DE69801596T2 - Veresterungskatalysatoren - Google Patents

Veresterungskatalysatoren

Info

Publication number
DE69801596T2
DE69801596T2 DE69801596T DE69801596T DE69801596T2 DE 69801596 T2 DE69801596 T2 DE 69801596T2 DE 69801596 T DE69801596 T DE 69801596T DE 69801596 T DE69801596 T DE 69801596T DE 69801596 T2 DE69801596 T2 DE 69801596T2
Authority
DE
Germany
Prior art keywords
esterification
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69801596T
Other languages
English (en)
Other versions
DE69801596D1 (de
Inventor
John Ridland
Wesley Hepplewhite
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ACMA Ltd RUNCORN
Original Assignee
ACMA Ltd RUNCORN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ACMA Ltd RUNCORN filed Critical ACMA Ltd RUNCORN
Publication of DE69801596D1 publication Critical patent/DE69801596D1/de
Application granted granted Critical
Publication of DE69801596T2 publication Critical patent/DE69801596T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201Oxygen-containing compounds
    • B01J31/0211Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212Alkoxylates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255Phosphorus containing compounds
    • B01J31/0257Phosphorus acids or phosphorus acid esters
    • B01J31/0258Phosphoric acid mono-, di- or triesters ((RO)(R'O)2P=O), i.e. R= C, R'= C, H
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/068Polyalkylene glycols
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/08Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/82Preparation processes characterised by the catalyst used
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/82Preparation processes characterised by the catalyst used
    • C08G63/84Boron, aluminium, gallium, indium, thallium, rare-earth metals, or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • C08G63/82Preparation processes characterised by the catalyst used
    • C08G63/85Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/40Substitution reactions at carbon centres, e.g. C-C or C-X, i.e. carbon-hetero atom, cross-coupling, C-H activation or ring-opening reactions
    • B01J2231/49Esterification or transesterification
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/31Aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/46Titanium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/40Complexes comprising metals of Group IV (IVA or IVB) as the central metal
    • B01J2531/48Zirconium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2204Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208Oxygen, e.g. acetylacetonates
    • B01J31/2226Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/223At least two oxygen atoms present in one at least bidentate or bridging ligand
DE69801596T 1997-12-02 1998-11-16 Veresterungskatalysatoren Expired - Lifetime DE69801596T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB9725419.7A GB9725419D0 (en) 1997-12-02 1997-12-02 Esterification catalysts
PCT/GB1998/003448 WO1999028033A1 (en) 1997-12-02 1998-11-16 Esterification catalysts

Publications (2)

Publication Number Publication Date
DE69801596D1 DE69801596D1 (de) 2001-10-11
DE69801596T2 true DE69801596T2 (de) 2002-04-18

Family

ID=10822947

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69801596T Expired - Lifetime DE69801596T2 (de) 1997-12-02 1998-11-16 Veresterungskatalysatoren

Country Status (25)

Country Link
US (1) US6372929B1 (de)
EP (1) EP1035916B1 (de)
JP (1) JP4377053B2 (de)
KR (1) KR100552882B1 (de)
CN (1) CN1167508C (de)
AR (1) AR017422A1 (de)
AT (1) ATE205114T1 (de)
AU (1) AU746951B2 (de)
BR (1) BR9814709A (de)
CA (1) CA2309697A1 (de)
CO (1) CO4810385A1 (de)
DE (1) DE69801596T2 (de)
ES (1) ES2162478T3 (de)
GB (1) GB9725419D0 (de)
HU (1) HUP0004493A3 (de)
ID (1) ID24715A (de)
MY (1) MY128075A (de)
NO (1) NO20002782L (de)
NZ (1) NZ504219A (de)
PL (1) PL192913B1 (de)
RU (1) RU2181307C2 (de)
SK (1) SK8312000A3 (de)
TR (1) TR200001539T2 (de)
TW (1) TW448073B (de)
WO (1) WO1999028033A1 (de)

Families Citing this family (63)

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US6255441B1 (en) 1998-04-17 2001-07-03 E. I. Du Pont De Nemours And Company Titanium-containing catalyst composition and processes therefor and therewith
GB9912210D0 (en) * 1999-05-25 1999-07-28 Acma Ltd Esterification catalysts
IT1315212B1 (it) * 1999-07-26 2003-02-03 Consiglio Nazionale Ricerche Impiego di ortoesteri per la sintesi di acidi chirali in processi diesterificazione irreversibili biocatalizzati.
MXPA02001863A (es) 1999-08-24 2003-07-14 Toyo Boseki Catalizador de polimerizacion de poliester, poliester producido usando el mismo y proceso para producir poliester.
US6075115A (en) * 1999-10-19 2000-06-13 E. I. Du Pont De Nemours And Company Process for the production of 5-sulfo isophthalate bis-glycolate ester metal salts and oxysulfonated polyesters made therefrom
US6166170A (en) * 1999-12-02 2000-12-26 E. I. Du Pont De Nemours And Company Esterification catalysts and processes therefor and therewith
US6372879B1 (en) 2000-01-07 2002-04-16 Atofina Chemicals, Inc. Polyester polycondensation with catalyst and a catalyst enhancer
TW546330B (en) * 2000-01-07 2003-08-11 Teijin Ltd Biaxially oriented polyester film for metal sheet laminating molding
JP5152608B2 (ja) * 2000-01-26 2013-02-27 東洋紡株式会社 ポリエステル重合触媒およびこれを用いて製造されたポリエステル並びにポリエステルの製造方法
US6355817B1 (en) * 2000-07-15 2002-03-12 Exxonmobil Chemical Patents Inc. Optimized catalyst addition to enhance esterification catalyst performance
US6303738B1 (en) * 2000-08-04 2001-10-16 E. I. Du Pont De Nemours And Company Esterification process
CA2420958C (en) 2000-09-12 2010-01-12 Toyo Boseki Kabushiki Kaisha Polyester polymerization catalyst and polyester produced by using the same and production method of polyester
JP2004514764A (ja) * 2000-11-21 2004-05-20 インペリアル・ケミカル・インダストリーズ・ピーエルシー エステル化触媒、ポリエステルプロセス、およびポリエステル製品
DE10059612A1 (de) * 2000-12-01 2002-06-20 Bayer Ag Titan-/Zirkonium-Katalysatoren sowie deren Verwendung zur Herstellung von Estern oder Polyestern
WO2002057335A1 (fr) * 2001-01-18 2002-07-25 Toyo Boseki Kabushiki Kaisha Catalyseur de polymerisation de polyester, polyester et procede de fabrication de celui-ci
US6914107B2 (en) * 2001-01-24 2005-07-05 E. I. Du Pont De Nemours And Company Catalyst composition and process therewith
US6489433B2 (en) 2001-02-23 2002-12-03 E. I. Du Pont De Nemours And Company Metal-containing composition and process therewith
JP5028712B2 (ja) * 2001-02-23 2012-09-19 東洋紡績株式会社 白色配向ポリエステルフィルム
WO2002068500A1 (fr) * 2001-02-23 2002-09-06 Toyo Boseki Kabushiki Kaisha Catalyseur de polymerisation pour polyester, polyester produit par le meme et procede de production de polyester
US6506853B2 (en) 2001-02-28 2003-01-14 E. I. Du Pont De Nemours And Company Copolymer comprising isophthalic acid
DE10127146A1 (de) * 2001-06-02 2002-12-05 Zimmer Ag Verfahren zur Herstellung von Polybutylenterephthalat
EP1413593B1 (de) 2001-07-16 2015-10-28 Teijin Limited Katalysator für die polyesterherstellung und verfahren zur herstellung von polyester mit dem katalysator
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JP3962235B2 (ja) * 2001-08-29 2007-08-22 帝人ファイバー株式会社 ポリエステル繊維及びその製造方法
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DE60328083D1 (de) 2002-02-14 2009-08-06 Mitsui Chemicals Inc Polyesterharz und katalysator für die polyesterherstellung, verfahren zur herstellung von polyesterharz mit dem katalysator.
KR100469901B1 (ko) * 2002-04-08 2005-02-02 도레이새한 주식회사 폴리에스테르 제조용 촉매조성물
US20030203811A1 (en) 2002-04-25 2003-10-30 Putzig Donald Edward Stable aqueous solutions comprising titanium and zinc and process therewith
KR20030084183A (ko) * 2002-04-25 2003-11-01 켐엔텍 주식회사 폴리에스테르의 제조방법
GB0215961D0 (en) * 2002-07-10 2002-08-21 Ici Plc Supported catalyst
US6841505B2 (en) 2002-07-26 2005-01-11 E..I. Du Pont De Nemours And Company Titanium-zirconium catalyst compositions and use thereof
US6953768B2 (en) 2002-11-26 2005-10-11 Teck Cominco Metals Ltd. Multi-component catalyst system for the polycondensation manufacture of polyesters
GB0228267D0 (en) * 2002-12-04 2003-01-08 Johnson Matthey Plc Catalyst and process
JP4684890B2 (ja) * 2003-06-17 2011-05-18 三井化学株式会社 チタン含有溶液、ポリエステル製造用触媒およびポリエステル樹脂の製造方法
JP4329427B2 (ja) 2003-06-26 2009-09-09 東レ株式会社 ポリエステル組成物及びそれからなる繊維
US20050215425A1 (en) * 2004-03-26 2005-09-29 Clair Jerry D S Esterification catalyst and process therewith
US20050215426A1 (en) * 2004-03-26 2005-09-29 Putzig Donald E Esterification catalyst and process therewith
JP4660107B2 (ja) * 2004-04-02 2011-03-30 帝人ファイバー株式会社 ポリエステル製造用難沈殿性チタン触媒
JP4660108B2 (ja) * 2004-04-02 2011-03-30 帝人ファイバー株式会社 ポリエステル製造用難沈殿性微細チタン触媒
US7226888B2 (en) * 2004-08-06 2007-06-05 E. I. Du Pont De Nemours And Company Composition comprising titanium and aluminium and polyester production
KR101270863B1 (ko) * 2005-01-21 2013-06-05 미쓰비시 가가꾸 가부시키가이샤 폴리에스테르 제조용 중축합 촉매 및 이를 이용한폴리에스테르 수지의 제조 방법
EP1820814B1 (de) * 2006-01-24 2007-08-29 Lurgi Zimmer GmbH Verfahren zur Veresterung von Terephthalsäure mit Butandiol, Verfahren zur Herstellung von Polybutylenterephthalat und Vorrichtung dafür
TWI402293B (zh) * 2006-04-06 2013-07-21 Teijin Fibers Ltd Production method of polyethylene terephthalate
US7745368B2 (en) * 2006-07-28 2010-06-29 Eastman Chemical Company Non-precipitating alkali/alkaline earth metal and aluminum compositions made with organic hydroxyacids
US7709595B2 (en) * 2006-07-28 2010-05-04 Eastman Chemical Company Non-precipitating alkali/alkaline earth metal and aluminum solutions made with polyhydroxyl ether solvents
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CN101148499B (zh) * 2006-09-20 2010-08-11 中国石油化工股份有限公司 钛系催化剂
CN101148500B (zh) * 2006-09-20 2010-12-22 中国石油化工股份有限公司 钛系聚酯催化剂的制备方法
US8563677B2 (en) * 2006-12-08 2013-10-22 Grupo Petrotemex, S.A. De C.V. Non-precipitating alkali/alkaline earth metal and aluminum solutions made with diols having at least two primary hydroxyl groups
CN101323661B (zh) * 2007-06-13 2011-04-27 中国石油化工股份有限公司 聚酯的生产方法
KR101044393B1 (ko) * 2007-12-27 2011-06-27 주식회사 엘지화학 지르코늄 화합물을 포함하는 에스테르화 촉매 조성물 및이를 이용한 에스테르 화합물의 제조방법
KR101109045B1 (ko) * 2008-01-07 2012-01-31 주식회사 엘지화학 지르코늄 화합물을 포함하는 에스테르화 촉매 조성물 및이를 이용한 에스테르 화합물의 제조방법
US7851645B2 (en) * 2008-02-11 2010-12-14 Catalytic Distillation Technologies Process for continuous production of organic carbonates or organic carbamates and solid catalysts therefore
JP5326741B2 (ja) 2008-09-29 2013-10-30 東レ株式会社 ポリエステル重合触媒およびそれを用いるポリエステルの製造方法
JP5911734B2 (ja) * 2012-02-24 2016-04-27 大和製罐株式会社 ポリエステル樹脂組成物及びその製造方法
US8759559B2 (en) 2012-04-18 2014-06-24 E I Du Pont De Nemours And Company Processes for preparing polytrimethylene ether glycol esters
CN102718958A (zh) * 2012-07-03 2012-10-10 常州大学 一种钛系聚酯催化剂及其制备方法和应用
US9670313B2 (en) * 2012-07-30 2017-06-06 Sabic Global Technologies B.V. Hydrostability of polyester composition
EP2880077B1 (de) 2012-07-30 2021-08-25 SABIC Global Technologies B.V. Verfahren zur herstellung von polyalkylenterephthalatharzzusammensetzungen mit einem titanhaltigen katalysatorkomplex
WO2015087412A1 (ja) * 2013-12-11 2015-06-18 賢次郎 牧野 線状のアルコキシチタン酸・リン酸重合体の製造方法
CN104117378B (zh) * 2014-06-29 2016-03-02 陈昆 酯化反应催化剂的制备方法
JP5861129B2 (ja) * 2014-07-24 2016-02-16 健一 牧野 線状のアルコキシチタン酸・リン酸重合体の製造方法

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Also Published As

Publication number Publication date
US6372929B1 (en) 2002-04-16
HUP0004493A3 (en) 2006-04-28
DE69801596D1 (de) 2001-10-11
EP1035916B1 (de) 2001-09-05
PL192913B1 (pl) 2006-12-29
RU2181307C2 (ru) 2002-04-20
CA2309697A1 (en) 1999-06-10
KR100552882B1 (ko) 2006-02-20
SK8312000A3 (en) 2000-10-09
BR9814709A (pt) 2000-10-03
ID24715A (id) 2000-08-03
WO1999028033A1 (en) 1999-06-10
EP1035916A1 (de) 2000-09-20
NO20002782D0 (no) 2000-05-31
NZ504219A (en) 2001-11-30
JP2001524536A (ja) 2001-12-04
AR017422A1 (es) 2001-09-05
MY128075A (en) 2007-01-31
AU746951B2 (en) 2002-05-09
HUP0004493A2 (hu) 2001-04-28
CN1167508C (zh) 2004-09-22
CN1280522A (zh) 2001-01-17
TR200001539T2 (tr) 2000-12-21
NO20002782L (no) 2000-06-26
TW448073B (en) 2001-08-01
PL340912A1 (en) 2001-03-12
CO4810385A1 (es) 1999-06-30
AU1166499A (en) 1999-06-16
KR20010032669A (ko) 2001-04-25
GB9725419D0 (en) 1998-01-28
ES2162478T3 (es) 2001-12-16
ATE205114T1 (de) 2001-09-15
JP4377053B2 (ja) 2009-12-02

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