CN214361837U - Substrate table structure for diamond growth - Google Patents

Substrate table structure for diamond growth Download PDF

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Publication number
CN214361837U
CN214361837U CN202120411661.9U CN202120411661U CN214361837U CN 214361837 U CN214361837 U CN 214361837U CN 202120411661 U CN202120411661 U CN 202120411661U CN 214361837 U CN214361837 U CN 214361837U
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molybdenum sheet
molybdenum
diamond
growth
substrate table
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余***
王连忠
王斌
卢泽
杨成武
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Walder Meixing Diamond Technology (Jiaxing) Co.,Ltd.
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Langfang Supower Diamond Technology Co ltd
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Abstract

The application relates to the technical field of single crystal diamond growth, in particular to a substrate table structure for diamond growth, which has the technical scheme that: the seed crystal growth device comprises a molybdenum sheet, wherein a plurality of movable bolts are arranged on the molybdenum sheet, extend towards the outer side of one end face of the molybdenum sheet, and divide the molybdenum sheet into a plurality of seed crystal growth areas; the movable bolt is connected with the molybdenum sheet in a sliding way; the diamond is conveniently taken down from the substrate table so as to improve the reutilization property of the substrate table and further reduce the cost of the growth of the single crystal diamond.

Description

Substrate table structure for diamond growth
Technical Field
The application relates to the technical field of single crystal diamond growth, in particular to a substrate table structure for diamond growth.
Background
Diamond has extremely excellent physical and chemical properties, and is widely concerned and applied in a plurality of fields; the chemical vapor deposition technology is one of the main technologies for preparing high-quality monocrystalline diamond films, wherein the microwave CVD method is considered to be the first method for preparing the high-quality diamond films due to the advantages of electrodeless discharge, high energy conversion efficiency, pure plasma and the like; the growth of the single crystal diamond requires a substrate stage as a growth carrier.
Referring to fig. 1, a plurality of protrusions are arranged on the upper surface of a substrate table, and are uniformly distributed on the surface of the substrate table in an array manner, so that the upper surface of the substrate table is divided into a plurality of seed crystal growth regions 3 for growing single crystal diamonds; each diamond seed may be placed in a respective seed growth region 3 prior to diamond growth.
In view of the above-described related art, since the growth of the single crystal diamond is accompanied by the generation of polycrystalline diamond, the generated polycrystalline diamond is firmly adhered to the substrate stage; the inventor finds that: in the related art, polycrystalline diamond growing on the substrate table is difficult to clean, and the substrate table may be damaged in the cleaning process, so that the substrate table cannot be reused; the substrate table is expensive, indirectly increasing the cost of diamond growth.
SUMMERY OF THE UTILITY MODEL
In order to facilitate the diamond to be taken down from the substrate table so as to improve the reusability of the substrate table and further reduce the cost of the growth of the single crystal diamond, the application provides a substrate table structure for the growth of the diamond.
The application provides a substrate platform structure for diamond growth adopts following technical scheme:
a substrate table structure for diamond growth comprises a molybdenum sheet, wherein a plurality of movable bolts are arranged on the molybdenum sheet, extend towards the outer side of one end face of the molybdenum sheet, and divide the molybdenum sheet into a plurality of seed crystal growth areas; the movable bolt is connected with the molybdenum sheet in a sliding way.
By adopting the technical scheme, the polycrystalline diamond can be generated along with the growth process of the single crystal diamond, and the lattice coefficient of the polycrystalline diamond is similar to that of molybdenum, so that the generated polycrystalline diamond can be firmly adhered to the movable plug; after the growth of the diamond is finished, the movable bolt is taken down from the molybdenum sheet, after the movable bolt is taken down, the four walls of the polycrystalline diamond film lose the force points, and the diamond automatically falls off, so that the adhesion of the diamond on the molybdenum sheet is reduced, the diamond on the molybdenum sheet is more easily taken down, and the possibility that the molybdenum sheet is scrapped due to the strong adhesion of the diamond is reduced; therefore, the diamond is conveniently taken down from the substrate table so as to improve the reutilization property of the substrate table and further reduce the growth cost of the single crystal diamond.
Preferably, a plurality of bolt mounting holes matched with the movable bolts are formed in the molybdenum sheet, and the movable bolts are perpendicular to the end face of the molybdenum sheet.
By adopting the technical scheme, when the movable bolt is required to be installed on the molybdenum sheet, the movable bolt is sequentially inserted into the bolt installation holes; when the movable bolt needs to be taken down, the movable bolt is pushed from the upper part or the lower part until the movable bolt is pushed out of the bolt mounting hole; therefore, the movable bolt is more convenient to mount and dismount.
Preferably, the upper end of the movable bolt is at least 0.2mm higher than the upper surface of the molybdenum sheet.
Through adopting above-mentioned technical scheme, make the seed crystal growth region have certain degree of depth, the diamond that produces and then can be better finds the impetus on the activity bolt, the production of diamond is more even, has reduced the diamond and has broken away from corresponding seed crystal growth region and influence the possibility of diamond quality in the growth process.
Preferably, the movable bolt is a waist-shaped block structure, the width of the narrow side of the movable bolt is greater than or equal to 2mm, the length of the long side of the movable bolt is greater than or equal to 4 mm, and the thickness of the movable bolt is greater than or equal to 3 mm.
By adopting the technical scheme, the surface area of the movable bolt is large enough, so that the movable bolt still has enough heat dissipation surface under the condition of high temperature, and the possibility that the growth and development of the diamond are influenced due to overhigh temperature of the movable bolt is reduced; on the other hand, the possibility that the movable plug is easy to discharge and cause danger or influence the growth of the diamond due to overhigh temperature and undersize is reduced.
Preferably, the device also comprises a molybdenum bracket, and one end face of the molybdenum sheet is embedded into the molybdenum bracket.
By adopting the technical scheme, as the molybdenum material has better heat dissipation performance compared with reaction gas and air, the molybdenum support improves the heat dissipation performance of the surface of the molybdenum sheet and reduces the possibility that the growth and development of diamond are influenced by overhigh temperature of the molybdenum sheet; in addition, the molybdenum support and the molybdenum sheet are installed in a split mode, when the substrate table needs to be replaced, the molybdenum sheet only needs to be replaced due to the fact that the diamond does not contact with the molybdenum support, and replacement cost of the substrate table is reduced to a certain extent.
Preferably, the molybdenum support is of a cylindrical structure, and an annular groove is coaxially formed in the surface of the molybdenum support, which is far away from the molybdenum sheet.
By adopting the technical scheme, the temperature generated by the plasma ball on the molybdenum sheet is not uniformly distributed on the molybdenum sheet, so that the growth and development of a plurality of diamonds on the same molybdenum sheet are not synchronous and the growth and development of a single diamond can be nonuniform due to overlarge temperature difference; because the heat dissipation coefficient of the reaction gas (such as hydrogen, methane and the like) in the deposition chamber is smaller than that of the molybdenum material, the heat dissipation performance of the region with lower temperature can be properly reduced, so that the temperature distribution on the molybdenum sheet is more uniform, the temperature difference of different parts on the molybdenum sheet is reduced, and the growth of the diamond is more uniform.
Preferably, the lower surface of the molybdenum support is provided with an exhaust hole which radially penetrates through the molybdenum support.
By adopting the technical scheme, the pressure difference between the bottom of the molybdenum sheet and the interior of the reaction chamber is reduced by the exhaust holes, and the possibility of vibration of the molybdenum sheet caused by the pressure difference between the upper part and the lower part of the molybdenum sheet in the air exhaust process is reduced; in addition, the air exhaust hole can completely exhaust the air accumulated at the bottom of the molybdenum sheet as much as possible, and the possibility of polluting diamond growth due to the residual air is reduced.
In summary, the present application has the following technical effects:
1. by arranging the molybdenum sheet and the movable bolt, polycrystalline diamond adhered to the molybdenum sheet is reduced, and the diamond is conveniently taken down from the substrate table to improve the reusability of the substrate table, so that the growth cost of the single crystal diamond is reduced;
2. by arranging the annular grooves, the heat dissipation performance of a region with lower temperature can be properly reduced, so that the temperature distribution on the molybdenum sheet is more uniform, the temperature difference of different parts on the molybdenum sheet is reduced, and the growth of diamond is more uniform;
3. the exhaust holes are formed, so that the possibility of vibration of the molybdenum sheet caused by the pressure difference between the upper part and the lower part of the molybdenum sheet in the air exhaust process is reduced; in addition, the air exhaust hole can completely exhaust the air accumulated at the bottom of the molybdenum sheet as much as possible, and the possibility of polluting diamond growth due to the residual air is reduced.
Drawings
FIG. 1 is an overall configuration diagram of a substrate stage in the related art;
FIG. 2 is an overall structural view of a substrate stage structure in the embodiment of the present application;
FIG. 3 is an exploded view of a substrate table structure in an embodiment of the present application;
fig. 4 is a bottom structural view of a molybdenum bracket in an embodiment of the present application.
In the figure, 1, molybdenum sheet; 2. a movable bolt; 3. a seed crystal growth area; 4. a bolt mounting hole; 5. a molybdenum bracket; 6. a molybdenum sheet mounting hole; 7. an annular groove; 8. and (4) exhausting holes.
Detailed Description
The present application is described in further detail below with reference to the attached drawings.
Referring to fig. 2, the present application provides a substrate table structure for diamond growth, comprising a molybdenum support 5 horizontally disposed on a cooling table in a deposition chamber and a molybdenum sheet 1 placed on the molybdenum support 5, wherein the upper surface of the molybdenum sheet 1 is divided into a plurality of seed crystal growth regions 3 for placing diamond seed crystals; exciting low-pressure reaction gas in the deposition chamber to form a plasma ball by an electromagnetic field, and placing the molybdenum sheet 1 right below the plasma ball; the seed crystal placed on the molybdenum sheet 1 grows and develops into single crystal diamond under a couple with proper conditions.
Referring to fig. 2 and 3, the molybdenum sheet 1 has a cylindrical structure; a plurality of movable bolts 2 are vertically arranged on the molybdenum sheet 1, the movable bolts 2 are in a kidney-shaped block structure, and the movable bolts 2 are distributed on the molybdenum sheet 1 in a grid shape, namely, four adjacent movable bolts 2 are arranged in a square shape and form a square seed crystal growth area 3 on the molybdenum sheet 1; a plurality of kidney-shaped bolt mounting holes 4 for inserting the corresponding movable bolts 2 into the molybdenum sheet 1 are formed in the molybdenum sheet 1 in a penetrating manner, and the bolt mounting holes 4 are matched with the movable bolts 2 so as to realize detachable sliding connection between the movable bolts 2 and the molybdenum sheet 1; the molybdenum support 5 is of a cylindrical structure, a molybdenum sheet mounting hole 6 for placing the molybdenum sheet 1 is formed in the upper surface of the molybdenum support 5, the diameter of the molybdenum sheet mounting hole 6 is equal to that of the molybdenum sheet 1, and the depth of the molybdenum sheet mounting hole 6 is equal to the thickness of the molybdenum sheet 1; after the growth of the diamond is finished, the molybdenum sheet 1 is taken down from the cooling table, and the movable bolt 2 is inserted into the molybdenum sheet 1 through the bolt mounting hole 4, so that the movable bolt 2 is pushed from bottom to top or from top to bottom with small force to enable the movable bolt 2 to drive the diamond to be separated from the molybdenum sheet 1; when the movable bolt 2 needs to be installed on the molybdenum sheet 1, the movable bolt 2 is sequentially inserted into the bolt installation holes 4 to form a seed crystal growth area 3; this facilitates the mounting and dismounting of the movable bolt 2.
Before diamond growth is carried out, diamond seed crystals are placed in seed crystal growth areas 3 on the molybdenum sheet 1, the molybdenum sheet 1 with the diamond seed crystals is horizontally placed on a cooling table of MPCVD, and growth and cultivation of single crystal diamond are carried out in a deposition chamber; because the molybdenum material has better heat dispersion than reaction gas and air, the molybdenum sheet 1 is installed inside the molybdenum support 5, the heat dispersion of the surface of the molybdenum sheet 1 is improved, the heat absorbed by the molybdenum sheet 1 due to the plasma balls can be quickly dissipated from the inside of the molybdenum sheet 1 through the molybdenum support 5, and the possibility that the growth and development of diamond are influenced by the molybdenum sheet 1 due to overhigh temperature is reduced.
In addition, if the molybdenum bracket 5 and the molybdenum sheet 1 are made into an integrated structure, when the molybdenum sheet 1 needs to be replaced after being used for a long time, the molybdenum bracket 5 needs to be communicated with the molybdenum sheet 1 for replacement together, so that more molybdenum materials are wasted and the cost is higher; by the molybdenum bracket 5 and the molybdenum sheet 1 which are installed separately, when the substrate table needs to be replaced, only the molybdenum sheet 1 needs to be replaced, and the replacement cost of the substrate table is reduced to a certain extent.
During the growth of the diamond, a single crystal diamond film grows on the surface of each seed crystal growth region 3, and in addition, a small amount of polycrystalline diamond is generated along with the growth of the single crystal diamond, and the lattice coefficient of the polycrystalline diamond is similar to that of molybdenum, so that the generated polycrystalline diamond can firmly adhere to the movable plug 2; after the growth of the diamond is finished, the movable bolts 2 are taken down from the molybdenum sheet 1, and the diamond grows in the seed crystal growth areas 3 between the movable bolts 2, so that after the movable bolts 2 are taken down, the four walls of the polycrystalline diamond film lose the force points, the diamond automatically falls off, the adhesion of the diamond on the molybdenum sheet 1 is reduced, and the diamond on the molybdenum sheet 1 is more easily taken down; even if the movable bolt 2 is still adhered with the diamond, the movable bolt 2 has a small volume, so the processing cost and the material cost of the movable bolt 2 are far less than those of the molybdenum sheet 1, the replacement frequency of the molybdenum sheet 1 is reduced to a certain extent by replacing the movable bolt 2, and the molybdenum sheet 1 can be repeatedly utilized; therefore, the diamond is conveniently taken down from the substrate table so as to improve the reutilization property of the substrate table and further reduce the growth cost of the single crystal diamond.
Furthermore, the upper end surface of the movable bolt 2 is at least 0.2mm higher than the upper surface of the molybdenum sheet 1, namely the depth of the seed crystal growth area 3 is at least 0.2mm, the generated diamond can find a force application point on the movable bolt 2 more easily, the generation of the diamond is more uniform, and the possibility that the diamond breaks away from the corresponding seed crystal growth area 3 to influence the quality of the diamond in the growth process is reduced; in addition, the width of the narrow side of the movable plug 2 is greater than or equal to 2mm, the length of the long side is greater than or equal to 4 mm, and the thickness is greater than or equal to 3 mm; in the process of diamond growth, electromagnetic waves excite a plasma ball above the molybdenum sheet 1, and the plasma ball can heat the molybdenum sheet 1 and the movable bolt 2 at a higher temperature; the surface area of the movable bolt 2 is large enough by making the three edges of the movable bolt 2 be above a certain size value, so that the movable bolt 2 still has enough heat dissipation surfaces under the condition of high temperature, and on one hand, the possibility that the diamond influences the growth and development due to overhigh temperature of the movable bolt 2 is reduced; on the other hand, the possibility that the movable plug 2 is easy to discharge and cause danger or influence the growth of the diamond due to overhigh temperature and undersize is reduced.
Referring to fig. 2 and 4, the lower surface of the molybdenum bracket 5 is coaxially provided with an annular groove 7; the diameter, the width and the number of the annular grooves 7 can be adjusted in the growth and experiment process of the diamond, and the aim is to ensure that the temperature of the molybdenum bracket 5 and the molybdenum sheet 1 is more uniform; it is further explained that, in the process of diamond growth, the molybdenum sheet 1 needs to be placed under the excited plasma ball, the plasma ball heats the molybdenum sheet 1, the temperature generated by the plasma ball on the molybdenum sheet 1 is not uniformly distributed on the molybdenum sheet 1, and the diamonds need to be produced on the molybdenum sheet 1 in batch, so that the excessive temperature difference can cause the growth and development of the diamonds in different seed crystal growth areas 3 on the same molybdenum sheet 1 to be asynchronous and cause the growth and development of single diamonds to be nonuniform and other adverse effects; at this time, the annular groove 7 needs to be formed at the position with lower temperature on the lower surface of the molybdenum sheet 1, and because the heat dissipation coefficient of the reaction gas in the deposition chamber, such as hydrogen or methane, is smaller than that of the molybdenum material, the heat dissipation performance of the region with lower temperature can be properly reduced, so that the temperature distribution on the molybdenum sheet 1 is more uniform, the temperature difference of different parts on the molybdenum sheet 1 is reduced, and the growth of diamond is more uniform;
adjusting the diameter of the annular groove 7, namely, arranging the annular groove 7 at the annular line with the lowest temperature of the molybdenum bracket 5, and further reducing the heat dissipation performance at the position with the lowest temperature; the number of the annular grooves 7 is adjusted, namely the number can be increased according to the actual temperature distribution condition of the molybdenum sheets 1, namely the molybdenum support 5; adjusting the width of the annular groove 7, namely making the width of the annular groove 7 and the temperature of the molybdenum bracket 5 in a negative correlation, namely, the lower the temperature, the larger the width of the annular groove 7 is, the higher the temperature is, the smaller the width of the annular groove 7 is; when the temperature is too low and the temperature difference is too large, the width of the annular groove 7 is increased, so that more gas at the bottom of the molybdenum sheet 1 replaces the molybdenum sheet 1 to dissipate heat, the temperature is increased to a certain value more quickly and more highly, the temperature difference on the surface of the molybdenum sheet 1 is reduced as much as possible, and the growth of the diamond is further more uniform.
Furthermore, the lower surface of the molybdenum support 5 is provided with a rectangular exhaust hole 8, the exhaust hole 8 is horizontal and is arranged along the radial direction of the molybdenum support 5, and the exhaust hole 8 penetrates through the circumferential surface of the molybdenum support 5 and penetrates through the annular groove 7; the depth of the exhaust hole 8 is shallow; before the diamond growth, the air in the deposition chamber needs to be pumped out and reaction gas such as hydrogen or methane is injected; in the air extraction process, the exhaust holes 8 can quickly extract the gas accumulated between the bottom surface of the molybdenum sheet 1 and the upper surface of the cooling table, so that the air extraction efficiency is improved; in addition, the exhaust holes 8 reduce the pressure difference between the bottom of the molybdenum sheet 1 and the inside of the reaction chamber, and reduce the possibility that the molybdenum sheet 1 vibrates due to the pressure difference between the upper part and the lower part of the molybdenum sheet 1 in the air exhaust process; furthermore, the vent holes 8 can completely draw out the air accumulated at the bottom of the molybdenum sheet 1 as much as possible, reducing the possibility of contamination of diamond growth due to the residual air.
The application also provides a use method of the substrate table structure, which comprises the following steps:
s1, assembling a substrate table: mounting the molybdenum sheet 1 on a molybdenum bracket 5; sequentially inserting a plurality of movable bolts 2 into corresponding bolt mounting holes 4, wherein the movable bolts 2 are arranged in a grid shape, and the surface of the molybdenum sheet 1 is divided into a plurality of seed crystal growth areas 3;
s2, sequentially placing a plurality of seed crystals in the corresponding seed crystal growth areas 3 on the molybdenum sheet 1;
s3, depositing a diamond film: placing the substrate table with the seed crystals on a cooling table in a deposition chamber at the corresponding position of the MPCVD equipment to wait for the growth of the single crystal diamond; in the process, the electromagnetic wave generated by the microwave equipment excites low-pressure reaction gas out of the plasma ball in the deposition chamber to excite the growth of the diamond;
s4, taking down the diamond: taking the substrate table out of the MPCVD equipment, and taking the molybdenum sheet 1 down from the molybdenum bracket 5; the movable bolt 2 is pushed upwards or downwards until the movable bolt 2 is taken out of the bolt mounting hole 4; the movable bolt 2 is taken down from the molybdenum sheet 1 by using small force, and the movable bolt 2 is shaken out from the inside of the bolt mounting hole 4 in a knocking or vibrating mode, so that the damage to the molybdenum sheet 1 is reduced, the service life of the molybdenum sheet 1 is prolonged, and the adverse effect of knocking and vibrating diamond on the molybdenum sheet 1 is further reduced.
S5, cleaning the molybdenum sheet 1, the molybdenum bracket 5 and the movable bolt 2 for the next use.
Application example one
The width of the narrow side of the movable plug pin 2 is 2mm, the length of the long side is 5 mm, and the thickness is 3.2 mm; the upper surface and the lower surface of the movable bolt 2 are both finish machined surfaces; the diameter of the molybdenum sheet 1 is 45 mm, the thickness of the molybdenum sheet is 3mm, and the upper surface of the molybdenum sheet 1 is a finish-machined surface, so that the fitting degree of the diamond seed crystal and the surface of the molybdenum sheet 1 can be improved; the inner diameter of the annular groove 7 is 12 mm, the groove width is 3mm, the groove depth is 2mm, and the width of the exhaust hole 8 is 1 mm.
The MPCVD in the application example adopts 2.45GHz microwave equipment.
Uniformly placing diamond seed crystals to be grown in a seed crystal growth area 3 on a molybdenum sheet 1, and then placing the molybdenum sheet 1 with the seed crystals on a cooling table together with a molybdenum support 5; when the power reaches 5KW and the air pressure in the deposition chamber reaches 170torr, stable growth is started; in the process, the distribution condition of the seed crystal temperature on the molybdenum sheet 1 is observed, and the width, the diameter and the number of the subsequent annular grooves 7 are adjusted according to the experimental result.
Application example two
The width of the narrow side of the movable plug pin 2 is 3mm, the length of the long side is 7 mm, the thickness is 3.2 mm, and the upper surface and the lower surface of the movable plug pin 2 are finish-machined surfaces; the diameter of the molybdenum sheet 1 is 150 mm, and the thickness of the molybdenum sheet is 3 mm; the upper surface of the molybdenum sheet 1 is a finish machining surface; the annular grooves 7 are provided with a plurality of diameters of 5 mm, 20 mm, 35 mm and 60 mm on the lower surface of the molybdenum support 5; the groove depth of the annular groove 7 is 2mm, and the width of the exhaust hole 8 is 3 mm.
The MPCVD in the application example adopts 915MHz microwave equipment.
Uniformly placing diamond seed crystals to be grown in a seed crystal growth area 3 on a molybdenum sheet 1, and then placing the molybdenum sheet 1 with the seed crystals on a cooling table together with a molybdenum support 5; stable growth was started when the power reached 40KW and the gas pressure in the deposition chamber reached 100 torr.
The present embodiment is only for explaining the present application, and it is not limited to the present application, and those skilled in the art can make modifications of the present embodiment without inventive contribution as needed after reading the present specification, but all of them are protected by patent law within the scope of the claims of the present application.

Claims (7)

1. A substrate table structure for diamond growth is characterized in that: the seed crystal growth device comprises a molybdenum sheet (1), wherein a plurality of movable bolts (2) are arranged on the molybdenum sheet (1), the movable bolts (2) extend towards the outer side of one end face of the molybdenum sheet (1), and the molybdenum sheet (1) is divided into a plurality of seed crystal growth areas (3) by the movable bolts (2); the movable bolt (2) is connected with the molybdenum sheet (1) in a sliding way.
2. A diamond grown substrate table structure according to claim 1, wherein: a plurality of bolt mounting holes (4) matched with the movable bolts (2) are formed in the molybdenum sheet (1), and the movable bolts (2) are perpendicular to the end face of the molybdenum sheet (1).
3. A diamond grown substrate table structure according to claim 1, wherein: the upper end of the movable bolt (2) is higher than the upper surface of the molybdenum sheet (1) by at least 0.2 mm.
4. A diamond grown substrate table structure according to claim 1, wherein: the movable plug pin (2) is of a waist-shaped block structure, the width of the narrow side of the movable plug pin (2) is greater than or equal to 2mm, the length of the long side of the movable plug pin is greater than or equal to 4 mm, and the thickness of the movable plug pin is greater than or equal to 3 mm.
5. A diamond grown substrate table structure according to claim 1, wherein: the molybdenum sheet is characterized by further comprising a molybdenum support (5), and one end face of the molybdenum sheet (1) is embedded into the molybdenum support (5).
6. A diamond grown substrate table structure according to claim 5, wherein: the molybdenum support (5) is of a cylindrical structure, and an annular groove (7) is coaxially formed in the surface, deviating from the molybdenum sheet (1), of the molybdenum support (5).
7. A diamond grown substrate table structure according to claim 5, wherein: the lower surface of the molybdenum support (5) is provided with an exhaust hole (8), and the exhaust hole (8) radially penetrates through the molybdenum support (5).
CN202120411661.9U 2021-02-25 2021-02-25 Substrate table structure for diamond growth Active CN214361837U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112831835A (en) * 2021-02-25 2021-05-25 廊坊西波尔钻石技术有限公司 Substrate table structure for diamond growth and use method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112831835A (en) * 2021-02-25 2021-05-25 廊坊西波尔钻石技术有限公司 Substrate table structure for diamond growth and use method thereof
CN112831835B (en) * 2021-02-25 2023-09-05 廊坊西波尔钻石技术有限公司 Substrate table structure for diamond growth and use method thereof

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Effective date of registration: 20220601

Address after: 314000 1st floor, No. 1 plant, 1136 Bazi Road, Gaozhao street, Xiuzhou District, Jiaxing City, Zhejiang Province

Patentee after: Walder Meixing Diamond Technology (Jiaxing) Co.,Ltd.

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Patentee before: LANGFANG SUPOWER DIAMOND TECHNOLOGY Co.,Ltd.