DE3586585D1 - Verfahren zur synthese eines zeolithkatalysators unter ph-kontrollierten bedingungen zur verlaengerung der lebensdauer des katalysators. - Google Patents

Verfahren zur synthese eines zeolithkatalysators unter ph-kontrollierten bedingungen zur verlaengerung der lebensdauer des katalysators.

Info

Publication number
DE3586585D1
DE3586585D1 DE8585309382T DE3586585T DE3586585D1 DE 3586585 D1 DE3586585 D1 DE 3586585D1 DE 8585309382 T DE8585309382 T DE 8585309382T DE 3586585 T DE3586585 T DE 3586585T DE 3586585 D1 DE3586585 D1 DE 3586585D1
Authority
DE
Germany
Prior art keywords
sub
catalyst
controlled conditions
synthesising
life
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE8585309382T
Other languages
English (en)
Other versions
DE3586585T2 (de
Inventor
Arie Bortinger
Robert Allen Maggio
Wim Johan Meindert Pieters
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of DE3586585D1 publication Critical patent/DE3586585D1/de
Application granted granted Critical
Publication of DE3586585T2 publication Critical patent/DE3586585T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
    • C01B33/28—Base exchange silicates, e.g. zeolites
    • C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
    • C01B33/2876—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures from a reacting mixture containing an amine or an organic cation, e.g. a quaternary onium cation-ammonium, phosphonium, stibonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/22—MFI, e.g. ZSM-5. silicalite, LZ-241

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
DE8585309382T 1984-12-21 1985-12-20 Verfahren zur synthese eines zeolithkatalysators unter ph-kontrollierten bedingungen zur verlaengerung der lebensdauer des katalysators. Expired - Fee Related DE3586585T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/685,153 US4764356A (en) 1984-12-21 1984-12-21 Process for synthesizing a zeolite catalyst on a pH controlled basis to improve catalyst life

Publications (2)

Publication Number Publication Date
DE3586585D1 true DE3586585D1 (de) 1992-10-08
DE3586585T2 DE3586585T2 (de) 1993-03-11

Family

ID=24750986

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8585309382T Expired - Fee Related DE3586585T2 (de) 1984-12-21 1985-12-20 Verfahren zur synthese eines zeolithkatalysators unter ph-kontrollierten bedingungen zur verlaengerung der lebensdauer des katalysators.

Country Status (5)

Country Link
US (2) US4764356A (de)
EP (1) EP0186480B1 (de)
JP (1) JPS61183115A (de)
AT (1) ATE80130T1 (de)
DE (1) DE3586585T2 (de)

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IL79906A (en) * 1986-09-01 1990-08-31 Yeda Res & Dev Crystalline aluminosilicate zeolite catalyst for the selective isomerization of xylene
NZ225813A (en) * 1987-09-02 1990-11-27 Mobil Oil Corp Zsm-5 in crystal form having specific dimensions, and preparation thereof
US5166111A (en) * 1989-07-07 1992-11-24 Chevron Research Company Low-aluminum boron beta zeolite
DE4009459A1 (de) * 1990-03-23 1991-09-26 Metallgesellschaft Ag Verfahren zur erzeugung von niederen olefinen
US7838708B2 (en) * 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
WO2005021468A1 (en) * 2003-07-15 2005-03-10 Grt, Inc. Hydrocarbon synthesis
US20050171393A1 (en) * 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
US7674941B2 (en) * 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US20060100469A1 (en) 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US7390358B2 (en) * 2004-05-21 2008-06-24 Intevep, S.A. Modified kaolin compositions and methods for making same
UA95943C2 (ru) * 2006-02-03 2011-09-26 ДжиАрТи, ИНК. Отделение легких газов от галогенов
EP1993979A4 (de) 2006-02-03 2011-07-06 Grt Inc Kontinuierliches verfahren zur umwandlung von erdgas in flüssige kohlenwasserstoffe
AU2008254937C1 (en) * 2007-05-14 2013-05-30 Grt, Inc. Process for converting hydrocarbon feedstocks with electrolytic recovery of halogen
EA017699B1 (ru) * 2007-05-24 2013-02-28 Грт, Инк. Зонный реактор с обратимым захватыванием и высвобождением галогеноводородов
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
SG192538A1 (en) * 2008-07-18 2013-08-30 Grt Inc Continuous process for converting natural gas to liquid hydrocarbons
WO2010124041A1 (en) * 2009-04-22 2010-10-28 Grt, Inc. Process for converting hydrocarbon feedstocks with electrolytic and photoelectrocatalytic recovery of halogens
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
WO2012141833A1 (en) 2011-04-15 2012-10-18 Exxonmobil Chemical Patents Inc. Process for producing molecular sieve materials
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems
CN109651036B (zh) * 2017-10-10 2022-03-11 中国石油化工股份有限公司 一种由合成气制备低碳烯烃的方法
CN107827691B (zh) * 2017-11-06 2020-09-01 中石化炼化工程（集团）股份有限公司 一种合成气制取低碳烯烃的方法
CN109647329A (zh) * 2019-01-29 2019-04-19 大连理工大学盘锦产业技术研究院 一种无粘结剂复合分子筛制备方法及其在油品吸附脱硫中的应用

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US3775299A (en) * 1970-04-13 1973-11-27 Mobil Oil Corp Catalytic cracking with catalyst of zeolite in weighted matrix
US3894107A (en) * 1973-08-09 1975-07-08 Mobil Oil Corp Conversion of alcohols, mercaptans, sulfides, halides and/or amines
US4139600A (en) * 1977-04-22 1979-02-13 Mobil Oil Corporation Synthesis of zeolite ZSM-5
US4296083A (en) * 1977-04-22 1981-10-20 Mobil Oil Corporation Zeolite synthesis
NZ193927A (en) * 1979-06-11 1982-09-07 Mobil Oil Corp Continuous stream method of preparing crystalline zeolite
NZ193928A (en) * 1979-06-11 1982-09-07 Mobil Oil Corp Preparation of large crystal zeolite zsm-5
NZ193929A (en) * 1979-10-09 1982-09-07 Mobil Oil Corp Preparation of large crystal zeolite zsm-5
GB2079735A (en) * 1980-07-07 1982-01-27 Chevron Res Novel zeolite designated CZH-5
GB2084552A (en) * 1980-09-26 1982-04-15 Norton Co Silica polymorph
EP0054386B1 (de) * 1980-12-17 1985-03-27 Imperial Chemical Industries Plc Zeolithe
US4323481A (en) * 1981-02-26 1982-04-06 Standard Oil Company (Indiana) Synthesis of molecular sieves using beta-diketones as organic templates
AU559968B2 (en) * 1982-04-29 1987-03-26 Mobil Oil Corp. Controlled morphology high silica zeolites
US4665268A (en) * 1982-09-30 1987-05-12 Mobil Oil Corporation Catalytic conversion of methanol to light olefins
US4665269A (en) * 1984-06-13 1987-05-12 Mobil Oil Corporation Conversion of oxygenates over novel catalyst composition
US4709114A (en) * 1985-06-27 1987-11-24 Mobil Oil Corporation Catalytic oxygenate conversion

Also Published As

Publication number Publication date
US4804800A (en) 1989-02-14
JPS61183115A (ja) 1986-08-15
EP0186480A3 (en) 1989-05-31
US4764356A (en) 1988-08-16
EP0186480A2 (de) 1986-07-02
EP0186480B1 (de) 1992-09-02
ATE80130T1 (de) 1992-09-15
DE3586585T2 (de) 1993-03-11

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee