DE69213760D1 - Haftfreie elastomere acrylat-mikrokugeln - Google Patents

Haftfreie elastomere acrylat-mikrokugeln

Info

Publication number
DE69213760D1
DE69213760D1 DE69213760T DE69213760T DE69213760D1 DE 69213760 D1 DE69213760 D1 DE 69213760D1 DE 69213760 T DE69213760 T DE 69213760T DE 69213760 T DE69213760 T DE 69213760T DE 69213760 D1 DE69213760 D1 DE 69213760D1
Authority
DE
Germany
Prior art keywords
microballs
adhesive elastomer
acrylate
elastomer acrylate
adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69213760T
Other languages
English (en)
Other versions
DE69213760T2 (de
Inventor
Joaquin Delgado
Spencer Silver
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Co
Original Assignee
Minnesota Mining and Manufacturing Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Minnesota Mining and Manufacturing Co filed Critical Minnesota Mining and Manufacturing Co
Application granted granted Critical
Publication of DE69213760D1 publication Critical patent/DE69213760D1/de
Publication of DE69213760T2 publication Critical patent/DE69213760T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1809—C9-(meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/18—Suspension polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1805—C5-(meth)acrylate, e.g. pentyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1812—C12-(meth)acrylate, e.g. lauryl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Manufacturing Of Micro-Capsules (AREA)
  • Polymerisation Methods In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
DE69213760T 1991-12-17 1992-12-07 Haftfreie elastomere acrylat-mikrokugeln Expired - Fee Related DE69213760T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US80942291A 1991-12-17 1991-12-17
PCT/US1992/010588 WO1993012147A1 (en) 1991-12-17 1992-12-07 Tack-free elastomeric acrylate microspheres

Publications (2)

Publication Number Publication Date
DE69213760D1 true DE69213760D1 (de) 1996-10-17
DE69213760T2 DE69213760T2 (de) 1997-04-10

Family

ID=25201301

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69213760T Expired - Fee Related DE69213760T2 (de) 1991-12-17 1992-12-07 Haftfreie elastomere acrylat-mikrokugeln

Country Status (10)

Country Link
EP (1) EP0617708B1 (de)
JP (1) JP3251585B2 (de)
KR (1) KR100210974B1 (de)
AU (1) AU670054B2 (de)
CA (1) CA2124342C (de)
DE (1) DE69213760T2 (de)
ES (1) ES2092805T3 (de)
MX (1) MX9207268A (de)
TW (1) TW222005B (de)
WO (1) WO1993012147A1 (de)

Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6440880B2 (en) 1993-10-29 2002-08-27 3M Innovative Properties Company Pressure-sensitive adhesives having microstructured surfaces
ATE203755T1 (de) * 1994-05-15 2001-08-15 Apbiotech Aktiebolag Verfahren zur herstellung von teilchen und teilchen die mit hilfe dieses verfahrens hergestellt werden können
US5578650A (en) * 1995-12-01 1996-11-26 Minnesota Mining And Manufacturing Company Methods of preparing hollow acrylate polymer microspheres
US5696199A (en) * 1995-12-07 1997-12-09 Minnesota Mining And Manufacturing Company Pressure-sensitive adhesive polyacrylate polymer and method of making
EP0888412B1 (de) * 1996-03-21 2002-09-11 Minnesota Mining And Manufacturing Company Druckempfindlicher klebefilm aus klebrigen mikroteilchen
US5888650A (en) * 1996-06-03 1999-03-30 Minnesota Mining And Manufacturing Company Temperature-responsive adhesive article
US6479073B1 (en) 1996-10-07 2002-11-12 3M Innovative Properties Company Pressure sensitive adhesive articles and methods for preparing same
US5756625A (en) * 1996-10-11 1998-05-26 Minnesota Mining And Manufacturing Company Stabilized adhesive microspheres
US6197397B1 (en) 1996-12-31 2001-03-06 3M Innovative Properties Company Adhesives having a microreplicated topography and methods of making and using same
US6524675B1 (en) 1999-05-13 2003-02-25 3M Innovative Properties Company Adhesive-back articles
GB9917119D0 (en) * 1999-07-21 1999-09-22 Bicc Gen Uk Cables Ltd Resin compositions and electric cable joints
US6531541B1 (en) 2000-05-19 2003-03-11 Ppg Industries Ohio, Inc. Coating compositions, coated substrates and methods for inhibiting sound transmission through a substrate
US6984429B2 (en) 2001-01-12 2006-01-10 3M Innovative Properties Company Laminate from which decorative films can be applied to a substrate
US6613411B2 (en) 2001-01-25 2003-09-02 3M Innovative Properties Company Conformable multi-layer sheet materials
US6631030B2 (en) 2001-03-30 2003-10-07 3M Innovative Properties Company Projection screens and methods for making such projection screens
US20030162890A1 (en) * 2002-02-15 2003-08-28 Kalantar Thomas H. Nanoscale polymerized hydrocarbon particles and methods of making and using such particles
US6872268B2 (en) 2002-06-11 2005-03-29 3M Innovative Properties Company Method of conforming an adherent film to a substrate by application of vacuum
GB0711621D0 (en) * 2007-06-18 2007-07-25 3M Innovative Properties Co Additive to reduce fluid loss for drilling fluids
US8110280B2 (en) 2008-03-27 2012-02-07 3M Innovative Properties Company Adhesive composition having non-tacky microspheres and sheets made therefrom
EP2739484B1 (de) 2011-08-02 2020-11-18 3M Innovative Properties Company Graphischer artikel
EP2578412B1 (de) 2011-10-07 2014-06-25 3M Innovative Properties Company Bedruckbare Folie
EP2604665B1 (de) 2011-12-15 2015-12-09 3M Innovative Properties Company Farbige Polyvinylchlorid-Haftfolie
EP2604444B1 (de) 2011-12-15 2015-10-14 3M Innovative Properties Company Verfahren zum Dekorieren einer Oberfläche mit selbstklebenden Farbfolienelementen
EP2604664B1 (de) 2011-12-15 2014-11-26 3M Innovative Properties Company Polyvinylchlorid-Klebefolie
US10259258B2 (en) 2011-12-15 2019-04-16 3M Innovative Properties Company Adhesive film and method of making a graphic
EP2953792B1 (de) 2013-02-05 2019-03-20 3M Innovative Properties Company Grafikartikel
EP2772507A1 (de) 2013-02-28 2014-09-03 3M Innovative Properties Company Graffitischutzschicht für Polyvinylchlorid-basierte graphische Folie
EP2803710A1 (de) 2013-05-14 2014-11-19 3M Innovative Properties Company Klebefilm für Grafiken mit Antigraffitibeschichtung
EP2808369B1 (de) 2013-05-30 2018-10-24 3M Innovative Properties Company Basisfolie zur Herstellung einer grafischen Folie
EP2975097B1 (de) * 2014-07-17 2022-03-09 3M Innovative Properties Company Mehrschichtige druckempfindliche haftanordnung mit thermoplastischem füllmaterial
US10619019B2 (en) 2014-12-08 2020-04-14 3M Innovative Properties Company Acrylic polyvinyl acetal films, composition, and heat bondable articles
BR112018001281A2 (pt) 2015-07-30 2018-09-11 3M Innovative Properties Co ?métodos para fabricação de um artigo à base de película?
EP3328953A1 (de) 2015-07-30 2018-06-06 3M Innovative Properties Company Bahn mit haftschicht mit teilweise eingebetteten filamenten
CN107848192B (zh) 2015-07-30 2021-11-05 3M创新有限公司 具有部分嵌入的原丝的幅材衬垫
WO2017079046A1 (en) 2015-11-02 2017-05-11 3M Innovative Properties Company Low gloss laminated article
EP3393799A2 (de) 2015-12-22 2018-10-31 3M Innovative Properties Company Acryl-polyvinylacetal-folien mit einer zweiten schicht
WO2017112468A2 (en) 2015-12-22 2017-06-29 3M Innovative Properties Company Acrylic films comprising a structured layer
CN108472936B (zh) 2015-12-22 2020-10-27 3M创新有限公司 包括粘合剂层的丙烯酸类聚乙烯醇缩醛膜
AU2016378200B2 (en) 2015-12-22 2019-08-15 3M Innovative Properties Company Acrylic polyvinyl acetal graphic films
CN105859935B (zh) * 2016-04-12 2018-10-02 昆明理工大学 一种内部具有体型网状结构的海绵体聚合物微球的制备方法
EP3838591B1 (de) 2019-12-20 2024-05-01 Mondi AG Trennschicht für umpositionierbare klebstoffartikel
WO2022144728A1 (en) 2020-12-31 2022-07-07 3M Innovative Properties Company Adhesive with thermally reversible, covalent crosslinks

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3691140A (en) * 1970-03-09 1972-09-12 Spencer Ferguson Silver Acrylate copolymer microspheres
GR78476B (de) * 1980-01-30 1984-09-27 Calgon Corp
US5045569A (en) * 1988-11-30 1991-09-03 Minnesota Mining And Manufacturing Company Hollow acrylate polymer microspheres
US5266402A (en) * 1990-12-18 1993-11-30 Minnesota Mining And Manufacturing Company Interpenetrating pressure-sensitive adhesive polymer networks

Also Published As

Publication number Publication date
CA2124342A1 (en) 1993-06-24
AU3244193A (en) 1993-07-19
WO1993012147A1 (en) 1993-06-24
AU670054B2 (en) 1996-07-04
CA2124342C (en) 2003-03-25
KR100210974B1 (ko) 1999-07-15
TW222005B (en) 1994-04-01
KR940703862A (ko) 1994-12-12
MX9207268A (es) 1993-06-01
DE69213760T2 (de) 1997-04-10
ES2092805T3 (es) 1996-12-01
JPH07502294A (ja) 1995-03-09
EP0617708A1 (de) 1994-10-05
JP3251585B2 (ja) 2002-01-28
EP0617708B1 (de) 1996-09-11

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee