DE08164013T1 - Verfahren zum Herstellen von Hodge-Carbonylen und oligomerischem Lignin - Google Patents

Verfahren zum Herstellen von Hodge-Carbonylen und oligomerischem Lignin Download PDF

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Publication number
DE08164013T1
DE08164013T1 DE08164013T DE08164013T DE08164013T1 DE 08164013 T1 DE08164013 T1 DE 08164013T1 DE 08164013 T DE08164013 T DE 08164013T DE 08164013 T DE08164013 T DE 08164013T DE 08164013 T1 DE08164013 T1 DE 08164013T1
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biomass
carbonyls
stream
lignin
hodge
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Jan Waterloo Piskorz
Piotr Waterloo Majerski
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Majerski Piotr A Waterloo
Piskorz Jan K Waterloo
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Majerski Piotr A Waterloo
Piskorz Jan K Waterloo
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D9/00Other inorganic fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/30Layered or coated, e.g. dust-preventing coatings
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B51/00Destructive distillation of solid carbonaceous materials by combined direct and indirect heating
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10CWORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
    • C10C5/00Production of pyroligneous acid distillation of wood, dry distillation of organic waste
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/02Dust removal
    • C10K1/026Dust removal by centrifugal forces
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/08Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/141Feedstock
    • Y02P20/145Feedstock the feedstock being materials of biological origin
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982Particulate matter [e.g., sphere, flake, etc.]

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Pest Control & Pesticides (AREA)
  • Inorganic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)
  • Fertilizers (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

Verfahren zur Behandlung eines Biomassenstromes, umfassend:
schnelle Pyrolyse des Biomassenstromes in Gegenwart von supererhitztem Dampf einer gewählten Temperatur, um mindestens einen Produktstrom zu produzieren.

Claims (21)

  1. Verfahren zur Behandlung eines Biomassenstromes, umfassend: schnelle Pyrolyse des Biomassenstromes in Gegenwart von supererhitztem Dampf einer gewählten Temperatur, um mindestens einen Produktstrom zu produzieren.
  2. Verfahren nach Anspruch 1, wobei der Produktstrom Hodge's Carbonyle, oligomeres Lignin und Biokohlepartikel enthält.
  3. Verfahren nach Anspruch 1, wobei der erste Produktstrom eine wässrige Aufschlämmung von entstandenen Aktivkohlepartikeln und oligomerem Lignin enthält.
  4. Verfahren nach Anspruch 1, wobei die Hodge's Carbonyle wasserlöslich sind, aus Kohlehydraten hervorgebrachte Carbonyle.
  5. Verfahren nach Anspruch 1, wobei die Temperatur 400°C übersteigt.
  6. Verfahren nach Anspruch 4, wobei die Hodge's Carbonyle mindestens einen Bestandteil enthalten aus Hydroxyd-Acetataldehyden, Glyceraldehyden, Acetolen, Pyruvaldehyden, Glyoxalen, 5-Hydroxydmethylfurfuralen, Furfuralen, und Formaldehyden.
  7. Verfahren nach Anspruch 1, wobei der Biomassenstrom aus Zellulose mit geringem Ligninganteil ist.
  8. Verfahren nach Anspruch 7, wobei die Temperatur in dem Bereich von 490°C bis 590°C liegt.
  9. Verfahren nach Anspruch 7, wobei die Zellulose aus der Gruppe sind, die aus zellulosen Pulpen und Aufschlämmungen, sowie aus mikrokristallinen zellulosen Pulvern bestehen.
  10. Verfahren nach Anspruch 7, wobei der Produktstrom eine wasserlösliche Mischung aus den Hodge's Carbonylen mit Hydroxyd-Acetataldehyden, Glyoxalen, Methylglyoxalen, Formaldehyden, Acetolen, Furfuralen und 5-Hydroxydmethylfurfuralen ist.
  11. Verfahren nach Anspruch 1, wobei der Biomassenstrom Ligno-Zellulose ist.
  12. Verfahren nach Anspruch 11, wobei die Temperatur in dem Bereich von 430°C bis 550°C liegt.
  13. Verfahren nach Anspruch 11, wobei die Ligno-Zellulose gewählt sind aus Forst-Biomasse oder Landwirtschafts-Biomasse, einschließlich Abfall und Reststoffen.
  14. Verfahren nach Anspruch 11, wobei ein Produktstrom aus oligomerem Lignin produziert wird.
  15. Verfahren nach Anspruch 11, wobei der zweite Produktstrom eine lösliche Mischung aus Hodge's Carbonylen mit Hydroxyd-Acetataldehyden, Glyoxalen, Methyl-Glyoxalen, Formaldehyden, Acetolen, Furfuralen und 5-HMF ist, und Ameisensäure, Essigsäure, und wasserlösliche Phenolharze umfasst.
  16. Verfahren nach Anspruch 1, wobei das oligomere Lignin und die Biokohle physikalisch kombiniert sind.
  17. Verfahren nach Anspruch 16, wobei die Kohle einen hohen Anteil an sauerstoffangereicherten funktionalen Gruppen hat und nicht nur als Absorber dient, sondern überdies Stickstoff direkt durch eine Reaktion mit NH2-Gruppen bindet.
  18. Produkt aus der schnellen Pyrolyse des Biomassenstromes, aufweisend Aktivkohle kombiniert mit oligomerem Lignin.
  19. Produkt aus der schnellen Pyrolyse des Biomassenstromes, das zur Bildung eines Bodenbildners oligomeres Lignin und oligomeres Lignin in Kombination mit Biokohle aufweist.
  20. Produkt aus der schnellen Pyrolyse des Biomassenstromes, das ein oligomeres Lignin-Schmelzschicht N, P, K-Düngemittel aufweist, das als langsam oder steuerbares Düngemittel-Abgabemittel dient.
  21. Produkt gemäß Anspruch 20, das Biokohlenstoff enthält und durch den 4-Buchstabencode N, P, K, C beschrieben ist.
DE08164013T 2007-11-20 2008-09-10 Verfahren zum Herstellen von Hodge-Carbonylen und oligomerischem Lignin Pending DE08164013T1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/943,422 US8436120B2 (en) 2007-11-20 2007-11-20 Method of producing hodge carbonyls and oligomeric lignin
US943422 2007-11-20

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DE08164013T1 true DE08164013T1 (de) 2010-01-21

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US (1) US8436120B2 (de)
EP (1) EP2072600B1 (de)
CN (1) CN101440026B (de)
BR (1) BRPI0804974B1 (de)
CA (1) CA2639022C (de)
DE (1) DE08164013T1 (de)
DK (1) DK2072600T3 (de)
ES (1) ES2329645T3 (de)
PL (1) PL2072600T3 (de)

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BRPI0804974B1 (pt) 2017-09-12
CA2639022C (en) 2014-07-15
CN101440026A (zh) 2009-05-27
EP2072600A3 (de) 2011-03-23
US8436120B2 (en) 2013-05-07
PL2072600T3 (pl) 2019-11-29
CN101440026B (zh) 2016-08-03
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