CN213480731U - Liquid air energy storage and ammonia synthesis integrated device - Google Patents

Liquid air energy storage and ammonia synthesis integrated device Download PDF

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CN213480731U
CN213480731U CN202022266823.2U CN202022266823U CN213480731U CN 213480731 U CN213480731 U CN 213480731U CN 202022266823 U CN202022266823 U CN 202022266823U CN 213480731 U CN213480731 U CN 213480731U
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air
temperature
way valve
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丁玉龙
折晓会
张童童
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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0012—Primary atmospheric gases, e.g. air
    • F25J1/0015—Nitrogen
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    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
    • F25J1/0035—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work
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    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04521—Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
    • F25J3/04612—Heat exchange integration with process streams, e.g. from the air gas consuming unit
    • F25J3/04618—Heat exchange integration with process streams, e.g. from the air gas consuming unit for cooling an air stream fed to the air fractionation unit
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/72—Refluxing the column with at least a part of the totally condensed overhead gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00—Processes or apparatus using other separation and/or other processing means
    • F25J2205/02—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum
    • F25J2205/04—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum in the feed line, i.e. upstream of the fractionation step
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00—Processes or apparatus using other separation and/or other processing means
    • F25J2205/24—Processes or apparatus using other separation and/or other processing means using regenerators, cold accumulators or reversible heat exchangers
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
    • F25J2230/04—Compressor cooling arrangement, e.g. inter- or after-stage cooling or condensate removal
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2230/00—Processes or apparatus involving steps for increasing the pressure of gaseous process streams
    • F25J2230/30—Compression of the feed stream
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2240/00—Processes or apparatus involving steps for expanding of process streams
    • F25J2240/90—Hot gas waste turbine of an indirect heated gas for power generation

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Separation By Low-Temperature Treatments (AREA)

Abstract

The utility model discloses a liquid air energy storage and ammonia synthesis integrated device, including liquid air energy storage circulating system and the synthetic circulation system of ammonia, liquid air energy storage circulating system comprises air separation liquefaction unit and air power generation unit. In the electricity consumption valley period, redundant electric power drives the air separation liquefaction unit to obtain liquid nitrogen and store the liquid nitrogen in the liquid air storage tank; the source of nitrogen in the ammonia synthesis circulation system can utilize liquid nitrogen in a liquid air storage tank on one hand, and can also utilize gaseous nitrogen separated from an air separation plant on the other hand. During the electricity consumption peak period, after liquid nitrogen in the liquid air storage tank is pressurized and preheated, the liquid nitrogen can be used as a raw material to be directly supplied to an ammonia synthesis circulating system on one hand, and on the other hand, the liquid nitrogen can be heated and then enters an air turbine unit to be expanded and generated, and then the heated liquid nitrogen is pressurized and supplied to the ammonia synthesis circulating system.

Description

Liquid air energy storage and ammonia synthesis integrated device
Technical Field
The utility model relates to a novel liquid air energy storage and ammonia synthesis integrated device belongs to liquid air energy storage, ammonia synthesis and air separation's technical field.
Background
The liquid air energy storage technology is a cryogenic energy storage technology which utilizes liquid air or nitrogen as an energy storage medium. In the electricity consumption valley period, liquid air or nitrogen is produced by utilizing electric energy, and meanwhile, compression heat generated in the air or nitrogen compression process is stored; during the peak period of electricity utilization, liquid air or nitrogen is pressurized by a pressurizing pump, low-temperature cold energy is recovered and further preheated, and then the liquid air or nitrogen drives an air turbine to do work and generate electricity. Liquid air energy storage is used as a new large-scale energy storage technology, has the characteristics of high energy storage density, short response time, no geographic condition limit, no environmental pollution and the like, and is widely concerned.
Ammonia gas is the most potential long-term hydrogen storage medium as a carrier of hydrogen gas. In addition, ammonia can be used for manufacturing ammonia water, compound fertilizer, nitric acid, soda ash and the like, and is widely applied to the fields of chemical industry, light industry, pharmacy, synthetic fiber and the like. Liquid ammonia can also be used as a green refrigerant and applied to the field of refrigeration and air conditioning. Ammonia is commercially produced by the haber process by direct combination of nitrogen and hydrogen at elevated temperature and pressure in the presence of a catalyst. Nitrogen is one of the important raw materials in ammonia synthesis, and is generally obtained by air separation device preparation. The air separation unit needs to be operated all day long to provide the high-purity nitrogen needed for ammonia synthesis, which is one of the reasons for high energy consumption and high cost in the ammonia synthesis process.
In conclusion, nitrogen is a working medium which is commonly required by liquid air energy storage and ammonia synthesis, so that the nitrogen has a good combination point. The liquid nitrogen can be stored in the liquid air in the electricity consumption valley period (with low electricity price), and the liquid nitrogen can be released by the liquid air in the electricity consumption peak period (with high electricity price) to supply ammonia for synthesis, so that the consumption of high-price electricity to produce nitrogen and supply ammonia for synthesis is avoided. Therefore, how to efficiently integrate the liquid air energy storage with the ammonia synthesis has important significance for reducing the operation and investment cost of the ammonia synthesis and improving the power generation efficiency of the liquid air energy storage.
SUMMERY OF THE UTILITY MODEL
Utility model purpose: the utility model aims to solve the technical problem that it is not enough to prior art, a synthetic integrated device of liquid air energy storage and ammonia is provided, the device utilizes liquid air energy storage nitrogen gas at power consumption trough time section, it is synthetic to supply with ammonia at power consumption peak time section release nitrogen gas, avoid consuming peak power production nitrogen gas, can realize utilizing peak valley price of electricity to reduce synthetic operation and the investment cost of ammonia, improve liquid air energy storage efficiency, purposes such as liquid air energy storage and the synthetic independent operation of ammonia, a high-efficient reasonable liquid air energy storage and the synthetic integrated mode of ammonia.
In order to realize the purpose of the utility model, the utility model adopts the following technical scheme:
an integrated device for liquid air energy storage and ammonia synthesis, comprising: a liquid air energy storage circulating system and an ammonia synthesis circulating system;
the liquid air energy storage circulation system comprises: an air separation liquefaction unit and an air power generation unit; wherein the air separation liquefaction unit comprises: an air compressor unit having a right side input, a left side output, a lower input, and a lower output; the left output end of the first air three-way valve is connected with the right input end of the air compressor unit; the right side input end of the first air three-way valve is connected with the purified ambient air; the right side input end of the low-temperature cooler is connected with the left side output end of the air compressor unit; the input end of the low-temperature turbo expander is connected with the left output end of the low-temperature cooler; the upper input end of the liquid air separator is connected with the output end of the low-temperature turbo-expander; the upper input end of the second air three-way valve is connected with the lower output end of the liquid air separator; the upper input end of the third air three-way valve is connected with the lower output end of the second air three-way valve; the input end of the liquid air storage tank is connected with the right output end of the third air three-way valve; the right input end of the fourth air three-way valve is connected with the left output end of the liquid air separator; a lower input end of the fifth air three-way valve is connected with an upper output end of the fourth air three-way valve; the right output end of the fifth air three-way valve is connected with the left upper input end of the cryocooler; the lower input end of the sixth air three-way valve is connected with the right upper side output end of the cryocooler; the right side input end of the sixth air three-way valve is connected with the right side input end of the air compressor unit; the left output end of the sixth air three-way valve is connected with the environment; a cold storage unit having a right port and a left port; a first low-temperature three-way valve, a right port of which is connected with a left port of the cold storage unit; the input end of the first low-temperature circulating pump is connected with the upper output end of the first low-temperature three-way valve; the output end of the first low-temperature circulating pump is connected with the input end of the lower left side of the cryocooler; the upper input end of the second low-temperature three-way valve is connected with the right lower side output end of the cryocooler; the left port of the second low-temperature three-way valve is connected with the right port of the cold storage unit; the medium-temperature heat storage unit is provided with a right side port and a left side port; the right port of the first medium-temperature three-way valve is connected with the left port of the medium-temperature heat storage unit; the input end of the first medium-temperature circulating pump is connected with the upper output end of the first medium-temperature three-way valve; the output end of the first medium-temperature circulating pump is connected with the lower input end of the air compressor unit; the upper input end of the second medium-temperature three-way valve is connected with the lower output end of the air compressor unit; the left port of the second medium-temperature three-way valve is connected with the right port of the medium-temperature heat storage unit; the right upper side output end of the rectifying tower is connected with the left side input end of the fifth air three-way valve; the right upper side input end of the rectifying tower is connected with the left side output end of the second air three-way valve; the right lower side input end of the rectifying tower is connected with the lower output end of the fourth air three-way valve; the right lower side output end of the rectifying tower is connected with the left side input end of the third air three-way valve; the air power generation unit with air separation liquefaction unit sharing liquid air storage tank, cold storage unit, first low temperature three-way valve, second low temperature three-way valve, medium temperature heat-retaining unit, first medium temperature three-way valve and the medium temperature three-way valve of second still include: the input end of the low-temperature pressure pump is connected with the output end of the liquid air storage tank; the left input end of the evaporator is connected with the output end of the low-temperature pressure pump; the left output end of the evaporator is connected with the lower input end of the first low-temperature three-way valve; the left input end of the first nitrogen three-way valve is connected with the right output end of the evaporator; the upper input end of the third low-temperature three-way valve is connected with the lower output end of the second low-temperature three-way valve; the left output end of the third low-temperature three-way valve is connected with the right input end of the evaporator; the input end of the second low-temperature circulating pump is connected with the lower output end of the third low-temperature three-way valve; the output end of the second low-temperature circulating pump is connected with the right input end of the evaporator; the input end of the second medium-temperature circulating pump is connected with the lower output end of the second medium-temperature three-way valve; the upper input end of the third medium-temperature three-way valve is connected with the output end of the second medium-temperature circulating pump; the left input end of the third medium-temperature three-way valve is connected with the right port of the medium-temperature heat storage unit; the left input end of the air turbine unit is connected with the right output end of the first nitrogen three-way valve; the upper output end of the air turbine unit is connected with the lower input end of the first medium-temperature three-way valve; the upper input end of the air turbine unit is connected with the lower output end of the third medium-temperature three-way valve;
the ammonia synthesis circulation system comprises: an air separation plant having a nitrogen output and an oxygen output; the lower input end of the second nitrogen three-way valve is connected with the nitrogen output end of the air separation plant; the upper output end of the second air three-way valve is connected with the lower input end of the first air three-way valve; the right side input end of the first mixing chamber is connected with the left side output end of the second nitrogen three-way valve; the upper input end of the first mixing chamber is connected with the right output end of the air turbine set; the hydrogen output end of the hydrogen generator is connected with the lower input end of the first mixing chamber; the upper input end of the second mixing chamber is connected with the lower output end of the first nitrogen three-way valve; the right side input end of the preheater is connected with the left side output end of the second mixing chamber; the input end of the normal temperature cooler is connected with the right output end of the preheater; the upper input end of the liquid ammonia separator is connected with the output end of the normal temperature cooler; the input end of the liquid ammonia throttle valve is connected with the lower output end of the liquid ammonia separator; the input end of the liquid ammonia storage tank is connected with the output end of the liquid ammonia throttling valve; the left input end of the scavenging unit is connected with the right output end of the liquid ammonia separator; the upper output end of the scavenging unit is connected with the lower input end of the second mixing chamber; the left input end of the hydrogen separation unit is connected with the right output end of the scavenging unit; the lower output end of the hydrogen separation unit is connected with an external waste gas treatment unit, and the waste gas is discharged into the atmospheric environment after being qualified; the input end of the third medium-temperature circulating pump is connected with the lower left output end of the air turbine unit; a high temperature heat storage unit having an upper port and a lower port; the upper port of the first high-temperature three-way valve is connected with the lower port of the high-temperature heat storage unit; the input end of the first high-temperature circulating pump is connected with the right output end of the first high-temperature three-way valve; the lower port of the second high-temperature three-way valve is connected with the upper port of the high-temperature heat storage unit; the upper output end of the second high-temperature three-way valve is connected with the lower right input end of the air turbine unit; the output end of the second high-temperature circulating pump is connected with the left input end of the first high-temperature three-way valve; the input end of the second high-temperature circulating pump is connected with the output end of the lower middle part of the air turbine unit; the right input end of the mixed gas compressor unit is connected with the left output end of the first mixing chamber; the upper output end of the mixed gas compressor unit is connected with the lower middle input end of the air turbine unit; the upper input end of the mixed gas compressor unit is connected with the output end of the third medium-temperature circulating pump; the left output end of the mixed gas compressor unit is connected with the right input end of the second mixing chamber; the lower input end of the mixed gas compressor unit is connected with the upper output end of the hydrogen separation unit; the upper input end of the ammonia synthesis unit is connected with the left output end of the preheater; the lower output end of the ammonia synthesis unit is connected with the left input end of the preheater; the left input end of the ammonia synthesis unit is connected with the output end of the first high-temperature circulating pump; and the left output end of the ammonia synthesis unit is connected with the right input end of the second high-temperature three-way valve.
Further, the air compressor set comprises one or more stages of air compressors and air coolers; the air turbine set comprises a first-stage or multi-stage medium-temperature heater, a high-temperature heater, a turbine and a medium-temperature three-way valve; the mixed gas compressor unit comprises one-stage or multi-stage mixed gas compressors and a mixed gas cooler; the ammonia synthesis unit comprises a one-stage or multi-stage ammonia reactor and an ammonia cooler.
Further, the rectifying column includes: a high pressure chamber having an upper input, an upper output, a lower output, an upper right input and a lower right input; the right upper side input end of the high-pressure chamber is connected with the right upper side input end of the rectifying tower; the right lower side input end of the high-pressure chamber is connected with the right lower side input end of the rectifying tower; a packing located inside the high pressure chamber; the input end of the liquid oxygen throttle valve is connected with the lower output end of the high-pressure chamber; a low pressure chamber located at a top of the high pressure chamber; the left side input end of the low-pressure chamber is connected with the output end of the liquid oxygen throttle valve; the upper output end of the low-pressure chamber is connected with the upper right output end of the rectifying tower; an evaporative condenser located inside the low pressure chamber; the input end of the evaporative condenser is connected with the upper output end of the high-pressure chamber; the output end of the evaporative condenser is divided into two paths: one path is connected with the upper input end of the high-pressure chamber, and the other path is connected with the right lower side output end of the rectifying tower.
Further, the cold storage unit, the medium-temperature heat storage unit and the high-temperature heat storage unit respectively adopt latent heat, sensible heat or thermochemical energy storage materials with working temperature ranges of at least-195-20 ℃ (such as sensible heat cold storage materials of basalt, Naro VLT and the like, phase change cold storage materials of sodium salt aqueous solution, ethylene glycol aqueous solution and the like, thermochemical cold storage materials of silica gel, fluorite and the like), 20-300 ℃ (such as sensible heat storage materials of Naro T55, T66 and the like, phase change materials of high-density polyethylene, sugar alcohols, nitrate and the like) and 20-500 ℃ (such as sensible heat storage materials of cast iron, cobblestone, molten salt and the like, latent heat, sensible heat or thermochemical energy storage materials of chlorate, carbonate and the like), can be operated in series.
Preferably, the air separation liquefaction unit can adopt air or nitrogen as a working medium; the heat transfer fluid of the cold storage unit can be methanol, propane or air and the like; the heat transfer fluid of the medium-temperature heat storage unit can be heat transfer oil or silicone oil and the like; the heat transfer fluid of the high-temperature heat storage unit can be molten salt and the like; the hydrogen generator can be an electrolytic water tank or a hydrogen preparation device for producing hydrogen by using mineral fuel and the like.
Compared with the prior art, the beneficial effects of the utility model are as follows:
1) the utility model discloses the device utilizes the nitrogen gas of the production of liquid air energy storage air separation factory at power consumption trough time section, and liquid air energy storage release nitrogen gas supplies with the ammonia synthesis in power consumption peak time section, avoids the air separation factory to move in power consumption peak time section to reduce the running cost of ammonia synthesis circulation system.
2) The utility model discloses the device combines the rectifying column to improve the air liquefaction flow of liquid air energy storage, realizes with nitrogen gas from air direct separation and liquefaction, does not need extra investment construction air separation plant to reduce the investment cost of ammonia synthesis circulation system.
3) The utility model discloses the device is through the synthetic reaction heat of the medium temperature gas compression heat of reasonable recovery and high temperature ammonia, heats the nitrogen gas two-stage before expanding to high temperature in the air turbine unit, can show and increase liquid air energy storage generated energy, improves the whole efficiency of system.
4) The utility model discloses liquid air energy storage and ammonia synthesis can the independent operation in the device, and the two does not influence each other, provides a feasible effective scheme for realizing that liquid air energy storage and ammonia synthesis are high-efficient integrated.
Drawings
These and/or other advantages of the present invention will become more apparent from the following detailed description of the present invention when taken in conjunction with the accompanying drawings and the following detailed description.
Fig. 1 is a schematic view of the overall structure of the liquid air energy storage and ammonia synthesis integrated device of the present invention.
Fig. 2 is a schematic diagram of a first embodiment of the integrated liquid air energy storage and ammonia synthesis apparatus shown in fig. 1.
Fig. 2-1 is a schematic diagram of the operation of the first embodiment of the integrated device for liquid air energy storage and ammonia synthesis shown in fig. 2 during the electricity consumption valley period.
Fig. 2-2 is a schematic diagram of the operation of the integrated liquid air energy storage and ammonia synthesis apparatus shown in fig. 2 during peak periods of electricity consumption.
Fig. 3 is a schematic diagram of a second embodiment of the integrated liquid air energy storage and ammonia synthesis apparatus shown in fig. 1.
Fig. 3-1 is a schematic diagram of the operation of the liquid air energy storage and ammonia synthesis integrated device shown in fig. 3 in the power consumption valley period according to the second embodiment.
Fig. 3-2 is a schematic diagram of the second embodiment of the integrated liquid air energy storage and ammonia synthesis apparatus shown in fig. 3 during peak hours of electricity consumption.
Wherein, the air compressor set 100, the nth stage air compressor 101, the nth stage air cooler 102, the first air three-way valve 201, the cryocooler 202, the low temperature turboexpander 203, the liquid air separator 204, the second air three-way valve 205, the third air three-way valve 206, the liquid air storage tank 207, the fourth air three-way valve 208, the fifth air three-way valve 209, the sixth air three-way valve 210, the cold storage unit 211, the first low temperature three-way valve 212, the first low temperature circulating pump 213, the second low temperature three-way valve 214, the medium temperature heat storage unit 215, the first medium temperature three-way valve 216, the first medium temperature circulating pump 217, the second medium temperature three-way valve 218, the rectifying tower 300, the high pressure chamber 301, the filler 302, the liquid oxygen throttle valve 303, the low pressure chamber 304, the evaporative condenser 305, the low temperature pressurizing pump 401, the evaporator 402, the first nitrogen 403, the third low temperature three-way valve 404, the second low temperature circulating, a third medium temperature three-way valve 407, an air turbine unit 500, an nth stage medium temperature heater 501, an nth stage high temperature heater 502, an nth stage turbine 503, a fourth medium temperature three-way valve 504, a fifth medium temperature three-way valve 505, an air separation plant 601, a second nitrogen three-way valve 602, a first mixing chamber 603, a hydrogen generator 604, a second mixing chamber 605, a preheater 606, a normal temperature cooler 607, a liquid ammonia separator 608, a liquid ammonia throttle valve 609, a liquid ammonia storage tank 610, a scavenging unit 611, a hydrogen separation unit 612, a third medium temperature circulating pump 613, a high temperature heat storage unit 614, a first high temperature three-way valve 615, a first high temperature circulating pump 616, a second high temperature three-way valve 617, a second high temperature circulating pump 618, a mixed gas compressor unit 700, an nth stage mixed gas compressor 701, an nth stage mixed gas cooler 702, an ammonia synthesis unit 800, an nth stage ammonia reactor 801 and an nth stage ammonia cooler 802.
Detailed Description
The invention will be better understood from the following examples.
The drawings in the specification show the structure, ratio, size, etc. only for the purpose of matching with the content disclosed in the specification, so as to be known and read by those skilled in the art, and not for the purpose of limiting the present invention, so the present invention does not have the essential meaning in the art, and any structure modification, ratio relationship change or size adjustment should still fall within the scope covered by the technical content disclosed in the present invention without affecting the function and achievable purpose of the present invention. Meanwhile, the terms "upper", "lower", "front", "rear", "middle", and the like used in the present specification are for the sake of clarity only, and are not intended to limit the scope of the present invention, and changes or adjustments of the relative relationship thereof are also considered to be the scope of the present invention without substantial changes in the technical content.
As shown in fig. 1, the utility model discloses a liquid air energy storage and ammonia synthesis integrated device, including liquid air energy storage circulating system and ammonia synthesis circulating system:
the liquid air energy storage circulation system comprises: air separation liquefaction unit and air power generation unit:
wherein the air separation liquefaction unit includes: the system comprises an air compressor set 100, an nth-stage air compressor 101, an nth-stage air cooler 102, a first air three-way valve 201, a low-temperature cooler 202, a low-temperature turbo expander 203, a liquid air separator 204, a second air three-way valve 205, a third air three-way valve 206, a liquid air storage tank 207, a fourth air three-way valve 208, a fifth air three-way valve 209, a sixth air three-way valve 210, a cold storage unit 211, a first low-temperature three-way valve 212, a first low-temperature circulating pump 213, a second low-temperature three-way valve 214, a medium-temperature heat storage unit 215, a first medium-temperature three-way valve 216, a first medium-temperature circulating pump 217, a second medium-temperature three-way valve 218, a rectifying tower 300, a high-pressure chamber 301, a filler 302;
specifically, the air compressor package 100 has a right input, a left output, a lower input, and a lower output; the left output end of the first air three-way valve 201 is connected with the right input end of the air compressor unit 100, and the right input end of the first air three-way valve 201 is connected with the purified ambient air; the right input end of the cryocooler 202 is connected with the left output end of the air compressor unit 100; the input end of the low-temperature turboexpander 203 is connected with the left output end of the cryocooler 202; the upper input end of the liquid air separator 204 is connected with the output end of the low-temperature turbo-expander 203; the upper input end of the second air three-way valve 205 is connected with the lower output end of the liquid air separator 204; the upper input end of the third air three-way valve 206 is connected with the lower output end of the second air three-way valve 205; the input end of the liquid air storage tank 207 is connected with the right output end of the third air three-way valve 206; the right input end of the fourth air three-way valve 208 is connected with the left output end of the liquid air separator 204; the lower input end of the fifth air three-way valve 209 is connected with the upper output end of the fourth air three-way valve 208, and the right output end of the fifth air three-way valve 209 is connected with the left upper input end of the cryocooler 202; the lower input end of the sixth air three-way valve 210 is connected with the upper right output end of the cryocooler 202, the right input end of the sixth air three-way valve 210 is connected with the right input end of the air compressor set 100, and the left output end of the sixth air three-way valve 210 is connected with the environment; the cold storage unit 211 has a right port and a left port; a right port of the first low temperature three-way valve 212 is connected with a left port of the cold storage unit 211; the input end of the first low-temperature circulating pump 213 is connected with the upper output end of the first low-temperature three-way valve 212, and the output end of the first low-temperature circulating pump 213 is connected with the left lower input end of the cryocooler 202; the upper input end of the second low-temperature three-way valve 214 is connected with the right lower output end of the cryocooler 202, and the left port of the second low-temperature three-way valve 214 is connected with the right port of the cold storage unit 211; the medium-temperature heat storage unit 215 has a right port and a left port; the right port of the first medium-temperature three-way valve 216 is connected with the left port of the medium-temperature heat storage unit 215; the input end of the first medium-temperature circulating pump 217 is connected with the upper output end of the first medium-temperature three-way valve 216, and the output end of the first medium-temperature circulating pump 217 is connected with the lower input end of the air compressor unit 100; the upper input end of the second medium-temperature three-way valve 218 is connected with the lower output end of the air compressor unit 100, and the left port of the second medium-temperature three-way valve 218 is connected with the right port of the medium-temperature heat storage unit 215; the right upper side output end of the rectifying tower 300 is connected with the left side input end of the fifth air three-way valve 209, the right upper side input end of the rectifying tower 300 is connected with the left side output end of the second air three-way valve 205, the right lower side input end of the rectifying tower 300 is connected with the lower output end of the fourth air three-way valve 208, and the right lower side output end of the rectifying tower 300 is connected with the left side input end of the third air three-way valve 206;
the air power generation unit and the air separation liquefaction unit share the liquid air storage tank 207, the cold storage unit 211, the first low-temperature three-way valve 212, the second low-temperature three-way valve 214, the medium-temperature heat storage unit 215, the first medium-temperature three-way valve 216, and the second medium-temperature three-way valve 218, and further include: a low-temperature pressure pump 401, an evaporator 402, a first nitrogen three-way valve 403, a third low-temperature three-way valve 404, a second low-temperature circulating pump 405, a second medium-temperature circulating pump 406, a third medium-temperature three-way valve 407, an air turbine unit 500, an nth-stage medium-temperature heater 501, an nth-stage high-temperature heater 502, an nth-stage turbine 503, a fourth medium-temperature three-way valve 504, and a fifth medium-temperature three-way valve 505;
specifically, the input end of the cryogenic booster pump 401 is connected with the output end of the liquid air storage tank 207; the left input end of the evaporator 402 is connected with the output end of the low-temperature booster pump 401, and the left output end of the evaporator 402 is connected with the lower input end of the first low-temperature three-way valve 212; the left input end of the first nitrogen three-way valve 403 is connected with the right output end of the evaporator 402; the upper input end of the third low-temperature three-way valve 404 is connected with the lower output end of the second low-temperature three-way valve 214, and the left output end of the third low-temperature three-way valve 404 is connected with the right input end of the evaporator 402; the input end of the second low-temperature circulating pump 405 is connected with the lower output end of the third low-temperature three-way valve 404, and the output end of the second low-temperature circulating pump 405 is connected with the right input end of the evaporator 402; the input end of the second medium-temperature circulating pump 406 is connected with the lower output end of the second medium-temperature three-way valve 218; the upper input end of the third medium-temperature three-way valve 407 is connected with the output end of the second medium-temperature circulating pump 406, and the left input end of the third medium-temperature three-way valve 407 is connected with the right port of the medium-temperature heat storage unit 215; the left input end of the air turbine set 500 is connected to the right output end of the first nitrogen three-way valve 403, the upper output end of the air turbine set 500 is connected to the lower input end of the first medium temperature three-way valve 216, and the upper input end of the air turbine set 500 is connected to the lower output end of the third medium temperature three-way valve 407;
the ammonia synthesis circulation system comprises: an air separation plant 601, a second nitrogen three-way valve 602, a first mixing chamber 603, a hydrogen generator 604, a second mixing chamber 605, a preheater 606, a normal-temperature cooler 607, a liquid ammonia separator 608, a liquid ammonia throttle valve 609, a liquid ammonia storage tank 610, a scavenging unit 611, a hydrogen separation unit 612, a third medium-temperature circulating pump 613, a high-temperature heat storage unit 614, a first high-temperature three-way valve 615, a first high-temperature circulating pump 616, a second high-temperature three-way valve 617, a second high-temperature circulating pump 618, a mixed gas compressor unit 700, an nth-stage mixed gas compressor 701, an nth-stage mixed gas cooler 702, an ammonia synthesis unit 800, an nth-stage ammonia reactor 801 and an nth-stage ammonia cooler 802;
specifically, the air separation plant 601 has a nitrogen output and an oxygen output; the lower input end of the second nitrogen three-way valve 602 is connected with the nitrogen output end of the air separation plant 601, and the upper output end of the second nitrogen three-way valve 602 is connected with the lower input end of the first air three-way valve 201; the right input end of the first mixing chamber 603 is connected to the left output end of the second nitrogen three-way valve 602, and the upper input end of the first mixing chamber 603 is connected to the right output end of the air turbine unit 500; the hydrogen output end of the hydrogen generator 604 is connected with the lower input end of the first mixing chamber 603; the upper input end of the second mixing chamber 605 is connected with the lower output end of the first nitrogen three-way valve 403; the right input end of the preheater 606 is connected with the left output end of the second mixing chamber 605; the input end of the normal temperature cooler 607 is connected with the right output end of the preheater 606; the upper input end of the liquid ammonia separator 608 is connected with the output end of the normal temperature cooler 607; the input end of the liquid ammonia throttling valve 609 is connected with the lower output end of the liquid ammonia separator 608; the input end of the liquid ammonia storage tank 610 is connected with the output end of the liquid ammonia throttling valve 609; the left input end of the scavenging unit 611 is connected with the right output end of the liquid ammonia separator 608, and the upper output end of the scavenging unit 611 is connected with the lower input end of the second mixing chamber 605; the left input end of the hydrogen separation unit 612 is connected with the right output end of the scavenging unit 611, and the lower output end of the hydrogen separation unit 612 is connected with the external environment; the input end of the third medium temperature circulating pump 613 is connected to the lower left output end of the air turbine group 500; the high temperature heat storage unit 614 has an upper port and a lower port; an upper port of the first high-temperature three-way valve 615 is connected with a lower port of the high-temperature heat storage unit 614; the input end of the first high-temperature circulating pump 616 is connected with the right output end of the first high-temperature three-way valve 615; the lower port of the second high-temperature three-way valve 617 is connected to the upper port of the high-temperature heat storage unit 614, and the upper output end of the second high-temperature three-way valve 617 is connected to the lower right input end of the air turbine unit 500; the output end of the second high temperature circulation pump 618 is connected with the left side input end of the first high temperature three-way valve 615, and the input end of the second high temperature circulation pump 618 is connected with the lower middle output end of the air turbine unit 500; the right input end of the mixed gas compressor unit 700 is connected to the left output end of the first mixing chamber 603, the upper output end of the mixed gas compressor unit 700 is connected to the lower middle input end of the air turbine unit 500, the upper input end of the mixed gas compressor unit 700 is connected to the output end of the third medium temperature circulating pump 613, the left output end of the mixed gas compressor unit 700 is connected to the right input end of the second mixing chamber 605, and the lower input end of the mixed gas compressor unit 700 is connected to the upper output end of the hydrogen separation unit 612; the upper input end of the ammonia synthesis unit 800 is connected with the left output end of the preheater 606, the lower output end of the ammonia synthesis unit 800 is connected with the left input end of the preheater 606, the left input end of the ammonia synthesis unit 800 is connected with the output end of the first high-temperature circulating pump 616, and the left output end of the ammonia synthesis unit 800 is connected with the right input end of the second high-temperature three-way valve 617.
The method for performing liquid air energy storage and ammonia synthesis by adopting the device comprises the following steps:
during the electricity consumption trough period, the air separation liquefaction unit and the ammonia synthesis circulation system work, and the device operation divides two kinds of modes:
in the first mode, a part of gaseous nitrogen produced by the air separation plant 601 is supplied to the air separation liquefaction unit to acquire and store liquid nitrogen, and the other part is supplied to the ammonia synthesis circulation system, and the method specifically comprises the following steps: the air separation liquefaction unit works: a part of gaseous nitrogen produced by the air separation plant 601 enters the air compressor unit 100 through the second nitrogen three-way valve 602 and the first air three-way valve 201, the gaseous nitrogen is compressed to a high pressure, and meanwhile, compression heat generated in the compression process is recovered and stored in the medium-temperature heat storage unit 215; the high-pressure gaseous nitrogen at the outlet of the air compressor unit 100 enters the low-temperature cooler 202, is cooled to low temperature by the low-temperature cold energy stored in the cold storage unit 211 and the returned gaseous nitrogen, then enters the low-temperature turboexpander 203 to be expanded and decompressed, wherein a part of the gaseous nitrogen is liquefied, and the gaseous nitrogen and the liquid nitrogen are separated by the liquid air separator 204: the liquid nitrogen enters the liquid air storage tank 207 through the second air three-way valve 205 and the third air three-way valve 206, and the gaseous nitrogen enters the air compressor set 100 through the fourth air three-way valve 208, the fifth air three-way valve 209, the cryocooler 202 and the sixth air three-way valve 210; the ammonia synthesis circulating system works: another part of gaseous nitrogen produced by the air separation plant 601 enters the first mixing chamber 603 through the second nitrogen three-way valve 602, is fully mixed with hydrogen produced by the hydrogen generator 604, enters the mixed gas compressor unit 700 to be pressurized to the medium pressure, is mixed with unreacted hydrogen recycled by the hydrogen separation unit 612 and is further pressurized to the high pressure, and simultaneously recovers compression heat generated in the compression process and stores the compression heat in the medium-temperature heat storage unit 215; high-pressure gas at the outlet of the mixed gas compressor unit 700 enters the second mixing chamber 605, is fully mixed with unreacted gas recovered from the scavenging unit 611, enters the ammonia gas synthesis unit 800 to synthesize ammonia gas after being preheated by the preheater 606, and stores reaction heat generated in the ammonia gas synthesis reaction process in the high-temperature heat storage unit 614; the mixed gas after the reaction is cooled to normal temperature sequentially through a preheater 606 and a normal temperature cooler 607, ammonia gas in the mixed gas is condensed, and then the mixed gas enters a liquid ammonia separator 608 to separate liquid ammonia and unreacted gas: liquid ammonia enters a liquid ammonia storage tank 610 after throttling and pressure reduction through a liquid ammonia throttle valve 609, and unreacted gas is discharged finally after completing scavenging and hydrogen recovery through a scavenging unit 611 and a hydrogen separation unit 612 in sequence;
in the second mode, the air separation liquefaction unit separates and liquefies nitrogen from air, one part of liquid nitrogen is stored in the liquid air storage tank 207, and the other part of liquid nitrogen is pressurized and preheated and then is supplied to the ammonia synthesis circulation system, and the method specifically comprises the following steps: the air separation liquefaction unit works: after being purified, the ambient air enters the air compressor unit 100 through the first air three-way valve 201 to be pressurized to a high pressure, and meanwhile, the compression heat generated in the air compression process is recovered and stored in the medium-temperature heat storage unit 215; the high-pressure air at the outlet of the air compressor unit 100 passes through the low-temperature cooler 202, is cooled to low temperature by the low-temperature cold energy stored in the cold storage unit 211 and the returned oxygen-enriched air, enters the low-temperature turboexpander 203 for expansion and pressure reduction, wherein a part of air is liquefied, and then enters the liquid air separator 204 for separating gas air and liquid air: liquid air enters the high-pressure chamber 301 of the rectifying tower 300 through the second air three-way valve 205 and is sprayed from top to bottom, and gaseous air enters the high-pressure chamber 301 of the rectifying tower 300 through the fourth air three-way valve 208 and is blown from bottom to top; the gaseous air and the liquid air complete heat and mass exchange in the filler 302, the high-purity gaseous nitrogen is gathered at the top of the high-pressure chamber 301, and the oxygen-enriched liquid air is gathered at the bottom of the high-pressure chamber 301; the oxygen-enriched liquid air at the bottom of the high-pressure chamber 301 is cooled and depressurized through the liquid oxygen throttle valve 303, enters the low-pressure chamber 304 to release cold energy to become gaseous oxygen-enriched air, and is discharged into the environment through the fifth air three-way valve 209, the cryocooler 202 and the sixth air three-way valve 210; the high-purity gaseous nitrogen at the top of the high-pressure chamber 301 enters an evaporative condenser 305 of the low-pressure chamber 304, the oxygen-enriched liquid air after throttling and pressure reduction is condensed into liquid nitrogen, one part of the liquid nitrogen flows back to the high-pressure chamber 301 for spraying, and the other part of the liquid nitrogen enters the liquid air storage tank 207 through a third air three-way valve 206; one part of liquid nitrogen in the liquid air storage tank 207 is stored, the other part of the liquid nitrogen is pressurized by a low-temperature pressurizing pump 401 and then enters an evaporator 402 for preheating, and meanwhile, released cold energy is stored in a cold storage unit 211; the normal-temperature high-pressure gaseous nitrogen at the outlet of the evaporator 402 is supplied to the ammonia synthesis circulation system through a first nitrogen three-way valve 403; the ammonia synthesis circulating system works: hydrogen produced by the hydrogen generator 604 enters the mixed gas compressor unit 700 through the first mixing chamber 603, is primarily compressed to medium pressure, is mixed with unreacted hydrogen recovered from the hydrogen separation unit 612, is further compressed to high pressure, and simultaneously recovers compression heat generated in the hydrogen compression process and stores the compression heat in the medium-temperature heat storage unit 215; the high-pressure hydrogen at the outlet of the mixed gas compressor unit 700 enters the second mixing chamber 605, is fully mixed with the high-pressure nitrogen supplied by the liquid air storage tank 207 and the unreacted gas recovered by the scavenging unit 611, is preheated by the preheater 606, enters the ammonia synthesis unit 800 to complete the ammonia synthesis reaction, and recovers the reaction heat and stores the reaction heat in the high-temperature heat storage unit 614; the fully reacted mixed gas is cooled to normal temperature through a preheater 606 and a normal temperature cooler 607 in sequence, ammonia gas in the mixed gas is condensed, and then the mixed gas enters a liquid ammonia separator 608 to separate liquid ammonia and unreacted gas: liquid ammonia enters the liquid ammonia storage tank 610 after throttling and pressure reduction through the liquid ammonia throttling valve 609, and unreacted gas is discharged finally after completing scavenging and hydrogen recovery through the scavenging unit 611 and the hydrogen separation unit 612 in sequence.
During the peak period of electricity utilization, the air power generation unit and the ammonia synthesis circulating system work, and the method specifically comprises the following steps:
the air power generation unit works: liquid nitrogen stored in the liquid air storage tank 207 is pressurized to high pressure by a low-temperature pressurizing pump 401, then enters an evaporator 402 for preheating, is evaporated and vaporized into gaseous nitrogen, and simultaneously stores cold energy released by evaporation of the liquid nitrogen in a cold storage unit 211; the normal-temperature high-pressure gaseous nitrogen at the outlet of the evaporator 402 is divided into two paths by a first nitrogen three-way valve 403: one part of the mixed gas enters a second mixing chamber 605 to be supplied to the ammonia synthesis circulation system, the other part of the mixed gas enters an air turbine unit 500 to be subjected to two-stage preheating and then expansion power generation, and then the mixed gas enters a first mixing chamber 603 to be supplied to the ammonia synthesis circulation system; the ammonia synthesis circulating system works: hydrogen produced by the hydrogen generator 604 enters the first mixing chamber 603, is fully mixed with nitrogen at the outlet of the air turbine unit 500, then enters the mixed gas compressor unit 700 for preliminary compression to medium pressure, is further compressed to high pressure after being mixed with unreacted hydrogen recycled by the hydrogen separation unit 612, and simultaneously, the compression heat generated in the compression process is recycled for preliminary preheating of nitrogen in the air turbine unit 500; the high-pressure gas at the outlet of the mixed gas compressor unit 700 enters the second mixing chamber 605, is fully mixed with a part of nitrogen shunted at the outlet of the evaporator 402 and unreacted gas recovered from the scavenging unit 611, enters the ammonia synthesis unit 800 to synthesize ammonia after being preheated by the preheater 606, and simultaneously recovers reaction heat generated in the ammonia synthesis reaction process for further preheating the nitrogen in the air turbine unit 500; the mixed gas after the reaction is cooled to normal temperature sequentially through a preheater 606 and a normal temperature cooler 607, ammonia gas in the mixed gas is condensed, and then the mixed gas enters a liquid ammonia separator 608 to separate liquid ammonia and unreacted gas: liquid ammonia enters the liquid ammonia storage tank 610 after throttling and pressure reduction through the liquid ammonia throttling valve 609, and unreacted gas is discharged finally after completing scavenging and hydrogen recovery through the scavenging unit 611 and the hydrogen separation unit 612 in sequence.
During the electricity consumption peak period, the air turbine set 500 preheats the nitrogen to the intermediate temperature primarily by using the compression heat stored in the intermediate-temperature heat storage unit 215 and the compression heat generated in real time by the mixed gas compressor set 700, and then preheats the nitrogen to the high temperature further by using the reaction heat stored in the high-temperature heat storage unit 614 and the reaction heat generated in real time by the ammonia synthesis unit 800, so that the power generation amount and the efficiency of the liquid air energy storage circulation system are improved; when the demand for heat for the air turbine unit 500 is reduced, the excess compression heat generated in real time by the mixed gas compressor unit 700 may be stored in the medium-temperature heat storage unit 215, and the excess reaction heat generated in real time by the ammonia gas synthesizing unit 800 may be stored in the high-temperature heat storage unit 614.
Fig. 2 is a first embodiment of the integrated liquid air energy storage and ammonia synthesis apparatus shown in fig. 1. The embodiment is suitable for the situation that the air separation plant 601 is already built, the liquid air energy storage circulation system only provides the liquefaction function (does not have the rectifying tower 300), and the operation cost of the ammonia synthesis circulation system can be reduced; the ammonia synthesis circulation system supplies nitrogen through the air separation plant 601 during the electricity consumption valley period and supplies nitrogen through the liquid air energy storage circulation system during the electricity consumption peak period.
Specifically, the liquid air energy storage circulation system includes: an air separation liquefaction unit and an air power generation unit. The air separation liquefaction unit comprises: the system comprises an air compressor set 100, an nth-stage air compressor 101, an nth-stage air cooler 102, a first air three-way valve 201, a low-temperature cooler 202, a low-temperature turbo expander 203, a liquid air separator 204, a second air three-way valve 205, a third air three-way valve 206, a liquid air storage tank 207, a fourth air three-way valve 208, a fifth air three-way valve 209, a sixth air three-way valve 210, a cold storage unit 211, a first low-temperature three-way valve 212, a first low-temperature circulating pump 213, a second low-temperature three-way valve 214, a medium-temperature heat storage unit 215, a first medium-temperature three-way valve 216, a first medium-temperature circulating pump 217 and a; the air power generation unit and the air separation liquefaction unit share the liquid air storage tank 207, the cold storage unit 211, the first low-temperature three-way valve 212, the second low-temperature three-way valve 214, the medium-temperature heat storage unit 215, the first medium-temperature three-way valve 216, and the second medium-temperature three-way valve 218, and further include: a low-temperature pressure pump 401, an evaporator 402, a first nitrogen three-way valve 403, a third low-temperature three-way valve 404, a second low-temperature circulating pump 405, a second medium-temperature circulating pump 406, a third medium-temperature three-way valve 407, an air turbine unit 500, an nth-stage medium-temperature heater 501, an nth-stage high-temperature heater 502, an nth-stage turbine 503, a fourth medium-temperature three-way valve 504, and a fifth medium-temperature three-way valve 505; the ammonia synthesis circulation system comprises: an air separation plant 601, a second nitrogen three-way valve 602, a first mixing chamber 603, a hydrogen generator 604, a second mixing chamber 605, a preheater 606, a normal-temperature cooler 607, a liquid ammonia separator 608, a liquid ammonia throttle valve 609, a liquid ammonia storage tank 610, a scavenging unit 611, a hydrogen separation unit 612, a third medium-temperature circulating pump 613, a high-temperature heat storage unit 614, a first high-temperature three-way valve 615, a first high-temperature circulating pump 616, a second high-temperature three-way valve 617, a second high-temperature circulating pump 618, a mixed gas compressor unit 700, an nth-stage mixed gas compressor 701, an nth-stage mixed gas cooler 702, an ammonia synthesis unit 800, an nth-stage ammonia reactor 801 and an nth-stage ammonia cooler 802;
during the electricity consumption valley period, the air separation liquefaction unit and the ammonia synthesis circulation system work, as shown in figure 2-1:
one part of the gaseous nitrogen produced by the air separation plant 601 is supplied to the air separation liquefaction unit to obtain and store liquid nitrogen, and the other part of the gaseous nitrogen is supplied to the ammonia synthesis circulation system, and the method specifically comprises the following steps: the air separation liquefaction unit works: a part of gaseous nitrogen produced by the air separation plant 601 enters the air compressor unit 100 through the second nitrogen three-way valve 602 and the first air three-way valve 201, the gaseous nitrogen is compressed to a high pressure (about 120 bar), and meanwhile, compression heat (about 220 ℃) generated in the compression process is recovered and stored in the medium-temperature heat storage unit 215; the high-pressure gaseous nitrogen at the outlet of the air compressor unit 100 enters the low-temperature cooler 202, is cooled to low temperature by the low-temperature cold energy stored in the cold storage unit 211 and the returned gaseous nitrogen, and then enters the low-temperature turbo expander 203 to be expanded and decompressed (1bar), wherein a part of the gaseous nitrogen is liquefied, and the gaseous nitrogen and the liquid nitrogen are separated by the liquid air separator 204: the liquid nitrogen enters the liquid air storage tank 207 through the second air three-way valve 205 and the third air three-way valve 206, and the gaseous nitrogen enters the air compressor set 100 through the fourth air three-way valve 208, the fifth air three-way valve 209, the cryocooler 202 and the sixth air three-way valve 210; the ammonia synthesis circulating system works: the other part of gaseous nitrogen produced by the air plant 601 enters the first mixing chamber 603 through the second nitrogen three-way valve 602, is fully mixed with the hydrogen produced by the hydrogen generator 604, enters the mixed gas compressor unit 700 to be pressurized to the middle pressure (about 28 bar), is then mixed with the unreacted hydrogen recovered by the hydrogen separation unit 612 and is further pressurized to the high pressure (about 150 bar), and simultaneously recovers the compression heat (about 230 ℃) generated in the compression process and stores the compression heat in the medium-temperature heat storage unit 215; high-pressure gas at the outlet of the mixed gas compressor unit 700 enters the second mixing chamber 605, is fully mixed with unreacted gas recovered from the scavenging unit 611, enters the ammonia gas synthesis unit 800 to synthesize ammonia gas after being preheated by the preheater 606, and simultaneously stores reaction heat (about 500 ℃) generated in the ammonia gas synthesis reaction process in the high-temperature heat storage unit 614; the mixed gas after the reaction is cooled to normal temperature sequentially through a preheater 606 and a normal temperature cooler 607, ammonia gas in the mixed gas is condensed, and then the mixed gas enters a liquid ammonia separator 608 to separate liquid ammonia and unreacted gas: liquid ammonia enters a liquid ammonia storage tank 610 after throttling and pressure reduction through a liquid ammonia throttle valve 609, and unreacted gas is discharged finally after completing scavenging and hydrogen recovery through a scavenging unit 611 and a hydrogen separation unit 612 in sequence;
during the peak period of electricity utilization, the air power generation unit and the ammonia synthesis circulation system work, as shown in the figure 2-2:
the air power generation unit works: liquid nitrogen stored in the liquid air storage tank 207 is pressurized to a high pressure (about 150 bar) by a low-temperature pressurizing pump 401, then enters an evaporator 402 for preheating, is evaporated and vaporized into gaseous nitrogen, and simultaneously stores cold energy released by evaporation of the liquid nitrogen in a cold storage unit 211; the normal-temperature high-pressure gaseous nitrogen at the outlet of the evaporator 402 is divided into two paths by a first nitrogen three-way valve 403: one part of the mixed gas enters a second mixing chamber 605 to be supplied to the ammonia synthesis circulation system, the other part of the mixed gas enters an air turbine unit 500 to be subjected to two-stage preheating and then expansion power generation, and then the mixed gas enters a first mixing chamber 603 to be supplied to the ammonia synthesis circulation system; the ammonia synthesis circulating system works: hydrogen produced by the hydrogen generator 604 enters the first mixing chamber 603, is fully mixed with nitrogen at the outlet of the air turbine unit 500, then enters the mixed gas compressor unit 700 to be preliminarily compressed to a medium pressure (about 28 bar), is further compressed to a high pressure (about 150 bar) after being mixed with unreacted hydrogen recycled by the hydrogen separation unit 612, and simultaneously recovers compression heat (about 230 ℃) generated in the compression process for preliminarily preheating the nitrogen in the air turbine unit 500; the high-pressure gas at the outlet of the mixed gas compressor unit 700 enters the second mixing chamber 605, is fully mixed with a part of nitrogen shunted at the outlet of the evaporator 402 and unreacted gas recovered from the scavenging unit 611, enters the ammonia synthesis unit 800 to synthesize ammonia after being preheated by the preheater 606, and simultaneously recovers reaction heat (about 500 ℃) generated in the ammonia synthesis reaction process for further preheating the nitrogen in the air turbine unit 500; the mixed gas after the reaction is cooled to normal temperature sequentially through a preheater 606 and a normal temperature cooler 607, ammonia gas in the mixed gas is condensed, and then the mixed gas enters a liquid ammonia separator 608 to separate liquid ammonia and unreacted gas: liquid ammonia enters the liquid ammonia storage tank 610 after throttling and pressure reduction through the liquid ammonia throttling valve 609, and unreacted gas is discharged finally after completing scavenging and hydrogen recovery through the scavenging unit 611 and the hydrogen separation unit 612 in sequence.
To further illustrate the operational performance of the first embodiment (fig. 2), thermodynamic and economic analyses were performed on the entire system. According to the electricity price for saving labor in Jiangsu (as shown in Table 1, wherein the flat period and the low valley period are electricity consumption low valley periods), the power generation efficiency of the liquid air energy storage circulation system is improved by about 30% (absolute value), and as shown in Table 2, the corresponding ammonia synthesis circulation system can save the operation cost by about 100 yuan per ton of ammonia produced in the electricity consumption peak period.
TABLE 1 Utility price of electricity for Jiangsu province
Figure BDA0002721671050000151
Table 2 performance of the liquid air energy storage cycle system in the first embodiment
Figure BDA0002721671050000161
Fig. 3 is a second embodiment of the integrated liquid air energy storage and ammonia synthesis apparatus shown in fig. 1. The embodiment is suitable for the condition that the air separation plant 601 is not built (or not available), and the liquid air energy storage circulation system is combined with the rectifying tower 300 to realize the air separation and liquefaction functions, so that the operation and investment cost of the ammonia synthesis circulation system can be reduced; the ammonia synthesis circulation system supplies nitrogen and stores liquid nitrogen through liquid air energy storage circulation system at the electricity consumption valley time period, and supplies ammonia synthesis circulation system through the liquid nitrogen that liquid air energy storage circulation system stored at the electricity consumption peak time period, and the concrete operation steps are as follows:
during the electricity consumption valley period, the air separation liquefaction unit and the ammonia synthesis circulation system work, as shown in figure 3-1:
the air separation liquefaction unit works: after being purified, the ambient air enters the air compressor unit 100 through the first air three-way valve 201 to be pressurized to a high pressure, and meanwhile, the compression heat generated in the air compression process is recovered and stored in the medium-temperature heat storage unit 215; the high-pressure air at the outlet of the air compressor unit 100 passes through the low-temperature cooler 202, is cooled to low temperature by the low-temperature cold energy stored in the cold storage unit 211 and the returned oxygen-enriched air, enters the low-temperature turboexpander 203 for expansion and pressure reduction, wherein a part of air is liquefied, and then enters the liquid air separator 204 for separating gas air and liquid air: liquid air enters the high-pressure chamber 301 of the rectifying tower 300 through the second air three-way valve 205 and is sprayed from top to bottom, and gaseous air enters the high-pressure chamber 301 of the rectifying tower 300 through the fourth air three-way valve 208 and is blown from bottom to top; the gaseous air and the liquid air complete heat and mass exchange in the filler 302, the high-purity gaseous nitrogen is gathered at the top of the high-pressure chamber 301, and the oxygen-enriched liquid air is gathered at the bottom of the high-pressure chamber 301; the oxygen-enriched liquid air at the bottom of the high-pressure chamber 301 is cooled and depressurized through the liquid oxygen throttle valve 303, enters the low-pressure chamber 304 to release cold energy to become gaseous oxygen-enriched air, and is discharged into the environment through the fifth air three-way valve 209, the cryocooler 202 and the sixth air three-way valve 210; the high-purity gaseous nitrogen at the top of the high-pressure chamber 301 enters an evaporative condenser 305 of the low-pressure chamber 304, the oxygen-enriched liquid air after throttling and pressure reduction is condensed into liquid nitrogen, one part of the liquid nitrogen flows back to the high-pressure chamber 301 for spraying, and the other part of the liquid nitrogen enters the liquid air storage tank 207 through a third air three-way valve 206; one part of liquid nitrogen in the liquid air storage tank 207 is stored, the other part of the liquid nitrogen is pressurized by a low-temperature pressurizing pump 401 and then enters an evaporator 402 for preheating, and meanwhile, released cold energy is stored in a cold storage unit 211; the normal-temperature high-pressure gaseous nitrogen at the outlet of the evaporator 402 is supplied to the ammonia synthesis circulation system through a first nitrogen three-way valve 403; the ammonia synthesis circulating system works: hydrogen produced by the hydrogen generator 604 enters the mixed gas compressor unit 700 through the first mixing chamber 603, is primarily compressed to medium pressure, is mixed with unreacted hydrogen recovered from the hydrogen separation unit 612, is further compressed to high pressure, and simultaneously recovers compression heat generated in the hydrogen compression process and stores the compression heat in the medium-temperature heat storage unit 215; the high-pressure hydrogen at the outlet of the mixed gas compressor unit 700 enters the second mixing chamber 605, is fully mixed with the high-pressure nitrogen supplied by the liquid air storage tank 207 and the unreacted gas recovered by the scavenging unit 611, is preheated by the preheater 606, enters the ammonia synthesis unit 800 to complete the ammonia synthesis reaction, and recovers the reaction heat and stores the reaction heat in the high-temperature heat storage unit 614; the fully reacted mixed gas is cooled to normal temperature through a preheater 606 and a normal temperature cooler 607 in sequence, ammonia gas in the mixed gas is condensed, and then the mixed gas enters a liquid ammonia separator 608 to separate liquid ammonia and unreacted gas: liquid ammonia enters the liquid ammonia storage tank 610 after throttling and pressure reduction through the liquid ammonia throttling valve 609, and unreacted gas is discharged finally after completing scavenging and hydrogen recovery through the scavenging unit 611 and the hydrogen separation unit 612 in sequence.
During peak electricity consumption, the air power generation unit and the ammonia synthesis circulation system are operated as shown in fig. 3-2, and the specific steps are the same as those of the first embodiment (fig. 2-2).
The utility model provides a thinking and method of liquid air energy storage and ammonia synthesis integrated device specifically realize that this technical scheme's method and approach are many, above only the utility model discloses a preferred embodiment should point out, to the ordinary technical personnel of this technical field, not deviating from the utility model discloses under the prerequisite of principle, can also make a plurality of improvements and moist decorations, these improvements should also be regarded as with moist decorations the utility model discloses a protection scope. All the components not specified in the present embodiment can be realized by the prior art.

Claims (5)

1. The utility model provides a liquid air energy storage and ammonia synthesis integrated device, its characterized in that, the device includes liquid air energy storage circulating system and ammonia synthesis circulating system, wherein:
the liquid air energy storage circulation system comprises: an air separation liquefaction unit and an air power generation unit;
the air separation liquefaction unit comprises:
an air compressor package (100), the air compressor package (100) having a right side input, a left side output, a lower input, and a lower output;
a first air three-way valve (201), wherein the left output end of the first air three-way valve (201) is connected with the right input end of the air compressor unit (100); the right input end of the first air three-way valve (201) is connected with the purified ambient air;
the right side input end of the low-temperature cooler (202) is connected with the left side output end of the air compressor unit (100);
a low temperature turboexpander (203), an input of the low temperature turboexpander (203) being connected to a left side output of the cryocooler (202);
a liquid air separator (204), wherein the upper input end of the liquid air separator (204) is connected with the output end of the low-temperature turbo-expander (203);
a second three-way air valve (205), wherein the upper input end of the second three-way air valve (205) is connected with the lower output end of the liquid air separator (204);
a third air three-way valve (206), wherein the upper input end of the third air three-way valve (206) is connected with the lower output end of the second air three-way valve (205);
a liquid air storage tank (207), wherein the input end of the liquid air storage tank (207) is connected with the right output end of the third air three-way valve (206);
a fourth air three-way valve (208), wherein the right input end of the fourth air three-way valve (208) is connected with the left output end of the liquid air separator (204);
a fifth air three-way valve (209), wherein the lower input end of the fifth air three-way valve (209) is connected with the upper output end of the fourth air three-way valve (208); the right output end of the fifth air three-way valve (209) is connected with the left upper input end of the cryocooler (202);
a sixth air three-way valve (210), wherein the lower input end of the sixth air three-way valve (210) is connected with the upper right output end of the cryocooler (202); the right input end of the sixth air three-way valve (210) is connected with the right input end of the air compressor unit (100); the left output end of the sixth air three-way valve (210) is connected with the environment;
a cold storage unit (211), the cold storage unit (211) having a right side port and a left side port;
a first low temperature three-way valve (212), a right port of the first low temperature three-way valve (212) being connected with a left port of the cold storage unit (211);
the input end of the first low-temperature circulating pump (213) is connected with the upper output end of the first low-temperature three-way valve (212); the output end of the first low-temperature circulating pump (213) is connected with the lower left input end of the cryocooler (202);
a second low-temperature three-way valve (214), wherein the upper input end of the second low-temperature three-way valve (214) is connected with the lower right output end of the cryocooler (202); a left port of the second low-temperature three-way valve (214) is connected with a right port of the cold storage unit (211);
a medium-temperature heat storage unit (215), the medium-temperature heat storage unit (215) having a right-side port and a left-side port;
a first medium-temperature three-way valve (216), wherein a right port of the first medium-temperature three-way valve (216) is connected with a left port of the medium-temperature heat storage unit (215);
the input end of the first medium-temperature circulating pump (217) is connected with the upper output end of the first medium-temperature three-way valve (216); the output end of the first medium-temperature circulating pump (217) is connected with the lower input end of the air compressor unit (100);
the upper input end of the second medium-temperature three-way valve (218) is connected with the lower output end of the air compressor unit (100); the left port of the second medium-temperature three-way valve (218) is connected with the right port of the medium-temperature heat storage unit (215);
the right upper side output end of the rectifying tower (300) is connected with the left side input end of the fifth air three-way valve (209); the right upper side input end of the rectifying tower (300) is connected with the left side output end of the second air three-way valve (205); the right lower side input end of the rectifying tower (300) is connected with the lower output end of the fourth air three-way valve (208); the right lower side output end of the rectifying tower (300) is connected with the left side input end of the third air three-way valve (206);
the air power generation unit with air separation liquefaction unit sharing liquid air storage tank (207), cold storage unit (211), first low temperature three-way valve (212), second low temperature three-way valve (214), medium temperature heat-retaining unit (215), first medium temperature three-way valve (216) and second medium temperature three-way valve (218), still include:
the input end of the low-temperature booster pump (401) is connected with the output end of the liquid air storage tank (207);
the left input end of the evaporator (402) is connected with the output end of the low-temperature booster pump (401); the left output end of the evaporator (402) is connected with the lower input end of the first low-temperature three-way valve (212);
a first nitrogen three-way valve (403), wherein the left input end of the first nitrogen three-way valve (403) is connected with the right output end of the evaporator (402);
a third low-temperature three-way valve (404), wherein the upper input end of the third low-temperature three-way valve (404) is connected with the lower output end of the second low-temperature three-way valve (214); the left output end of the third low-temperature three-way valve (404) is connected with the right input end of the evaporator (402);
the input end of the second low-temperature circulating pump (405) is connected with the lower output end of the third low-temperature three-way valve (404); the output end of the second low-temperature circulating pump (405) is connected with the right input end of the evaporator (402);
the input end of the second medium-temperature circulating pump (406) is connected with the lower output end of the second medium-temperature three-way valve (218);
a third medium-temperature three-way valve (407), wherein the upper input end of the third medium-temperature three-way valve (407) is connected with the output end of the second medium-temperature circulating pump (406); the left input end of the third medium-temperature three-way valve (407) is connected with the right port of the medium-temperature heat storage unit (215);
an air turbine set (500), wherein the left input end of the air turbine set (500) is connected with the right output end of the first nitrogen three-way valve (403); the upper output end of the air turbine unit (500) is connected with the lower input end of the first medium-temperature three-way valve (216); the upper input end of the air turbine unit (500) is connected with the lower output end of the third medium-temperature three-way valve (407);
the ammonia synthesis circulation system comprises:
an air separation plant (601), the air separation plant (601) having a nitrogen output and an oxygen output;
the lower input end of the second nitrogen three-way valve (602) is connected with the nitrogen output end of the air separation plant (601); the upper output end of the second air three-way valve (602) is connected with the lower input end of the first air three-way valve (201);
a first mixing chamber (603), wherein the right input end of the first mixing chamber (603) is connected with the left output end of the second nitrogen three-way valve (602); the upper input end of the first mixing chamber (603) is connected with the right output end of the air turbine set (500);
a hydrogen gas generator (604), wherein the hydrogen gas output end of the hydrogen gas generator (604) is connected with the lower input end of the first mixing chamber (603);
the upper input end of the second mixing chamber (605) is connected with the lower output end of the first nitrogen three-way valve (403);
the right side input end of the preheater (606) is connected with the left side output end of the second mixing chamber (605);
the input end of the normal-temperature cooler (607) is connected with the right output end of the preheater (606);
the upper input end of the liquid ammonia separator (608) is connected with the output end of the normal temperature cooler (607);
an input end of the liquid ammonia throttling valve (609) is connected with a lower output end of the liquid ammonia separator (608);
the input end of the liquid ammonia storage tank (610) is connected with the output end of the liquid ammonia throttling valve (609);
a scavenging unit (611), a left input of the scavenging unit (611) being connected to a right output of the liquid ammonia separator (608); the upper output end of the scavenging unit (611) is connected with the lower input end of the second mixing chamber (605);
a hydrogen separation unit (612), wherein a left input end of the hydrogen separation unit (612) is connected with a right output end of the scavenging unit (611); the lower output end of the hydrogen separation unit (612) is connected with an external waste gas treatment unit;
a third medium temperature circulating pump (613), an input end of the third medium temperature circulating pump (613) being connected to a lower left output end of the air turbine group (500);
a high temperature heat storage unit (614), the high temperature heat storage unit (614) having an upper port and a lower port;
a first high temperature three-way valve (615), an upper port of the first high temperature three-way valve (615) being connected with a lower port of the high temperature heat storage unit (614);
the input end of the first high-temperature circulating pump (616) is connected with the right output end of the first high-temperature three-way valve (615);
a second high-temperature three-way valve (617), a lower port of the second high-temperature three-way valve (617) being connected with an upper port of the high-temperature heat storage unit (614); the upper output end of the second high-temperature three-way valve (617) is connected with the lower right input end of the air turbine unit (500);
the output end of the second high-temperature circulating pump (618) is connected with the left input end of the first high-temperature three-way valve (615); the input end of the second high-temperature circulating pump (618) is connected with the lower middle output end of the air turbine set (500);
a mixed gas compressor set (700), wherein the right input end of the mixed gas compressor set (700) is connected with the left output end of the first mixing chamber (603); the upper output end of the mixed gas compressor unit (700) is connected with the lower middle input end of the air turbine unit (500); the upper input end of the mixed gas compressor unit (700) is connected with the output end of the third medium-temperature circulating pump (613); the left output end of the mixed gas compressor set (700) is connected with the right input end of the second mixing chamber (605); the lower input end of the mixed gas compressor set (700) is connected with the upper output end of the hydrogen separation unit (612);
the upper input end of the ammonia synthesis unit (800) is connected with the left output end of the preheater (606); the lower output end of the ammonia synthesis unit (800) is connected with the left input end of the preheater (606); the left input end of the ammonia synthesis unit (800) is connected with the output end of the first high-temperature circulating pump (616); and the left output end of the ammonia synthesis unit (800) is connected with the right input end of the second high-temperature three-way valve (617).
2. The integrated liquid air energy storage and ammonia synthesis plant according to claim 1, characterized in that said air compressor group (100) comprises one or more stages of air compressors and air coolers; the air turbine set (500) comprises a one-stage or multi-stage medium-temperature heater, a high-temperature heater, a turbine and a medium-temperature three-way valve; the mixed gas compressor set (700) comprises one or more stages of mixed gas compressors and mixed gas coolers; the ammonia synthesis unit (800) comprises one or more stages of ammonia reactors and ammonia coolers.
3. The integrated device for liquid air energy storage and ammonia synthesis according to claim 1, characterized in that said rectifying column (300) comprises:
a high pressure chamber (301), said high pressure chamber (301) having an upper input, an upper output, a lower output, an upper right input and a lower right input; the right upper side input end of the high-pressure chamber (301) is connected with the right upper side input end of the rectifying tower (300); the right lower side input end of the high-pressure chamber (301) is connected with the right lower side input end of the rectifying tower (300);
a filler (302), the filler (302) being located inside the high pressure chamber (301);
the input end of the liquid oxygen throttle valve (303) is connected with the lower output end of the high-pressure chamber (301);
a low pressure chamber (304), the low pressure chamber (304) being located on top of the high pressure chamber (301); the left input end of the low-pressure chamber (304) is connected with the output end of the liquid oxygen throttle valve (303); the upper output end of the low-pressure chamber (304) is connected with the upper right output end of the rectifying tower (300);
an evaporative condenser (305), the evaporative condenser (305) located inside the low pressure chamber (304); the input end of the evaporative condenser (305) is connected with the upper output end of the high-pressure chamber (301); the output end of the evaporative condenser (305) is divided into two paths: one path is connected with the upper input end of the high-pressure chamber (301), and the other path is connected with the right lower output end of the rectifying tower (300).
4. The integrated device for liquid air energy storage and ammonia synthesis according to claim 1, wherein the cold storage unit (211), the medium-temperature heat storage unit (215) and the high-temperature heat storage unit (614) respectively adopt latent heat, sensible heat or thermochemical energy storage materials with working temperature ranges of at least-195-20 ℃, 20-300 ℃ and 20-500 ℃, operate in single-stage or multi-stage series, and adopt heat insulation materials for heat insulation.
5. The integrated device for liquid air energy storage and ammonia synthesis according to claim 1, wherein the air separation liquefaction unit uses air or nitrogen as a working medium; the heat transfer fluid of the cold storage unit (211) is methanol, propane or air; the heat transfer fluid of the medium-temperature heat storage unit (215) is heat conduction oil or silicone oil; the heat transfer fluid of the high-temperature heat storage unit (614) is molten salt; the hydrogen generator (604) is an electrolytic water tank or a fossil fuel hydrogen production device.
CN202022266823.2U 2020-10-13 2020-10-13 Liquid air energy storage and ammonia synthesis integrated device Active CN213480731U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112179046A (en) * 2020-10-13 2021-01-05 丁玉龙 Liquid air energy storage and ammonia synthesis integrated device and method
CN115750017A (en) * 2022-11-30 2023-03-07 国家电投集团科学技术研究院有限公司 Liquid air energy storage coupling ammonia production power generation system and method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112179046A (en) * 2020-10-13 2021-01-05 丁玉龙 Liquid air energy storage and ammonia synthesis integrated device and method
CN112179046B (en) * 2020-10-13 2022-09-06 丁玉龙 Liquid air energy storage and ammonia synthesis integrated device and method
CN115750017A (en) * 2022-11-30 2023-03-07 国家电投集团科学技术研究院有限公司 Liquid air energy storage coupling ammonia production power generation system and method
CN115750017B (en) * 2022-11-30 2024-05-24 国家电投集团科学技术研究院有限公司 Liquid air energy storage coupling ammonia production power generation system and method

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