DE69224184T2 - Verfahren zur Herstellung von verbrückten, chiralen Metallocenkatalysatoren des Types Bisindenyl - Google Patents

Verfahren zur Herstellung von verbrückten, chiralen Metallocenkatalysatoren des Types Bisindenyl

Info

Publication number
DE69224184T2
DE69224184T2 DE69224184T DE69224184T DE69224184T2 DE 69224184 T2 DE69224184 T2 DE 69224184T2 DE 69224184 T DE69224184 T DE 69224184T DE 69224184 T DE69224184 T DE 69224184T DE 69224184 T2 DE69224184 T2 DE 69224184T2
Authority
DE
Germany
Prior art keywords
preparation
bridged
metallocene catalysts
formula
chiral metallocene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69224184T
Other languages
English (en)
Other versions
DE69224184D1 (de
Inventor
Juergen Rohrmann Kelkheim T Dr
Frank Kueber Oberursel Dr Dr
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Polyolefine GmbH
Original Assignee
Targor GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8209704&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE69224184(T2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Targor GmbH filed Critical Targor GmbH
Publication of DE69224184D1 publication Critical patent/DE69224184D1/de
Application granted granted Critical
Publication of DE69224184T2 publication Critical patent/DE69224184T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C—Si linkages
    • C07F7/0803Compounds with Si-C or Si-Si linkages
    • C07F7/0825Preparations of compounds not comprising Si-Si or Si-cyano linkages
    • C07F7/0827Syntheses with formation of a Si-C bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/22Tin compounds
    • C07F7/2208Compounds having tin linked only to carbon, hydrogen and/or halogen
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/30Germanium compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63927Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE69224184T 1992-06-13 1992-06-13 Verfahren zur Herstellung von verbrückten, chiralen Metallocenkatalysatoren des Types Bisindenyl Expired - Lifetime DE69224184T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP92109988A EP0574597B2 (de) 1992-06-13 1992-06-13 Verfahren zur Herstellung von verbrückten, chiralen Metallocenkatalysatoren des Types Bisindenyl

Publications (2)

Publication Number Publication Date
DE69224184D1 DE69224184D1 (de) 1998-02-26
DE69224184T2 true DE69224184T2 (de) 1999-06-02

Family

ID=8209704

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69224184T Expired - Lifetime DE69224184T2 (de) 1992-06-13 1992-06-13 Verfahren zur Herstellung von verbrückten, chiralen Metallocenkatalysatoren des Types Bisindenyl

Country Status (13)

Country Link
US (2) US5391790A (de)
EP (1) EP0574597B2 (de)
JP (1) JP3419501B2 (de)
KR (1) KR100293042B1 (de)
AT (1) ATE162529T1 (de)
AU (1) AU664896B2 (de)
CA (1) CA2098258A1 (de)
DE (1) DE69224184T2 (de)
DK (1) DK0574597T3 (de)
ES (1) ES2113900T3 (de)
GR (1) GR3026690T3 (de)
TW (1) TW223645B (de)
ZA (1) ZA934148B (de)

Families Citing this family (102)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5700896A (en) * 1988-07-30 1997-12-23 Hoechst Aktiengesellschaft Polymer having long isotactic sequences and randomly-distributed ethylene content obtained by polymerizing propylene in presence of specific catalysts
ATE177436T1 (de) * 1992-08-15 1999-03-15 Targor Gmbh Verfahren zur herstellung von polyolefinen
JPH06271594A (ja) * 1993-03-22 1994-09-27 Mitsui Petrochem Ind Ltd シクロペンタジエニル基含有ケイ素化合物またはシクロペンタジエニル基含有ゲルマニウム化合物の製造方法
ATE198893T1 (de) * 1993-11-24 2001-02-15 Targor Gmbh Metallocene, verfahren zu ihrer herstellung und ihrer verwendung als katalysatoren
DE4344689A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
WO1996030380A1 (fr) * 1995-03-30 1996-10-03 Idemitsu Kosan Co., Ltd. Compose de metaux de transition, catalyseur de polymerisation pour olefines et procede d'elaboration de polymeres d'olefines
US5705578A (en) * 1995-05-04 1998-01-06 Phillips Petroleum Company Method for making and using a supported metallocene catalyst system
US5631203A (en) * 1995-05-04 1997-05-20 Phillips Petroleum Company Metallocene compounds and preparation thereof containing terminal alkynes
DE19517851A1 (de) * 1995-05-16 1996-11-21 Hoechst Ag Organometallverbindung
US5679814A (en) * 1995-12-11 1997-10-21 Albemarle Corporation Purification of metallocenes
EP0780396B1 (de) * 1995-12-18 2002-10-02 Basell Polyolefine GmbH Verfahren zur Abreicherung von Nebenprodukten in Produktgemischen
ID16442A (id) 1996-01-22 1997-10-02 Dow Chemical Co Polimer etilena berat molekul ultra rendah
AT403919B (de) 1996-02-02 1998-06-25 Danubia Petrochem Polymere Verfahren zur herstellung von katalysatorträgern und geträgerter polyolefin-katalysatoren sowie deren verwendung für die herstellung von polyolefinen
EP0816371A1 (de) * 1996-06-28 1998-01-07 PCD-Polymere Gesellschaft m.b.H. Verfahren zur stereoselektiven Herstellung von chiralen Metallocenen
JP3566819B2 (ja) * 1996-10-04 2004-09-15 関東化学株式会社 新規な有機遷移金属化合物
JP3694371B2 (ja) * 1996-10-04 2005-09-14 関東化学株式会社 メタロセン化合物の新規な合成方法
PT835886E (pt) * 1996-10-09 2004-05-31 Atofina Res Processo para a preparacao e utilizacao de compostos de dicloreto de (bis(indenil)etano)zirconio meso/racemico
US5780660A (en) * 1996-11-07 1998-07-14 Albemarle Corporation Zirconocene ismerization process
WO1998022477A1 (en) * 1996-11-22 1998-05-28 Boulder Scientific Company Preparation of chiral titanocenes
CA2273794A1 (en) 1996-12-17 1998-06-25 Narayanaswami Raja Dharmarajan Themoplastic olefin compositions
ID19264A (id) * 1996-12-20 1998-06-28 Union Carbide Chem Plastic Pro-katalisator dan pengolahan untuk membuatnya
US6107501A (en) * 1997-01-30 2000-08-22 Fina Technology, Inc. Synthesis of metallocenes and enrichment of their rac isomer
DE69808243T2 (de) 1997-02-07 2003-05-08 Exxonmobil Chem Patents Inc Thermoplastische,elastomere zusammensetzungen aus verzweigten olefincopolymeren
BR9806952A (pt) 1997-02-07 2000-03-21 Exxon Chemical Patents Inc Preparação de macrÈmeros contendo vinila.
US6184327B1 (en) 1997-12-10 2001-02-06 Exxon Chemical Patents, Inc. Elastomeric propylene polymers
US6197910B1 (en) 1997-12-10 2001-03-06 Exxon Chemical Patents, Inc. Propylene polymers incorporating macromers
US6117962A (en) * 1997-12-10 2000-09-12 Exxon Chemical Patents Inc. Vinyl-containing stereospecific polypropylene macromers
EP0953582A1 (de) 1998-04-27 1999-11-03 Fina Research S.A. Herstellung von Polyolefin
DE69918100T2 (de) 1998-05-13 2005-07-07 Exxonmobil Chemical Patents Inc., Baytown Propylenhomopolymere und herstellungsverfahren
US6784269B2 (en) 1998-05-13 2004-08-31 Exxonmobil Chemical Patents Inc. Polypropylene compositions methods of making the same
US6306960B1 (en) 1998-05-13 2001-10-23 Exxonmobil Chemical Patents Inc. Articles formed from foamable polypropylene polymer
US6245868B1 (en) 1998-05-29 2001-06-12 Univation Technologies Catalyst delivery method, a catalyst feeder and their use in a polymerization process
BR9913647B1 (pt) 1998-08-26 2008-11-18 polipropileno ramificado e processo para produzir o mesmo.
US5965759A (en) * 1998-09-23 1999-10-12 Albemarle Corporation Catalytic process for isomerizing metallocenes
ATE371636T1 (de) * 1999-01-21 2007-09-15 Boulder Scient Co Synthese und isomerisierung von 1,2-bis(indenyl)- ethanen
US6174930B1 (en) 1999-04-16 2001-01-16 Exxon Chemical Patents, Inc. Foamable polypropylene polymer
JP4564612B2 (ja) * 1999-10-18 2010-10-20 日本ポリプロ株式会社 ラセミ体メタロセン化合物の製造方法
US6153777A (en) * 1999-11-02 2000-11-28 University Of Iowa Research Foundation Synthesis of ansa-metallocene catalysts
JP2003516440A (ja) * 1999-12-10 2003-05-13 エクソンモービル・ケミカル・パテンツ・インク プロピレンジエン共重合ポリマー
US6809168B2 (en) * 1999-12-10 2004-10-26 Exxonmobil Chemical Patents Inc. Articles formed from propylene diene copolymers
US6977287B2 (en) * 1999-12-10 2005-12-20 Exxonmobil Chemical Patents Inc. Propylene diene copolymers
WO2001062690A1 (en) 2000-02-23 2001-08-30 Akzo Nobel N.V. Process for preparing bisindenylalkanes
US7122498B2 (en) * 2000-06-30 2006-10-17 Exxonmobil Chemical Patents Inc. Metallocenes and catalyst compositions derived therefrom
WO2002100908A1 (en) * 2001-06-12 2002-12-19 Basell Polyolefine Gmbh Process for the polymerization of 1-butene
US7582708B2 (en) * 2001-06-13 2009-09-01 Beta Technologie Ag Bulk polymerization reactor methods
DE60234268D1 (de) * 2001-11-16 2009-12-17 Cdt Oxford Ltd Leuchtdiode und verwendete verbindungen
US6916892B2 (en) * 2001-12-03 2005-07-12 Fina Technology, Inc. Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene
EP1495038B1 (de) * 2002-04-12 2008-07-23 Dow Global Technologies Inc. Azaborolylkomplexe mit metallen der gruppe 4, katalysatoren und verfahren zur olefinepolymerisation
US20030236365A1 (en) * 2002-06-24 2003-12-25 Fina Technology, Inc. Polyolefin production with a high performance support for a metallocene catalyst system
US20040052690A1 (en) * 2002-09-12 2004-03-18 Eaton Gerald B. Polymerization reactant injection system
US7589160B2 (en) * 2002-12-04 2009-09-15 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
DE60329523D1 (de) * 2002-12-04 2009-11-12 Basell Polyolefine Gmbh 1-Buten-Copolymere und Herstellungsverfahren dafür
US7195806B2 (en) * 2003-01-17 2007-03-27 Fina Technology, Inc. High gloss polyethylene articles
EP1611169B1 (de) * 2003-03-21 2010-06-02 Dow Global Technologies Inc. Verfahren zur herstellung von polyolefinen mit kontrollierter morphologie
US20050234198A1 (en) * 2004-04-20 2005-10-20 Fina Technology, Inc. Heterophasic copolymer and metallocene catalyst system and method of producing the heterophasic copolymer using the metallocene catalyst system
US20060052540A1 (en) 2004-09-09 2006-03-09 Maria Ellul Thermoplastic vulcanizates
US7169864B2 (en) * 2004-12-01 2007-01-30 Novolen Technology Holdings, C.V. Metallocene catalysts, their synthesis and their use for the polymerization of olefins
EP2218751A1 (de) 2004-12-17 2010-08-18 Dow Global Technologies Inc. Rheologiemodifizierte Polyethylenzusammensetzungen
US7232869B2 (en) * 2005-05-17 2007-06-19 Novolen Technology Holdings, C.V. Catalyst composition for olefin polymerization
DE102005061326A1 (de) * 2005-12-20 2007-06-21 Basell Polyolefine Gmbh Verfahren zur Herstellung von Metallocenen aus recycelten, substituierten Cyclopentadienylderivaten
EP1803747A1 (de) 2005-12-30 2007-07-04 Borealis Technology Oy Oberflächemodifizierte Polymerisationskatalysatoren zur Herstellung von Polyolefinfilmen mit niedrigem Gelgehalt
DE102006020486A1 (de) 2006-04-28 2007-10-31 Basell Polyolefine Gmbh Geträgerte Metallalkylverbindung und Verfahren zur Polymerisation von Olefinen in deren Gegenwart
EP2016128B1 (de) 2006-05-02 2010-07-21 Dow Global Technologies Inc. Sehr dichte polyethylenzusammensetzungen, verfahren zu deren herstellung, draht- und kabelhüllen, die daraus hergestellt wurden und verfahren zur herstellung derartiger draht- und kabelhüllen
US7456244B2 (en) * 2006-05-23 2008-11-25 Dow Global Technologies High-density polyethylene compositions and method of making the same
KR20100014214A (ko) * 2007-05-02 2010-02-10 다우 글로벌 테크놀로지스 인크. 고-밀도 폴리에틸렌 조성물, 그의 제조 방법, 그로부터 만들어진 사출 성형 물품, 및 이러한 물품의 제조 방법
US8487033B2 (en) 2007-05-16 2013-07-16 Exxonmobil Chemical Patents Inc. Thermoplastic elastomer compositions, methods for making the same, and articles made therefrom
US8962762B2 (en) * 2007-06-13 2015-02-24 Exxonmobil Chemical Patents Inc. Thermoplastic polymer compositions, methods for making the same, and articles made therefrom
US7981517B2 (en) * 2007-08-28 2011-07-19 Dow Global Technologies Inc. Bituminous compositions and methods of making and using same
WO2009054831A1 (en) * 2007-10-25 2009-04-30 Novolen Technology Holdings, C.V. Racemoselective synthesis of ansa-metallocene compounds, ansa-metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers
BRPI0922454A2 (pt) 2008-12-18 2018-05-22 Univation Tech Llc método para tratamento de leito de semente para uma reação de polimerização
CN102361925B (zh) 2009-01-30 2013-08-14 陶氏环球技术有限责任公司 高密度聚乙烯组合物、其制备方法、由其制备的封闭器件、和制备所述封闭器件的方法
WO2011159400A1 (en) 2010-06-15 2011-12-22 Exxonmobil Chemical Patents Inc. Nonwoven fabrics made from polymer blends and methods for making same
EP2573091A1 (de) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Verfahren zur Wiedergewinnung freier Liganden aus ihren jeweiligen Metallocenkomplexen
ES2823768T3 (es) 2012-12-28 2021-05-10 Univation Tech Llc Métodos para integrar la producción de aluminoxano en la producción de catalizador
CN105121015A (zh) 2013-01-14 2015-12-02 尤尼威蒂恩技术有限责任公司 制备高产率催化剂***的方法
US9376518B2 (en) 2013-08-28 2016-06-28 Exxonmobil Chemical Patents Inc. Racemo selective metallation process
SG11201508765TA (en) * 2013-08-28 2015-11-27 Exxonmobil Chem Patents Inc Racemo selective metallation process
US10294312B2 (en) 2014-12-12 2019-05-21 Exxonmobil Research And Engineering Company Olefin polymerization catalyst system comprising mesoporous organosilica support
US10351639B2 (en) 2014-12-12 2019-07-16 Exxonmobil Research And Engineering Company Organosilica materials for use as adsorbents for oxygenate removal
EP3274381B1 (de) 2015-04-20 2019-05-15 ExxonMobil Chemical Patents Inc. Katalysatorzusammensetzung mit fluoridiertem träger und verfahren zur verwendung davon
EP3274380B1 (de) 2015-04-20 2020-08-19 ExxonMobil Chemical Patents Inc. Katalysatorzusammensetzung mit fluoridiertem träger und verfahren zur verwendung davon
CN107660216B (zh) 2015-05-08 2021-05-14 埃克森美孚化学专利公司 聚合方法
WO2018063765A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063767A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063764A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018118155A1 (en) 2016-12-20 2018-06-28 Exxonmobil Chemical Patents Inc. Polymerization process
WO2019118073A1 (en) 2017-12-13 2019-06-20 Exxonmobil Chemical Patents Inc. Deactivation methods for active components from gas phase polyolefin polymerization process
WO2019173030A1 (en) 2018-03-08 2019-09-12 Exxonmobil Chemical Patents Inc. Methods of preparing and monitoring a seed bed for polymerization reactor startup
CN112055720B (zh) 2018-05-02 2022-11-22 埃克森美孚化学专利公司 从中试装置放大到较大生产设施的方法
EP3788081A1 (de) 2018-05-02 2021-03-10 ExxonMobil Chemical Patents Inc. Verfahren zur aufskalierung von einer pilotanlage zu einer grösseren produktionsanlage
WO2020014138A1 (en) 2018-07-09 2020-01-16 Exxonmobil Chemical Patents Inc. Polyethylene cast films and methods for making the same
CN112469556B (zh) 2018-07-26 2023-05-02 埃克森美孚化学专利公司 多层泡沫膜及其制造方法
US11993699B2 (en) 2018-09-14 2024-05-28 Fina Technology, Inc. Polyethylene and controlled rheology polypropylene polymer blends and methods of use
CN113195603B (zh) 2018-11-13 2023-05-26 埃克森美孚化学专利公司 聚乙烯膜
US11649331B2 (en) 2018-11-13 2023-05-16 Exxonmobil Chemical Patents Inc. Polyethylene blends and films
WO2020163079A1 (en) 2019-02-06 2020-08-13 Exxonmobil Chemical Patents Inc. Films and backsheets for hygiene articles
MX2021006769A (es) 2019-02-20 2021-07-15 Fina Technology Composiciones de polimero con baja distorsion.
EP4053175A4 (de) 2019-10-30 2023-11-15 China Petroleum & Chemical Corporation Metallocenverbindung und herstellungsverfahren dafür und anwendung davon
US20230018505A1 (en) 2019-12-17 2023-01-19 Exxonmobil Chemical Patents Inc. Films Made of Polyethylene Blends for Improved Sealing Performance and Mechanical Properties
US20230097375A1 (en) 2020-03-12 2023-03-30 Exxonmobil Chemical Patents Inc. Films made of polyethylene blends for improved bending stiffness and high md tear resistance
JP2024518327A (ja) 2021-04-26 2024-05-01 フイナ・テクノロジー・インコーポレーテツド 薄シングルサイト触媒ポリマーシート
WO2022232760A1 (en) 2021-04-30 2022-11-03 Exxonmobil Chemical Patents Inc. Processes for transitioning between different polymerization catalysts in a polymerization reactor

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3742934A1 (de) * 1987-12-18 1989-06-29 Hoechst Ag Verfahren zur herstellung einer chiralen, stereorigiden metallocen-verbindung
IL89525A0 (en) * 1988-03-21 1989-09-10 Exxon Chemical Patents Inc Silicon-bridged transition metal compounds
US5017714A (en) * 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
DE3844282A1 (de) 1988-12-30 1990-07-05 Hoechst Ag Bisindenyl-derivat und verfahren zu seiner herstellung
US5117020A (en) * 1989-10-30 1992-05-26 Fina Research, S.A. Process for the preparation of metallocenes
EP0426643B1 (de) * 1989-10-30 1995-12-27 Fina Research S.A. Verfahren zur Herstellung von Metallocenen
EP0485823B1 (de) * 1990-11-12 1995-03-08 Hoechst Aktiengesellschaft 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation
TW300901B (de) 1991-08-26 1997-03-21 Hoechst Ag
NL9101502A (nl) 1991-09-06 1993-04-01 Dsm Nv Werkwijze voor het bereiden van een gebrugde metalloceenverbinding alsmede een katalysatorcomponent en een werkwijze voor de polymerisatie van een olefinen.

Also Published As

Publication number Publication date
US5616747A (en) 1997-04-01
ES2113900T3 (es) 1998-05-16
DK0574597T3 (da) 1998-09-14
JPH06122692A (ja) 1994-05-06
DE69224184D1 (de) 1998-02-26
US5391790A (en) 1995-02-21
TW223645B (de) 1994-05-11
ZA934148B (en) 1994-01-13
EP0574597A1 (de) 1993-12-22
AU664896B2 (en) 1995-12-07
JP3419501B2 (ja) 2003-06-23
KR100293042B1 (ko) 2001-11-22
EP0574597B1 (de) 1998-01-21
AU4018193A (en) 1993-12-16
ATE162529T1 (de) 1998-02-15
CA2098258A1 (en) 1993-12-14
KR940000472A (ko) 1994-01-03
GR3026690T3 (en) 1998-07-31
EP0574597B2 (de) 2002-06-26

Similar Documents

Publication Publication Date Title
DE69224184T2 (de) Verfahren zur Herstellung von verbrückten, chiralen Metallocenkatalysatoren des Types Bisindenyl
HUT56379A (en) Process for producing a-norsteroid-3-carboxylic acid derivatives and compositions comprising such compounds
KR840000515A (ko) N-아릴-피페라진알칸아미드의 제조법
HUT54357A (en) Process for producing benzilidene-(azolylmethyl)-cycloalkane and -cycloalkene derivatives, fungicidal compositions comprising such compounds as active ingredient and intermediates usable for the production of the active ingredients
PT85943A (en) Antibacterial agents
DE59409435D1 (de) Verfahren zur Herstellung von 3-Arylbenzofuranonen
DE3883456D1 (de) Verfahren zur Herstellung von substituierten Indolinonderivaten.
DE69226590T2 (de) Verfahren zur Herstellung von substituierten N-Aryl-1,2,4-Triazolopyrimidin-2-Sulfonamiden
DE59509910D1 (de) Verfahren zur Herstellung von Alkylhydrogenchlorsilanen
IL107068A0 (en) 5-oxo-dibenzo(a,d)cyclohepta-1,4-dienes,their preparation and pharmaceutical compositions containing them
HU903266D0 (en) Process for producing amine-derivatives and pharmaceutical preparatives containing these compounds as active substance
ATE82292T1 (de) Verfahren zur herstellung von 2-alpha-methyl-2beta-(1,2,3-triazol-1-yl)methylpenam-3-alphacarbons|urederivaten.
DE69100196T2 (de) Verfahren zur Herstellung von Benzylaminen.
DE3781879D1 (de) Anthracyclinderivate, verfahren zu ihrer herstellung und ihre verwendung als arzneimittel.
DE59307005D1 (de) Verfahren zur Herstellung von Ph3C[B(C6F5)4]
EP0448774A3 (en) Triazinic compounds
GR3019711T3 (en) Spiro-indoline-oxazine compounds with photochromatic and photosensitizing characteristics and the process for their preparation
IN159806B (de)
DE69125569T2 (de) 8-Azabicyclo[3.2.1]octylalkylthiazolidinone, Verfahren zu ihrer Herstellung und ihre Verwendung als Arzneimittel
DE69016380D1 (de) Verfahren zur Herstellung von molluskiziden 2,4,5-Tribrompyrrol-3-Carbonitrilen.
ATE111093T1 (de) Verfahren zur herstellung von enantiomeren von 3- aminchromanderivaten.
DE68926016T2 (de) Halogeno-4-Methylpyrazole und Verfahren zu ihrer Herstellung
DE69130995D1 (de) Verfahren zur Herstellung von 5-Arylhydantoin
ATE92481T1 (de) Verfahren zur herstellung von n,n'-bis-(2hydroxyethyl)-piperazin.
DE69700036D1 (de) Verfahren zur Substitution von Cyclopentadien

Legal Events

Date Code Title Description
8327 Change in the person/name/address of the patent owner

Owner name: TARGOR GMBH, 55116 MAINZ, DE

8332 No legal effect for de
8370 Indication related to discontinuation of the patent is to be deleted
8380 Miscellaneous part iii

Free format text: IM HEFT 33/98, SEITE 10399, SP.4: DIE VEROEFFENTLICHUNG IST ZU STREICHEN

8327 Change in the person/name/address of the patent owner

Owner name: BASELL POLYPROPYLEN GMBH, 55116 MAINZ, DE

8363 Opposition against the patent
8366 Restricted maintained after opposition proceedings
8327 Change in the person/name/address of the patent owner

Owner name: BASELL POLYOLEFINE GMBH, 50389 WESSELING, DE

8332 No legal effect for de