DK0958270T3 - Fremgangsmåde til fremstilling af aldehyder i nærværelse af en vandig fase indeholdende rhodium og sulfonerede triarylphosphiner som katalysator. - Google Patents

Fremgangsmåde til fremstilling af aldehyder i nærværelse af en vandig fase indeholdende rhodium og sulfonerede triarylphosphiner som katalysator.

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Publication number
DK0958270T3
DK0958270T3 DK97953929T DK97953929T DK0958270T3 DK 0958270 T3 DK0958270 T3 DK 0958270T3 DK 97953929 T DK97953929 T DK 97953929T DK 97953929 T DK97953929 T DK 97953929T DK 0958270 T3 DK0958270 T3 DK 0958270T3
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Prior art keywords
catalyst
aqueous phase
phase containing
aldehydes
preparation
Prior art date
Application number
DK97953929T
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Danish (da)
English (en)
Inventor
Sandra Bogdanovic
Carl-Dieter Frohning
Helmut Bahrmann
Original Assignee
Celanese Chem Europe Gmbh
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Publication date
Application filed by Celanese Chem Europe Gmbh filed Critical Celanese Chem Europe Gmbh
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Publication of DK0958270T3 publication Critical patent/DK0958270T3/da

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/068Polyalkylene glycols
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2409Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2447Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • B01J31/2442Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
    • B01J31/2447Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring
    • B01J31/2452Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as substituents on a ring of the condensed system or on a further attached ring with more than one complexing phosphine-P atom
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/50Organo-phosphines
    • C07F9/5027Polyphosphines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32Addition reactions to C=C or C-C triple bonds
    • B01J2231/321Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0266Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/822Rhodium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/90Catalytic systems characterized by the solvent or solvent system used
    • B01J2531/96Water
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2540/00Compositional aspects of coordination complexes or ligands in catalyst systems
    • B01J2540/30Non-coordinating groups comprising sulfur
    • B01J2540/32Sulfonic acid groups or their salts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
DK97953929T 1997-01-13 1997-12-30 Fremgangsmåde til fremstilling af aldehyder i nærværelse af en vandig fase indeholdende rhodium og sulfonerede triarylphosphiner som katalysator. DK0958270T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19700804A DE19700804C1 (de) 1997-01-13 1997-01-13 Verfahren zur Herstellung von Aldehyden durch Hydroformylierung olefinischer Verbindungen mit 6 bis 16 Kohlenstoffatomen in Anwesenheit einer Rhodium und sulfonierte Triarylphosphine als Katalysator enthaltenden wäßrigen Phase
PCT/EP1997/007314 WO1998030526A1 (de) 1997-01-13 1997-12-30 Verfahren zur herstellung von aldehyden in anwesenheit einer rhodium und sulfonierte triarylphosphine als katalysator enthaltenden wässrigen phase

Publications (1)

Publication Number Publication Date
DK0958270T3 true DK0958270T3 (da) 2002-08-05

Family

ID=7817210

Family Applications (1)

Application Number Title Priority Date Filing Date
DK97953929T DK0958270T3 (da) 1997-01-13 1997-12-30 Fremgangsmåde til fremstilling af aldehyder i nærværelse af en vandig fase indeholdende rhodium og sulfonerede triarylphosphiner som katalysator.

Country Status (13)

Country Link
US (1) US6274774B1 (es)
EP (1) EP0958270B1 (es)
JP (1) JP2002511055A (es)
KR (1) KR20000070133A (es)
CN (1) CN1247527A (es)
AT (1) ATE216691T1 (es)
DE (2) DE19700804C1 (es)
DK (1) DK0958270T3 (es)
ES (1) ES2175516T3 (es)
PT (1) PT958270E (es)
TW (1) TW467890B (es)
WO (1) WO1998030526A1 (es)
ZA (1) ZA98212B (es)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19740672A1 (de) 1997-09-16 1999-03-18 Hoechst Ag Verfahren zur Herstellung von Aldehyden durch Hydroformylierung
DE10243446B4 (de) 2002-09-19 2005-12-15 Celanese Chemicals Europe Gmbh Verfahren zur Herstellung von Aldehyden
DE10352263A1 (de) * 2003-11-08 2005-06-23 Celanese Chemicals Europe Gmbh Verfahren zur Herstellung von TCD-Monenal
EP2506970A4 (en) * 2009-12-01 2014-03-12 Mycell Technologies Llc TENSIDACTIVATED TRANSITION METAL CATALYZED CHEMISTRY
KR101641759B1 (ko) * 2011-05-09 2016-07-21 미쓰이 가가쿠 가부시키가이샤 알데히드 화합물의 제조 방법
TW201710276A (zh) * 2015-07-02 2017-03-16 烏明克股份有限兩合公司 2-乙基己酸銠(iii)之製備
TWI793216B (zh) * 2017-12-07 2023-02-21 美商陶氏科技投資公司 氫甲醯化方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4248802A (en) 1975-06-20 1981-02-03 Rhone-Poulenc Industries Catalytic hydroformylation of olefins
GB2085874B (en) * 1980-09-04 1984-08-08 Johnson Matthey Plc Hydroformylation of olefins
DE3412335A1 (de) * 1984-04-03 1985-10-10 Ruhrchemie Ag, 4200 Oberhausen Verfahren zur herstellung von aldehyden
US5091350A (en) * 1984-03-26 1992-02-25 Hoechst Aktiengesellschaft Process for hydroformylation with rhodium catalysts and the separation of rhodium therefrom
US4731486A (en) * 1986-11-18 1988-03-15 Union Carbide Corporation Hydroformylation using low volatile phosphine ligands
DE19630536C2 (de) * 1996-07-29 1998-11-05 Hoechst Ag Katalysator und dessen Verwendung für die Herstellung von Aldehyden durch Hydroformylierung olefinischer Verbindungen

Also Published As

Publication number Publication date
JP2002511055A (ja) 2002-04-09
ZA98212B (en) 1998-09-02
CN1247527A (zh) 2000-03-15
PT958270E (pt) 2002-09-30
DE59707120D1 (de) 2002-05-29
WO1998030526A1 (de) 1998-07-16
TW467890B (en) 2001-12-11
EP0958270B1 (de) 2002-04-24
KR20000070133A (ko) 2000-11-25
DE19700804C1 (de) 1998-08-06
ES2175516T3 (es) 2002-11-16
EP0958270A1 (de) 1999-11-24
ATE216691T1 (de) 2002-05-15
US6274774B1 (en) 2001-08-14

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