DK2467354T3 - Fremgangsmåde til samtidig fremstilling af methanol og ammoniak - Google Patents

Fremgangsmåde til samtidig fremstilling af methanol og ammoniak Download PDF

Info

Publication number
DK2467354T3
DK2467354T3 DK10745184.1T DK10745184T DK2467354T3 DK 2467354 T3 DK2467354 T3 DK 2467354T3 DK 10745184 T DK10745184 T DK 10745184T DK 2467354 T3 DK2467354 T3 DK 2467354T3
Authority
DK
Denmark
Prior art keywords
methanol
stream
ammonia
synthesis gas
section
Prior art date
Application number
DK10745184.1T
Other languages
English (en)
Inventor
Ijaz Ahmed
Mubarak Bashir
Original Assignee
Saudi Basic Ind Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saudi Basic Ind Corp filed Critical Saudi Basic Ind Corp
Application granted granted Critical
Publication of DK2467354T3 publication Critical patent/DK2467354T3/da

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/025—Preparation or purification of gas mixtures for ammonia synthesis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C1/00—Ammonia; Compounds thereof
    • C01C1/02—Preparation, purification or separation of ammonia
    • C01C1/04—Preparation of ammonia by synthesis in the gas phase
    • C01C1/0405—Preparation of ammonia by synthesis in the gas phase from N2 and H2 in presence of a catalyst
    • C01C1/0488—Processes integrated with preparations of other compounds, e.g. methanol, urea or with processes for power generation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1516—Multisteps
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/061—Methanol production
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/068—Ammonia synthesis
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1258—Pre-treatment of the feed
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Claims (10)

1. Fremgangsmåde til samtidig fremstilling af methanol og ammoniak, hvori en syntesegasblanding bestående af i al væsentlighed af carbonmonoxid (CO), carbondioxid (C02) og hydrogen (H2) først delvis omsættes i en methanolgen-nemløbsreaktor, og ureageret syntesegas opdeles i en første og en anden strøm, hvor den første strøm oprenses og fødes til en ammoniaksyntesesektion, og den anden strøm fødes til en methanolsyntese- og oprensningssektion omfattende en methanolsløjfereaktor.
2. Fremgangsmåde til samtidig fremstilling af methanol og ammoniak ifølge krav 1 omfattende trinnene: a) fødning af en syntegasblanding bestående i al væsentlighed af CO, C02 og H2 til en methanolgennemløbsreaktor for at fremstille en methanol/syn-tesegasblanding, b) separering af blandingen fra trin a) i råmethanol og uomsat syntesegas, c) opdeling af den ureagerede syntesegas fra trin b) i en første og en anden strøm, d) fødning af den første strøm fra trin c) til en syntesegasoprensningsfunk-tion for at fremstille en CO-, en C02- og en Fl2-strøm, e) fødning af Fl2-strømmen fra trin d) sammen med en N2-strøm til en ammoniaksyntesesektion for at fremstille en ammoniakstrøm, f) fødning af den anden strøm fra trin c) og CO-strømmen fra trin d) til en methanolsløjfereaktor for at fremstille en methanolholdig blanding, g) adskillelse af råmethanol fra den methanolholdige blanding og tilbageførsel af den resterende gas til trin f), h) fødning af den rå methanol fra trin b) og fra trin g) til en methanoloprens-ningssektion for at resultere i en methanol-strøm.
3. Fremgangsmåde til samtidig fremstilling af methanol og ammoniak ifølge krav 1 eller 2 omfattende trinnene: a”) fødning af luft til en luftadskillelsessektion for at fremstille en 02- og en N2-strøm, a’) reforming af en afsvovlet carbonhydridråvare med 02 fra trin a”) og damp i en kombineret reformningssektion for at fremstille en syntesegasblanding bestående i al væsentlighed CO, C02 og H2, a) fødning af syntesegasblandingen fra trin a’) til en methanolgennemløbs-reaktor for at fremstille en methanol/syntesegas-blanding, b) separering af blandingen fra trin a) i rå methanol og uomsat syntesegas, c) opdeling af den ureagerede syntesegas fra trin b) i en første og en anden strøm, d) fødning af den første strøm fra trin c) til en syntesegasoprensningssek-tion for at fremstille en CO-, C02- og en H2-strøm, e) fødning af H2-strømmen fra trin d) sammen med N2-strømmen fra trin a”) til en ammoniaksyntesesektion for at fremstille en ammoniakstrøm, f) fødning af den anden strøm fra trin c) og CO-strømmen fra trin b) til en methanolsløjfereaktor for at fremstille en methanolholdig blanding, g) adskillelse af råmethanol fra den methanolholdige blanding og tilbageføring af den resterende gas til trin f), h) fødning af råmethanolen fra trin b) og fra trin g) til en methanoloprens-ningssektion, hvilket resulterer i en methanolstrøm.
4. Fremgangsmåde ifølge et vilkårligt af kravene 1 - 3, hvor syntesegasblandingen har et støkiometrisk tal SN fra 1,9 til 2,3.
5. Fremgangsmåde ifølge krav 3, hvor en methanrigråvare blandes med damp og ledes gennem en adiabatisk præreformer (APR), og hvor præreformet gas fra APR deles i tre strømme, som fødes til en dampmethanreformer (SMR), en gasopvarmet reformer (GFIR) og sammen med oxygenet til en autotermisk reformer (ATR), hvilke 3 reformingsreaktorer betjenes parallelt.
6. Fremgangsmåde ifølge et vilkårligt af kravene 1 - 5, hvor carbonhydridrå-varen er en methanrig råvare, som indeholder mindst 75 mol% methan.
7. Fremgangsmåde ifølge et vilkårligt af kravene 1 - 6, hvor den første og anden strøm af uomsat syntesegas deles i et forhold fra 50/50 til 80/20.
8. Fremgangsmåde ifølge krav 7, hvor forholdet af den første til den anden strøm er 70/30.
9. Fremgangsmåde til samtidig fremstilling af methanol og urinstof omfattende fremgangsmåden ifølge et vilkårligt af kravene 1 - 8, og et efterfølgende trin med fremstilling af urinstof i en urinstofsyntesesektion, fra C02 og H2 dannet i fremgangsmåden.
10. Fremstillingsanlæg til at fremstille methanol og ammoniak fra syntesegas ifølge fremgangsmåden ifølge et vilkårligt af kravene 1 - 9 omfattende en me-thanolgennemløbsreaktor, en methanolsløjfereaktor, en methanoloprensnings-sektion, en syntesegasoprensningssektion og en ammoniaksyntesesektion.
DK10745184.1T 2009-08-20 2010-08-17 Fremgangsmåde til samtidig fremstilling af methanol og ammoniak DK2467354T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09075380 2009-08-20
PCT/EP2010/005114 WO2011020618A1 (en) 2009-08-20 2010-08-17 Process for methanol and ammonia co-production

Publications (1)

Publication Number Publication Date
DK2467354T3 true DK2467354T3 (da) 2014-03-10

Family

ID=41334410

Family Applications (1)

Application Number Title Priority Date Filing Date
DK10745184.1T DK2467354T3 (da) 2009-08-20 2010-08-17 Fremgangsmåde til samtidig fremstilling af methanol og ammoniak

Country Status (8)

Country Link
US (1) US9321639B2 (da)
EP (1) EP2467354B1 (da)
JP (1) JP5633980B2 (da)
KR (1) KR20120049343A (da)
CN (1) CN102482183B (da)
DK (1) DK2467354T3 (da)
ES (1) ES2440016T3 (da)
WO (1) WO2011020618A1 (da)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2860386C (en) 2012-01-04 2020-04-28 Haldor Topsoe A/S Co-production of methanol and urea
JP2014015341A (ja) * 2012-07-06 2014-01-30 Mitsubishi Heavy Ind Ltd アンモニア及びメタノールの製造システム
WO2014122894A1 (en) * 2013-02-08 2014-08-14 Toyo Engineering Corporation Process for recovering carbon dioxide from combustion exhaust gas
CN103149838B (zh) * 2013-03-01 2015-10-14 浙江大学 甲醇自热重整制氢过程的自适应控制方法
PL2805914T3 (pl) * 2013-05-23 2018-02-28 Haldor Topsøe A/S Sposób współwytwarzania amoniaku, mocznika i metanolu
WO2015006317A1 (en) * 2013-07-08 2015-01-15 Ihi E&C International Corporation Use of methanol loop purge gas for adjustment of hydrogen to carbon monoxide ratio
US9643856B2 (en) * 2013-08-07 2017-05-09 Kellogg Brown+Root LLC Methods and systems for making ammonia in a double ammonia converter system
EA201791153A1 (ru) * 2014-11-25 2017-11-30 Хальдор Топсёэ А/С Способ получения синтез-газа посредством рециркуляции газообразных продуктов горения
EP3034488B1 (en) * 2014-12-15 2017-10-18 Haldor Topsøe A/S A process for co-production of ammonia and methanol
GB201502894D0 (en) * 2015-02-20 2015-04-08 Johnson Matthey Plc Process
EP3150553A1 (en) * 2015-09-30 2017-04-05 Casale SA Method for purification of a co2 stream
US10288346B2 (en) * 2016-08-05 2019-05-14 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Method for liquefaction of industrial gas by integration of methanol plant and air separation unit
US10281203B2 (en) * 2016-08-05 2019-05-07 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Method for liquefaction of industrial gas by integration of methanol plant and air separation unit
EP3323786B1 (de) * 2016-11-16 2020-12-02 GasConTec GmbH Verfahren zur kombinierten herstellung von methanol und ammoniak
WO2018166872A1 (en) 2017-03-12 2018-09-20 Haldor Topsøe A/S Co-production of methanol and ammonia
RU2766961C1 (ru) 2017-03-12 2022-03-16 Хальдор Топсёэ А/С Совместное получение метанола, аммиака и мочевины
EP3401280B1 (de) * 2017-05-11 2021-12-22 GasConTec GmbH Verfahren zur herstellung von ammoniak
WO2019020513A1 (en) 2017-07-25 2019-01-31 Haldor Topsøe A/S METHOD OF PREPARING A SYNTHESIS GAS
UA126346C2 (uk) * 2017-07-25 2022-09-21 Хальдор Топсьое А/С Спосіб отримання газу для синтезу аміаку
US11124424B2 (en) * 2017-07-25 2021-09-21 Haldor Topsoe A/S Process for the co-production of methanol and ammonia in parallel
MY195274A (en) 2018-06-08 2023-01-12 Casale Sa Process for Methanol Production
US20230312444A1 (en) * 2020-08-31 2023-10-05 Sumitomo Chemical Company, Limited Method for producing methanol
CN114110424B (zh) * 2021-11-26 2023-09-01 鲁西化工集团股份有限公司煤化工二分公司 一种优化资源配制合成气（co：h2=1:1）的***及工艺方法
WO2023194270A1 (en) 2022-04-05 2023-10-12 Topsoe A/S Revamp process for an ammonia and methanol co-production plant

Family Cites Families (46)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB306512A (en) 1928-02-22 1930-07-21 Air Liquide Improved manufacture of oxygenated organic compounds
GB366268A (en) 1930-02-28 1932-02-04 Mines De Dourges Soc D Process for the transformation of coke oven gas or town gas into ammonia and methyl alcohol
US2014757A (en) 1930-02-28 1935-09-17 Mines De Dourges Soc D Process for the integral transformation of coke oven gas or town gas into ammonia and methyl alcohol
GB715881A (en) 1949-12-30 1954-09-22 Ronald James Morley Improvements in and relating to the production of hydrogen-containing gas mixtures for use in the synthesis of methanol and/or ammonia
US3615200A (en) 1967-06-14 1971-10-26 Toyo Engineering Corp Process for concentrating inert components in pressurized synthesis loop
US3598527A (en) 1968-10-11 1971-08-10 Pullman Inc Ammonia and methanol production
DE1920001A1 (de) 1969-04-19 1970-12-17 Metallgesellschaft Ag Verfahren zur Erzeugung eines Synthesegases fuer die Herstellung von Ammoniak
GB1314984A (en) 1969-08-21 1973-04-26 Chemical Construction Corp Process for recovering and using waste heat in the steam reforming
US3872025A (en) 1969-10-31 1975-03-18 Bethlehem Steel Corp Production and utilization of synthesis gas
US3957449A (en) * 1972-02-28 1976-05-18 Imperial Chemical Industries Limited Synthesis plant
GB1502190A (en) 1975-01-15 1978-02-22 Capital Plant International Lt Methanol synthesis gas production
US4013454A (en) 1975-03-04 1977-03-22 Robert Kenneth Jordan Coproduction of iron with methanol and ammonia
IT1060622B (it) 1976-05-14 1982-08-20 Snam Progetti Procedimento per la riutilizzazio ne delle acque di processo negli impianti combinati urea e ammoniaca
US4110359A (en) 1976-12-10 1978-08-29 Texaco Development Corporation Production of cleaned and purified synthesis gas and carbon monoxide
DE2943356A1 (de) 1978-10-30 1980-05-14 Davy Int Oil & Chemi Verfahren zur gemeinsamen herstellung von ammoniak und methanol
EP0011404B1 (en) 1978-11-10 1982-12-29 Imperial Chemical Industries Plc Integrated process for synthesis of methanol and of ammonia
JPS5567501A (en) 1978-11-10 1980-05-21 Hitachi Zosen Corp Production of mixed gas for ammonia synthesis using methanol synthesis exhaust gas
JPS55154314A (en) 1979-05-18 1980-12-01 Toyo Eng Corp Joint production of methanol and ammonia
EP0026057B1 (en) 1979-09-14 1984-03-14 Imperial Chemical Industries Plc Synthesis reactor and processes
GB2084973B (en) 1980-10-07 1984-04-18 Toyo Engineering Corp An integrated process for the production of methanol and ammonia
DE3201776A1 (de) 1982-01-21 1983-09-08 Krupp-Koppers Gmbh, 4300 Essen Verfahren zur gleichzeitigen erzeugung von methanol- und ammoniak-synthesegas.
EP0112613B1 (en) 1982-09-30 1991-03-06 Engelhard Corporation Process for producing hydrogen-rich gas from hydrocarbonaceous feeds
DK411983A (da) 1983-09-12 1985-03-13 Haldor Topsoe As Fremgangsmaade til rensning af en hydrogenholdig gas
DE3336649A1 (de) 1983-10-08 1985-04-25 Uhde Gmbh, 4600 Dortmund Verfahren zur gemeinsamen herstellung von methanol und ammoniak
DE3443017A1 (de) 1983-11-24 1985-06-05 Linde Ag, 6200 Wiesbaden Verfahren zur herstellung von ammoniaksynthesegas
US4946477A (en) * 1988-04-07 1990-08-07 Air Products And Chemicals, Inc. IGCC process with combined methanol synthesis/water gas shift for methanol and electrical power production
US4886651A (en) 1988-05-18 1989-12-12 Air Products And Chemicals, Inc. Process for co-production of higher alcohols, methanol and ammonia
DK166722B1 (da) 1990-12-21 1993-07-05 Topsoe Haldor As Fremgangsmaade til fremstilling af ammoniaksyntesegas
GB2252317B (en) 1991-01-03 1995-02-15 Enserch Int Investment Combined ammonia/methanol process
US5180570A (en) * 1992-01-23 1993-01-19 Lee Jing M Integrated process for making methanol and ammonia
JPH0733253B2 (ja) 1993-02-09 1995-04-12 東洋エンジニアリング株式会社 アンモニア及びメタノールの併産方法
WO1997010194A1 (en) 1995-09-11 1997-03-20 Methanol Casale S.A. Process for the ammonia and methanol co-production
UA48186C2 (uk) 1995-11-23 2002-08-15 Метанол Казале С.А. Спосіб сумісного виробництва аміаку і метанолу, установка для сумісного виробництва аміаку і метанолу, спосіб модернізації установки синтезу аміаку та спосіб модернізації установки сумісного виробництва аміаку і метанолу
JP4168210B2 (ja) 1998-08-14 2008-10-22 三菱瓦斯化学株式会社 メタノール・アンモニア併産方法
JP3594898B2 (ja) * 2000-11-24 2004-12-02 川崎重工業株式会社 溶融還元炉ガスの利用方法および利用装置
CN1451642A (zh) * 2002-04-15 2003-10-29 中国成达化学工程公司 甲醇联产合成氨的方法
EP1604967A4 (en) 2003-02-19 2006-06-07 Din Zhong Xie COMMON METHOD FOR THE PRODUCTION OF ALCOHOL ETHER, ALCOHOL CARBON DIOXIDE AND AMMONIA CYNTHESIS
KR100555294B1 (ko) * 2003-09-17 2006-03-03 한국과학기술연구원 역수성가스 반응을 이용한 디메틸에테르의 제조방법
DE102004013539A1 (de) 2004-03-19 2005-10-06 Lurgi Ag Verfahren zur Koproduktion von Methanol und Ammoniak aus Erdgas
DE102004014292A1 (de) 2004-03-22 2005-10-20 Lurgi Ag Koproduktion von Methanol und Ammoniak aus Erdgas
MY146697A (en) * 2004-07-09 2012-09-14 Acetex Cyprus Ltd Preparation of syngas for acetic acid synthesis by partial oxidation of methanol feedstock
US20080039625A1 (en) * 2004-11-05 2008-02-14 Mark Lautens Screening Methods
WO2007108014A1 (en) * 2006-03-20 2007-09-27 Cri Ehf Process for producing liquid fuel from carbon dioxide and water
EP1914219A1 (en) * 2006-10-20 2008-04-23 BP Chemicals Limited Process for the conversion of hydrocarbons to alcohols
ES2357185T5 (es) * 2007-04-04 2015-04-14 Saudi Basic Industries Corporation Proceso combinado de reformado para producción de metanol
US9227895B2 (en) * 2007-07-09 2016-01-05 Albemarle Corporation Methods and apparatus for producing alcohols from syngas

Also Published As

Publication number Publication date
WO2011020618A1 (en) 2011-02-24
KR20120049343A (ko) 2012-05-16
JP5633980B2 (ja) 2014-12-03
US9321639B2 (en) 2016-04-26
CN102482183A (zh) 2012-05-30
EP2467354B1 (en) 2013-12-04
ES2440016T3 (es) 2014-01-27
JP2013502390A (ja) 2013-01-24
US20120148472A1 (en) 2012-06-14
EP2467354A1 (en) 2012-06-27
CN102482183B (zh) 2015-07-01

Similar Documents

Publication Publication Date Title
DK2467354T3 (da) Fremgangsmåde til samtidig fremstilling af methanol og ammoniak
CN109071387B (zh) 用于合成甲醇的方法
CN110382406B (zh) 用于生产氢气和甲醇的方法
US7879919B2 (en) Production of hydrocarbons from natural gas
US8388864B2 (en) Process and plant for producing synthesis gas
US9085513B2 (en) Co-production of methanol and urea
US11673805B2 (en) Process and plant for preparation of hydrogen and separation of carbon dioxide
BRPI0418477B1 (pt) Método para a fabricação de metanol e ácido acético
EA027871B1 (ru) Способ получения аммиака и мочевины
JPH1143306A (ja) 一酸化炭素および水素を得る方法
EP1742901A1 (en) System and process for synthesis of methanol
WO2006117499A1 (en) Synthesis gas production process
CN113501495A (zh) 用于生产纯一氧化碳和氢气的方法和设备
JP4065413B2 (ja) 空気からのクリプトン及びキセノン回収方法
WO2003016250A1 (en) Production of hydrocarbons
AU2002317369A1 (en) Production of hydrocarbons
US20220144654A1 (en) Process For Producing Methanol And Ammonia
CA2882170C (en) Method for operating a steam reforming plant
US20220315434A1 (en) Process and plant for producing methanol and ammonia