DE60315741D1 - Verfahren zur Herstellung von Acrylsäure - Google Patents

Verfahren zur Herstellung von Acrylsäure

Info

Publication number
DE60315741D1
DE60315741D1 DE60315741T DE60315741T DE60315741D1 DE 60315741 D1 DE60315741 D1 DE 60315741D1 DE 60315741 T DE60315741 T DE 60315741T DE 60315741 T DE60315741 T DE 60315741T DE 60315741 D1 DE60315741 D1 DE 60315741D1
Authority
DE
Germany
Prior art keywords
production
acrylic acid
acrylic
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60315741T
Other languages
English (en)
Other versions
DE60315741T2 (de
Inventor
Hiroyuki Uhara
Kazuo Anyouji
Hideyuki Hironaka
Hideo Onodera
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Publication of DE60315741D1 publication Critical patent/DE60315741D1/de
Application granted granted Critical
Publication of DE60315741T2 publication Critical patent/DE60315741T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/44—Preparation of carboxylic acid esters by oxidation-reduction of aldehydes, e.g. Tishchenko reaction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/001—Controlling catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067—Heating or cooling the reactor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00212—Plates; Jackets; Cylinders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00548—Flow
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00654—Controlling the process by measures relating to the particulate material
    • B01J2208/00699—Moisture content regulation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00654—Controlling the process by measures relating to the particulate material
    • B01J2208/00707—Fouling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00716—Means for reactor start-up
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE60315741T 2002-02-07 2003-02-03 Verfahren zur Herstellung von Acrylsäure Expired - Lifetime DE60315741T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2002030890A JP3884967B2 (ja) 2002-02-07 2002-02-07 メタクリル酸の製造方法
JP2002030890 2002-02-07

Publications (2)

Publication Number Publication Date
DE60315741D1 true DE60315741D1 (de) 2007-10-04
DE60315741T2 DE60315741T2 (de) 2008-06-05

Family

ID=27621376

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60315741T Expired - Lifetime DE60315741T2 (de) 2002-02-07 2003-02-03 Verfahren zur Herstellung von Acrylsäure

Country Status (7)

Country Link
US (1) US7253309B2 (de)
EP (1) EP1336598B1 (de)
JP (1) JP3884967B2 (de)
KR (1) KR100653435B1 (de)
CN (1) CN100379714C (de)
DE (1) DE60315741T2 (de)
TW (1) TWI250146B (de)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7419932B2 (en) * 2003-01-09 2008-09-02 Mitsubishi Rayon Co., Ltd. Method for preserving catalyst
WO2005053839A1 (ja) * 2003-12-03 2005-06-16 Mitsubishi Chemical Corporation 不飽和アルデヒド及び不飽和カルボン酸製造用触媒及びその製造方法
JP2005314314A (ja) * 2004-04-30 2005-11-10 Mitsubishi Chemicals Corp （メタ）アクリル酸または（メタ）アクロレインの製造方法
JP2005336085A (ja) * 2004-05-26 2005-12-08 Mitsubishi Chemicals Corp （メタ）アクリル酸または（メタ）アクロレインの製造方法
DE102007028333A1 (de) * 2007-06-15 2008-12-18 Basf Se Verfahren zum Einbringen einer wenigstens einer Produktionscharge von ringförmigen Schalenkatalysatoren K entnommenen Teilmenge in ein Reaktionsrohr eines Rohrbündelreaktors
FR2919058B1 (fr) * 2007-07-17 2010-06-11 Inst Francais Du Petrole Procede et installation de test de catalyseurs
JP5107084B2 (ja) * 2008-02-12 2012-12-26 三菱レイヨン株式会社 メタクリル酸の製造方法
WO2009123872A1 (en) * 2008-04-01 2009-10-08 Dow Global Technologies Inc. Procedure for the startup of a (meth)acrylic acid plant
JP5099903B2 (ja) * 2008-04-16 2012-12-19 日本化薬株式会社 気相−固相接触反応の反応開始方法
WO2011065529A1 (ja) * 2009-11-30 2011-06-03 日本化薬株式会社 メタクリル酸製造触媒の製造方法およびメタクリル酸の製造方法
EP2781260A4 (de) * 2011-11-17 2015-07-08 Nippon Kayaku Kk Katalysator zur herstellung von methacrylsäure und verfahren zur herstellung von methacrylsäure mit diesem katalysator
CN106076413A (zh) * 2016-06-05 2016-11-09 王金明 一种异丁烷生产甲基丙烯酸催化剂的制备方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3516800A (en) * 1965-08-25 1970-06-23 Hisao Yamamoto Synthesis reaction apparatus equipped with means for temperature control of catalyst bed
JPS5924140B2 (ja) * 1977-10-31 1984-06-07 日本化薬株式会社 メタクリル酸の製造法及び触媒
JPS6012134A (ja) 1983-07-04 1985-01-22 Ube Ind Ltd 不飽和酸製造用触媒の製造法
DE3410565A1 (de) * 1984-03-22 1985-10-03 Hermann 7465 Geislingen Weißer Universal-wc-wasserstop
KR900002454B1 (ko) * 1986-01-08 1990-04-16 미쯔비시 레이욘 가부시끼가이샤 메타크릴산의 제조방법 및 이 방법에 사용되는 촉매
US5191116A (en) * 1989-05-22 1993-03-02 Asahi Kasei Kogyo Kabushiki Kaisha Process for the preparation of methacrylic acid and methacrolein
DE69013623T3 (de) * 1989-08-29 2002-12-19 Nippon Catalytic Chem Ind Katalysator zur Herstellung von Methacrylsäure.
FR2652760B1 (fr) 1989-10-06 1993-12-10 Ceca Sa Procede d'activation thermique de zeolites par percolation d'un gaz chaud.
US5211929A (en) * 1989-10-06 1993-05-18 Ceca S.A. Process for the thermal activation of zeolites and resultant products
KR950006522B1 (ko) * 1989-12-06 1995-06-16 가부시끼가이샤 닛뽕쇼꾸바이 메타크롤레인 및 메타크릴산의 제조방법
JP2814321B2 (ja) 1991-10-09 1998-10-22 三菱レイヨン株式会社 メタクリル酸の製造方法
JP3316880B2 (ja) 1992-09-08 2002-08-19 住友化学工業株式会社 メタクリル酸製造用触媒の製造方法
DE4329906A1 (de) 1993-09-04 1995-03-09 Basf Ag Massen der allgemeinen Formel Mo¶1¶¶2¶P¶a¶V¶b¶X·1·¶c¶X·2·¶d¶X·3·¶e¶Sb¶f¶Re¶g¶S¶h¶O¶n¶
JP4045693B2 (ja) * 1999-04-27 2008-02-13 住友化学株式会社 メタクリル酸の製造方法
JP4648515B2 (ja) * 2000-05-02 2011-03-09 株式会社日本触媒 反応器のスタートアップ方法
TW572885B (en) * 2001-05-30 2004-01-21 Mitsubishi Rayon Co Method for producing (meth)acrolein and/or (meth)acrylic acid

Also Published As

Publication number Publication date
KR20030067555A (ko) 2003-08-14
EP1336598B1 (de) 2007-08-22
TWI250146B (en) 2006-03-01
EP1336598A1 (de) 2003-08-20
US20030162997A1 (en) 2003-08-28
US7253309B2 (en) 2007-08-07
JP2003238477A (ja) 2003-08-27
KR100653435B1 (ko) 2006-12-01
CN100379714C (zh) 2008-04-09
JP3884967B2 (ja) 2007-02-21
TW200302820A (en) 2003-08-16
DE60315741T2 (de) 2008-06-05
CN1436764A (zh) 2003-08-20

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