DE22787208T1 - Verfahren und System zur Herstellung von erneuerbarem Wasserstoff mit niedriger Kohlenstoffintensität - Google Patents
Verfahren und System zur Herstellung von erneuerbarem Wasserstoff mit niedriger Kohlenstoffintensität Download PDFInfo
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- DE22787208T1 DE22787208T1 DE22787208.2T DE22787208T DE22787208T1 DE 22787208 T1 DE22787208 T1 DE 22787208T1 DE 22787208 T DE22787208 T DE 22787208T DE 22787208 T1 DE22787208 T1 DE 22787208T1
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- Prior art keywords
- biogas
- carbon dioxide
- hydrogen
- renewable
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- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract 35
- 239000001257 hydrogen Substances 0.000 title claims abstract 35
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract 31
- 238000000034 method Methods 0.000 title claims abstract 27
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract 12
- 229910052799 carbon Inorganic materials 0.000 title claims abstract 12
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract 60
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract 30
- 239000001569 carbon dioxide Substances 0.000 claims abstract 30
- 239000007789 gas Substances 0.000 claims abstract 18
- 230000015572 biosynthetic process Effects 0.000 claims abstract 16
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract 16
- 238000003786 synthesis reaction Methods 0.000 claims abstract 16
- 238000002407 reforming Methods 0.000 claims abstract 5
- 150000002431 hydrogen Chemical class 0.000 claims abstract 4
- 238000004519 manufacturing process Methods 0.000 claims 6
- 239000000446 fuel Substances 0.000 claims 5
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims 4
- 239000003546 flue gas Substances 0.000 claims 4
- 239000002028 Biomass Substances 0.000 claims 2
- 239000003575 carbonaceous material Substances 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 239000010779 crude oil Substances 0.000 claims 1
- 230000029087 digestion Effects 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 239000003921 oil Substances 0.000 claims 1
- 230000009919 sequestration Effects 0.000 claims 1
- 239000007858 starting material Substances 0.000 claims 1
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- C—CHEMISTRY; METALLURGY
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- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/08—Production of synthetic natural gas
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- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
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- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/62—Carbon oxides
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- C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
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- C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
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- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/002—Removal of contaminants
- C10K1/003—Removal of contaminants of acid contaminants, e.g. acid gas removal
- C10K1/005—Carbon dioxide
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- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
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- C10L3/104—Carbon dioxide
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- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
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- C12P5/00—Preparation of hydrocarbons or halogenated hydrocarbons
- C12P5/02—Preparation of hydrocarbons or halogenated hydrocarbons acyclic
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/16—Hydrogen
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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- B01D2257/504—Carbon dioxide
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- B01D2258/0283—Flue gases
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- B01D2258/05—Biogas
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- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
- C01B2203/0211—Processes for making hydrogen or synthesis gas containing a reforming step containing a non-catalytic reforming step
- C01B2203/0216—Processes for making hydrogen or synthesis gas containing a reforming step containing a non-catalytic reforming step containing a non-catalytic steam reforming step
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- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
- C01B2203/0288—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step containing two CO-shift steps
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- C01B2203/0811—Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
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- C01B2203/1041—Composition of the catalyst
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- Preparation Of Compounds By Using Micro-Organisms (AREA)
Abstract
Prozess zum Herstellen eines Produkts, wobei das Produkt aus erneuerbarem Wasserstoff und einem unter Verwendung des erneuerbaren Wasserstoffs hergestellten Produkt ausgewählt ist, wobei der Prozess Folgendes umfasst:Bereitstellen von Biogas, wobei das Biogas Methan und Kohlenstoffdioxid umfasst;Entfernen von mindestens 50 % des Kohlenstoffdioxids aus dem Biogas, wodurch aufbereitetes Biogas hergestellt wird;Transportieren des aufbereiteten Biogases zu einer Wasserstoffanlage;Verarbeiten des aufbereiteten Biogases in der Wasserstoffanlage zum Herstellen von Synthesegas, wobei das Verarbeiten das Bereitstellen von zumindest etwas des transportierten aufbereiteten Biogases als Ausgangsmaterial für die Methanreformierung umfasst,wobei das Synthesegas Kohlenstoffdioxid und Wasserstoff umfasst; undReinigung von zumindest einem von dem Synthesegas oder einem von dem Synthesegas stammenden Strom, um erneuerbaren Wasserstoff herzustellen, und Bereitstellen einer Menge des Erneuerbaren,wobei der Prozess ferner Folgendes umfasst:a) Abscheiden und Speichern einer ersten Menge an Kohlenstoffdioxid, wobei das Kohlenstoffdioxid in der ersten Menge aus dem Biogas entfernt wird; undb) Abscheiden und Speichern einer zweiten Menge an Kohlenstoffdioxid, wobei das Kohlenstoffdioxid in der zweiten Menge aus zumindest einem von (i') dem Synthesegas oder (ii') einem von dem Synthesegas zumindest teilweise stammenden Strom entfernt wird, und wobei die Menge an erneuerbarem Wasserstoff eine Kohlenstoffintensität von weniger als 0 gCO2-eq/MJ aufweist, undwobei die Kohlenstoffintensität von den Schritten a) und b) abhängig ist.
Claims (15)
- Prozess zum Herstellen eines Produkts, wobei das Produkt aus erneuerbarem Wasserstoff und einem unter Verwendung des erneuerbaren Wasserstoffs hergestellten Produkt ausgewählt ist, wobei der Prozess Folgendes umfasst: Bereitstellen von Biogas, wobei das Biogas Methan und Kohlenstoffdioxid umfasst; Entfernen von mindestens 50 % des Kohlenstoffdioxids aus dem Biogas, wodurch aufbereitetes Biogas hergestellt wird; Transportieren des aufbereiteten Biogases zu einer Wasserstoffanlage; Verarbeiten des aufbereiteten Biogases in der Wasserstoffanlage zum Herstellen von Synthesegas, wobei das Verarbeiten das Bereitstellen von zumindest etwas des transportierten aufbereiteten Biogases als Ausgangsmaterial für die Methanreformierung umfasst, wobei das Synthesegas Kohlenstoffdioxid und Wasserstoff umfasst; und Reinigung von zumindest einem von dem Synthesegas oder einem von dem Synthesegas stammenden Strom, um erneuerbaren Wasserstoff herzustellen, und Bereitstellen einer Menge des Erneuerbaren, wobei der Prozess ferner Folgendes umfasst: a) Abscheiden und Speichern einer ersten Menge an Kohlenstoffdioxid, wobei das Kohlenstoffdioxid in der ersten Menge aus dem Biogas entfernt wird; und b) Abscheiden und Speichern einer zweiten Menge an Kohlenstoffdioxid, wobei das Kohlenstoffdioxid in der zweiten Menge aus zumindest einem von (i') dem Synthesegas oder (ii') einem von dem Synthesegas zumindest teilweise stammenden Strom entfernt wird, und wobei die Menge an erneuerbarem Wasserstoff eine Kohlenstoffintensität von weniger als 0 gCO2-eq/MJ aufweist, und wobei die Kohlenstoffintensität von den Schritten a) und b) abhängig ist.
- Prozess nach
Anspruch 1 , wobei das Produkt den erneuerbaren Wasserstoff umfasst. - Prozess nach
Anspruch 1 , wobei das Bereitstellen der Menge des erneuerbaren Wasserstoffs das Bereitstellen des erneuerbaren Wasserstoffs zum Herstellen des Produkts umfasst. - Prozess nach
Anspruch 3 , wobei das Produkt Kraftstoff umfasst, und wobei der Prozess das Bereitstellen der Menge an erneuerbarem Wasserstoff als Ausgangsmaterial für einen Kraftstoffherstellungsprozess umfasst, der das Hydrieren von aus Rohöl stammendem flüssigem Kohlenwasserstoff mit dem erneuerbaren Wasserstoff umfasst, um den Kraftstoff herzustellen. - Prozess nach
Anspruch 3 , wobei das Produkt Kraftstoff umfasst und wobei der Prozess das Bereitstellen der Menge an erneuerbarem Wasserstoff als Ausgangsmaterial für einen Kraftstoffherstellungsprozess umfasst, der das Hydrieren eines erneuerbaren Ausgangsmaterials, ausgewählt aus erneuerbarem Öl, erneuerbarem Fett oder einer Kombination davon, umfasst. - Prozess nach einem der
Ansprüche 1 bis5 , wobei die Menge an erneuerbarem Wasserstoff eine Kohlenstoffintensität aufweist, die -20 gCO2-eq/MJ nicht überschreitet. - Prozess nach einem der
Ansprüche 1 bis6 , wobei das Speichern der ersten Menge an Kohlenstoffdioxid und das Speichern der zweiten Menge an Kohlenstoffdioxid eine geologische Sequestrierung umfasst. - Prozess nach einem der
Ansprüche 1 bis7 , wobei das Ausgangsmaterial für die Methanreformierung ferner Gas auf fossiler Basis umfasst. - Prozess nach einem der
Ansprüche 1 bis8 , wobei das Entfernen von mindestens 50 % des Kohlenstoffdioxids aus dem Biogas das Entfernen von zwischen 55 % und 90 % des Kohlenstoffdioxids aus dem Biogas umfasst. - Prozess nach einem der
Ansprüche 1 bis9 , wobei das Abscheiden und Speichern einer zweiten Menge an Kohlenstoffdioxid das Abtrennen des Kohlenstoffdioxids vom Wasserstoff im Synthesegas umfasst. - Prozess nach einem der
Ansprüche 1 bis9 , wobei beim Verarbeiten des aufbereiteten Biogases in der Wasserstoffanlage Rauchgas hergestellt wird, und wobei das Kohlenstoffdioxid aus dem Rauchgas nicht zur Kohlenstoffabscheidung und -speicherung bereitgestellt wird. - Prozess nach einem der
Ansprüche 1 bis9 , wobei beim Verarbeiten des aufbereiteten Biogases in der Wasserstoffanlage Rauchgas hergestellt wird, und wobei das Kohlenstoffdioxid in der zweiten Menge an Kohlenstoffdioxid Kohlenstoffdioxid umfasst, das aus dem Synthesegas und aus dem Rauchgas abgeschieden wurde. - Prozess nach einem der
Ansprüche 1 bis12 , wobei die zweite Menge an Kohlenstoffdioxid mindestens 50 % des Kohlenstoffs in dem transportierten aufbereiteten Biogas umfasst, das als Ausgangsmaterial für die Methanreformierung bereitgestellt wird. - Prozess nach einem der
Ansprüche 1 bis13 , wobei das Biogas Deponiegas ist. - Prozess zum Herstellen von erneuerbarem Wasserstoff mit geringer Kohlenstoffintensität, wobei der Prozess Folgendes umfasst: Herstellen von Wasserstoff aus einem Wasserstoffherstellungsprozess, wobei ein Ausgangsmaterial für den Wasserstoffherstellungsprozess aufbereitetes Biogas umfasst, wobei das aufbereitete Biogas in einem Prozess hergestellt wird, der Folgendes umfasst: (i) Unterziehen von Biomasse einer anaeroben Vergärung, wodurch Biogas und Gärrückstände hergestellt werden, wobei das Biogas Methan und Kohlenstoffdioxid umfasst, (ii) Unterziehen des Biogases einer Biogasaufbereitung, wodurch mindestens 50 % des Kohlenstoffdioxids aus dem Biogas entfernt und aufbereitetes Biogas hergestellt wird, (iii) Transportieren des aufbereiteten Biogases, und (iv) Bereitstellen von aus der Biomasse stammendem, kohlenstoffhaltigem Material zur Speicherung als Teil eines ersten Kohlenstoffabscheidungs- undspeicherungsprozesses, wobei das kohlenstoffhaltige Material Kohlenstoffdioxid aus dem Biogas umfasst, wobei der Wasserstoffherstellungsprozess Folgendes umfasst: (a) Unterziehen des Ausgangsmaterials einer Methanreformierung, um Synthesegas herzustellen, das Kohlenstoffdioxid und Wasserstoff umfasst, (b) Reinigen eines Stroms, der aus dem Synthesegas und einem aus dem Synthesegas stammenden Strom ausgewählt ist, um Wasserstoff herzustellen, der erneuerbaren Wasserstoff umfasst, und (c) Bereitstellen des bei der Wasserstoffherstellung hergestellten Kohlenstoffdioxids zur Speicherung als Teil eines zweiten Kohlenstoffabscheidungs- und - speicherungsprozesses, wobei eine Kohlenstoffintensität des erneuerbaren Wasserstoffs als ein Ergebnis der Schritte (iv) und (c) reduziert wird.
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CA3214940A1 (en) | 2022-10-20 |
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