DE69514834D1 - Verfahren zur herstellung von ethylbenzol durch alkylierung in der flüssigphase und transalkylierung in der gasphase - Google Patents

Verfahren zur herstellung von ethylbenzol durch alkylierung in der flüssigphase und transalkylierung in der gasphase

Info

Publication number
DE69514834D1
DE69514834D1 DE69514834T DE69514834T DE69514834D1 DE 69514834 D1 DE69514834 D1 DE 69514834D1 DE 69514834 T DE69514834 T DE 69514834T DE 69514834 T DE69514834 T DE 69514834T DE 69514834 D1 DE69514834 D1 DE 69514834D1
Authority
DE
Germany
Prior art keywords
ethylbenzol
transalkylation
alkylation
producing
liquid phase
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69514834T
Other languages
English (en)
Other versions
DE69514834T2 (de
Inventor
Chi-Ya Cheng
Morris Smith
Rao Venkat
Edward Walsh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Application granted granted Critical
Publication of DE69514834D1 publication Critical patent/DE69514834D1/de
Publication of DE69514834T2 publication Critical patent/DE69514834T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/02—Monocyclic hydrocarbons
    • C07C15/067—C8H10 hydrocarbons
    • C07C15/073—Ethylbenzene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE69514834T 1994-12-27 1995-12-04 Verfahren zur herstellung von ethylbenzol durch alkylierung in der flüssigphase und transalkylierung in der gasphase Expired - Fee Related DE69514834T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/364,145 US5600048A (en) 1994-12-27 1994-12-27 Continuous process for preparing ethylbenzene using liquid phase alkylation and vapor phase transalkylation
PCT/US1995/015660 WO1996020148A1 (en) 1994-12-27 1995-12-04 Continuous process for preparing ethylbenzene using liquid phase alkylation and vapor phase transalkylation

Publications (2)

Publication Number Publication Date
DE69514834D1 true DE69514834D1 (de) 2000-03-02
DE69514834T2 DE69514834T2 (de) 2000-10-12

Family

ID=23433220

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69514834T Expired - Fee Related DE69514834T2 (de) 1994-12-27 1995-12-04 Verfahren zur herstellung von ethylbenzol durch alkylierung in der flüssigphase und transalkylierung in der gasphase

Country Status (11)

Country Link
US (1) US5600048A (de)
EP (1) EP0800497B1 (de)
JP (1) JP3802060B2 (de)
KR (1) KR100356039B1 (de)
CN (1) CN1046928C (de)
AU (1) AU689687B2 (de)
DE (1) DE69514834T2 (de)
ES (1) ES2141398T3 (de)
MY (1) MY123672A (de)
TW (1) TW330193B (de)
WO (1) WO1996020148A1 (de)

Families Citing this family (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998003455A1 (fr) * 1996-07-19 1998-01-29 Asahi Kasei Kogyo Kabushiki Kaisha Procede pour la preparation d'ethylbenzene
EP0920404B1 (de) * 1996-10-02 2000-12-13 The Dow Chemical Company Auf zeolite basiertes verfahren zur herstellung von ethylbenzol das geeignet ist zur verwendung in einer auf aluminumchlorid basierten vorrichtung zur herstellung von ehtylbenzol
US5907073A (en) * 1998-02-24 1999-05-25 Fina Technology, Inc. Aromatic alkylation process
US6642426B1 (en) * 1998-10-05 2003-11-04 David L. Johnson Fluid-bed aromatics alkylation with staged injection of alkylating agents
DE60011814T2 (de) * 1999-09-20 2005-07-07 Consejo Superior de Investigaciónes Científicas Alkylierung von aromaten
US6489529B1 (en) 2000-01-24 2002-12-03 Exxonmobil Oil Corporation Production of monocycloalkyl aromatic compounds
RU2277081C2 (ru) * 2000-02-02 2006-05-27 Дзе Дау Кемикал Компани Интегрированный процесс получения алкенилзамещенного ароматического соединения
AU2001294700A1 (en) * 2000-09-25 2002-04-08 Exxonmobil Chemical Patents Inc Maximizing meta-isomers in the production of dialkylbenzene compounds
US20020042548A1 (en) * 2001-07-11 2002-04-11 Dandekar Ajit B. Process for producing cumene
US6995295B2 (en) * 2002-09-23 2006-02-07 Exxonmobil Chemical Patents Inc. Alkylaromatics production
US7019185B2 (en) * 2002-12-06 2006-03-28 Exxonmobil Chemical Patents Inc. Aromatic alkylation process
US7238843B2 (en) * 2003-02-28 2007-07-03 Abb Lummus Global, Inc. Process for the production of alkylaromatics
CN1296133C (zh) * 2004-01-19 2007-01-24 中国石油化工股份有限公司 一种含mcm－22沸石的催化剂
US7592282B2 (en) * 2004-11-11 2009-09-22 Battelle Energy Alliance, Llc Enhancement of alkylation catalysts for improved supercritical fluid regeneration
EP1856012B1 (de) * 2005-02-28 2020-03-18 ExxonMobil Research and Engineering Company Aromatischer alkylierungsprozess in dampfphase
US7476774B2 (en) * 2005-02-28 2009-01-13 Exxonmobil Research And Engineering Company Liquid phase aromatics alkylation process
CA2599351C (en) * 2005-02-28 2011-08-30 Exxonmobil Research And Engineering Company Gasoline production by olefin polymerization with aromatics alkylation
US7501547B2 (en) * 2006-05-10 2009-03-10 Exxonmobil Chemical Patents Inc. Alkylaromatics production
US20080033222A1 (en) * 2006-05-24 2008-02-07 Clark Michael C Process and apparatus for preparing ethylbenzene using vapor phase alkylation and liquid phase transalkylation
JP5306586B2 (ja) * 2006-09-07 2013-10-02 旭化成ケミカルズ株式会社 シクロヘキセンの製造方法
US7790940B2 (en) * 2007-06-21 2010-09-07 Exxonmobil Chemical Patents Inc. Liquid phase alkylation process
US8816145B2 (en) 2007-06-21 2014-08-26 Exxonmobil Chemical Patents Inc. Liquid phase alkylation process
US8633343B2 (en) 2009-05-26 2014-01-21 Exxonmobil Chemical Patents Inc. Transalkylation of polycyclohexylbenzenes
EP2571833B1 (de) 2010-05-20 2018-05-30 ExxonMobil Chemical Patents Inc. Verbessertes alkylierungsverfahren
WO2012030440A1 (en) 2010-08-30 2012-03-08 Exxonmobil Chemical Patents Inc. Improved alkylation process
CN103180042B (zh) 2010-10-15 2015-07-22 埃克森美孚化学专利公司 选择改进的催化剂组合物和使用所述催化剂组合物的烃转化方法
US20140323665A1 (en) 2011-03-30 2014-10-30 Exxonmobil Chemical Patents Inc. Polyalphaolefins by Oligomerization and Isomerization
ES2541052T3 (es) 2012-02-24 2015-07-15 Repsol, S.A. Proceso para la producción de destilados medios
CN103831129B (zh) * 2012-11-27 2016-06-08 中国石油天然气股份有限公司 一种经乙烯和苯液相法合成乙苯的催化剂及其制备和应用
CN105312024B (zh) * 2014-07-11 2019-04-16 中国石油化工股份有限公司 一种mww结构分子筛及其制备方法
CN105983437B (zh) * 2015-01-29 2019-02-01 中国石油化工股份有限公司 一种含mww结构分子筛的催化剂、制备方法及其应用
ES2774981T3 (es) * 2015-10-15 2020-07-23 Badger Licensing Llc Producción de compuestos alquilaromáticos
JP6918133B2 (ja) * 2017-03-29 2021-08-11 エクソンモービル ケミカル パテンツ インコーポレイテッド 炭化水素ストリームから不純物を除去する方法及び芳香族アルキル化プロセスにおけるそれらの使用
US11591527B2 (en) 2019-10-22 2023-02-28 ExxonMobil Technology and Engineering Company Processes for producing high octane reformate having high C5+ yield
CN112694386A (zh) * 2019-10-22 2021-04-23 中国石油化工股份有限公司 一种以煤基乙炔为原料制备乙苯的方法
CN113880107A (zh) * 2020-07-01 2022-01-04 中国石油化工股份有限公司 一种zsm-5分子筛及其合成方法和应用
CN114057531B (zh) * 2020-07-31 2024-07-09 中国石油化工股份有限公司 一种乙苯的合成方法
CN114534777B (zh) * 2020-11-26 2023-04-14 中国科学院大连化学物理研究所 一种用于多乙苯和苯反应的分子筛催化剂的制备方法
CN114602541A (zh) * 2020-12-03 2022-06-10 中国石油天然气股份有限公司 改性mcm-56分子筛催化剂及其制备方法

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3914383A (en) * 1966-08-25 1975-10-21 Sun Research Development Dy zeolite hydrocarbon conversion catalyst
US3751504A (en) * 1972-05-12 1973-08-07 Mobil Oil Corp Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation
US4070407A (en) * 1974-03-08 1978-01-24 Mobil Oil Corporation Alkylation/transalkylation in presence of crystalline aluminosilicate catalyst
FR2312479A1 (fr) * 1975-05-27 1976-12-24 Mobil Oil Procede d'alkylation ou de transalkylation en presence de catalyseur a base d'aluminosilicate cristallin
US4016218A (en) * 1975-05-29 1977-04-05 Mobil Oil Corporation Alkylation in presence of thermally modified crystalline aluminosilicate catalyst
US4169111A (en) * 1978-02-02 1979-09-25 Union Oil Company Of California Manufacture of ethylbenzene
US4288646A (en) * 1979-10-05 1981-09-08 Pcuk Produits Chimiques Ugine Kuhlmann Regioselective preparation of β-isopropylnaphthalene over superacidic solid or supported perfluorinated sulfonic acid catalysts
US4459426A (en) * 1980-04-25 1984-07-10 Union Oil Company Of California Liquid-phase alkylation and transalkylation process
US4547605A (en) * 1983-09-28 1985-10-15 Mobil Oil Corporation Catalyst for alkylation of aromatic hydrocarbons
US4555311A (en) * 1983-11-18 1985-11-26 Uop Inc. Integrated fractionation in the recovery of alkylaromatic hydrocarbons
US4735929A (en) * 1985-09-03 1988-04-05 Uop Inc. Catalytic composition for the isomerization of paraffinic hydrocarbons
US5149894A (en) * 1986-01-29 1992-09-22 Chevron Research And Technology Company Alkylation using zeolite SSZ-25
US4885426A (en) * 1987-09-02 1989-12-05 Mobil Oil Corporation Transalkylation of polyaromatics
US4774377A (en) * 1987-09-11 1988-09-27 Uop Inc. Alkylation/transalkylation process
US4857666A (en) * 1987-09-11 1989-08-15 Uop Alkylation/transalkylation process
US4891458A (en) * 1987-12-17 1990-01-02 Innes Robert A Liquid phase alkylation or transalkylation process using zeolite beta
US5081323A (en) * 1987-12-17 1992-01-14 Chevron Research And Technology Company Liquid phase alkylation or transalkylation process using zeolite beta
US5157185A (en) * 1989-09-01 1992-10-20 Mobil Oil Corporation Alkylation of aromatics
US5334795A (en) * 1990-06-28 1994-08-02 Mobil Oil Corp. Production of ethylbenzene
US5236575A (en) * 1991-06-19 1993-08-17 Mobil Oil Corp. Synthetic porous crystalline mcm-49, its synthesis and use
US5118894A (en) * 1991-07-18 1992-06-02 Mobil Oil Corporation Production of ethylbenzene
US5227558A (en) * 1992-02-10 1993-07-13 Fina Technology, Inc. Aromatic alkylation process employing steam modified zeolite beta catalyst

Also Published As

Publication number Publication date
ES2141398T3 (es) 2000-03-16
KR980700945A (ko) 1998-04-30
EP0800497B1 (de) 2000-01-26
TW330193B (en) 1998-04-21
DE69514834T2 (de) 2000-10-12
JP3802060B2 (ja) 2006-07-26
AU689687B2 (en) 1998-04-02
US5600048A (en) 1997-02-04
EP0800497A1 (de) 1997-10-15
CN1171096A (zh) 1998-01-21
MY123672A (en) 2006-05-31
EP0800497A4 (de) 1998-03-25
JPH10511942A (ja) 1998-11-17
WO1996020148A1 (en) 1996-07-04
CN1046928C (zh) 1999-12-01
KR100356039B1 (ko) 2002-12-28
AU4291296A (en) 1996-07-19

Similar Documents

Publication Publication Date Title
DE69514834D1 (de) Verfahren zur herstellung von ethylbenzol durch alkylierung in der flüssigphase und transalkylierung in der gasphase
DE69526010D1 (de) Verfahren zur Herstellung von aromatischen Polyisocyanatverbindungen in der Gasphase
DE69216903D1 (de) Verfahren zur Herstellung von Isoparaffinen
DE59506978D1 (de) Verfahren zur Herstellung von aromatischen Aminen
DE59505480D1 (de) Verfahren zur Herstellung von aromatischen Aminen
DE69334108D1 (de) Elektrisches Verfahren zur Bestimmung von Molekülen
DE69523623D1 (de) Verfahren zur herstellung von flüssigen zusammensetzungen
DE69520139D1 (de) Verfahren zur herstellung von flüssigkristallcomposit
DE59708143D1 (de) Verfahren zur herstellung von aromatischen aminen durch gasphasenhydrierung
DE59509204D1 (de) Verfahren zur Herstellung von Hydrogenalkoxysilanen
DE59509333D1 (de) Verfahren zur Herstellung von 3-Acryloxypropylalkoxysilanen
DE69519831D1 (de) Verfahren zur Herstellung von Methacryloxypropyl-Dimethylchlorosilan
DE69403885D1 (de) Verfahren zur Herstellung von Cycloolefinen
DE69501412D1 (de) Verfahren zur Herstellung von Isocanaten
DE69706117D1 (de) Verfahren zur Alkylierung in der Gasphase und zur Transalkylierung in der Flüssigphase
DE69529764D1 (de) Mischungen von polyphenylenethern und verfahren zu ihrer herstellung
DE59501150D1 (de) Verfahren zur Herstellung von Polyisoolefinen
DE69520322D1 (de) Verfahren zur Herstellung von L-Ketohexose
DE59408481D1 (de) Verfahren zur Herstellung von aromatischen Aminen
ATA341386A (de) Verfahren zur herstellung von wasserverduennbaren lackbindemitteln und deren verwendung
DE59501307D1 (de) Verfahren zur Herstellung von Fluoranilinen
DE69307770D1 (de) Verfahren zur Herstellung von monoalkenylierten aromatischen Kohlenwasserstoffen
DE69305791D1 (de) Verfahren zur Herstellung von monoalkenylierten aromatischen Kohlenwasserstoffen
DE59500712D1 (de) Verfahren zur Herstellung von 4,6-Diaminoresorcin
DE69400225D1 (de) Verfahren zur Isomerisierung von Dimethylnaphthalen

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee