DE69911626D1 - Magnesium, titanium, halogen und elektronendonor-enthaltende katalysatorkomponente, ihre herstellung und verwendung - Google Patents

Magnesium, titanium, halogen und elektronendonor-enthaltende katalysatorkomponente, ihre herstellung und verwendung

Info

Publication number
DE69911626D1
DE69911626D1 DE69911626T DE69911626T DE69911626D1 DE 69911626 D1 DE69911626 D1 DE 69911626D1 DE 69911626 T DE69911626 T DE 69911626T DE 69911626 T DE69911626 T DE 69911626T DE 69911626 D1 DE69911626 D1 DE 69911626D1
Authority
DE
Germany
Prior art keywords
catalyst component
titanium
magnesium
halogen
production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69911626T
Other languages
English (en)
Other versions
DE69911626T2 (de
Inventor
Thomas Garoff
Timo Leinonen
Sirpa Ala-Huikku
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
WR Grace and Co Conn
Original Assignee
Borealis Technology Oy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Borealis Technology Oy filed Critical Borealis Technology Oy
Application granted granted Critical
Publication of DE69911626D1 publication Critical patent/DE69911626D1/de
Publication of DE69911626T2 publication Critical patent/DE69911626T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651Pretreating with non-metals or metal-free compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6543Pretreating with metals or metal-containing compounds with magnesium or compounds thereof halides of magnesium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof
    • C08F4/6548Pretreating with metals or metal-containing compounds with magnesium or compounds thereof magnesium or compounds thereof, not provided for in C08F4/6543 or C08F4/6546

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE69911626T 1998-08-07 1999-08-09 Magnesium, titanium, halogen und elektronendonor-enthaltende katalysatorkomponente, ihre herstellung und verwendung Expired - Lifetime DE69911626T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FI981717 1998-08-07
FI981717A FI981717A (fi) 1998-08-07 1998-08-07 Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektronidonorin, sen valmistus ja käyttö
PCT/FI1999/000657 WO2000008073A1 (en) 1998-08-07 1999-08-09 Catalyst component comprising magnesium, titanium, a halogen and an electron donor, its preparation and use

Publications (2)

Publication Number Publication Date
DE69911626D1 true DE69911626D1 (de) 2003-10-30
DE69911626T2 DE69911626T2 (de) 2004-06-24

Family

ID=8552278

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69911626T Expired - Lifetime DE69911626T2 (de) 1998-08-07 1999-08-09 Magnesium, titanium, halogen und elektronendonor-enthaltende katalysatorkomponente, ihre herstellung und verwendung

Country Status (9)

Country Link
US (2) US6703455B1 (de)
EP (1) EP1109842B9 (de)
JP (1) JP2002522577A (de)
CN (1) CN1133663C (de)
AT (1) ATE250636T1 (de)
AU (1) AU5167399A (de)
DE (1) DE69911626T2 (de)
FI (1) FI981717A (de)
WO (1) WO2000008073A1 (de)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI991069A0 (fi) * 1999-05-10 1999-05-10 Borealis As Katalysaattorikomponentti, joka käsittää magnesiumia, titaania, halogeenia ja elektronidonorin, sen valmistus ja käyttö
EP1205496A1 (de) * 2000-11-10 2002-05-15 Borealis Technology Oy Magnesium, Titan, Halogen und Elektronendonor-enthaltende Katalysatorkomponente, ihre Herstellung und ihre Verwendung
EP1229054B1 (de) * 2001-01-30 2003-10-22 Borealis Technology Oy Magnesium, Titanium, Halogen und Elektronendonor-enthaltende Kalalysatorkomponente und deren Herstellung
ATE328015T1 (de) 2001-06-20 2006-06-15 Borealis Polymers Oy Herstellung eines katalysatorbestandteils zur olefinpolymerisation
DE60120389T2 (de) * 2001-06-20 2007-06-14 Borealis Technology Oy Herstellung eines Katalysatorbestandteils zur Olefinpolymerisation
EP1375528A1 (de) 2002-06-18 2004-01-02 Borealis Polymers Oy Verfahren zur Herstellung von Olefinpolymerisationskatalysatoren
EP1403292B1 (de) 2002-09-30 2016-04-13 Borealis Polymers Oy Verfahren zur herstellung eines olefinpolymerisationskatalysatorbestandteils mit verbesserter aktivität bei hoher temperatur
US20060135720A1 (en) * 2004-12-17 2006-06-22 Fina Technology, Inc. Soluble magnesium complexes useful for the production of polyolefin catalysts and catalysts prepared therewith
US7765785B2 (en) * 2005-08-29 2010-08-03 Kashmerick Gerald E Combustion engine
EP2845868A1 (de) 2006-05-31 2015-03-11 Borealis Technology Oy Oxydationsstufe von Ti als Mittel für zunehmende Katalysatoraktivität
EP1862479A1 (de) * 2006-05-31 2007-12-05 Borealis Technology Oy Olefinpolymerisationskatalysator
EP2138517B1 (de) 2008-06-26 2012-09-12 Borealis AG Katalysatorherstellung mit H2
EP2570438A3 (de) 2010-07-13 2013-12-25 Borealis AG Katalysatorkomponente
EP2407492B1 (de) 2010-07-13 2015-04-29 Borealis AG Katalysatorkomponente
US10711077B2 (en) * 2011-02-07 2020-07-14 Fina Technology, Inc. Ziegler-natta catalyst composition with controlled morphology
US8501653B2 (en) * 2011-02-16 2013-08-06 Fina Technology, Inc. Heat-treated Ziegler-Natta catalysts for ethylene polymerization
US9382347B2 (en) 2011-02-16 2016-07-05 Fina Technology Inc Ziegler-Natta catalysts doped with non-group IV metal chlorides
ES2727405T3 (es) 2011-12-30 2019-10-16 Borealis Ag Preparación de catalizadores de ZN PP libres de ftalato
EP2610273B1 (de) 2011-12-30 2018-02-07 Borealis AG Katalysatorkomponente
EP2610272B1 (de) 2011-12-30 2017-05-10 Borealis AG Katalysatorkomponente
ES2554864T3 (es) 2011-12-30 2015-12-23 Borealis Ag Componente de catalizador
EP2897985B1 (de) 2012-09-24 2017-03-08 Indian Oil Corporation Ltd Katalysator zur olefinpolymerisation und verfahren dafür
ES2653868T3 (es) 2012-12-21 2018-02-09 Borealis Ag Procatalizador de Ziegler Natta soportado para la polimerización de etileno
ES2615499T3 (es) 2012-12-21 2017-06-07 Borealis Ag Procedimiento para la producción de un procatalizador de Ziegler-Natta para la polimerización de etileno
PL3074435T3 (pl) 2013-11-27 2022-01-24 W.R. Grace & Co. - Conn. Cząstki prokatalizatora i proces polimeryzacji kopolimerów udarowych
EP2960256B1 (de) 2014-06-27 2018-04-25 Borealis AG Katalysatorkomponenten zur Herstellung von nukleierten Polyolefinen
ES2929284T3 (es) 2014-06-27 2022-11-28 Borealis Ag Proceso mejorado para preparar un componente catalizador de polimerización de olefinas en partículas
WO2017009405A1 (en) 2015-07-16 2017-01-19 Borealis Ag Catalyst component
US20190177446A1 (en) * 2016-02-15 2019-06-13 Basell Polyolefine Gmbh Preactivated catalyst component for the polymerization of olefins
MX2019015360A (es) 2017-10-02 2020-02-07 Laboratorios Silanes S A De C V Proceso de alto rendimiento para la produccion de antivenenos de fragmentos f(ab')2 de anticuerpos.
WO2019094216A1 (en) 2017-11-13 2019-05-16 W.R. Grace & Co.-Conn. Catalyst components for propylene polymerization
EP3898720A1 (de) * 2018-12-21 2021-10-27 Borealis AG Katalysator und herstellung davon
US11214633B2 (en) * 2019-09-10 2022-01-04 Braskem America, Inc. Ziegler-Natta catalyst systems and methods of controlling particle size
CN118076652A (zh) 2021-10-14 2024-05-24 博里利斯股份公司 用于形成齐格勒-纳塔催化剂组分的方法

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3354139A (en) * 1955-05-18 1967-11-21 Hercules Inc Process for polymerizing olefins
JPH0655782B2 (ja) * 1984-07-31 1994-07-27 東燃株式会社 オレフイン重合用触媒成分
JPH072776B2 (ja) 1985-01-28 1995-01-18 東燃株式会社 オレフイン重合用触媒成分
JPH072777B2 (ja) 1985-01-28 1995-01-18 東燃株式会社 オレフイン重合用触媒成分
JPH072775B2 (ja) 1985-01-28 1995-01-18 東燃株式会社 オレフイン重合用触媒成分の製造法
DE3540698A1 (de) 1985-11-16 1987-05-21 Basf Ag Verfahren zum herstellen von homo- und copolymerisaten des propylens mittels eines ziegler-natta-katalysatorsystems
US4804648A (en) 1986-06-18 1989-02-14 Shell Oil Company Crystalline olefin polymerization catalyst component
US5093415A (en) 1987-05-19 1992-03-03 Union Carbide Chemicals & Plastics Technology Corporation Process for producing stereoregular polymers having a narrow molecular weight distribution
ATE122690T1 (de) 1987-11-25 1995-06-15 Shell Oil Co Propylenpolymere und herstellung derselben.
FR2640273B1 (fr) * 1988-12-14 1992-09-04 Atochem Procede de polymerisation en phase gazeuse de l'ethylene permettant la fabrication de polyethylene lineaire de distribution etroite de masse moleculaire
US5118767A (en) 1990-02-26 1992-06-02 Shell Oil Company Process for producing mildly elastomeric primarily isotatic polypropylene and poly-1-butene
CA2155304C (en) 1993-02-05 2010-07-20 Charles Swindell Syntheses of paclitaxel, analogs and intermediates with variable a-ring side chains
US5414063A (en) 1993-03-30 1995-05-09 Huntsman Polypropylene Corporation Process for the production of polypropylene
FI96615C (fi) 1993-06-04 1996-07-25 Neste Oy Menetelmä C4-C40- -olefiinien polymeroimiseksi tai kopolymeroimiseksi muiden -olefiinien kanssa
US5338790A (en) 1993-07-14 1994-08-16 Shell Oil Company Polymer compositions
ATE181931T1 (de) 1994-01-31 1999-07-15 Toho Titanium Co Ltd Katalysator für olefinpolymerisation und verfahren zur olefinpolymerisation unter anwendung desselben
TW412546B (en) 1994-05-19 2000-11-21 Mitsui Petrochemical Ind Solid titanium catalyst component for olefin polymerization, process for preparation of the same, olefin polymerization catalyst and process for olefin polymerization
JP3595864B2 (ja) 1995-06-07 2004-12-02 住友化学工業株式会社 α−オレフィン重合用触媒ならびにα−オレフィン重合体の製造方法
DE69803973T2 (de) 1997-12-23 2002-08-29 Borealis Tech Oy Magnesium, Titanium, Halogen und Elektronendonor-enthaltendes Kalalysatorkomponent, seine Herstellung und Verwendung
US6449827B1 (en) 1999-10-22 2002-09-17 Merck & Co., Inc Apparatus for gripping microplates

Also Published As

Publication number Publication date
EP1109842B1 (de) 2003-09-24
EP1109842B9 (de) 2004-08-11
JP2002522577A (ja) 2002-07-23
FI981717A (fi) 2000-02-08
US20010008869A1 (en) 2001-07-19
US6703455B1 (en) 2004-03-09
AU5167399A (en) 2000-02-28
DE69911626T2 (de) 2004-06-24
US6706655B2 (en) 2004-03-16
ATE250636T1 (de) 2003-10-15
EP1109842A1 (de) 2001-06-27
CN1317022A (zh) 2001-10-10
FI981717A0 (fi) 1998-08-07
WO2000008073A1 (en) 2000-02-17
CN1133663C (zh) 2004-01-07

Similar Documents

Publication Publication Date Title
DE69911626D1 (de) Magnesium, titanium, halogen und elektronendonor-enthaltende katalysatorkomponente, ihre herstellung und verwendung
DE69922669D1 (de) Magnesium, titanium, halogen und elektronendonor-enthaltende katalysatorkomponente, ihre herstellung und verwendung
FI945486A0 (fi) Metalloseeneja, menetelmä niiden valmistamiseksi sekä niiden käyttö katalyytteinä
ES2178704T3 (es) Complejos matalicos de azaborolinilo como catalizadores de polimerizacion de olefinas.
DE69232608D1 (de) Verwendung von Fluorenylorganometallverbindungen.
KR910011919A (ko) 올레핀중합용 촉매 및 이 올레핀중합용 촉매를 사용한 올레핀의 중합방법
MXPA00006908A (es) Pelicula de poliester orientada biaxialmente, blanca, con copolimero de cicloolefina (coc), procedimiento para producir la pelicula y su uso.
ATE334135T1 (de) Metallocene und verfahren zur herstellung von propylenpolymeren
RU93004723A (ru) Катализатор для полимеризации олефинов, способ его получения и способ гомо- или сополимеризации олефинов
WO1996020223A3 (en) Azametallocene polymerization catalysts
FI900466A0 (fi) Katalysatorer anvaendbara vid polymerisering av olefiner.
DE69706839D1 (de) Zusammensetzung enthaltend magnesium, titan, halogen und einen inneren elektronendonor, ihre herstellung sowie ihre verwendung zur polymerisierung von alpha-olefinen
RU95106820A (ru) Катализатор или компонент катализатора полимеризации и сополимеризации альфа-олефинов
ATE183523T1 (de) Festes titan enthaltendes katalysatorbestandteil, verfahren zur herstellung desselben, dieses enthaltender olefinpolymerisationkatalysator und olefinpolymerisationverfahren
DE69417751T2 (de) Polymerzusammensetzungen, die naphthalendicarbonsäure und halogenverbindungen enthalten mit verminderter fluoreszenz
ATE119169T1 (de) Prokatalysatormischung zur polymerisation von alpha-olefinen, herstellung und verwendung.
NO962064L (no) Fremgangsmåte for fremstilling av en Ziegler-Natta katalysator
DE60122922D1 (de) Magnesium, Titan, ein Halogen und einen Elektronendonator enthaltende Katalysatorkomponente, ihre Herstellung und Verwendung
DE60101041D1 (de) Magnesium, Titanium, Halogen und Elektronendonor-enthaltende Kalalysatorkomponente und deren Herstellung
KR940014448A (ko) 올레핀 중합체 제조용 촉매 조성물
NO306953B1 (no) Fremgangsmåte for fremstilling av hoeyaktive katalysatorer for olefinpolymerisasjon og polymerisasjonsfremgangsmåte under anvendelse av disse katalysatorene
KR950005848A (ko) 올레핀계 중합체의 제조방법
TH6669EX (th) กรรมวิธีสำหรับผลิตพอลิโพรพิลีนและพอลิโพรพิลีนฟิล์มชนิดยึด

Legal Events

Date Code Title Description
8327 Change in the person/name/address of the patent owner

Owner name: W.R. GRACE & CO.-CONN., COLUMBIA, MD., US

8364 No opposition during term of opposition