DE51248C - Production of white security paper - Google Patents
Production of white security paperInfo
- Publication number
- DE51248C DE51248C DENDAT51248D DE51248DA DE51248C DE 51248 C DE51248 C DE 51248C DE NDAT51248 D DENDAT51248 D DE NDAT51248D DE 51248D A DE51248D A DE 51248DA DE 51248 C DE51248 C DE 51248C
- Authority
- DE
- Germany
- Prior art keywords
- resinous
- production
- paper
- security paper
- white
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 239000011347 resin Substances 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 8
- 239000000344 soap Substances 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- 239000011780 sodium chloride Substances 0.000 claims description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N manganese Chemical class [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 239000011572 manganese Chemical class 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical class [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 1
- 239000011133 lead Chemical class 0.000 claims 1
- 239000011135 tin Chemical class 0.000 claims 1
- 229910052718 tin Inorganic materials 0.000 claims 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N tin hydride Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical class [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 239000011701 zinc Chemical class 0.000 claims 1
- 229910052725 zinc Chemical class 0.000 claims 1
- 229920001131 Pulp (paper) Polymers 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 239000005083 Zinc sulfide Substances 0.000 description 3
- 229940037003 alum Drugs 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 239000004328 sodium tetraborate Substances 0.000 description 3
- 235000010339 sodium tetraborate Nutrition 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- WGPCGCOKHWGKJJ-UHFFFAOYSA-N sulfanylidenezinc Chemical compound [Zn]=S WGPCGCOKHWGKJJ-UHFFFAOYSA-N 0.000 description 3
- CXKCTMHTOKXKQT-UHFFFAOYSA-N Cadmium oxide Chemical compound [Cd]=O CXKCTMHTOKXKQT-UHFFFAOYSA-N 0.000 description 2
- GUWSLQUAAYEZAF-UHFFFAOYSA-L Lead(II) acetate Chemical compound O1C(C)=O[Pb]21O=C(C)O2 GUWSLQUAAYEZAF-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M NaHCO3 Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 230000002378 acidificating Effects 0.000 description 2
- 238000007792 addition Methods 0.000 description 2
- 150000001661 cadmium Chemical class 0.000 description 2
- 229940046892 lead acetate Drugs 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- FRLJSGOEGLARCA-UHFFFAOYSA-N Cadmium sulfide Chemical compound [S-2].[Cd+2] FRLJSGOEGLARCA-UHFFFAOYSA-N 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L Iron(II) sulfate Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- NUJOXMJBOLGQSY-UHFFFAOYSA-N Manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N Molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N Sodium sulfide Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J Tin(IV) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L Zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- XMYHHSMIUHHPEW-UHFFFAOYSA-N azane;molybdenum Chemical compound N.[Mo] XMYHHSMIUHHPEW-UHFFFAOYSA-N 0.000 description 1
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 229910000460 iron oxide Inorganic materials 0.000 description 1
- 159000000014 iron salts Chemical class 0.000 description 1
- 229910000358 iron sulfate Inorganic materials 0.000 description 1
- 229910000468 manganese oxide Inorganic materials 0.000 description 1
- 229940099596 manganese sulfate Drugs 0.000 description 1
- 239000011702 manganese sulphate Substances 0.000 description 1
- 235000007079 manganese sulphate Nutrition 0.000 description 1
- ISPYRSDWRDQNSW-UHFFFAOYSA-L manganese(II) sulfate monohydrate Chemical compound O.[Mn+2].[O-]S([O-])(=O)=O ISPYRSDWRDQNSW-UHFFFAOYSA-L 0.000 description 1
- AMWRITDGCCNYAT-UHFFFAOYSA-L manganese(II,III) oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002751 molybdenum Chemical class 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 230000001264 neutralization Effects 0.000 description 1
- 239000000276 potassium ferrocyanide Substances 0.000 description 1
- OCPOWIWGGAATRP-UHFFFAOYSA-N potassium hexacyanoferrate(4-) Chemical compound [K+].[K+].[K+].[K+].N#C[Fe-4](C#N)(C#N)(C#N)(C#N)C#N OCPOWIWGGAATRP-UHFFFAOYSA-N 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000008149 soap solution Substances 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 239000011686 zinc sulphate Substances 0.000 description 1
- 235000009529 zinc sulphate Nutrition 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/40—Agents facilitating proof of genuineness or preventing fraudulent alteration, e.g. for security paper
- D21H21/44—Latent security elements, i.e. detectable or becoming apparent only by use of special verification or tampering devices or methods
- D21H21/46—Elements suited for chemical verification or impeding chemical tampering, e.g. by use of eradicators
Landscapes
- Paper (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
KLASSE 54: Papiererzeugnisse.CLASS 54: Paper products.
Vorliegend beschriebenes Verfahren zur Herstellung von Sicherheitspapier besteht in der besonderen Bereitung der Papiermasse, welcher man verschiedene Ingredienzen wie harzsaure, metallische Salze beimischt, z. B. harzsaures Eisenoxydul mit einem Gemenge einer harzigen Verbindung von Ferrocyanblei oder Ferrocyanzinnoxyd und einer harzigen Verbindung von Ferrocyanmanganoxyd.The presently described method for producing security paper consists in the special preparation of the paper pulp, to which various ingredients such as resinous acid, metallic salts admixed, e.g. B. resinous iron oxide with a mixture of a resinous one Connection of ferrocyan lead or ferrocyanine oxide and a resinous compound of Ferrocyan Manganese Oxide.
Um besonders empfindliche Sicherheitspapiere herzustellen, wird der oben genannten Mischung noch ein Gemenge von harzsaurem Molybdänsalz oder harzsaurem Cadmiumoxyd zugesetzt, dem man harziges Schwefelzink beimischt. Das Ganze wird mit etwas Borax versetzt und mit der Papiermasse weiter verarbeitet.In order to produce particularly sensitive security papers, the mixture mentioned above is used another mixture of resinous molybdenum salt or resinous cadmium oxide added, which is mixed with resinous zinc sulphide. The whole thing is mixed with a little borax and with the paper pulp further processed.
Auf gewöhnlichem Wege würde ein Zusatz von Eisensalzen mit Ferrocyankali die Papiermasse blau färben, besonders wenn man zum Schlufs der Fabrikation die Harzseife mit Alaun zersetzt, wie es beim Leimen der Fall ist. Diese Färbung wird aber durch die Isolireigenschaften der harzigen metallischen Verbindungen verhindert. In the usual way, an addition of iron salts with ferrocyanic potassium would make the paper pulp Color blue, especially if you add the resin soap with alum at the end of the manufacturing process decomposes, as is the case with gluing. This coloring is due to the insulating properties the resinous metallic compounds prevented.
Um Schwefelzink direct auf der Faser zu fixiren, wird ein Theil der angewendeten Papiermasse mit schwefelsaurem Zink angerührt und dann ohne jeden Ueberschufs mit Harzseife und Schwefelnatrium zersetzt.In order to fix zinc sulphide directly on the fiber, part of the paper pulp used is used mixed with zinc sulphate and then decomposed without any excess with resin soap and sodium sulphide.
Alle diese harzigen Verbindungen haben den Hauptzweck, die verschiedenen metallischen Niederschläge in alkalischem Zustand auf der Faser leicht haften zu machen; ohne dies würden die nicht harzigen einzelnen Niederschläge im Lauf der Fabrikation gröfstentheils verschwinden.All of these resinous compounds have the main purpose of being the various metallic ones To make precipitates in an alkaline state easily adhere to the fiber; without this the non-resinous individual precipitates would for the most part in the course of manufacture disappear.
Die verschiedenen Salze werden in folgendem Verhältnifs bei Herstellung von 50 kg Papier verwendet: Zu den hierzu erforderlichen 150 kg Papiermasse, welche wie gewöhnlich gebleicht und gereinigt wird, bringt man während des Betriebes der Papiermaschine noch 100 bis 150 g Eisensulfat, das in etwas Wasser gelöst und mit einem kleinen Ueberschufs von Harzseife versetzt ist, ferner ein Gemenge von 600 bis 700 g Borax, 900 bis 1 000 g Ferrocyankalium in 20 1 Wasser, und so viel Kolophoniumseife, dafs sich 1 kg Harz in der genannten Seifenlösung befindet. Nach gehörigem Umrühren und Vermischen der Papiermasse mit dieser harzigen Verbindung setzt man noch eine Lösung von 400 bis 500 g Bleiacetat oder Zinnchlorür in 10 1 Wasser zu. Dann wird wieder umgerührt und nochmals folgende Mischung zugegeben: a) 10 1 Wasser, 800 bis 1 000 g Ferrocyankalium, b) ι 000 bis ι 200 g Mangansulfat oder -Chlorür.The different salts are used in the following proportions in the production of 50 kg of paper: In addition to the 150 kg of paper pulp required for this, which is bleached as usual and is cleaned, 100 to 150 g are added while the paper machine is in operation Iron sulfate, which is dissolved in a little water and with a small excess of resin soap is added, furthermore a mixture of 600 to 700 g of borax, 900 to 1,000 g of potassium ferrocyanine in 20 liters of water, and so much rosin soap that there is 1 kg of resin in the above-mentioned soap solution is located. After proper stirring and mixing of the paper pulp with this resinous one A solution of 400 to 500 g of lead acetate or tin chloride is added to the compound in 10 l of water. Then stir again and add the following mixture again: a) 10 1 water, 800 to 1,000 g of potassium ferrocyanide, b) ι 000 to ι 200 g of manganese sulfate or chlorine.
Der gebildete Niederschlag von Ferrocyanmangan wird alsdann mit einer Lösung von 60 1 Harzseife (3 kg Kolophonium enthaltend) versetzt.The precipitate formed of ferrocyanized manganese is then treated with a solution of 60 1 resin soap (containing 3 kg rosin) are added.
Wenn nun ein Molybdän- oder Cadmiumsalz gebraucht werden soll, so nimmt man im ersteren Falle etwa 400 g molybdänsaures Ammoniak, das man mit der äquivalenten Menge Bleiacetat zersetzt und der obigen Masse beimischt. If a molybdenum or cadmium salt is to be used, then one takes the in the first case about 400 g of ammonia molybdenum, which is mixed with the equivalent amount Lead acetate decomposes and mixed with the above mass.
Cadmiumsalz dagegen wird der Manganlösung beigemischt, und zwar im Verhältnifs von 400 bis 500 g.Cadmium salt, on the other hand, is added to the manganese solution, in proportion from 400 to 500 g.
In beiden Fällen wird harziges Schwefelzink, das, wie oben erklärt, auf der Faser fixirt ist, beigemengt, so dafs unter jeder sauren Reaction im Falle einer Fälschung sich ein echtes braun oder dunkel gefärbtes Molybdän- oder Cadmiumsulfid auf dem Papier bildet.In both cases, resinous zinc sulphide, which, as explained above, is fixed on the fiber, added, so that under every acidic reaction, in the case of a forgery, a real brown appears or forms dark colored molybdenum or cadmium sulfide on the paper.
Zum Schlufs zersetzt man, um das Papier fertig zu machen, die überschüssige Harzseife, die sich mit oben erwähntem Metallsalze nicht gebunden hat, mit 3 bis 4 kg Alaun. Nur wenn die Masse zu sauer reagirt, neutralisirt man mit etwa 500 g Borax oder phosphorsaurem Natron. Dieser Zusatz hat den Zweck, überschüssigen Alaun in Form eines neutralen Niederschlages zu fixiren.Finally, to finish the paper, you decompose the excess resin soap, which has not bonded with the metal salts mentioned above, with 3 to 4 kg of alum. Just if the mass reacts too acidic, it is neutralized with about 500 g of borax or phosphoric acid Baking soda. The purpose of this addition is to make excess alum in the form of a neutral To fix the precipitation.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE51248C true DE51248C (en) |
Family
ID=326033
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT51248D Expired - Lifetime DE51248C (en) | Production of white security paper |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE51248C (en) |
-
0
- DE DENDAT51248D patent/DE51248C/en not_active Expired - Lifetime
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