DE162009C - - Google Patents
Info
- Publication number
- DE162009C DE162009C DENDAT162009D DE162009DA DE162009C DE 162009 C DE162009 C DE 162009C DE NDAT162009 D DENDAT162009 D DE NDAT162009D DE 162009D A DE162009D A DE 162009DA DE 162009 C DE162009 C DE 162009C
- Authority
- DE
- Germany
- Prior art keywords
- hydrogen peroxide
- chlorine
- hypochlorites
- alkalis
- diazo compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- MHAJPDPJQMAIIY-UHFFFAOYSA-N hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 8
- WQYVRQLZKVEZGA-UHFFFAOYSA-N Hypochlorite Chemical class Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 claims description 3
- 239000000460 chlorine Substances 0.000 claims description 3
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims description 2
- OUUQCZGPVNCOIJ-UHFFFAOYSA-M superoxide Chemical class [O-][O] OUUQCZGPVNCOIJ-UHFFFAOYSA-M 0.000 claims description 2
- 239000000975 dye Substances 0.000 claims 1
- 239000002253 acid Substances 0.000 description 4
- 150000008049 diazo compounds Chemical class 0.000 description 3
- GHMLBKRAJCXXBS-UHFFFAOYSA-N Resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- GWIAAIUASRVOIA-UHFFFAOYSA-N 2-aminonaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(N)=CC=C21 GWIAAIUASRVOIA-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 239000001045 blue dye Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001804 chlorine Chemical class 0.000 description 1
- VNEBWJSWMVTSHK-UHFFFAOYSA-L disodium;3-hydroxynaphthalene-2,7-disulfonate Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C=C2C=C(S([O-])(=O)=O)C(O)=CC2=C1 VNEBWJSWMVTSHK-UHFFFAOYSA-L 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B45/00—Complex metal compounds of azo dyes
- C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
- C09B45/14—Monoazo compounds
- C09B45/16—Monoazo compounds containing chromium
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
Im Patent 160536 ist gezeigt worden, daß man bei Verwendung der Diazoverbindungen von Mono- und Polysulfo- oder Chlorderivaten der i-Naphtylamin-2-sulfosäure und denjenigen der 2-Naphtylamin-1-sulfosäure einen glatten Austausch der Sulfogruppe gegen Hydroxyl bewirken kann, wenn man in der dort beschriebenen Weise bei Gegenwart von Chlor oder Hypochloriten arbeitet bezw. die aus den Diazoverbindungen mit mineralsäurebindenden Mitteln entstehenden Diazosulfonsäuren nachträglich durch Behandeln mit den genannten Mitteln in die gewünschten Diazooxyde überführt.It has been shown in patent 160536 that when using the diazo compounds of mono- and polysulfo- or chlorine derivatives of i-naphthylamine-2-sulfonic acid and that of 2-naphthylamine-1-sulfonic acid can cause a smooth exchange of the sulfo group for hydroxyl if one works in the manner described there in the presence of chlorine or hypochlorites respectively those arising from the diazo compounds with mineral acid binding agents Diazosulfonic acids subsequently by treatment with the agents mentioned in the desired diazooxides transferred.
Es hat sich nun gezeigt, daß auch eine Reihe anderer Oxydationsmittel an Stelle von Chlor oder von Hypochloriten für diesen Zweck vorzüglich geeignet sind. Insbesondere haben sich das Wasserstoffsuperoxyd sowie die Superoxyde der Alkalien und Erdalkalien, ferner die Persulfate der Alkalien und des Ammoniums u. dgl. als geeignet erwiesen.It has now been shown that a number of other oxidizing agents can be used instead of Chlorine or hypochlorites are eminently suitable for this purpose. In particular have hydrogen peroxide as well as the superoxides of alkalis and alkaline earths, furthermore, the persulfates of alkalis and ammonium, and the like, have been shown to be suitable.
Die Anwendungsweise ist ganz ähnlich derjenigen, wie sie im Hauptpatent für die dort benutzten Substanzen angegeben ist, wobei es vorteilhaft erscheint, die als Ausgangsmaterial dienenden Diazoverbindungen schon vor Behandlung mit mineralsäurebindenden Mitteln mit dem Wasserstoffsuperoxyd u. dgl. zu versetzen.The application is very similar to that as it is in the main patent for the The substances used there are indicated, although it appears advantageous to use them as the starting material Serving diazo compounds even before treatment with mineral acid binding agents with hydrogen peroxide and the like.
Wir erläutern das Verfahren durch folgendes We explain the procedure by the following
303 Teile 2-Naphtylarnin-i · 5-disulfosäure werden in der üblichen Weise diazotiert, mit einer 37,4 Teile H.20.2 enthaltenden Wasserstoffsuperoxydlösung versetzt, dann wird dem Gemisch unter Rühren allmählich Soda bis zur stark alkalischen Reaktion zugefügt. Durch Erwärmen auf 400 entsteht die gelbe Diazooxydlösung, welche dadurch charakterisiert ist, daß sie mit verdünnter R-Salzlösung nicht mehr kuppelt, dagegen mit sodaalkalischer Resorcinlösung einen rotvioletten, mit konzentrierter Betanaphtolnatriumlosung beim Erwärmen einen blauen Farbstoff liefert.303 parts of 2-Naphtylarnin-i · 5-disulfonic acid are diazotized in the usual manner, with a 37.4 parts by H. added 2 0. 2 containing hydrogen peroxide solution, then the mixture is gradually added with stirring soda to produce a strongly alkaline reaction. By heating to 40 0 yellow Diazooxydlösung, which is characterized by the fact that they no longer couple with dilute R-salt solution, red-violet, however, provides with a sodaalkalischer resorcinol with concentrated Betanaphtolnatriumlosung upon heating a blue dye.
Claims (1)
Abänderung in dem VerfahrenPatent claim:
Change in the procedure
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE162009C true DE162009C (en) |
Family
ID=427835
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT162009D Active DE162009C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE162009C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5925275A (en) * | 1993-11-30 | 1999-07-20 | Alliedsignal, Inc. | Electrically conductive composite heater and method of manufacture |
| EP0965580A1 (en) * | 1998-06-15 | 1999-12-22 | Toyo Gosei Kogyo Co., Ltd. | Method for producing 1,2-Naphthoquinone-2-diazide derivative |
-
0
- DE DENDAT162009D patent/DE162009C/de active Active
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5925275A (en) * | 1993-11-30 | 1999-07-20 | Alliedsignal, Inc. | Electrically conductive composite heater and method of manufacture |
| EP0965580A1 (en) * | 1998-06-15 | 1999-12-22 | Toyo Gosei Kogyo Co., Ltd. | Method for producing 1,2-Naphthoquinone-2-diazide derivative |
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