DE69323096D1 - Verfahren zur herstellung von poly-alpha-olefinen mit monozyklopentadienylkomplexen von übergangsmetallen - Google Patents

Verfahren zur herstellung von poly-alpha-olefinen mit monozyklopentadienylkomplexen von übergangsmetallen

Info

Publication number
DE69323096D1
DE69323096D1 DE69323096T DE69323096T DE69323096D1 DE 69323096 D1 DE69323096 D1 DE 69323096D1 DE 69323096 T DE69323096 T DE 69323096T DE 69323096 T DE69323096 T DE 69323096T DE 69323096 D1 DE69323096 D1 DE 69323096D1
Authority
DE
Germany
Prior art keywords
transitional metals
monocyclopentadienyl complexes
polyalpha olefins
producing
producing polyalpha
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69323096T
Other languages
English (en)
Other versions
DE69323096T2 (de
Inventor
Jo Canich
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of DE69323096D1 publication Critical patent/DE69323096D1/de
Application granted granted Critical
Publication of DE69323096T2 publication Critical patent/DE69323096T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE69323096T 1993-06-24 1993-06-24 Verfahren zur herstellung von poly-alpha-olefinen mit monozyklopentadienylkomplexen von übergangsmetallen Expired - Lifetime DE69323096T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US1993/006051 WO1995000562A1 (en) 1993-06-24 1993-06-24 PROCESS FOR PRODUCING AMORPHOUS POLY-α-OLEFINS WITH A MONOCYCLOPENTADIENYL TRANSITION METAL CATALYST SYSTEM

Publications (2)

Publication Number Publication Date
DE69323096D1 true DE69323096D1 (de) 1999-02-25
DE69323096T2 DE69323096T2 (de) 1999-08-05

Family

ID=22236720

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69323096T Expired - Lifetime DE69323096T2 (de) 1993-06-24 1993-06-24 Verfahren zur herstellung von poly-alpha-olefinen mit monozyklopentadienylkomplexen von übergangsmetallen

Country Status (6)

Country Link
EP (1) EP0705283B1 (de)
JP (1) JPH08512063A (de)
CA (1) CA2166055C (de)
DE (1) DE69323096T2 (de)
ES (1) ES2128431T3 (de)
WO (1) WO1995000562A1 (de)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69607147T2 (de) * 1995-01-31 2000-09-28 Exxon Chemical Patents, Inc. Thermoplastische propylen-elastomere und verfahren zu ihrer herstellung und zwei katalysatoren in einem reaktor
JPH11501342A (ja) * 1995-03-01 1999-02-02 ミネソタ マイニング アンド マニュファクチャリング カンパニー トリス(ペンタフルオロフェニル)ボレート錯体およびそれらから誘導された触媒
FI104825B (fi) 1996-01-26 2000-04-14 Borealis As Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö
NL1003013C2 (nl) * 1996-05-03 1997-11-06 Dsm Nv Met cyclische groepen gesubstitueerde cyclopentadieenverbinding.
NL1003000C2 (nl) * 1996-05-03 1997-11-06 Dsm Nv Synthese van een amine-bevattend cyclopentadieen.
NL1003006C2 (nl) * 1996-05-03 1997-11-06 Dsm Nv Met vertakte alkylgroepen gesubstitueerde cyclopentadieenverbinding.
NL1003012C2 (nl) * 1996-05-03 1997-11-06 Dsm Nv Met aralkylgroepen gesubstitueerde cyclopentadieenverbinding.
US6117811A (en) * 1996-05-03 2000-09-12 Dsm N.V. Cyclopentadiene compound substituted with linear groups
US6124488A (en) * 1996-05-03 2000-09-26 Dsm N.V. Cyclopentadiene compound substituted with branched alkyl groups
NL1003004C2 (nl) * 1996-05-03 1997-11-06 Dsm Nv Met onderling verschillende groepen gesubstitueerde cyclopentadieen- verbinding.
US6288192B1 (en) 1998-01-14 2001-09-11 Sumitomo Chemical Company, Ltd. Olefin polymer, olefin polymerization catalyst and process for producing olefin polymer
JP3533923B2 (ja) 1998-01-28 2004-06-07 住友化学工業株式会社 オレフィン重合体、オレフィン重合用触媒およびオレフィン重合体の製造方法
JP2002519484A (ja) 1998-07-02 2002-07-02 モンテル テクノロジー カンパニー ビーブイ 実質的非晶質α−オレフィンポリマーの製造法とそれを含有する組成物および橋状リガンドの製造法
EP1010709A1 (de) * 1998-12-14 2000-06-21 Fina Research S.A. Metallocenverbindung und ihre Verwendung für die Herstellung von Polyolefinen
JP2001261737A (ja) * 2000-03-14 2001-09-26 Chisso Corp 耐熱性に優れた柔軟性ポリプロピレン
JP2005171139A (ja) * 2003-12-12 2005-06-30 Tonen Chem Corp 変性ポリプロピレン
US7872080B2 (en) 2008-03-06 2011-01-18 Sumitomo Chemical Company, Limited Processes for producing a catalyst component for addition polymerization, a catalyst and an addition polymer
JP2011213804A (ja) 2010-03-31 2011-10-27 Sumitomo Chemical Co Ltd 予備重合方法、予備重合済付加重合触媒成分およびそれを用いる付加重合体の製造方法
JP2013082891A (ja) 2011-09-28 2013-05-09 Sumitomo Chemical Co Ltd 洗浄方法、付加重合方法、予備重合方法、予備重合済付加重合触媒成分およびそれを用いる付加重合体の製造方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
EP0616618B1 (de) * 1991-12-13 1997-07-02 Exxon Chemical Patents Inc. ETHYLEN/HöHERE ALPHA-OLEFINCOPOLYMERE
WO1993019103A1 (en) * 1992-03-16 1993-09-30 Exxon Chemical Patents Inc. IONIC CATALYST FOR THE PRODUCTION OF POLY-α-OLEFINS OF CONTROLLED TACTICITY

Also Published As

Publication number Publication date
WO1995000562A1 (en) 1995-01-05
JPH08512063A (ja) 1996-12-17
ES2128431T3 (es) 1999-05-16
CA2166055A1 (en) 1995-01-05
EP0705283A1 (de) 1996-04-10
EP0705283B1 (de) 1999-01-13
DE69323096T2 (de) 1999-08-05
CA2166055C (en) 2006-10-17

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