DE69831791D1 - Übergangsmetallverbindungen der gruppe 5 - Google Patents

Übergangsmetallverbindungen der gruppe 5

Info

Publication number
DE69831791D1
DE69831791D1 DE69831791T DE69831791T DE69831791D1 DE 69831791 D1 DE69831791 D1 DE 69831791D1 DE 69831791 T DE69831791 T DE 69831791T DE 69831791 T DE69831791 T DE 69831791T DE 69831791 D1 DE69831791 D1 DE 69831791D1
Authority
DE
Germany
Prior art keywords
group
transition metal
metal compounds
compounds
transition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69831791T
Other languages
English (en)
Other versions
DE69831791T2 (de
Inventor
John Murphy
W Turner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
ExxonMobil Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ExxonMobil Chemical Patents Inc filed Critical ExxonMobil Chemical Patents Inc
Application granted granted Critical
Publication of DE69831791D1 publication Critical patent/DE69831791D1/de
Publication of DE69831791T2 publication Critical patent/DE69831791T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/005—Compounds of elements of Group 5 of the Periodic Table without metal-carbon linkages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69831791T 1997-02-07 1998-02-05 Übergangsmetallverbindungen der gruppe 5 Expired - Lifetime DE69831791T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/798,412 US5851945A (en) 1997-02-07 1997-02-07 Olefin polymerization catalyst compositions comprising group 5 transition metal compounds stabilized in their highest metal oxidation state
US798412 1997-02-07
PCT/US1998/002246 WO1998034964A1 (en) 1997-02-07 1998-02-05 Group 5 transition metal compounds

Publications (2)

Publication Number Publication Date
DE69831791D1 true DE69831791D1 (de) 2006-02-16
DE69831791T2 DE69831791T2 (de) 2006-06-22

Family

ID=25173338

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69831791T Expired - Lifetime DE69831791T2 (de) 1997-02-07 1998-02-05 Übergangsmetallverbindungen der gruppe 5

Country Status (7)

Country Link
US (2) US5851945A (de)
EP (1) EP0960142B1 (de)
JP (1) JP2001511208A (de)
CA (1) CA2278130C (de)
DE (1) DE69831791T2 (de)
ES (1) ES2246527T3 (de)
WO (1) WO1998034964A1 (de)

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US6143686A (en) * 1994-08-03 2000-11-07 Exxon Chemical Patents, Inc. Supported ionic catalyst compositions
PL197999B1 (pl) * 1998-06-09 2008-05-30 Cabot Corp Sposób i urządzenie modułowe do wytwarzania sadzy z surowca zawierającego węgiel
US6114270A (en) * 1998-08-07 2000-09-05 Equistar Chemicals, L.P. Polymerization-stable anionic ancillary ligand containing alkylimido catalysts and method of using the same
US6271325B1 (en) 1999-05-17 2001-08-07 Univation Technologies, Llc Method of polymerization
US6444302B1 (en) 1999-09-01 2002-09-03 Exxonmobil Chemical Patents Inc. Breathable films and method for making
US6271323B1 (en) 1999-10-28 2001-08-07 Univation Technologies, Llc Mixed catalyst compounds, catalyst systems and their use in a polymerization process
US6476164B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Carbenium cationic complexes suitable for polymerization catalysts
US6417304B1 (en) 1999-11-18 2002-07-09 Univation Technologies, Llc Method of polymerization and polymer produced therefrom
US6475946B1 (en) * 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Olefin polymerization catalysis with aryl substituted carbenium cationic complexes
US6624107B2 (en) 1999-10-22 2003-09-23 Univation Technologies, Llc Transition metal catalyst compounds having deuterium substituted ligand and catalyst systems thereof
US6300439B1 (en) 1999-11-08 2001-10-09 Univation Technologies, Llc Group 15 containing transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6380328B1 (en) 1999-12-10 2002-04-30 Univation Technologies, Llc Catalyst systems and their use in a polymerization process
US6265505B1 (en) 1999-11-18 2001-07-24 Univation Technologies, Llc Catalyst system and its use in a polymerization process
US6274684B1 (en) 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US6300438B1 (en) 1999-10-22 2001-10-09 Univation Technolgies, Llc Hafnium transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US6281155B1 (en) * 1999-11-19 2001-08-28 Equistar Chemicals, L.P. Supported olefin polymerization catalysts
US6489480B2 (en) 1999-12-09 2002-12-03 Exxonmobil Chemical Patents Inc. Group-15 cationic compounds for olefin polymerization catalysts
US6822057B2 (en) * 1999-12-09 2004-11-23 Exxon Mobil Chemical Patents Inc. Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them
CA2393327A1 (en) 1999-12-20 2001-06-28 Exxon Chemical Patents Inc. Processes for the preparation polyolefin resins using supported ionic catalysts
US6809209B2 (en) 2000-04-07 2004-10-26 Exxonmobil Chemical Patents Inc. Nitrogen-containing group-13 anionic compounds for olefin polymerization
US7390861B2 (en) * 2000-10-19 2008-06-24 Exxonmobil Chemical Patents Inc. Cationic group-3 catalyst system
US7511104B2 (en) 2001-06-20 2009-03-31 Exxonmobil Chemical Patents Inc. Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them
DE10140135A1 (de) * 2001-08-16 2003-02-27 Bayer Ag Vanadium-Imidoaryl-Komplexe für die Olefinpolymerisation
US7943700B2 (en) * 2002-10-01 2011-05-17 Exxonmobil Chemical Patents Inc. Enhanced ESCR of HDPE resins
WO2004046214A2 (en) 2002-10-15 2004-06-03 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
US6953764B2 (en) 2003-05-02 2005-10-11 Dow Global Technologies Inc. High activity olefin polymerization catalyst and process
US20070073012A1 (en) 2005-09-28 2007-03-29 Pannell Richard B Method for seed bed treatment before a polymerization reaction
US7985811B2 (en) * 2004-01-02 2011-07-26 Univation Technologies, Llc Method for controlling sheeting in gas phase reactors
US20050148742A1 (en) * 2004-01-02 2005-07-07 Hagerty Robert O. Method for controlling sheeting in gas phase reactors
CA2473378A1 (en) * 2004-07-08 2006-01-08 Nova Chemicals Corporation Novel borate activator
EP1803747A1 (de) 2005-12-30 2007-07-04 Borealis Technology Oy Oberflächemodifizierte Polymerisationskatalysatoren zur Herstellung von Polyolefinfilmen mit niedrigem Gelgehalt
US8198373B2 (en) * 2006-10-02 2012-06-12 Exxonmobil Chemical Patents Inc. Plastic toughened plastics
CN101274968B (zh) * 2007-03-28 2012-11-21 中国石油化工股份有限公司 一种用于生产宽分子量分布的聚乙烯的复合催化剂
CA2688217C (en) * 2009-12-11 2016-07-12 Nova Chemicals Corporation Multi reactor process
CA2864573C (en) 2014-09-22 2021-07-06 Nova Chemicals Corporation Shrink film from single site catalyzed polyethylene
CA2874895C (en) 2014-12-16 2022-02-15 Nova Chemicals Corporation High modulus single-site lldpe
WO2018022263A1 (en) 2016-07-29 2018-02-01 Exxonmobil Chemical Patents Inc. Polymerization processes using high molecular weight polyhydric quenching agents
EP4330294A1 (de) 2021-04-30 2024-03-06 ExxonMobil Chemical Patents Inc. Verfahren zum übergang zwischen verschiedenen polymerisationskatalysatoren in einem polymerisationsreaktor

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FR1317869A (de) * 1961-03-20 1963-05-08
US3700710A (en) * 1966-04-04 1972-10-24 Monsanto Co Methylene bis(aluminum dihalides) useful as polymerization catalyst components
US3655583A (en) * 1968-07-30 1972-04-11 Sumitomo Chemical Co Vanadye compound having cyclic hydrocarbon substituent and polymerization catalyst containing said compound
JPS5242095B2 (de) * 1972-06-16 1977-10-22
DE2256695A1 (de) * 1972-11-18 1974-05-22 Veba Chemie Ag Verfahren zur herstellung von polymerisationskatalysatoren und die polymerisation und copolymerisation von olefinen
DE2847986A1 (de) * 1978-11-04 1980-05-22 Huels Chemische Werke Ag Verfahren zur herstellung von pulverfoermigen, thermoplastischen copolymeren aus aethylen und buten-(1)
US4508842A (en) * 1983-03-29 1985-04-02 Union Carbide Corporation Ethylene polymerization using supported vanadium catalyst
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US5324800A (en) * 1983-06-06 1994-06-28 Exxon Chemical Patents Inc. Process and catalyst for polyolefin density and molecular weight control
US5384299A (en) * 1987-01-30 1995-01-24 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
PL276385A1 (en) * 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5017714A (en) * 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5036034A (en) * 1989-10-10 1991-07-30 Fina Technology, Inc. Catalyst for producing hemiisotactic polypropylene
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DE551277T1 (de) * 1990-06-22 1996-10-10 Exxon Chemical Patents Inc., Linden, N.J. Aluminiumfreie monocyclopentadienyl-metallocenkatalysatoren für olefinpolymerisation.
EP0569388B1 (de) * 1990-12-27 1996-03-13 Exxon Chemical Patents Inc. Übergangsmetall-amidoverbindung und katalysatorsystem zur herstellung von isotaktischem propylen
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US5434116A (en) * 1992-06-05 1995-07-18 Tosoh Corporation Organic transition metal compound having π-bonding heterocyclic ligand and method of polymerizing olefin by using the same
CA2139356C (en) * 1992-07-01 2001-02-06 Donna J. Crowther Transition metal olefin polymerization catalysts
BE1006453A3 (nl) * 1992-12-21 1994-08-30 Dsm Nv Katalysator en werkwijze voor een ziegler polymerisatie.
US5416053A (en) * 1993-06-28 1995-05-16 Union Carbide Chemicals & Plastics Technology Corporation Homogenous polyethylenes and ethylene/propylene copolymers rubbers
US5405924A (en) * 1993-07-22 1995-04-11 Shell Oil Company Imido transition metal complex metathesis catalysts
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US5707913A (en) * 1994-06-15 1998-01-13 Basf Aktiengesellschaft Amidinato catalyst systems for the polymerization of olefins
US5821278A (en) * 1994-11-17 1998-10-13 Ciba Specialty Chemicals Corporation Process for polymerizing of cyclic olefins and a photopolymerizable composition
US5670439A (en) * 1995-03-29 1997-09-23 Quantum Chemical Corporation Vanadium-containing catalyst system

Also Published As

Publication number Publication date
ES2246527T3 (es) 2006-02-16
US5851945A (en) 1998-12-22
DE69831791T2 (de) 2006-06-22
CA2278130C (en) 2008-04-22
CA2278130A1 (en) 1998-08-13
JP2001511208A (ja) 2001-08-07
WO1998034964A1 (en) 1998-08-13
EP0960142A1 (de) 1999-12-01
EP0960142B1 (de) 2005-10-05
US6232416B1 (en) 2001-05-15

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Legal Events

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