DE69315965T2 - Lösliche, anionische Polymerisationsinitiatoren und erhaltene Produkte - Google Patents
Lösliche, anionische Polymerisationsinitiatoren und erhaltene ProdukteInfo
- Publication number
- DE69315965T2 DE69315965T2 DE69315965T DE69315965T DE69315965T2 DE 69315965 T2 DE69315965 T2 DE 69315965T2 DE 69315965 T DE69315965 T DE 69315965T DE 69315965 T DE69315965 T DE 69315965T DE 69315965 T2 DE69315965 T2 DE 69315965T2
- Authority
- DE
- Germany
- Prior art keywords
- soluble
- products obtained
- polymerization initiators
- anionic polymerization
- anionic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
- C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
- C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D295/00—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms
- C07D295/22—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with hetero atoms directly attached to ring nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T152/00—Resilient tires and wheels
- Y10T152/10—Tires, resilient
- Y10T152/10495—Pneumatic tire or inner tube
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US96892992A | 1992-10-30 | 1992-10-30 |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69315965D1 DE69315965D1 (de) | 1998-02-05 |
DE69315965T2 true DE69315965T2 (de) | 1998-04-16 |
Family
ID=25514945
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69315965T Expired - Lifetime DE69315965T2 (de) | 1992-10-30 | 1993-10-20 | Lösliche, anionische Polymerisationsinitiatoren und erhaltene Produkte |
Country Status (6)
Country | Link |
---|---|
US (2) | US5578542A (de) |
EP (1) | EP0600208B1 (de) |
JP (1) | JPH06211915A (de) |
CA (1) | CA2102035C (de) |
DE (1) | DE69315965T2 (de) |
ES (1) | ES2110557T3 (de) |
Families Citing this family (55)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5643848A (en) * | 1992-10-30 | 1997-07-01 | Bridgestone Corporation | Soluble anionic polymerization initiators and products therefrom |
US6080835A (en) | 1995-02-01 | 2000-06-27 | Bridgestone Corporation | Aminoalkyllithium compounds containing cyclic amines and polymers therefrom |
US5866650A (en) * | 1997-07-11 | 1999-02-02 | Bridgestone Corporation | Composition of cyclic amine-initiated elastomers and amorphous silica and process for the production thereof |
US5935893A (en) * | 1997-08-01 | 1999-08-10 | Bridgestone Corporation | Aliphatic solutions of aminoalkyllithium compounds |
DE60316445T2 (de) * | 2002-08-30 | 2008-06-26 | Bridgestone Corp. | Funktionalisiertes polymer und verbesserte vulkanisate daraus |
US7718728B2 (en) | 2003-03-28 | 2010-05-18 | Bridgestone Corporation | Rubber composition containing modified conjugated diene polymer and tire |
CN1961011B (zh) * | 2004-04-05 | 2013-09-11 | 株式会社普利司通 | 改性共轭二烯类聚合物、聚合引发剂及其制备方法和橡胶组合物 |
US7671139B1 (en) | 2004-06-18 | 2010-03-02 | Bridgestone Corporation | Functionalized polymers and tires made therefrom |
BRPI0513096A (pt) * | 2004-08-05 | 2008-04-29 | Firestone Polymers Llc | sìntese de etapa única de polìmero funcional multibloco |
MX2007003991A (es) * | 2004-10-02 | 2007-06-15 | Firestone Polymers Llc | Pol??meros y su uso en composiciones de asfalto y concretos de asfalto. |
US20060264590A1 (en) * | 2005-05-20 | 2006-11-23 | Bridgestone Corporation | Anionic polymerization initiators and polymers therefrom |
US8158725B2 (en) * | 2005-08-22 | 2012-04-17 | Bridgestone Corporation | Functionalized polymers and tires therefrom |
US7875671B2 (en) | 2006-08-03 | 2011-01-25 | Bridgestone Corporation | Process for preparing filler-dispersed polymeric compositions |
KR101457981B1 (ko) * | 2006-10-06 | 2014-11-05 | 가부시키가이샤 브리지스톤 | 분지화 중합체 및 그의 합성 방법 및 용도 |
ZA200711159B (en) | 2006-12-28 | 2009-03-25 | Bridgestone Corp | Amine-containing alkoxysilyl-functionalized polymers |
EP2142602B1 (de) | 2007-04-20 | 2017-03-15 | Heritage Research Group | Polymermodifizierte asphaltzusammensetzungen |
US7829624B2 (en) | 2007-06-29 | 2010-11-09 | Bridgestone Corporation | One-pot synthesis of nanoparticles and liquid polymer for rubber applications |
RU2458937C2 (ru) * | 2007-08-31 | 2012-08-20 | Бриджстоун Корпорейшн | Синтез жидкого полимера и функционализированного полимера |
US8314189B2 (en) * | 2007-10-12 | 2012-11-20 | Bridgestone Corporation | Polymers functionalized with heterocyclic nitrile compounds |
US20090326176A1 (en) * | 2007-12-28 | 2009-12-31 | Yuan-Yong Yan | Novel multifunctional initiators for anionic polymerization and polymers therefrom |
US8227562B2 (en) * | 2008-03-15 | 2012-07-24 | Bridgestone Corporation | Functionalized polymers and initiators for making same |
US9732178B1 (en) | 2008-07-24 | 2017-08-15 | Bridgestone Corporation | Block copolymers including high vinyl segments |
FR2940294B1 (fr) | 2008-12-23 | 2011-02-18 | Michelin Soc Tech | Nouveau systeme d'amorcage pour polymerisation anionique de dienes conjugues, procede de preparation d'elastomeres dieniques. |
US8338544B2 (en) | 2009-12-21 | 2012-12-25 | Bridgestone Corporation | Polymers functionalized with polyoxime compounds and methods for their manufacture |
RU2564352C2 (ru) | 2010-01-22 | 2015-09-27 | Бриджстоун Корпорейшн | Полимеры, функционализованные нитрильными соединениями, имеющими защищенную аминогруппу |
WO2012061108A1 (en) | 2010-10-25 | 2012-05-10 | Stepan Company | Laundry detergents based on compositions derived from natural oil metathesis |
US8748531B2 (en) | 2010-12-10 | 2014-06-10 | Bridgestone Corporation | Polymers functionalized with oxime compounds containing an acyl group |
US8962745B2 (en) | 2010-12-27 | 2015-02-24 | Bridgestone Corporation | Functionalized polymers and vulcanizates with reduced hysteretic loss |
EP2699606B1 (de) | 2011-03-29 | 2016-09-28 | Bridgestone Corporation | Durch ein carbonsäure- oder thiocarboxyl-ester mit einer silylierten aminogruppe funktionalisierte polymere |
US8993683B2 (en) | 2011-08-31 | 2015-03-31 | Bridgestone Corporation | Polymers functionalized with lactones or thiolactones containing a protected amino group |
US9000070B2 (en) | 2011-10-19 | 2015-04-07 | Bridgestone Corporation | Mixing of telechelic rubber formulations |
RU2640800C2 (ru) | 2011-11-18 | 2018-01-12 | Бриджстоун Корпорейшн | Способ получения полидиенов и полидиеновых сополимеров с пониженной холодной текучестью |
US9512263B2 (en) | 2011-12-09 | 2016-12-06 | Bridgestone Corporation | Method for producing polydienes and polydiene copolymers with reduced cold flow |
US9694629B1 (en) | 2012-02-29 | 2017-07-04 | Carolyn Dry | Self-repairing inflatable articles incorporating an integrated self-repair system |
US8685513B1 (en) | 2012-02-29 | 2014-04-01 | Carolyn M. Dry | Inflatable articles comprising a self-repairing laminate |
EP2844678B1 (de) | 2012-05-01 | 2017-02-22 | Bridgestone Corporation | Polydiene und diencopolymere mit organophosphiner funktionalität |
US9469706B2 (en) | 2012-06-08 | 2016-10-18 | Bridgestone Corporation | Polymers functionalized with unsaturated heterocycles containing a protected amino group |
US9186933B2 (en) | 2012-10-12 | 2015-11-17 | The Goodyear Tire & Rubber Company | Functionalized polymer, rubber composition and pneumatic tire |
CN105026448B (zh) | 2012-11-09 | 2017-10-17 | 株式会社普利司通 | 生物基苯乙烯的用途 |
US9127092B2 (en) | 2012-12-31 | 2015-09-08 | Bridgestone Corporation | Method for producing polydienes and polydiene copolymers with reduced cold flow |
US9663637B2 (en) | 2012-12-31 | 2017-05-30 | Bridgestone Corporation | Polymers functionalized with unsaturated heterocycles containing an azolinyl group |
US9315599B2 (en) | 2013-01-02 | 2016-04-19 | Bridgestone Corporation | Functionalized polymers |
US9850328B2 (en) | 2013-03-15 | 2017-12-26 | Bridgestone Corporation | Polymers functionalized with heterocyclic imines |
KR102456909B1 (ko) | 2013-10-02 | 2022-10-21 | 가부시키가이샤 브리지스톤 | 시아노 기를 함유하는 이민 화합물로 작용화된 중합체 |
KR102301066B1 (ko) | 2013-12-12 | 2021-09-14 | 화이어스톤 폴리머스, 엘엘씨 | 작용화된 중합체를 포함하는 중합체 조성물의 제조 방법 |
US10030083B2 (en) | 2014-05-15 | 2018-07-24 | Bridgestone Corporation | Polymers functionalized with protected oxime compounds containing a cyano group |
MY187405A (en) | 2014-09-29 | 2021-09-22 | Malaysian Palm Oil Board | Powder form of methyl ester sulphonates (mes) and process for producing the same |
US10364300B2 (en) | 2014-10-07 | 2019-07-30 | Bridgestone Corporation | Method for producing polydienes and polydiene copolymers with reduced cold flow |
US10077323B2 (en) | 2015-07-24 | 2018-09-18 | Bridgestone Corporation | Polymers functionalized with imine compounds containing a protected thiol group |
EP3328919B1 (de) | 2015-07-29 | 2021-03-10 | Bridgestone Corporation | Verfahren zur herstellung von funktionalisierten polymeren, zugehörige funktionalisierungsverbindung und herstellung davon |
US10519266B2 (en) | 2015-09-23 | 2019-12-31 | Bridgestone Corporation | Polydienes and diene copolymers using 1,1-bis(hydrocarbylthio)hydrocarbyl-1-ene compounds |
EP3374407B1 (de) | 2015-11-13 | 2020-04-08 | Bridgestone Corporation | Funktioneller initiator für die anionische polymerisation |
JP7170045B2 (ja) | 2017-12-14 | 2022-11-11 | 株式会社ブリヂストン | 結合ポリマー生成物、作製方法及び組成物 |
CN111630075B (zh) | 2017-12-15 | 2023-04-28 | 株式会社普利司通 | 官能化聚合物、用于制备该官能化聚合物的方法和含有该官能化聚合物的橡胶组合物 |
US20240052139A1 (en) | 2020-12-18 | 2024-02-15 | Bridgestone Corporation | Tire rubber compositions combining bagasse-containing guayule rubber with silane and related methods |
Family Cites Families (69)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2849432A (en) * | 1956-02-06 | 1958-08-26 | Firestone Tire & Rubber Co | Polymerization of diolefines |
US3317918A (en) * | 1956-08-21 | 1967-05-02 | Firestone Tire & Rubber Co | Butadiene polymers prepared with a lithium based catalyst characterized by having at least 29 percent of the butadiene as cis-1, 4 |
NL252687A (de) * | 1959-06-30 | |||
US3178398A (en) * | 1960-10-24 | 1965-04-13 | Phillips Petroleum Co | Production and curing of polymers containing terminally reactive nitrogen |
US3109871A (en) * | 1960-12-27 | 1963-11-05 | Phillips Petroleum Co | Production and curing of polyfunctional terminally reactive polymers |
US3177190A (en) * | 1961-06-14 | 1965-04-06 | Phillips Petroleum Co | Preparing and curing compositions of terminally reactive polymers |
US3290277A (en) * | 1963-05-20 | 1966-12-06 | Shell Oil Co | Amino-containing block polymers of ethylene and alpha-alkyl styrene |
US3326881A (en) * | 1963-10-11 | 1967-06-20 | Phillips Petroleum Co | Polymerization of vinylidene-containing monomers with an initiator consisting of an alkali metal derivative of a functional halogen-substituted aromatic compound |
US3331821A (en) * | 1963-11-14 | 1967-07-18 | Phillips Petroleum Co | Catalyst composition and process of preparing conjugated diene polymers utilizing same |
DE1300240B (de) * | 1964-01-22 | 1969-07-31 | Bayer Ag | Verfahren zur Herstellung von Polymerisaten konjugierter Diolefine |
US3439049A (en) * | 1964-05-11 | 1969-04-15 | Phillips Petroleum Co | Organolithium polymerization initiator |
US3393182A (en) * | 1965-02-23 | 1968-07-16 | Phillips Petroleum Co | Prevention of cold flow in polymers of conjugated dienes |
US3652456A (en) * | 1969-06-09 | 1972-03-28 | Phillips Petroleum Co | Multifunctional polymerization initiators from allyl-substituted tertiary amines |
US4085265A (en) * | 1972-08-25 | 1978-04-18 | Nippon Oil Company, Limited | Process for isomerization of lower polymers of butadiene |
JPS4944091A (de) * | 1972-09-04 | 1974-04-25 | ||
JPS5633410B2 (de) * | 1972-11-15 | 1981-08-04 | ||
DE2355941A1 (de) * | 1973-11-09 | 1975-05-15 | Bayer Ag | Polymerisation und copolymerisation von dienen |
US4026865A (en) * | 1974-07-01 | 1977-05-31 | Phillips Petroleum Company | Preparation of organometal terminated polymers |
DD138070A1 (de) * | 1974-09-20 | 1979-10-10 | Peter Knoth | Verfahren zur polymerisation von konjugierten dienen zu"lebenden"polymeren |
US4015061A (en) * | 1975-02-14 | 1977-03-29 | The Firestone Tire & Rubber Company | Protected amino-functional initiators and amino-terminated polymers and their production |
US4316001A (en) * | 1976-05-26 | 1982-02-16 | Societe Nationale Des Poudres Et Explosifs | Anionic polymerization of heterocyclic monomers with alkali metal amide hydroxylated compound initiator |
JPS5489A (en) * | 1977-06-03 | 1979-01-05 | Denki Kagaku Kogyo Kk | Polymerization of diolefins |
JPS5465788A (en) * | 1977-11-07 | 1979-05-26 | Denki Kagaku Kogyo Kk | Preparation of copolymer |
US4247418A (en) * | 1979-10-18 | 1981-01-27 | The Firestone Tire & Rubber Company | Polymerization catalyst and process for polymerizing dienes therewith |
JPS5773030A (en) * | 1980-09-20 | 1982-05-07 | Bridgestone Corp | Rubber composition for tire |
US4381810A (en) * | 1981-05-22 | 1983-05-03 | The Goodyear Tire & Rubber Company | Tire with dual tread compound |
JPS58154703A (ja) * | 1982-03-09 | 1983-09-14 | Daicel Chem Ind Ltd | 光学活性な高分子の合成方法 |
JPS58162604A (ja) * | 1982-03-19 | 1983-09-27 | Nippon Zeon Co Ltd | ジエン系重合体ゴムの改質方法 |
US4414372A (en) * | 1982-06-17 | 1983-11-08 | E. I. Du Pont De Nemours & Co. | Process for preparing living polymers |
US4476240A (en) * | 1982-07-01 | 1984-10-09 | The Firestone Tire & Rubber Company | Catalyst system containing an anionic initiator based on lithium and phosphine oxide modifier |
JPS59140240A (ja) * | 1983-01-31 | 1984-08-11 | Japan Synthetic Rubber Co Ltd | ゴム組成物 |
JPS59164308A (ja) * | 1983-03-09 | 1984-09-17 | Asahi Chem Ind Co Ltd | ポリエチレンの製造方法 |
US4429091A (en) * | 1983-03-09 | 1984-01-31 | The Firestone Tire & Rubber Company | Oligomeric oxolanyl alkanes as modifiers for polymerization of dienes using lithium-based initiators |
CA1217122A (en) * | 1983-06-01 | 1987-01-27 | John Timar | Pneumatic tire inner liner having puncture sealing characteristics |
FR2567135B1 (fr) * | 1984-07-03 | 1989-01-13 | Asahi Chemical Ind | Polymere ou copolymere de butadiene et procede de preparation |
US4616069A (en) * | 1984-10-26 | 1986-10-07 | Nippon Zeon Co., Ltd. | Process for making diene polymer rubbers |
JPS61103901A (ja) * | 1984-10-26 | 1986-05-22 | Nippon Zeon Co Ltd | ジエン系共重合体ゴムの製造方法 |
JPS61225202A (ja) * | 1985-03-29 | 1986-10-07 | Nippon Zeon Co Ltd | ゴムの変性方法 |
IT1186746B (it) * | 1985-07-01 | 1987-12-16 | Eniricerche Spa | Metodo per la terminazione di polimeri viventi e composti adatti allo scopo |
IT1186743B (it) * | 1985-07-01 | 1987-12-16 | Eniricerche Spa | Metodo per la terminazione di polimeri ottenuti per polimerizzazione anionica di monomeri dienici e/o vinilaromatici e composti adatti allo scopo |
IT1206738B (it) * | 1985-07-01 | 1989-05-03 | Eniricerche Spa | Metodo per la terminazione di polimeri viventi ottenuti per polimerizzazione anionica di monomeri dienici e/o vinilaromatici e composti adatti allo scopo. |
DE3688466T3 (de) * | 1985-10-11 | 1997-03-27 | Asahi Chemical Ind | End-modifiziertes blockkopolymer und dieses kopolymer enthaltende zusammensetzung. |
US4835209A (en) * | 1986-01-10 | 1989-05-30 | Asahi Kasei Kogyo Kabushiki Kaisha | Rubber for tire treads and compositions thereof |
US4647634A (en) * | 1986-03-10 | 1987-03-03 | The Goodyear Tire & Rubber Company | Randomizers for use in solution polymerizations |
DD247455A1 (de) * | 1986-03-31 | 1987-07-08 | Buna Chem Werke Veb | Verfahren zur herstellung von polymeren mit funktionellen endgruppen |
DE3611421A1 (de) * | 1986-04-05 | 1987-10-08 | Basf Ag | Polymerisate mit aminogruppen, deren herstellung und verwendung |
US4736003A (en) * | 1986-04-07 | 1988-04-05 | E. I. Du Pont De Nemours And Company | Enhanced livingness of polymerization using silylated oxyanions |
US4843120A (en) * | 1986-09-29 | 1989-06-27 | The Goodyear Tire & Rubber Company | Rubber composition |
DE3639569A1 (de) * | 1986-11-20 | 1988-06-01 | Basf Ag | Am kettenende funktionalisierte polymere und verfahren zu ihrer herstellung |
US4845165A (en) * | 1987-03-13 | 1989-07-04 | The Goodyear Tire & Rubber Company | Anionic diene polymerization process with branching |
US5248737A (en) * | 1987-05-08 | 1993-09-28 | Aristech Chemical Corporation | Method of making amine/propylene copolymers |
CA1303264C (en) * | 1987-05-11 | 1992-06-09 | Hiroyoshi Takao | Modified diene polymer rubbers |
JPH0778151B2 (ja) * | 1987-07-17 | 1995-08-23 | 日本合成ゴム株式会社 | ゴム組成物 |
JPH0798880B2 (ja) * | 1987-09-11 | 1995-10-25 | 株式会社ブリヂストン | 空気入りタイヤ |
US4935471A (en) * | 1987-10-15 | 1990-06-19 | The Goodyear Tire & Rubber Company | Capped polydienes |
CA1322750C (en) * | 1987-12-17 | 1993-10-05 | Mitsui Toatsu Chemicals, Inc. | Preparation process of unsaturated carboxylic acid amide |
US5149457A (en) * | 1989-06-30 | 1992-09-22 | Cyprus Foote Mineral Company | Stable mixed lithium amide reagent compositions |
DE3932948A1 (de) * | 1989-10-03 | 1991-04-11 | Bayer Ag | Verfahren zur herstellung von segmentierten polyurethanharnstoff-elastomerloesungen, sowie faeden und folien daraus |
CA2018790A1 (en) * | 1989-10-11 | 1991-05-11 | Smith, (W.) Novis, Jr. | Mixed lithium amides and reagent compositions thereof |
US5153159A (en) * | 1990-04-09 | 1992-10-06 | Bridgestone/Firestone, Inc. | Elastomers and products having reduced hysteresis |
US5173209A (en) * | 1990-05-10 | 1992-12-22 | Cyprus Foote Mineral Company | Stable lithium cycloalkylimides |
JPH04173793A (ja) * | 1990-11-01 | 1992-06-22 | Cyprus Foote Mineral Co | 混合リチウムアミド及び試薬組成物 |
US5112929A (en) * | 1991-04-05 | 1992-05-12 | Bridgestone Corporation | Oxolanyl cyclic acetals as anionic polymerization modifiers |
US5292790A (en) * | 1991-07-31 | 1994-03-08 | Bridgestone Corporation | Conjugated diene series rubber compositions |
US5238893A (en) * | 1991-12-30 | 1993-08-24 | Bridgestone Corporation | Method of preparing an anionic polymerization initiator |
US5332810A (en) * | 1992-10-02 | 1994-07-26 | Bridgestone Corporation | Solubilized anionic polymerization initiator and preparation thereof |
US5329005A (en) * | 1992-10-02 | 1994-07-12 | Bridgestone Corporation | Soluble anionic polymerization initiators and preparation thereof |
US5393721A (en) * | 1992-10-16 | 1995-02-28 | Bridgestone Corporation | Anionic polymerization initiators and reduced hysteresis products therefom |
US5527753A (en) * | 1994-12-13 | 1996-06-18 | Fmc Corporation | Functionalized amine initiators for anionic polymerization |
-
1993
- 1993-10-20 EP EP93116951A patent/EP0600208B1/de not_active Expired - Lifetime
- 1993-10-20 ES ES93116951T patent/ES2110557T3/es not_active Expired - Lifetime
- 1993-10-20 DE DE69315965T patent/DE69315965T2/de not_active Expired - Lifetime
- 1993-10-28 JP JP5292726A patent/JPH06211915A/ja active Pending
- 1993-10-29 CA CA002102035A patent/CA2102035C/en not_active Expired - Fee Related
-
1994
- 1994-03-30 US US08/220,629 patent/US5578542A/en not_active Expired - Lifetime
-
1996
- 1996-11-26 US US08/756,548 patent/US5723533A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0600208A1 (de) | 1994-06-08 |
JPH06211915A (ja) | 1994-08-02 |
CA2102035A1 (en) | 1994-05-01 |
ES2110557T3 (es) | 1998-02-16 |
US5723533A (en) | 1998-03-03 |
US5578542A (en) | 1996-11-26 |
CA2102035C (en) | 2006-12-19 |
EP0600208B1 (de) | 1997-12-29 |
DE69315965D1 (de) | 1998-02-05 |
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