DE3779209D1 - Katalysatoren und ihr gebrauch zur entfernung von stickoxiden in abgasen. - Google Patents

Katalysatoren und ihr gebrauch zur entfernung von stickoxiden in abgasen.

Info

Publication number
DE3779209D1
DE3779209D1 DE8787110763T DE3779209T DE3779209D1 DE 3779209 D1 DE3779209 D1 DE 3779209D1 DE 8787110763 T DE8787110763 T DE 8787110763T DE 3779209 T DE3779209 T DE 3779209T DE 3779209 D1 DE3779209 D1 DE 3779209D1
Authority
DE
Germany
Prior art keywords
group
exhaust gas
angstrom
catalysts
removal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE8787110763T
Other languages
English (en)
Inventor
Makoto Imanari
Takeo Koshikawa
Akihiro Yamauchi
Masayuki Hanada
Morio Fukuda
Kiyoshi Nagano
Hiroaki Rikimaru
Tadao Nakatsuji
Toshikatsu Umaba
Kazuhiko Nagano
Kazuya Mishina
Hiromitsu Shimizu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Mitsubishi Petrochemical Co Ltd
Sakai Chemical Industry Co Ltd
Mitsubishi Petrochemicals Engineering Co Ltd
JGC Catalysts and Chemicals Ltd
Original Assignee
Catalysts and Chemicals Industries Co Ltd
Mitsubishi Heavy Industries Ltd
Mitsubishi Petrochemical Co Ltd
Sakai Chemical Industry Co Ltd
Mitsubishi Petrochemicals Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27474526&utm_source=***_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE3779209(D1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from JP61173812A external-priority patent/JPS6331540A/ja
Priority claimed from JP61251587A external-priority patent/JPS63147547A/ja
Application filed by Catalysts and Chemicals Industries Co Ltd, Mitsubishi Heavy Industries Ltd, Mitsubishi Petrochemical Co Ltd, Sakai Chemical Industry Co Ltd, Mitsubishi Petrochemicals Engineering Co Ltd filed Critical Catalysts and Chemicals Industries Co Ltd
Application granted granted Critical
Publication of DE3779209D1 publication Critical patent/DE3779209D1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8625—Nitrogen oxides
    • B01D53/8628—Processes characterised by a specific catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/20—Vanadium, niobium or tantalum
    • B01J23/22—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/653—500-1000 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
DE8787110763T 1986-07-25 1987-07-24 Katalysatoren und ihr gebrauch zur entfernung von stickoxiden in abgasen. Expired - Lifetime DE3779209D1 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP61173812A JPS6331540A (ja) 1986-07-25 1986-07-25 排ガス中の窒素酸化物をアンモニアで還元するための触媒
JP17834686 1986-07-29
JP23403186 1986-09-30
JP61251587A JPS63147547A (ja) 1986-07-29 1986-10-24 耐ヒ素毒性及び耐カルシウム性を有する脱硝触媒

Publications (1)

Publication Number Publication Date
DE3779209D1 true DE3779209D1 (de) 1992-06-25

Family

ID=27474526

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8787110763T Expired - Lifetime DE3779209D1 (de) 1986-07-25 1987-07-24 Katalysatoren und ihr gebrauch zur entfernung von stickoxiden in abgasen.

Country Status (3)

Country Link
EP (1) EP0256359B1 (de)
AT (1) ATE76325T1 (de)
DE (1) DE3779209D1 (de)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0817939B2 (ja) * 1986-11-19 1996-02-28 三菱化学株式会社 排煙脱硝触媒
DE3644461A1 (de) * 1986-12-24 1988-07-07 Basf Ag Verfahren zur entfernung von stickoxiden aus abgasen, die bei der verbrennung von kohle anfallen
JPH0729049B2 (ja) * 1987-04-30 1995-04-05 三菱重工業株式会社 燃焼排ガス中の砒素化合物除去方法
US4975256A (en) * 1988-06-09 1990-12-04 W. R. Grace & Co.-Conn. Process using catalysts for selective catalytic reduction denox technology
US5137855A (en) * 1988-06-09 1992-08-11 W. R. Grace & Co.-Conn. Catalysts for selective catalytic reduction denox technology
US4929586A (en) * 1988-06-09 1990-05-29 W. R. Grace & Co.-Conn. Catalysts for selective catalytic reduction DeNOx technology
US5395808A (en) * 1992-12-21 1995-03-07 W. R. Grace & Co.-Conn. Inorganic supports for bioremediation
JP3352494B2 (ja) * 1993-03-25 2002-12-03 三井鉱山株式会社 窒素酸化物分解触媒及びそれを用いた脱硝方法
DE4321555C1 (de) * 1993-06-29 1994-09-15 Bayer Ag Verfahren zur Herstellung von Mischoxidpulvern für Entstickungskatalysatoren
EP0850676B1 (de) * 1996-12-27 2002-03-27 Nippon Shokubai Co., Ltd. Verwendung eines Katalysator zur Entfernung von organischen Chlorverbindungen und Verfahren zur Entfernung von organischen Chlorverbindungen
JP3648125B2 (ja) * 1999-06-25 2005-05-18 株式会社日本触媒 有機ハロゲン化合物の除去用触媒および有機ハロゲン化合物の除去方法
CN110773211B (zh) * 2019-09-18 2022-09-13 上海瀚昱环保材料有限公司 高-低温脱硝催化剂及其制备方法
CN113772959B (zh) * 2021-09-14 2023-05-02 黄山市晶特美新材料有限公司 一种双玻太阳能电池组件用高反射低温结晶玻璃浆料及其制备方法
CN118236835A (zh) * 2024-05-27 2024-06-25 山西碳联环能科技有限公司 一种多功能干法脱硝方法和装置

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4085193A (en) * 1973-12-12 1978-04-18 Mitsubishi Petrochemical Co. Ltd. Catalytic process for reducing nitrogen oxides to nitrogen
US4140654A (en) * 1976-04-16 1979-02-20 Mitsui Petrochemical Industries Ltd. Catalyst composition with support comprising titanium oxide and clay mineral for vapor phase reduction of nitrogen oxides
FR2449474A1 (fr) * 1979-02-26 1980-09-19 Rhone Poulenc Ind Billes d'alumine a double porosite, leur procede de preparation et leurs applications comme supports de catalyseurs
US4520124A (en) * 1981-03-19 1985-05-28 Sakai Chemical Industry Co., Ltd. Method for producing a catalytic structure for the reduction of nitrogen oxides

Also Published As

Publication number Publication date
EP0256359A1 (de) 1988-02-24
EP0256359B1 (de) 1992-05-20
ATE76325T1 (de) 1992-06-15

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Legal Events

Date Code Title Description
8363 Opposition against the patent
8365 Fully valid after opposition proceedings