DE69226072T2 - Durch Säure aktivierte Bleichzusammensetzung - Google Patents

Durch Säure aktivierte Bleichzusammensetzung

Info

Publication number: DE69226072T2
Authority: DE; Germany
Prior art keywords: composition; hydrogen peroxide; composition according; organic peracid; peracid precursor
Prior art date: 1992-04-03
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

DE1992626072

Other languages

German (de)

English (en)

Other versions

DE69226072D1 (de

Inventor

Frederick Edward Ponteland Newcastle Upon Tyne Ne20 9Es Hardy

Barbara Manfredi (Nmn), I-00162 Rome

Stefano Scialla (Nmn), I-00128 Rome

Raffaele Scoccianti (Nmn), I-00153 Rome

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Procter and Gamble Co

Original Assignee

Procter and Gamble Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-04-03

Filing date

1992-04-03

Publication date

1999-02-25

1992-04-03 Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co

1998-08-06 Publication of DE69226072D1 publication Critical patent/DE69226072D1/de

1999-02-25 Application granted granted Critical

1999-02-25 Publication of DE69226072T2 publication Critical patent/DE69226072T2/de

2012-04-04 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims description 68
238000004061 bleaching Methods 0.000 title claims description 9
239000002253 acid Substances 0.000 title description 2
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 46
239000002243 precursor Substances 0.000 claims description 20
150000004967 organic peroxy acids Chemical class 0.000 claims description 15
URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 claims description 12
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 9
LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
239000001087 glyceryl triacetate Substances 0.000 claims description 6
235000013773 glyceryl triacetate Nutrition 0.000 claims description 6
229960002622 triacetin Drugs 0.000 claims description 6
150000001875 compounds Chemical class 0.000 claims description 5
239000004094 surface-active agent Substances 0.000 claims description 5
-1 ethylene glycol diesters Chemical class 0.000 claims description 4
125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 3
239000004322 Butylated hydroxytoluene Substances 0.000 claims description 3
NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 3
235000010354 butylated hydroxytoluene Nutrition 0.000 claims description 3
229940095259 butylated hydroxytoluene Drugs 0.000 claims description 3
JTXMVXSTHSMVQF-UHFFFAOYSA-N 2-acetyloxyethyl acetate Chemical compound CC(=O)OCCOC(C)=O JTXMVXSTHSMVQF-UHFFFAOYSA-N 0.000 claims description 2
239000004348 Glyceryl diacetate Substances 0.000 claims description 2
235000019443 glyceryl diacetate Nutrition 0.000 claims description 2
150000004965 peroxy acids Chemical class 0.000 description 10
239000000126 substance Substances 0.000 description 7
239000007844 bleaching agent Substances 0.000 description 5
239000012190 activator Substances 0.000 description 4
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
230000002378 acidificating effect Effects 0.000 description 3
239000004615 ingredient Substances 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
UYXTWWCETRIEDR-UHFFFAOYSA-N Tributyrin Chemical compound CCCC(=O)OCC(OC(=O)CCC)COC(=O)CCC UYXTWWCETRIEDR-UHFFFAOYSA-N 0.000 description 2
239000002738 chelating agent Substances 0.000 description 2
239000000460 chlorine Substances 0.000 description 2
229910052801 chlorine Inorganic materials 0.000 description 2
239000003599 detergent Substances 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
DGZNTAVAPWEJPK-UHFFFAOYSA-N 1,5,5-triacetyloxypentyl acetate Chemical compound CC(=O)OC(OC(C)=O)CCCC(OC(C)=O)OC(C)=O DGZNTAVAPWEJPK-UHFFFAOYSA-N 0.000 description 1
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
XXXVHMNOHZWOKW-UHFFFAOYSA-N 5,5-diacetyloxypent-1-enyl acetate Chemical compound CC(=O)OC=CCCC(OC(C)=O)OC(C)=O XXXVHMNOHZWOKW-UHFFFAOYSA-N 0.000 description 1
239000005725 8-Hydroxyquinoline Substances 0.000 description 1
GXCZOZXAPFPAFV-UHFFFAOYSA-N CC=CC(O)=O.CC=CC(O)=O.OC(=O)CCCCC(O)=O Chemical compound CC=CC(O)=O.CC=CC(O)=O.OC(=O)CCCCC(O)=O GXCZOZXAPFPAFV-UHFFFAOYSA-N 0.000 description 1
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
229940123457 Free radical scavenger Drugs 0.000 description 1
QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 description 1
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
230000004913 activation Effects 0.000 description 1
150000001298 alcohols Chemical class 0.000 description 1
150000008051 alkyl sulfates Chemical class 0.000 description 1
150000001412 amines Chemical class 0.000 description 1
229910021529 ammonia Inorganic materials 0.000 description 1
239000003945 anionic surfactant Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
239000003086 colorant Substances 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
235000011180 diphosphates Nutrition 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
239000004744 fabric Substances 0.000 description 1
238000009472 formulation Methods 0.000 description 1
150000002314 glycerols Chemical class 0.000 description 1
150000002334 glycols Chemical class 0.000 description 1
239000003752 hydrotrope Substances 0.000 description 1
WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
150000005204 hydroxybenzenes Chemical class 0.000 description 1
239000007788 liquid Substances 0.000 description 1
150000007522 mineralic acids Chemical class 0.000 description 1
IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
239000002736 nonionic surfactant Substances 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
230000001590 oxidative effect Effects 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
229960003540 oxyquinoline Drugs 0.000 description 1
239000002304 perfume Substances 0.000 description 1
150000002978 peroxides Chemical class 0.000 description 1
MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical compound C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 description 1
239000002516 radical scavenger Substances 0.000 description 1
WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
235000010234 sodium benzoate Nutrition 0.000 description 1
239000004299 sodium benzoate Substances 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
125000005402 stannate group Chemical group 0.000 description 1
239000000725 suspension Substances 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
150000003624 transition metals Chemical class 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
- C11D3/391—Oxygen-containing compounds

Landscapes

Chemical & Material Sciences (AREA)
Inorganic Chemistry (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)
Cosmetics (AREA)

DE1992626072 1992-04-03 1992-04-03 Durch Säure aktivierte Bleichzusammensetzung Expired - Fee Related DE69226072T2 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
EP19920200961 EP0563460B1 (en)	1992-04-03	1992-04-03	Acidic activated bleaching composition

Publications (2)

Publication Number	Publication Date
DE69226072D1 DE69226072D1 (de)	1998-08-06
DE69226072T2 true DE69226072T2 (de)	1999-02-25

Family

ID=8210529

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DE1992626072 Expired - Fee Related DE69226072T2 (de)	1992-04-03	1992-04-03	Durch Säure aktivierte Bleichzusammensetzung

Country Status (10)

Country	Link
EP (1)	EP0563460B1 (pt)
JP (1)	JPH07505437A (pt)
CN (1)	CN1078254A (pt)
AU (1)	AU668936B2 (pt)
BR (1)	BR9306183A (pt)
DE (1)	DE69226072T2 (pt)
ES (1)	ES2118105T3 (pt)
IE (1)	IE930263A1 (pt)
TW (1)	TW299351B (pt)
WO (1)	WO1993020167A1 (pt)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5753138A (en) *	1993-06-24	1998-05-19	The Procter & Gamble Company	Bleaching detergent compositions comprising bleach activators effective at low perhydroxyl concentrations
WO1995004127A1 (en) *	1993-08-03	1995-02-09	The Procter & Gamble Company	A process of cleaning carpets using active oxygen compounds in an acidic aqueous medium
GB9600159D0 (en) *	1996-01-05	1996-03-06	Warwick Int Group	Process for bleaching or disinfecting a substrate
US5879409A (en) *	1996-02-23	1999-03-09	The Procter & Gamble Company	Bleach additive and bleaching compositions having glycine anhydride activators
US6221341B1 (en) *	1997-11-19	2001-04-24	Oraceutical Llc	Tooth whitening compositions
EP1618786B1 (en) *	2003-04-02	2014-08-27	Kao Corporation	Composition for bactericide production and process for producing organic peracid
EP1496104B1 (en) *	2003-07-08	2008-05-07	The Procter & Gamble Company	Liquid activator composition
EP2331668A1 (en) *	2008-09-10	2011-06-15	Danisco US Inc.	Enzymatic textile bleaching compositions and methods of use thereof
US8546449B2 (en)	2011-03-24	2013-10-01	Enviro Tech Chemical Services, Inc.	Methods and compositions for the generation of peracetic acid on site at the point-of-use

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3956159A (en) *	1974-11-25	1976-05-11	The Procter & Gamble Company	Stable concentrated liquid peroxygen bleach composition
DE3465334D1 (en) *	1983-04-14	1987-09-17	Interox Chemicals Ltd	Peroxygen compounds
JPS6142600A (ja) *	1984-08-06	1986-03-01	花王株式会社	カビ取り剤組成物
JPS621796A (ja) *	1985-06-28	1987-01-07	花王株式会社	漂白剤組成物
JPS621794A (ja) *	1985-06-28	1987-01-07	花王株式会社	漂白剤組成物
JPS621792A (ja) *	1985-06-28	1987-01-07	花王株式会社	漂白剤組成物
JPS62252500A (ja) *	1986-04-25	1987-11-04	花王株式会社	漂白剤組成物
US4800038A (en) *	1988-01-21	1989-01-24	Colgate-Palmolive Company	Acetylated sugar ethers as bleach activators detergency boosters and fabric softeners
US5047168A (en) *	1988-01-21	1991-09-10	Colgate-Palmolive Co.	Sugar ethers as bleach stable detergency boosters
US5151212A (en) *	1990-03-21	1992-09-29	The Belzak Corporation	Peroxygen compound activation

1992
- 1992-04-03 ES ES92200961T patent/ES2118105T3/es not_active Expired - Lifetime
- 1992-04-03 EP EP19920200961 patent/EP0563460B1/en not_active Expired - Lifetime
- 1992-04-03 DE DE1992626072 patent/DE69226072T2/de not_active Expired - Fee Related
1993
- 1993-03-29 WO PCT/US1993/002944 patent/WO1993020167A1/en active Application Filing
- 1993-03-29 BR BR9306183A patent/BR9306183A/pt not_active Application Discontinuation
- 1993-03-29 AU AU39399/93A patent/AU668936B2/en not_active Ceased
- 1993-03-29 JP JP5517617A patent/JPH07505437A/ja active Pending
- 1993-04-02 IE IE930263A patent/IE930263A1/en not_active IP Right Cessation
- 1993-04-03 CN CN 93105485 patent/CN1078254A/zh active Pending
- 1993-05-03 TW TW82103446A patent/TW299351B/zh active

Also Published As

Publication number	Publication date
TW299351B (pt)	1997-03-01
AU668936B2 (en)	1996-05-23
BR9306183A (pt)	1998-06-23
DE69226072D1 (de)	1998-08-06
AU3939993A (en)	1993-11-08
IE930263A1 (en)	1993-10-06
EP0563460A1 (en)	1993-10-06
ES2118105T3 (es)	1998-09-16
EP0563460B1 (en)	1998-07-01
WO1993020167A1 (en)	1993-10-14
CN1078254A (zh)	1993-11-10
JPH07505437A (ja)	1995-06-15

Legal Events

Date	Code	Title	Description
1999-07-29	8364	No opposition during term of opposition
2002-06-27	8339	Ceased/non-payment of the annual fee

Publication	Publication Date	Title
DE69316842T2 (de)	1998-09-10	Stabile Zusammensetzungen, welche Persulfatsalze enthalten
DE69229957T2 (de)	2000-04-13	Acylierte citratester als ausgangsstoffe für persäuren
DE69122789T2 (de)	1997-03-13	Wässrige Bleichmittelzusammensetzung
DE69231180T2 (de)	2001-02-15	Komposition für desinfizierung und deren verwendung
DE69434227T3 (de)	2009-12-10	Durchsichtige, isotrope, wässrige Bleichmittelzusammensetzung
DE69010922T2 (de)	1995-03-16	Enzym und Enzymstabilisationssystem enthaltendes flüssiges Waschmittel.
EP0497337B1 (de)	1997-06-04	Wässrige Suspensionen von Peroxicarbonsäuren
DE3543500C2 (pt)	1992-02-20
DE2420009C3 (pt)	1980-06-19
DE69100809T2 (de)	1994-05-19	Wasserstoffperoxid enthaltende stabile Bleichmittelzusammensetzungen.
DE69226072T2 (de)	1999-02-25	Durch Säure aktivierte Bleichzusammensetzung
DE69022753T2 (de)	1996-05-30	Stabilisierte, Bleichmittel enthaltende, flüssige Waschmittelzusammensetzungen.
DE2422691A1 (de)	1974-12-05	Stabile bleichmittel
DE3022767C2 (de)	1985-11-21	Wäßrig-flüssiges, builderhaltiges, copolymerfreies Waschmittel
DE2938731C2 (pt)	1987-11-26
DE69423613T2 (de)	2000-11-02	Bleichmittelzusammensetzungen
DE69529533T2 (de)	2003-12-04	Verdickte bleichmittelzusammensetzungen, gebrauchsverfahren und verfahren zu deren herstellung
EP0799154B1 (de)	1999-07-28	Verfahren zur herstellung eines natriumpercarbonat-produktes
DE721317C (de)	1942-06-02	Verfahren zum Stabilisieren von Perverbindungen enthaltenden Textilbehandlungsflotten
CH667667A5 (de)	1988-10-31	Fluessiges grobwaschmittel.
DE69420388T2 (de)	2000-04-06	Persulfat-Salze enthaltende stabile, stark saure wässrige Zusammensetzungen
DE2132703A1 (de)	1973-01-18	Perverbindungen und aktivatoren fuer diese enthaltende waschmittel
EP0017052B1 (de)	1982-05-26	Verwendung von Farbstabilisatoren in alkalischen Reinigungsmitteln, die nicht ionische Tenside enthalten
DE69025728T2 (de)	1996-07-25	Verfahren zum Erhöhen des Bleicheffektes beim Waschen und Verwendung bestimmter amphoterer Verbindungen in einer Waschmittelzusammensetzung zum Erhöhen des Bleicheffektes
AU6771194A (en)	1994-12-12	Mixing order to prepare aqueous detergent compositions