-12-29 | Johnson Matthey Plc | Complexes |
US8933239B1 (en) | 2013-07-16 | 2015-01-13 | Dow Global Technologies Llc | Bis(aryl)acetal compounds |
US8962779B2 (en) | 2013-07-16 | 2015-02-24 | Dow Global Technologies Llc | Method of forming polyaryl polymers |
US9410016B2 (en) | 2013-07-16 | 2016-08-09 | Dow Global Technologies Llc | Aromatic polyacetals and articles comprising them |
US9063420B2 (en) | 2013-07-16 | 2015-06-23 | Rohm And Haas Electronic Materials Llc | Photoresist composition, coated substrate, and method of forming electronic device |
CN104031005B (zh) * | 2014-05-30 | 2016-04-27 | 济南诚汇双达化工有限公司 | 一种噻萘普汀钠中间体的制备方法 |
JP6657121B2 (ja) * | 2014-06-12 | 2020-03-04 | ジョンソン、マッセイ、パブリック、リミテッド、カンパニーJohnson Matthey Public Limited Company | 錯体 |
PL3154945T3 (pl) * | 2014-06-12 | 2021-09-27 | Johnson Matthey Public Limited Company | Kompleksy |
JP6791166B2 (ja) * | 2015-12-02 | 2020-11-25 | 住友化学株式会社 | 芳香族化合物の製造方法およびパラジウム錯体 |
CN105944761B (zh) * | 2016-04-29 | 2018-06-15 | 宁波大学 | 一种磺胺喹恶啉钴镍纳米复合材料及其制备方法 |
WO2018106338A1 (en) | 2016-12-06 | 2018-06-14 | Dow Global Technologies Llc | Mono-ligated palladium catalysts, their synthesis and use in suzuki coupling |
WO2018106336A1 (en) | 2016-12-06 | 2018-06-14 | Dow Global Technologies Llc | Mono-ligated palladium catalyts, their synthesis and use in suzuki coupling |
WO2018106337A1 (en) | 2016-12-06 | 2018-06-14 | Dow Global Technologies Llc | Mono-ligated palladium catalyts, their synthesis and use in suzuki coupling |
CN111116666B (zh) * | 2019-12-13 | 2020-12-29 | 中国科学院福建物质结构研究所 | 一种三苯基膦烯丙基卤化钯化合物及其衍生物的制备和应用 |
CN111848453B (zh) * | 2020-07-22 | 2022-09-02 | 浙江金立源药业有限公司 | 一种4-甲基-2’-氰基联苯生产工艺及生产线 |
CN112250715A (zh) * | 2020-10-29 | 2021-01-22 | 西安凯立新材料股份有限公司 | 一种氯(巴豆基)(3-叔-丁基磷)钯(ii)的制备方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5892101A (en) * | 1996-11-18 | 1999-04-06 | E. I. Du Pont De Nemours And Company | Cross-dimerization of olefins |
JP2002506836A (ja) | 1998-03-18 | 2002-03-05 | チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド | パラジウム触媒によるカップリング反応 |
WO2001016057A1 (en) | 1999-08-27 | 2001-03-08 | Ciba Specialty Chemicals Holding Inc. | Coupling reactions using palladium catalysts |
US6562989B2 (en) | 2000-08-07 | 2003-05-13 | Yale University | Catalyst for aromatic C—O, C—N, and C—C bond formation |
US6825198B2 (en) * | 2001-06-21 | 2004-11-30 | Pfizer Inc | 5-HT receptor ligands and uses thereof |
PE20080145A1 (es) | 2006-03-21 | 2008-02-11 | Janssen Pharmaceutica Nv | Tetrahidro-pirimidoazepinas como moduladores de trpv1 |
US7547757B2 (en) | 2006-08-01 | 2009-06-16 | Headwaters Technology Innovation, Llc | Methods for manufacturing aryl-aryl coupled polymers |
WO2011161451A1 (en) * | 2010-06-23 | 2011-12-29 | Johnson Matthey Plc | Complexes |
-
2011
- 2011-06-22 WO PCT/GB2011/051171 patent/WO2011161451A1/en active Application Filing
- 2011-06-22 ES ES11728654T patent/ES2769386T3/es active Active
- 2011-06-22 PL PL11728654T patent/PL2585216T3/pl unknown
- 2011-06-22 EP EP11728654.2A patent/EP2585216B1/en active Active
- 2011-06-22 US US13/806,575 patent/US10167305B2/en active Active
- 2011-06-22 EP EP19203075.7A patent/EP3613504A1/en not_active Withdrawn
- 2011-06-22 DK DK11728654.2T patent/DK2585216T3/da active
- 2011-06-22 CN CN201180037387.2A patent/CN103037969B/zh active Active
- 2011-06-22 PT PT117286542T patent/PT2585216T/pt unknown
-
2018
- 2018-09-20 US US16/136,685 patent/US10597416B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
EP2585216A1 (en) | 2013-05-01 |
EP3613504A1 (en) | 2020-02-26 |
PL2585216T3 (pl) | 2020-06-01 |
EP2585216B1 (en) | 2019-11-20 |
CN103037969A (zh) | 2013-04-10 |
US20190016742A1 (en) | 2019-01-17 |
WO2011161451A1 (en) | 2011-12-29 |
US20130165660A1 (en) | 2013-06-27 |
ES2769386T3 (es) | 2020-06-25 |
CN103037969B (zh) | 2015-07-29 |
US10597416B2 (en) | 2020-03-24 |
US10167305B2 (en) | 2019-01-01 |
PT2585216T (pt) | 2020-02-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
DK2585216T3 (da) | Pi-allylpalladium- og pi-allylnickel-komplekser til anvendelse som katalysatorer i carbon-carbon- og carbon-nitrogen-koblingsreaktioner | |
BRPI1012861A2 (pt) | catalisador, e, uso do catalisador | |
EP2659966A4 (en) | PT / GRAPHENE CATALYST, PREPARATION METHOD AND USE THEREOF | |
BR112012020718A2 (pt) | complexo de metal-ligante e catalisador | |
ZA201207969B (en) | Vanadia-based denox catalysts and catalyst supports | |
BR112013003705A2 (pt) | conduto de mistura, misturador estático e método para misturar | |
EP2659967A4 (en) | PT-RU NANO ALLOY / GRAPHIC CATALYST, METHOD FOR THE PRODUCTION AND USE THEREOF | |
SG2014011894A (en) | Catalyst support and catalysts prepared therefrom | |
EP2314544A4 (en) | BETA-ZEOLITE WITH HIGH RESISTANCE TO HEAT AND SCR CATALYST THEREFOR | |
BR112014010547A2 (pt) | composição de espessante, espessante, e, produto de reação de espessante | |
ECSP13012446A (es) | Ligandos fosfina para reacciones catalíticas | |
EP2928594A4 (en) | CATALYST COMPOSITIONS AND USE THEREOF IN A CATALYTIC BIOMASS PYROLYSIS | |
PT2649029T (pt) | Processo de despolimerização | |
DK2874787T3 (da) | Gribefatning, nøgle og fremgangsmåde til anvendelse | |
BR112012019275A2 (pt) | processos de produção de estireno e catalisadores para uso neles | |
DK2525907T3 (da) | Katalysatorbærer | |
ZA201308186B (en) | Solid, particulate tanning agent preparations | |
BRPI0913177A2 (pt) | sistema de reação para realizar experimentos paralelos, e, divisor de escoamento. | |
EP2570186A4 (en) | MIXED CATALYST | |
SG10201507873YA (en) | Catalyst supports, catalysts and their manufacture and use | |
BR112013019047A2 (pt) | método de produção de partículas de suporte de catalisador, partículas de suporte de catalisador, método de produção de partículas de catalisador, partículas de catalisador, e, uso das mesmas. | |
ZA201104840B (en) | Mixed bed polymeric catalyst | |
EP2832444A4 (en) | PALLADIUM CATALYST | |
EP2543437A4 (en) | HOMOGENEOUS ASYMMETRIC HYDROGENATION CATALYST | |
FR2968201B1 (fr) | Complexe saspase-flg2, agents modulateurs et utilisations |