DE69906552T2 - Katalysatorkomponente die mindestens einen phosphinimine-liganden und einen heteroatom-liganden enthält - Google Patents

Katalysatorkomponente die mindestens einen phosphinimine-liganden und einen heteroatom-liganden enthält Download PDF

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Publication number
DE69906552T2
DE69906552T2 DE69906552T DE69906552T DE69906552T2 DE 69906552 T2 DE69906552 T2 DE 69906552T2 DE 69906552 T DE69906552 T DE 69906552T DE 69906552 T DE69906552 T DE 69906552T DE 69906552 T2 DE69906552 T2 DE 69906552T2
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DE
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Prior art keywords
ligand
phosphinimine
catalyst component
component containing
heteroatom
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Expired - Lifetime
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DE69906552T
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English (en)
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DE69906552D1 (de
Inventor
John Brown
Xiaoliang Gao
Qinyan Wang
Peter Zoricak
Edward Spence
Wei Xu
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Nova Chemicals International SA
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Nova Chemicals International SA
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/535—Organo-phosphoranes
    • C07F9/5355—Phosphoranes containing the structure P=N-
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
    • C07F9/576—Six-membered rings
    • C07F9/59—Hydrogenated pyridine rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/14—Organic medium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/05—Cp or analog where at least one of the carbon atoms of the coordinating ring is replaced by a heteroatom
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Biochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
DE69906552T 1998-07-21 1999-06-08 Katalysatorkomponente die mindestens einen phosphinimine-liganden und einen heteroatom-liganden enthält Expired - Lifetime DE69906552T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CA002243775A CA2243775C (en) 1998-07-21 1998-07-21 Phosphinimine/heteroatom catalyst component
PCT/CA1999/000525 WO2000005237A1 (en) 1998-07-21 1999-06-08 Catalyst component having at least a phosphinimine ligand and a heteroatom ligand

Publications (2)

Publication Number Publication Date
DE69906552D1 DE69906552D1 (de) 2003-05-08
DE69906552T2 true DE69906552T2 (de) 2004-01-15

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Family Applications (1)

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DE69906552T Expired - Lifetime DE69906552T2 (de) 1998-07-21 1999-06-08 Katalysatorkomponente die mindestens einen phosphinimine-liganden und einen heteroatom-liganden enthält

Country Status (12)

Country Link
US (1) US6147172A (de)
EP (1) EP1112278B1 (de)
JP (1) JP4456273B2 (de)
KR (1) KR100545640B1 (de)
CN (1) CN1174990C (de)
AT (1) ATE236182T1 (de)
AU (1) AU4126299A (de)
BR (1) BR9912277A (de)
CA (1) CA2243775C (de)
DE (1) DE69906552T2 (de)
ES (1) ES2196809T3 (de)
WO (1) WO2000005237A1 (de)

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US20060293470A1 (en) * 2005-06-28 2006-12-28 Cao Phuong A Polymerization process using spray-dried catalyst
US6242545B1 (en) * 1997-12-08 2001-06-05 Univation Technologies Polymerization catalyst systems comprising substituted hafinocenes
US8497330B2 (en) * 1997-12-08 2013-07-30 Univation Technologies, Llc Methods for polymerization using spray dried and slurried catalyst
CA2254512C (en) * 1998-11-25 2008-02-12 Nova Chemicals Ltd. Slurry polymerization process using an unsupported phosphinimine catalyst
CA2254601C (en) * 1998-11-27 2007-10-23 Nova Chemicals Ltd. Aluminum-phosphinimine complexes as catalysts for the (co)polymerization of ethylene
CA2311068C (en) * 2000-06-08 2010-03-09 Nova Chemicals Corporation Process to prepare ethylene propylene elastomer
US6852659B1 (en) 2000-11-16 2005-02-08 Univation Technologies, Llc Method for preparing a catalyst composition and its use in a polymerization process
DE10140202A1 (de) 2001-08-16 2003-03-06 Bayer Ag Vanadium-Imido-Phosphoraniminato für die Olefinpolymerisation
JP2003207672A (ja) * 2002-01-17 2003-07-25 Sony Corp 光ファイバー、光ファイバーモジュール及び光学ピックアップ
EP1506974A1 (de) * 2003-08-04 2005-02-16 DSM IP Assets B.V. Verfahren zur Herstellung einer metallorganischen Verbindung, die mindestens einen Iminliganden besitzt
US7683140B2 (en) * 2004-05-20 2010-03-23 Univation Technologies, Llc Method for determining temperature value indicative of resin stickiness from data generated by polymerization reaction monitoring
US7754830B2 (en) 2004-05-20 2010-07-13 Univation Technologies, Llc Polymerization reaction monitoring with determination of induced condensing agent concentration for preventing discontinuity events
GB0425443D0 (en) 2004-11-18 2004-12-22 Bp Chem Int Ltd Supported polymerisation catalysts
EP1731536A1 (de) 2005-06-09 2006-12-13 Innovene Manufacturing France SAS Unterstützte Polymerisationskatalysatoren
US7534842B2 (en) 2005-11-16 2009-05-19 Chevron Phillips Chemical Company, Lp Catalysts for olefin polymerization
CA2662796A1 (en) * 2006-09-07 2008-03-13 Univation Technologies, Llc Methods for determining temperature value indicative of resin stickiness from data generated by polymerization reaction monitoring
JP2010502812A (ja) * 2006-09-07 2010-01-28 ユニベーション・テクノロジーズ・エルエルシー 溶融開始温度の降下に対するモデルを用いた樹脂粘着性の程度のオンライン決定のための方法
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CA2736685C (en) * 2011-04-07 2018-07-10 Nova Chemicals Corporation Supported phosphinimine-heteroligand catalyst systems
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JP6549578B2 (ja) 2013-12-19 2019-07-24 ダウ グローバル テクノロジーズ エルエルシー 金属−配位子錯体、それに由来するオレフィン重合触媒、及びその触媒を利用したオレフィン重合方法
CN107793510B (zh) * 2016-09-06 2020-06-09 中国石油化工股份有限公司 非茂金属化合物和乙烯-苯乙烯共聚物及制备方法和烯烃聚合用催化剂组合物及其应用
CA3037503A1 (en) 2018-04-26 2019-10-26 Nova Chemicals Corporation Phosphinimine amido-ether complexes
US20220185923A1 (en) * 2019-04-12 2022-06-16 Borealis Ag Catalyst system
JP7125569B2 (ja) * 2020-06-29 2022-08-24 ポリプラスチックス株式会社 環状オレフィン共重合体の製造方法、及びノルボルネン単量体とエチレンとの共重合用の触媒組成物
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CN114230604B (zh) * 2021-12-31 2023-12-26 常州汉韦聚合物有限公司 一种含双阴离子配体过渡金属配合物及其制备方法和应用
CN114292292B (zh) * 2021-12-31 2023-12-26 常州汉韦聚合物有限公司 一种含单阴离子配体过渡金属配合物及其制备方法和应用
CN115043965B (zh) * 2022-07-27 2023-04-21 中国科学技术大学 含有膦亚胺配体骨架的单茂金属催化剂及其制备方法和应用

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Also Published As

Publication number Publication date
CN1319104A (zh) 2001-10-24
KR20010070993A (ko) 2001-07-28
AU4126299A (en) 2000-02-14
JP4456273B2 (ja) 2010-04-28
EP1112278B1 (de) 2003-04-02
BR9912277A (pt) 2001-04-17
ATE236182T1 (de) 2003-04-15
EP1112278A1 (de) 2001-07-04
DE69906552D1 (de) 2003-05-08
CN1174990C (zh) 2004-11-10
US6147172A (en) 2000-11-14
CA2243775C (en) 2007-06-12
WO2000005237A1 (en) 2000-02-03
ES2196809T3 (es) 2003-12-16
KR100545640B1 (ko) 2006-01-24
CA2243775A1 (en) 2000-01-21
JP2002521501A (ja) 2002-07-16

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