DE69422411T2 - Olefinpolymerisation in der gasphase - Google Patents

Olefinpolymerisation in der gasphase

Info

Publication number
DE69422411T2
DE69422411T2 DE69422411T DE69422411T DE69422411T2 DE 69422411 T2 DE69422411 T2 DE 69422411T2 DE 69422411 T DE69422411 T DE 69422411T DE 69422411 T DE69422411 T DE 69422411T DE 69422411 T2 DE69422411 T2 DE 69422411T2
Authority
DE
Germany
Prior art keywords
gas phase
polymers
reactor
constrained geometry
olefin polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69422411T
Other languages
English (en)
Other versions
DE69422411D1 (de
Inventor
Robert Swindoll
Bruce A Story
Brian Kolthammer
Kevin Peil
David Wilson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of DE69422411D1 publication Critical patent/DE69422411D1/de
Application granted granted Critical
Publication of DE69422411T2 publication Critical patent/DE69422411T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/34Polymerisation in gaseous state
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/643Component covered by group C08F4/64 with a metal or compound covered by group C08F4/44 other than an organo-aluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
DE69422411T 1993-09-17 1994-09-16 Olefinpolymerisation in der gasphase Expired - Lifetime DE69422411T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12285293A 1993-09-17 1993-09-17
PCT/US1994/010621 WO1995007942A1 (en) 1993-09-17 1994-09-16 Gas phase polymerization of olefins

Publications (2)

Publication Number Publication Date
DE69422411D1 DE69422411D1 (de) 2000-02-03
DE69422411T2 true DE69422411T2 (de) 2000-07-20

Family

ID=22405180

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69422411T Expired - Lifetime DE69422411T2 (de) 1993-09-17 1994-09-16 Olefinpolymerisation in der gasphase

Country Status (21)

Country Link
EP (1) EP0719289B1 (de)
JP (1) JP2915995B2 (de)
KR (1) KR100350544B1 (de)
CN (1) CN1043648C (de)
AT (1) ATE188223T1 (de)
AU (1) AU686670B2 (de)
BR (1) BR9407700A (de)
CZ (1) CZ287329B6 (de)
DE (1) DE69422411T2 (de)
ES (1) ES2139757T3 (de)
FI (1) FI119991B (de)
HU (1) HU215173B (de)
NO (1) NO961084L (de)
NZ (1) NZ274069A (de)
PL (1) PL187060B1 (de)
PT (1) PT719289E (de)
RO (1) RO115265B1 (de)
RU (1) RU2139296C1 (de)
SG (1) SG55078A1 (de)
SK (1) SK282416B6 (de)
WO (1) WO1995007942A1 (de)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6291389B1 (en) 1994-04-28 2001-09-18 Exxonmobil Chemical Patents Inc. Cationic polymerization catalysts
US6008307A (en) * 1994-04-28 1999-12-28 Exxon Chemical Patents Inc Process for producing olefin polymers using cationic catalysts
CA2188722A1 (en) * 1995-10-26 1997-04-27 George Norris Foster Process for preparing an in situ polyethylene blend
US6114477A (en) * 1996-02-09 2000-09-05 Exxon Chemical Patents Inc. Polymerization process
CZ299688B6 (cs) * 1996-05-17 2008-10-22 Ineos Europe Limited Polyolefinový prostredek s maximem molární hmotnosti nacházející se v té cásti prostredku, která mánejvyšší obsah komonomeru
US6759499B1 (en) 1996-07-16 2004-07-06 Exxonmobil Chemical Patents Inc. Olefin polymerization process with alkyl-substituted metallocenes
JP3407074B2 (ja) 1996-08-08 2003-05-19 ザ ダウ ケミカル カンパニー 3―ヘテロ原子置換シクロペンタジエニル含有金属錯体及びオレフィン重合方法
US6255426B1 (en) 1997-04-01 2001-07-03 Exxon Chemical Patents, Inc. Easy processing linear low density polyethylene
GB9712663D0 (en) 1997-06-16 1997-08-20 Borealis As Process
WO2000018808A1 (en) 1998-09-30 2000-04-06 Exxon Chemical Patents Inc. Cationic group 3 catalyst system
US6486088B1 (en) 1998-10-23 2002-11-26 Exxonmobil Chemical Patents Inc. High activity carbenium-activated polymerization catalysts
MXPA01004337A (es) 1998-11-02 2002-04-24 Pont Dow Elastomers L L C Du Interpolimeros de alfa-olefina/etileno que disminuyen el esfuerzo cortante.
AU1987600A (en) 1998-12-16 2000-07-03 Borealis Technology Oy Multistep process for preparing polyolefins having high melt strength
US6617407B1 (en) 1999-04-29 2003-09-09 The Dow Chemical Company Bis(n,n-dihydrocarbylamino)-substituted cyclopentadienes and metal complexes thereof
US6646071B1 (en) 1999-05-13 2003-11-11 The Dow Chemical Company Metal complexes containing bridging heteroatom for olefin-polymerization-process
WO2000069871A1 (en) 1999-05-13 2000-11-23 The Dow Chemical Company Di- and tri-heteroatom substituted indenyl metal complexes
WO2000075146A1 (en) 1999-06-04 2000-12-14 The Dow Chemical Company Boron-substituted cyclopentadienes and metal complexes thereof
US6476164B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Carbenium cationic complexes suitable for polymerization catalysts
US6475946B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Olefin polymerization catalysis with aryl substituted carbenium cationic complexes
US6489480B2 (en) 1999-12-09 2002-12-03 Exxonmobil Chemical Patents Inc. Group-15 cationic compounds for olefin polymerization catalysts
US6822057B2 (en) 1999-12-09 2004-11-23 Exxon Mobil Chemical Patents Inc. Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them
US6825295B2 (en) 1999-12-10 2004-11-30 Dow Global Technologies Inc. Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
US6809209B2 (en) 2000-04-07 2004-10-26 Exxonmobil Chemical Patents Inc. Nitrogen-containing group-13 anionic compounds for olefin polymerization
WO2003000740A2 (en) 2001-06-20 2003-01-03 Exxonmobil Chemical Patents Inc. Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them
WO2003008496A1 (en) 2001-07-17 2003-01-30 Basell Polyolefine Gmbh Multistep process for the (co)polymerization of olefins
EP1312625A1 (de) * 2001-11-20 2003-05-21 BP Chemicals SNC Gasphasenpolymerisationsverfahren
AU2002357251B2 (en) 2001-12-21 2009-07-30 Dow Global Technologies Inc. Additive for rendering inert acidic or halogen-containing compounds contained in olefin polymers
EP1834983A1 (de) * 2006-03-14 2007-09-19 Ineos Europe Limited Polymerfilme
US9546446B2 (en) 2009-10-23 2017-01-17 Toyo Boseki Kabushiki Kaisha Highly functional polyethylene fibers, woven or knit fabric, and cut-resistant glove
US11174329B2 (en) 2016-09-30 2021-11-16 Dow Global Technologies Llc Multi- or dual-headed compositions useful for chain shuttling and process to prepare the same
EP3519456A1 (de) 2016-09-30 2019-08-07 Dow Global Technologies Llc Gekappte mehr- oder doppelköpfige zusammensetzungen für kettenübertragung und verfahren zur herstellung davon
BR112019006207B1 (pt) 2016-09-30 2022-11-29 Dow Global Technologies Llc Processo para preparar uma composição, processo de polimerização para preparar uma composição polimérica e composição polimérica
WO2022010622A1 (en) 2020-07-07 2022-01-13 Exxonmobil Chemical Patents Inc. Processes for making 3-d objects from blends of polyethylene and polar polymers

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5278272A (en) * 1991-10-15 1994-01-11 The Dow Chemical Company Elastic substantialy linear olefin polymers
DE69331112T2 (de) * 1992-08-05 2002-06-20 Exxonmobil Chem Patents Inc Ionische übergangsmetallkatalysatoreren auf träger für olefinpolymerisation
JPH07509753A (ja) * 1992-08-05 1995-10-26 エクソン・ケミカル・パテンツ・インク エチレンとc↓7乃至c↓1↓0オレフィンの気相重合
DE69312306T2 (de) * 1992-10-02 1997-11-13 Dow Chemical Co Aufträger homogener komplexkatalysator für olefinpolymerisation

Also Published As

Publication number Publication date
BR9407700A (pt) 1997-02-04
PL187060B1 (pl) 2004-05-31
CN1131425A (zh) 1996-09-18
RO115265B1 (ro) 1999-12-30
AU7799394A (en) 1995-04-03
NO961084L (no) 1996-05-15
SK32096A3 (en) 1997-03-05
WO1995007942A1 (en) 1995-03-23
SG55078A1 (en) 1998-12-21
HUT75191A (en) 1997-04-28
HU215173B (hu) 1998-10-28
DE69422411D1 (de) 2000-02-03
JPH09502761A (ja) 1997-03-18
NO961084D0 (no) 1996-03-15
FI119991B (fi) 2009-05-29
EP0719289B1 (de) 1999-12-29
KR960704945A (ko) 1996-10-09
AU686670B2 (en) 1998-02-12
KR100350544B1 (ko) 2003-01-24
FI961240A (fi) 1996-03-15
CZ287329B6 (en) 2000-10-11
JP2915995B2 (ja) 1999-07-05
PT719289E (pt) 2000-05-31
EP0719289A1 (de) 1996-07-03
SK282416B6 (sk) 2002-01-07
ATE188223T1 (de) 2000-01-15
NZ274069A (en) 1997-11-24
ES2139757T3 (es) 2000-02-16
HU9600633D0 (en) 1996-05-28
PL313493A1 (en) 1996-07-08
CZ80596A3 (en) 1996-10-16
CN1043648C (zh) 1999-06-16
RU2139296C1 (ru) 1999-10-10
FI961240A0 (fi) 1996-03-15

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Legal Events

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8364 No opposition during term of opposition
8327 Change in the person/name/address of the patent owner

Owner name: BP CHEMICALS LTD., LONDON, GB