DE3855283D1 - Polymerisationsverfahren und Polymerisationskatalysator - Google Patents

Polymerisationsverfahren und Polymerisationskatalysator

Info

Publication number
DE3855283D1
DE3855283D1 DE3855283T DE3855283T DE3855283D1 DE 3855283 D1 DE3855283 D1 DE 3855283D1 DE 3855283 T DE3855283 T DE 3855283T DE 3855283 T DE3855283 T DE 3855283T DE 3855283 D1 DE3855283 D1 DE 3855283D1
Authority
DE
Germany
Prior art keywords
alkyl group
groups
carbon atoms
compound
polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE3855283T
Other languages
English (en)
Other versions
DE3855283T2 (de
Inventor
Mamoru Kioka
Norio Kashiwa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsui Chemicals Inc
Original Assignee
Mitsui Petrochemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP62056726A external-priority patent/JP2537506B2/ja
Priority claimed from JP62056727A external-priority patent/JP2538584B2/ja
Application filed by Mitsui Petrochemical Industries Ltd filed Critical Mitsui Petrochemical Industries Ltd
Application granted granted Critical
Publication of DE3855283D1 publication Critical patent/DE3855283D1/de
Publication of DE3855283T2 publication Critical patent/DE3855283T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/58—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with silicon, germanium, tin, lead, antimony, bismuth or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
DE3855283T 1987-03-13 1988-03-11 Polymerisationsverfahren und Polymerisationskatalysator Expired - Fee Related DE3855283T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP62056726A JP2537506B2 (ja) 1987-03-13 1987-03-13 オレフインの重合方法
JP62056727A JP2538584B2 (ja) 1987-03-13 1987-03-13 オレフインの重合方法

Publications (2)

Publication Number Publication Date
DE3855283D1 true DE3855283D1 (de) 1996-06-13
DE3855283T2 DE3855283T2 (de) 1996-10-02

Family

ID=26397711

Family Applications (2)

Application Number Title Priority Date Filing Date
DE3855283T Expired - Fee Related DE3855283T2 (de) 1987-03-13 1988-03-11 Polymerisationsverfahren und Polymerisationskatalysator
DE8888302168T Expired - Fee Related DE3871190D1 (de) 1987-03-13 1988-03-11 Polymerisationsverfahren und polymerisationskatalysator.

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE8888302168T Expired - Fee Related DE3871190D1 (de) 1987-03-13 1988-03-11 Polymerisationsverfahren und polymerisationskatalysator.

Country Status (7)

Country Link
US (1) US5028671A (de)
EP (2) EP0282341B1 (de)
KR (1) KR920001318B1 (de)
CN (2) CN1030990C (de)
AT (1) ATE137771T1 (de)
CA (1) CA1310955C (de)
DE (2) DE3855283T2 (de)

Families Citing this family (70)

* Cited by examiner, † Cited by third party
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US5247031A (en) * 1988-09-13 1993-09-21 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst component, process for production thereof, olefin polymerization catalyst, and process for polymerizing olefins
WO1990012818A1 (en) * 1989-04-24 1990-11-01 Mitsui Petrochemical Industries, Ltd. HIGHER α-OLEFIN COPOLYMER, METHOD OF PRODUCTION THEREOF, PRODUCT OF VULCANIZATION THEREOF, AND VULCANIZABLE RUBBER COMPOSITION
WO1991002758A1 (en) * 1989-08-18 1991-03-07 Tonen Corporation CATALYTIC COMPONENT FOR α-OLEFIN POLYMERIZATION
US5556820A (en) * 1989-12-28 1996-09-17 Idemitsu Petrochemical Co., Ltd. Catalyst component for olefin polymerization and process for producing polyolefins
FR2658498B1 (fr) * 1990-02-19 1992-05-15 Atochem Particules de chlorure de magnesium a structure tronc conique, composante catalytique supportee sur ces particules, polyolefines obtenues a partir de cette composante catalytique, procedes de fabrication de ces produits.
FI86548C (fi) * 1990-11-07 1992-09-10 Neste Oy Foerbaettrad stereoselektiv katalysator foer polymerisation av olefiner.
FR2669915B1 (fr) * 1990-11-29 1993-01-29 Atochem Particules de chlorure de magnesium a structure polyedre, composante catalytique supportee sur ces particules, procedes de fabrication de ces produits et des polyolefines obtenues a partir de cette composante catalytique.
FI90083C (fi) * 1990-12-20 1993-12-27 Neste Oy Foer olefinpolymerisation avsett stereospecifikt katalysatorsystem
US6291384B1 (en) 1991-11-06 2001-09-18 Mobil Oil Corporation High activity catalyst prepared with alkoxysilanes
US5470812A (en) * 1991-11-06 1995-11-28 Mobil Oil Corporation High activity polyethylene catalysts prepared with alkoxysilane reagents
US5939348A (en) * 1991-11-06 1999-08-17 Mobil Oil Corporation Catalyst for the manufacture of polythylene with a narrow molecular weight distribution
TW299335B (de) * 1992-01-24 1997-03-01 Mitsui Petroleum Chemicals Ind
CA2089970A1 (en) * 1992-03-04 1993-09-05 Edwar S. Shamshoum Catalyst formulation and polymerization processes
DE4216548A1 (de) * 1992-05-19 1993-11-25 Basf Ag Ziegler-Natta-Katalysatorsysteme mit speziellen siliciumorganischen Verbindungen
US5773537A (en) * 1992-05-19 1998-06-30 Basf Aktiengesellschaft Ziegler-natta catalyst systems containing specific organosilicon compounds
US5891817A (en) * 1992-06-08 1999-04-06 Fina Technology, Inc. Electron donors for improved olefin polymerization
DE69323000T2 (de) * 1992-06-08 1999-08-05 Fina Technology Elektrondonor zur verbesserten Olefinpolymerisation
US6410663B2 (en) * 1992-06-08 2002-06-25 Fina Technology, Inc. Electron donors in a Ziegler-Natta catalyst for the production of high melt flow copolymers
WO1994011409A1 (en) * 1992-11-06 1994-05-26 Shell Oil Company Process for polymerizing alpha-olefin
US6489411B1 (en) * 1993-06-30 2002-12-03 Fina Technology, Inc. Catalyst formulation and polymerization processes
TW354792B (en) * 1993-08-13 1999-03-21 Mitsui Petrochemical Ind Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer
WO1995014045A1 (en) * 1993-11-18 1995-05-26 Mobil Oil Corporation A catalyst composition for the copolymerization of ethylene
DE69410757T3 (de) * 1993-12-06 2008-07-24 Sumitomo Chemical Co. Ltd. Alphaolefinpolymere, Katalysator zur Alphaolefinpolymerisation und Verfahren zur Herstellung von Alphaolefinpolymeren
US5608018A (en) * 1993-12-08 1997-03-04 Sumitomo Chemical Company, Limited α-olefin polymerization catalyst system and process for producing α-olefin catalyst
US6184328B1 (en) 1994-09-07 2001-02-06 Showa Denko Kabushiki Kaisha Propylene-based polymer, method for its production, composition thereof, catalyst component for polymerization, and method for its production
EP0821012B1 (de) * 1994-05-12 1999-01-13 Showa Denko Kabushiki Kaisha Polymer auf Propylenbasis, Verfahren zu seiner Herstellung und Zusammensetzungen davon
US5916990A (en) * 1994-05-12 1999-06-29 Showa Denko K.K. Propylene-based polymer, method of its production, composition thereof, catalyst component for polymerization, and method for its production
KR0139089B1 (ko) * 1994-12-08 1998-05-01 김은영 올레핀의 중합반응용 촉매계
FR2728181B1 (fr) 1994-12-16 1997-01-31 Appryl Snc Composante catalytique pour la polymerisation des olefines, son procede de fabrication, et procede de polymerisation des olefines en presence de ladite composante catalytique
US5661095A (en) * 1995-06-06 1997-08-26 Quantum Chemical Corporation Olefin polymerization catalyst component supported on a copolymer of an olefin and an unsaturated silane
CN1098286C (zh) * 1997-04-30 2003-01-08 中国石油化工总公司 一种用于乙烯聚合或共聚合的催化剂及其制法
US6664209B1 (en) * 1998-12-25 2003-12-16 Toho Titanium Co., Ltd. Solid catalyst component for propylene polymerization and catalyst
US6358372B1 (en) 2000-07-11 2002-03-19 Union Carbide Chemicals & Plastics Technology Corporation Method of reducing formation of precipitates in solvent recovery system
US6825146B2 (en) * 2001-05-29 2004-11-30 Union Carbide Chemicals & Plastics Technology Corporation Olefin polymerization catalyst compositions and method of preparation
US20030087755A1 (en) 2001-05-29 2003-05-08 Linfeng Chen Olefin polymerization catalyst compositions and method of preparation
US7141635B2 (en) * 2002-06-14 2006-11-28 Union Carbide Chemicals And Plastics Tech Catalyst composition and polymerization process using mixtures of selectivity control agents
CA2524761A1 (en) * 2003-05-12 2005-02-10 Union Carbide Chemicals & Plastics Technology Corporation Process for control of polymer fines in a gas-phase polymerization
US7521512B2 (en) * 2003-06-24 2009-04-21 Union Carbide Chemicals & Plastics Technology Llc Catalyst composition and polymerization process using mixture of silane electron donors
KR20060128827A (ko) * 2003-08-29 2006-12-14 다우 글로벌 테크놀로지스 인크. 부분적으로 건조된 쉽게 분산가능한 올레핀 중합프로촉매의 제조 방법
CN1856513A (zh) * 2003-09-23 2006-11-01 联合碳化化学及塑料技术公司 含有混合sca的催化剂组合物和丙烯聚合法
KR20060099512A (ko) * 2003-09-23 2006-09-19 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크날러지 코포레이션 혼합된 선택성 조절제를 갖는 촉매 조성물 및 프로필렌중합 방법
US7381779B2 (en) * 2003-09-23 2008-06-03 Dow Global Technologies Inc Self limiting catalyst composition with dicarboxylic acid ester internal donor and propylene polymerization process
WO2005035596A1 (en) * 2003-09-23 2005-04-21 Dow Global Technologies Inc. Catalyst composition with monocarboxylic acid ester internal donor and propylene polymerization process
KR101114748B1 (ko) 2003-09-23 2012-03-05 다우 글로벌 테크놀로지스 엘엘씨 자가 제한 촉매 조성물 및 프로필렌 중합 방법
CN1856516B (zh) * 2003-09-23 2010-07-07 陶氏环球技术公司 用于乙烯聚合的催化剂组合物
EP1735353A1 (de) * 2004-04-07 2006-12-27 Union Carbide Chemicals & Plastics Technology Corporation Olefinpolymerisationsprokatalysator-zusammensetzungen und herstellungsverfahren dafür
US20070224641A1 (en) * 2004-06-16 2007-09-27 Campbell Richard E Apparatus and method for ziegler-natta research
CN1968972A (zh) 2004-06-16 2007-05-23 陶氏环球技术公司 确定齐格勒－纳塔助催化剂的方法
CA2574364C (en) * 2004-08-09 2012-11-27 Robert J. Jorgensen Robust spray-dried ziegler-natta procatalyst and polymerization process employing same
US20060054692A1 (en) * 2004-08-09 2006-03-16 David Dickey Wireless inventory management system and method
KR100612108B1 (ko) * 2004-10-29 2006-08-11 삼성토탈 주식회사 프로필렌 중합용 촉매 및 이를 이용한 프로필렌의 중합방법
KR100874089B1 (ko) * 2007-04-25 2008-12-16 삼성토탈 주식회사 프로필렌 중합용 촉매의 제조방법
US7981517B2 (en) * 2007-08-28 2011-07-19 Dow Global Technologies Inc. Bituminous compositions and methods of making and using same
CN102176958A (zh) * 2008-08-19 2011-09-07 陶氏环球技术有限责任公司 分级催化剂组合物、设备、和方法
MY162815A (en) * 2008-11-25 2017-07-31 W R Grace & Co -Conn Procatalyst composition multiple internal donor having silyl ester and method
US8088872B2 (en) * 2008-11-25 2012-01-03 Dow Global Technologies Llc Procatalyst composition including silyl ester internal donor and method
MX2011007153A (es) 2008-12-31 2011-09-26 Dow Global Technologies Llc Composiciones de copolimero de propileno aleatorio, articulos y procedimiento.
US8288585B2 (en) 2008-12-31 2012-10-16 Dow Global Technologies Llc Procatalyst composition with substitute 1,2-phenylene aromatic diester internal donor and method
US8247341B2 (en) * 2009-04-17 2012-08-21 Dow Global Technologies Llc Procatalyst composition with silyl glutarate and method
MX2011011188A (es) * 2009-04-23 2012-01-12 Dow Global Technologies Llc Composicion de procatalizador con adamantano y metodo.
US8633126B2 (en) * 2009-12-02 2014-01-21 Dow Global Technologies Llc Three and four atom bridged dicarbonate compounds as internal donors in catalysts for polypropylene manufacture
RU2576519C2 (ru) * 2009-12-02 2016-03-10 У.Р.Грейс Энд Ко.-Конн. Дикарбонатные соединения с двумя мостиковыми атомами как внутренние доноры в катализаторах для получения полипропилена
KR101126918B1 (ko) * 2009-12-28 2012-03-20 호남석유화학 주식회사 폴리올레핀 중합용 촉매의 제조방법, 이에 따른 촉매 및 이를 이용한 폴리올레핀의 제조방법
KR101126946B1 (ko) 2009-12-28 2012-03-20 호남석유화학 주식회사 폴리올레핀 중합용 촉매 및 이의 제조방법
KR101169861B1 (ko) 2010-05-27 2012-07-31 삼성토탈 주식회사 올레핀 중합 촉매용 구형 담체의 제조방법 및 이를 이용한 고체 촉매
JP5995869B2 (ja) 2010-12-21 2016-09-21 ダブリュー・アール・グレイス・アンド・カンパニー−コネチカット 高メルトフロープロピレンベースポリマーを製造するプロセスおよび同プロセスによる生成物
US11591458B2 (en) 2016-08-30 2023-02-28 W.R. Grace & Co.-Conn. Polyolefins with low ash content and method of making same
KR102461635B1 (ko) 2016-10-06 2022-10-31 더블유.알. 그레이스 앤드 캄파니-콘. 내부 전자 공여체의 조합물로 제조된 전구촉매 조성물
WO2020064568A1 (en) * 2018-09-28 2020-04-02 Borealis Ag Process for producing a prepolymerized solid ziegler-natta catalyst
KR20230073831A (ko) * 2021-11-19 2023-05-26 롯데케미칼 주식회사 기계적 물성 및 열적 특성이 우수한 이차전지 분리막용 폴리프로필렌 제조방법

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US3135809A (en) * 1960-07-21 1964-06-02 Southern Res Inst Isomerization process
US4295991A (en) * 1978-09-26 1981-10-20 Exxon Research & Engineering Co. Titanium trichloride catalyst component and the process for the production thereof
JPS5883006A (ja) * 1981-11-13 1983-05-18 Mitsui Petrochem Ind Ltd オレフインの重合方法
JPS59117509A (ja) * 1982-12-24 1984-07-06 Mitsui Petrochem Ind Ltd オレフインの重合方法
JPS59206418A (ja) * 1983-05-11 1984-11-22 Mitsui Petrochem Ind Ltd ４−メチル−１−ペンテン重合体の製法
JPS60115603A (ja) * 1983-11-29 1985-06-22 Toa Nenryo Kogyo Kk オレフインの重合方法
JPH0655780B2 (ja) * 1984-07-09 1994-07-27 東燃株式会社 オレフイン重合用触媒成分
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JPH0721018B2 (ja) * 1985-07-05 1995-03-08 東燃料株式会社 オレフイン重合用触媒成分の製造方法
EP0303704B1 (de) * 1987-02-17 1992-12-23 Mitsui Petrochemical Industries, Ltd. Verfahren zur polymerisierung von alpha-polyolefinen

Also Published As

Publication number Publication date
EP0455313A1 (de) 1991-11-06
CN1030990C (zh) 1996-02-14
EP0455313B1 (de) 1996-05-08
DE3855283T2 (de) 1996-10-02
US5028671A (en) 1991-07-02
EP0282341A1 (de) 1988-09-14
KR920001318B1 (ko) 1992-02-10
KR880011205A (ko) 1988-10-27
ATE137771T1 (de) 1996-05-15
DE3871190D1 (de) 1992-06-25
CN1117055A (zh) 1996-02-21
CA1310955C (en) 1992-12-01
EP0282341B1 (de) 1992-05-20
CN1036202C (zh) 1997-10-22
CN88101916A (zh) 1988-10-26

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Owner name: MITSUI CHEMICALS, INC., TOKIO/TOKYO, JP

8339 Ceased/non-payment of the annual fee