DE69525679D1 - Katalysator zur Polymerisation eines Olefins und Verfahren zum Polymerisieren des Olefins - Google Patents

Katalysator zur Polymerisation eines Olefins und Verfahren zum Polymerisieren des Olefins

Info

Publication number
DE69525679D1
DE69525679D1 DE69525679T DE69525679T DE69525679D1 DE 69525679 D1 DE69525679 D1 DE 69525679D1 DE 69525679 T DE69525679 T DE 69525679T DE 69525679 T DE69525679 T DE 69525679T DE 69525679 D1 DE69525679 D1 DE 69525679D1
Authority
DE
Germany
Prior art keywords
polymerizing
olefin
catalyst
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69525679T
Other languages
English (en)
Other versions
DE69525679T2 (de
Inventor
Yoshinori Suga
Yasuo Maruyama
Eiji Isobe
Yumito Uehara
Yoshiyuki Ishihama
Takehiro Sagae
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical Corp filed Critical Mitsubishi Chemical Corp
Application granted granted Critical
Publication of DE69525679D1 publication Critical patent/DE69525679D1/de
Publication of DE69525679T2 publication Critical patent/DE69525679T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69525679T 1994-05-18 1995-05-17 Katalysator zur Polymerisation eines Olefins und Verfahren zum Polymerisieren des Olefins Expired - Lifetime DE69525679T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP10381594 1994-05-18
JP21475194 1994-09-08

Publications (2)

Publication Number Publication Date
DE69525679D1 true DE69525679D1 (de) 2002-04-11
DE69525679T2 DE69525679T2 (de) 2002-11-07

Family

ID=26444405

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69525679T Expired - Lifetime DE69525679T2 (de) 1994-05-18 1995-05-17 Katalysator zur Polymerisation eines Olefins und Verfahren zum Polymerisieren des Olefins

Country Status (3)

Country Link
US (2) US5928982A (de)
EP (1) EP0683180B1 (de)
DE (1) DE69525679T2 (de)

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JP3383155B2 (ja) * 1996-06-26 2003-03-04 三菱化学株式会社 エチレン系重合体
EP0839842B1 (de) 1996-10-31 2004-04-14 Mitsubishi Chemical Corporation Film, hergestellt aus einem Ethylen-Alphaolefin-Copolymer
EP0846696B1 (de) 1996-12-09 2003-06-18 Mitsubishi Chemical Corporation Katalysator für Alpha-Olefinpolymerisation
US6048817A (en) * 1997-04-25 2000-04-11 Mitsubishi Chemical Corporation Polymerization of olefins
AU8229898A (en) * 1997-07-08 1999-02-08 Bp Chemicals Limited Supported polymerisation catalyst
GB9722447D0 (en) 1997-10-23 1997-12-24 Borealis As Process
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US7354880B2 (en) 1998-07-10 2008-04-08 Univation Technologies, Llc Catalyst composition and methods for its preparation and use in a polymerization process
EP0974601B1 (de) * 1998-07-21 2003-09-10 Japan Polychem Corporation Olefinpolymerisationskatalysator und Verfahren zur Herstellung von Olefinpolymeren
CN1092216C (zh) * 1998-11-26 2002-10-09 中国石油化工集团公司 一种聚乙烯与粘土的纳米级复合材料
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WO2000069959A2 (en) * 1999-05-19 2000-11-23 National Institute Of Standards & Technology Polymer layered inorganic nanocomposites
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US6399535B1 (en) * 1999-11-01 2002-06-04 W. R. Grace & Co.-Conn. Coordination catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US6559090B1 (en) * 1999-11-01 2003-05-06 W. R. Grace & Co.-Conn. Metallocene and constrained geometry catalyst systems employing agglomerated metal oxide/clay support-activator and method of their preparation
US6632911B1 (en) * 1999-11-05 2003-10-14 Japan Polychem Corporation Ethylene/α-olefin copolymer and film made thereof
AU1362801A (en) * 1999-12-10 2001-06-18 Dow Chemical Company, The Treated clay compositions and olefin polymerization catalysts comprising the same
EP1255783B1 (de) 1999-12-15 2005-12-07 Univation Technologies LLC Polymerisationsverfahren
US6482903B1 (en) 1999-12-15 2002-11-19 Univation Technologies, Llc Method for preparing a supported catalyst system and its use in a polymerization process
US6576583B1 (en) * 2000-02-11 2003-06-10 Phillips Petroleum Company Organometal catalyst composition
DE60129075T2 (de) 2000-05-29 2008-03-06 Japan Polychem Corp. Olefinpolymerisationskatalysator, Verfahren zur Olefinpolymerisation damit
WO2002022693A1 (fr) * 2000-09-13 2002-03-21 Japan Polychem Corporation Catalyseur pour polymerisation d'olefines
KR100409018B1 (ko) * 2000-10-09 2003-12-06 주식회사 엘지화학 신디오탁틱 스티렌 중합용 촉매 및 이를 이용한신디오탁틱 스티렌 중합체의 제조방법
ATE446137T1 (de) * 2001-04-05 2009-11-15 Japan Polypropylene Corp Katalysator für olefinpolymerisation und verfahren zur olefinpolymerisation
KR100628620B1 (ko) 2001-04-30 2006-09-26 더블유.알. 그레이스 앤드 캄파니-콘. 이종 크롬 촉매 및 이를 사용하는 올레핀의 중합 방법
US6943224B2 (en) 2001-04-30 2005-09-13 W. R. Grace & Co.-Conn. Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby
WO2002088200A1 (en) 2001-04-30 2002-11-07 W.R. Grace & Co.-Conn. Supported dual transition metal catalyst systems
EP1453868A2 (de) 2001-04-30 2004-09-08 W. R. Grace & Co.-Conn Koordinationskatalysatorsysteme unter verwendung von chromträgeragglomerat und verfahren zu ihrer herstellung
EP1401889B1 (de) 2001-04-30 2010-06-09 W.R. Grace & Co.-Conn. Verfahren zur herstellung von geträgerten übergangsmetallpolymerisationskatalysatoren und daraus gebildete zusammensetzungen
CA2405241C (en) * 2002-09-24 2011-07-26 Nova Chemicals Corporation Olefin polymerization catalyst system
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
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US6982306B2 (en) 2003-11-26 2006-01-03 Chevron Phillips Chemical Company, L.P. Stannoxy-substituted metallocene catalysts for olefin and acetylene polymerization
US7741417B2 (en) * 2004-01-07 2010-06-22 Exxonmobil Chemical Patents Inc. Preparation of polymerization catalyst activators utilizing indole-modified silica supports
US7220695B2 (en) * 2004-01-07 2007-05-22 Exxonmobil Chemical Patents Inc. Supported activator
US20060040822A1 (en) * 2004-08-23 2006-02-23 Shveima Joseph S Catalyst compositions, processes, and products utilizing pillared clays
US7754789B1 (en) 2006-06-12 2010-07-13 The Regents Of The University Of California Method for forming flame-retardant clay-polyolefin composites
US8022005B2 (en) * 2007-11-08 2011-09-20 Exxonmobil Chemical Patents Inc. Halogen substituted heterocyclic heteroatom containing ligands-alumoxane activation of metallocenes
US8309485B2 (en) 2009-03-09 2012-11-13 Chevron Phillips Chemical Company Lp Methods for producing metal-containing sulfated activator-supports
US20150166688A1 (en) 2012-05-11 2015-06-18 Fundacion Cidaut Method for polymerisation over nanoparticles and polymer thus obtained
CN105683221B (zh) 2013-10-25 2018-06-26 日本聚丙烯株式会社 烯烃聚合用催化剂组分、烯烃聚合用催化剂、和使用其的烯烃(共)聚合物的制造方法
US9321854B2 (en) 2013-10-29 2016-04-26 Exxonmobil Chemical Patents Inc. Aluminum alkyl with C5 cyclic and pendent olefin polymerization catalyst
BR112017024302A2 (pt) 2015-05-11 2018-07-24 Grace W R & Co processo para a produção de argila modificada, catalisador de polimerização de metaloceno suportado, catalisador produzido e uso dos mesmos
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US10618988B2 (en) 2015-08-31 2020-04-14 Exxonmobil Chemical Patents Inc. Branched propylene polymers produced via use of vinyl transfer agents and processes for production thereof
CN107922527A (zh) 2015-08-31 2018-04-17 埃克森美孚化学专利公司 用于聚烯烃反应的具有悬垂烯烃的铝烷基
US9982067B2 (en) 2015-09-24 2018-05-29 Exxonmobil Chemical Patents Inc. Polymerization process using pyridyldiamido compounds supported on organoaluminum treated layered silicate supports
US10000593B2 (en) 2015-10-02 2018-06-19 Exxonmobil Chemical Patents Inc. Supported Salan catalysts
US10414887B2 (en) 2015-10-02 2019-09-17 Exxonmobil Chemical Patents Inc. Supported catalyst systems and methods of using same
US9994658B2 (en) 2015-10-02 2018-06-12 Exxonmobil Chemical Patents Inc. Polymerization process using bis phenolate compounds supported on organoaluminum treated layered silicate supports
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Also Published As

Publication number Publication date
US5973084A (en) 1999-10-26
EP0683180A2 (de) 1995-11-22
EP0683180B1 (de) 2002-03-06
EP0683180A3 (de) 1998-10-14
DE69525679T2 (de) 2002-11-07
US5928982A (en) 1999-07-27

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