CN212760298U - Recovery device for complete glass photovoltaic module - Google Patents

Recovery device for complete glass photovoltaic module Download PDF

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Publication number
CN212760298U
CN212760298U CN202021200054.XU CN202021200054U CN212760298U CN 212760298 U CN212760298 U CN 212760298U CN 202021200054 U CN202021200054 U CN 202021200054U CN 212760298 U CN212760298 U CN 212760298U
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photovoltaic module
glass
crushing roller
complete glass
crushing
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CN202021200054.XU
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Chinese (zh)
Inventor
马昀锋
梁汉
郑璐
马崇振
何银凤
张胜广
雷鸣宇
张建文
韩金豆
廖乾
张占升
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Yellow River Hydropower Photovoltaic Industry Technology Co ltd
Qinghai Huanghe Hydropower Development Co Ltd
Huanghe Hydropower Development Co Ltd
Changsha Research Institute of Mining and Metallurgy Co Ltd
State Power Investment Corp Ltd Huanghe Hydropower Development Co Ltd
Photovoltaic Industry Technology Branch of Qinghai Huanghe Hydropower Development Co Ltd
Original Assignee
Yellow River Hydropower Photovoltaic Industry Technology Co ltd
Qinghai Huanghe Hydropower Development Co Ltd
Huanghe Hydropower Development Co Ltd
Changsha Research Institute of Mining and Metallurgy Co Ltd
Photovoltaic Industry Technology Branch of Qinghai Huanghe Hydropower Development Co Ltd
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Application filed by Yellow River Hydropower Photovoltaic Industry Technology Co ltd, Qinghai Huanghe Hydropower Development Co Ltd, Huanghe Hydropower Development Co Ltd, Changsha Research Institute of Mining and Metallurgy Co Ltd, Photovoltaic Industry Technology Branch of Qinghai Huanghe Hydropower Development Co Ltd filed Critical Yellow River Hydropower Photovoltaic Industry Technology Co ltd
Priority to CN202021200054.XU priority Critical patent/CN212760298U/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/20Waste processing or separation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/82Recycling of waste of electrical or electronic equipment [WEEE]

Abstract

The utility model discloses a recovery unit of complete glass photovoltaic module, including mechanical separation room, crushing mechanism, heating chamber, screening mechanism, glass separating mechanism and transport mechanism, transport mechanism transmits the material in proper order between mechanical separation room, glass separating mechanism, crushing mechanism, heating chamber, screening mechanism, and glass separating mechanism is used for separating the complete glass on photovoltaic module surface, including preheating chamber and vacuum chuck subassembly, heating block, and the heating block heats photovoltaic module, and the vacuum chuck subassembly separates complete glass after the EVA material heats and softens; the crushing mechanism is used for crushing the photovoltaic module after the complete glass is separated into a granular mixture; the heating chamber is used for heating and gasifying the EVA material, and the screening mechanism is used for separating the silicon wafer from the metal welding strip. The utility model discloses a mode that machinery, thermal decomposition combined together is retrieved complete glass photovoltaic module, has realized the abundant separation of single component among the photovoltaic module, and can not produce the waste gas that influences the environment.

Description

Recovery device for complete glass photovoltaic module
Technical Field
The utility model relates to a photovoltaic product retrieves technical field, especially relates to a complete glass photovoltaic module's recovery unit.
Background
China begins to become the country with the largest installed capacity and the largest generated energy of global photovoltaic power generation from 2015. The service life of the photovoltaic module is about 20-25 years, and the recovery processing of the photovoltaic module after the service life is over is a major problem in the future. The solid waste of solar cells in China is greatly increased from 2020, and the accumulated waste amount is gradually increased. By 2030, the recycling scale of photovoltaic modules will reach 60GW, about 450 million tons of photovoltaic panels. The module contains valuable metals such as copper, aluminum, tin, silver and the like, solar grade silicon and the like, and has quite high recovery value and economic value. The huge loading capacity of the photovoltaic module also makes the development of the photovoltaic module recycling technology and equipment an urgent problem to be solved.
At present, the treatment methods of the photovoltaic module include an inorganic acid dissolution method, an organic solvent dissolution method, a heat treatment method, a mechanical treatment method, a combined treatment method and the like. The inorganic acid dissolution method can maintain the integrity of the silicon chip, but cannot ensure the recovery rate of valuable metals, and generates nitrogen oxides needing to be treated by tail gas in the operation process; the organic solvent dissolving method needs longer time, can generate a large amount of organic waste solvent, and has serious pollution to the environment and water; the heat treatment method can dissociate the cells, glass, frames and other monomers in the photovoltaic module, and other methods are needed for separation; the mechanical separation method comprises the steps of firstly removing an aluminum frame of the component and a junction box, then crushing the frameless component, separating a tin-coated welding strip from glass particles, grinding the rest part, and obtaining metal, silicon powder, backboard particles and EVA (Ethylene Vinyl Acetate) particles by using an electrostatic separation method.
SUMMERY OF THE UTILITY MODEL
In view of the deficiencies in the prior art, the utility model provides a complete glass photovoltaic module's recovery unit has overcome current photovoltaic module's processing method's defect, can realize the abundant separation of single component among the photovoltaic module, and can not produce the waste gas that influences the environment, has reduced the separation degree of difficulty, the operation cost is low, and the rate of recovery is high.
In order to achieve the above purpose, the utility model adopts the following technical scheme:
the recovery device for the complete glass photovoltaic module comprises a mechanical separation chamber, a crushing mechanism, a heating chamber, a screening mechanism, a glass separation mechanism and a conveying mechanism, wherein the conveying mechanism is used for conveying materials among the mechanical separation chamber, the glass separation mechanism, the crushing mechanism, the heating chamber and the screening mechanism in sequence; the mechanical separation chamber is used for dismantling the junction box, the metal frame and the back plate by adopting a mechanical separation method; the glass separation mechanism is used for separating complete glass on the surface of the photovoltaic assembly after the junction box, the metal frame and the back plate are removed, and comprises a preheating chamber, a vacuum sucker assembly and a heating block, wherein the vacuum sucker assembly and the heating block are arranged in the preheating chamber, the heating block is used for heating the photovoltaic assembly, and the vacuum sucker assembly is used for separating the complete glass after an EVA material is heated and softened; the crushing mechanism is used for crushing the photovoltaic module after the complete glass is separated into a granular mixture; the heating chamber is used for heating and gasifying EVA materials, and the screening mechanism is used for separating the silicon wafer from the metal welding strip.
In one embodiment, the glass separation mechanism further comprises a peeling knife, and the peeling knife is used for being inserted between the glass and the EVA material after being heated so as to separate the EVA material from the glass.
In one embodiment, the crushing mechanism comprises a crushing assembly which is composed of a lower crushing roller and an upper crushing roller, the lower crushing roller and the upper crushing roller are oppositely arranged at intervals, and crushing teeth are convexly arranged on the surfaces of the lower crushing roller and the upper crushing roller.
As one of the embodiments, a plurality of pairs of the lower crushing roller and the upper crushing roller are arranged at intervals on the conveying path of the photovoltaic module, and the interval between the lower crushing roller and the upper crushing roller located downstream of the conveying path is smaller than the interval between the lower crushing roller and the upper crushing roller located upstream of the conveying path.
In one embodiment, a cleaning tank is arranged in the mechanical separation chamber, and the cleaning tank is used for removing impurities adhered to the surface of the assembly before the junction box, the metal frame and the back plate are detached.
In one embodiment, the preheating chamber is hermetically arranged, and the preheating temperature of the heating block is 200 to 225 ℃.
In one embodiment, the heating temperature of the heating chamber is 500 to 520 ℃.
As one embodiment, the mechanical separation chamber is internally provided with an image sensor for capturing the position of the junction box, a micro control chip, a clamp for clamping and fixing the complete glass photovoltaic assembly and a manipulator for clamping and removing the junction box.
In one embodiment, a grinding mechanism is disposed within the mechanical separation chamber for contacting and grinding away the backing layer.
The utility model discloses an adopt machinery, the joint separation mode that thermal decomposition combined together retrieves complete glass photovoltaic module, and adopt to use mechanical separation mode as leading, the recovery mode is disassembled for assisting to the thermal treatment mode, isolate terminal box in proper order, the metal frame, the backplate, the EVA material, metal solder strip and silicon chip and glass, the abundant separation of single component among the photovoltaic module has been realized, and can not produce the waste gas that influences the environment, because peel off glass in advance, consequently, the monomer separation degree of difficulty in the follow-up recovery process has been reduced, the process is simple, the operation cost is low, and the rate of recovery is high.
Drawings
Fig. 1 is a block flow diagram of a recycling method of a complete glass photovoltaic module according to embodiment 1 of the present invention;
fig. 2 is a schematic view of a mechanical separation mode of a complete glass photovoltaic module before being crushed according to embodiment 1 of the present invention;
fig. 3 is a schematic structural diagram of a recycling device of a complete glass photovoltaic module according to embodiment 2 of the present invention;
the numbers in the figures illustrate the following:
1-a mechanical separation chamber; 2-a crushing mechanism; 3, a heating chamber; 4-a screening mechanism; 5-a glass separation mechanism; 6-a conveying mechanism; 50-a preheating chamber; 51-vacuum chuck assembly; 52-a heating block; 53-a stripping knife; 211-a lower crushing roller; 212-upper crushing roller; p-complete glass photovoltaic module.
Detailed Description
In the present invention, the terms "disposed", "provided" and "connected" should be interpreted broadly. For example, it may be a fixed connection, a removable connection, or a unitary construction; can be a mechanical connection, or an electrical connection; may be directly connected, or indirectly connected through intervening media, or may be in internal communication between two devices, elements or components. The specific meaning of the above terms in the present invention can be understood according to specific situations by those skilled in the art.
The terms "central," "longitudinal," "lateral," "length," "width," "thickness," "upper," "lower," "front," "rear," "left," "right," "vertical," "horizontal," "top," "bottom," "inner," "outer," "clockwise," "counterclockwise," "axial," "radial," "circumferential," and the like are used in an orientation or positional relationship indicated in the drawings for convenience in describing and simplifying the description, and are not intended to indicate or imply that the device or element so referred to must have a particular orientation, be constructed and operated in a particular orientation, and thus should not be construed as limiting the application.
Furthermore, the terms "first", "second" and "first" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defined as "first" or "second" may explicitly or implicitly include at least one such feature. In the description of the present application, "plurality" means at least two, e.g., two, three, etc., unless specifically limited otherwise.
Moreover, some of the above terms may be used to indicate other meanings besides the orientation or positional relationship, for example, the term "on" may also be used to indicate some kind of attachment or connection relationship in some cases. The specific meaning of these terms in the present invention can be understood by those of ordinary skill in the art as appropriate.
In order to make the objects, technical solutions and advantages of the present invention more clearly understood, the present invention is further described in detail below with reference to the accompanying drawings and embodiments. It should be understood that the specific embodiments described herein are merely illustrative of the invention and are not intended to limit the invention.
Example 1
The utility model discloses complete glass photovoltaic module's recovery method can be used to retrieve the photovoltaic module that surperficial glass is more complete, glass breakage does not appear, can retrieve whole complete glass, avoids glass to smash the influence to the recovery process degree of difficulty. Referring to fig. 1, the recycling method of the complete glass photovoltaic module of the present embodiment mainly includes:
and S01, removing the junction box, the metal frame and the back plate by adopting a mechanical separation method.
And S02, heating and softening the EVA material.
And S03, peeling the complete glass on the surface of the complete glass photovoltaic module.
And S04, crushing the photovoltaic module after the complete glass is peeled into a granular mixture.
S05, heating the granular mixture, gasifying the EVA material, and enabling the silicon chip and the metal welding strip to be in a mutually separated state.
And S06, screening the silicon chip and the metal welding strip which are in the separated state, and respectively recovering the silicon chip and the metal welding strip.
In the embodiment, a mechanical separation method is adopted when the junction box, the metal frame, the back plate and the complete glass are dismantled, then other structures are crushed into particles, then EVA materials serving as interlayer bonding materials in the particle mixture are removed through heating and gasification, silicon wafers and metal welding strips in mutually separated states are obtained, and the separated silicon wafers and the metal welding strips can be obtained and respectively recovered through screening and separating the structures in the separated states. Inorganic or organic solvent can not be used in the whole recovery process, harmful waste gas can not be generated, so that environmental pollution can not be caused, the process is simple, the operability is strong, the monomers of respective materials can be separated independently, and the final recovery rate is high.
Specifically, as shown in fig. 2, the present embodiment further provides a preferred specific implementation manner of each step, and it is understood that these preferred implementation manners are only used for explaining the present invention and are not used for limiting the protection scope of the present invention, and those skilled in the art can make substitutions or improvements according to this embodiment in combination with their respective technical means in the art.
(1) In step S01, the junction box, the metal bezel, and the back panel are removed by mechanical separation.
As shown in fig. 2, specifically, the step may include:
s011 and cleaning: the complete glass photovoltaic module is cleaned, impurities such as silt, weeds and the like adhered to the surface of the module are removed, the residual content (mass fraction) of the impurities such as silt, weeds and the like adhered to the photovoltaic module is not higher than 1% of all the impurities, and subsequent recovery of all components of the photovoltaic module is not influenced.
S012, dismantling the junction box: and (4) dismantling the junction box of the cleaned complete glass photovoltaic module by adopting a mechanical method. Here, the terminal box can be removed by using a terminal box removing tool with machine vision positioning, the terminal box removing tool comprises an image sensor for capturing the position of the terminal box, a micro control chip, a clamp for clamping and fixing the complete glass photovoltaic assembly and a manipulator for clamping and removing the terminal box, and when the image sensor detects the relative position coordinate of the terminal box relative to the clamp platform, the micro control chip controls the manipulator to move to a specified position and remove the terminal box.
S013, removing a metal frame: and (4) removing the metal frame of the photovoltaic module with the junction box removed by adopting a mechanical method.
In this step, it is also necessary to remove the silica gel filled between the periphery of the back plate surface of the photovoltaic module and the metal frame, so that the residual thickness of the silica gel attached to the back plate surface of the photovoltaic module is not more than 0.2mm, thereby avoiding unnecessary impurities brought to subsequent recovery.
S014, detaching the back plate.
After the junction box and the metal frame are removed, the surface of the photovoltaic module is also provided with a back plate, and the back plate can be removed by a grinding mechanism such as a grinding wheel through layer-by-layer grinding to expose glass at the bottom of the back plate, wherein the glass is usually toughened glass. By adopting the grinding mode, the removal rate of the back plate material can reach more than 95 percent, and the glass is not damaged.
(2) In step S02, the complete glass photovoltaic module with the junction box, the metal frame, and the back sheet removed needs to be heated to soften the EVA material between the complete glass and the cell panel.
The process can be carried out in a closed heating chamber, preheating of the EVA material is achieved, the aim is not to separate the EVA material, but to separate complete glass, the preheating temperature is preferably 200-225 ℃, and the heating time is 10-12 minutes. After preheating is completed, the bonding force between the EVA material and the complete glass is weakened, so that the complete glass can be conveniently peeled.
(3) In step S03, after the preheating is completed, the whole glass can be peeled off by using a vacuum chuck, specifically:
first, the outer surface of the whole glass is sucked at a plurality of portions by using a vacuum chuck, and then, the whole glass is separated outward in a direction perpendicular to the whole glass.
Sometimes, there is still some bonding force between the EVA material and the whole glass, and the peeling may not be smooth, and step S02 may further include, before sucking the whole glass with the suction cup:
heating a stripping knife;
inserting a peel knife between the glass and the EVA material from the end of the photovoltaic module until the entire piece of intact glass is completely separated from the EVA material. Therefore, the whole complete glass can be easily taken away by using the sucking disc.
(4) In step S04, the whole glass photovoltaic module after the whole glass is removed needs to be crushed into a granular mixture.
The step may specifically include:
and enabling the photovoltaic module stripped with the complete glass to enter a space between a lower crushing roller and an upper crushing roller which are oppositely arranged, and rotating the lower crushing roller and the upper crushing roller in opposite directions to enable the photovoltaic module stripped with the complete glass to be crushed into particles.
In order to improve the crushing effect, the crushing treatment steps can be realized in multiple steps, including:
coarse crushing pretreatment: and crushing the photovoltaic module stripped from the complete glass by using the lower crushing roller and the upper crushing roller with larger intervals to form coarse crushed particles.
Fine crushing treatment: the coarsely crushed particles are crushed again by the lower crushing roller and the upper crushing roller which are spaced at a large distance.
In order to realize the process, the interval between each pair of the lower crushing roller and the upper crushing roller is gradually reduced along the transmission direction of the photovoltaic assembly, the photovoltaic assembly stripped with complete glass sequentially enters between the plurality of pairs of the lower crushing rollers and the upper crushing rollers, and each pair of the lower crushing rollers and the upper crushing rollers are rotated along the opposite direction.
(5) In step S05, the crushed granular mixture is heated to vaporize the EVA material therein, so that the silicon wafer and the metal solder ribbon are separated from each other.
In the process of vaporizing the EVA material, the granular mixture obtained in step S02 is heated at 500 to 520 ℃ for 20 to 25 minutes, so that the EVA is vaporized by thermal decomposition, and the silicon wafer and the copper-tin solder tape monomer are separated.
(6) In step S06, the silicon wafer and the metal solder ribbon in the separated state are separated by screening, and the silicon wafer and the metal solder ribbon are recovered separately.
The screening step can be specifically carried out by adopting a centrifugal screen, a rotary screen, gravity settling separation and other modes according to the density characteristics of the silicon wafer and the metal solder strip.
Through the processes of mechanical separation, thermal softening stripping, thermal decomposition gasification and screening, the monomers of the respective materials in the complete glass photovoltaic module are separated independently, so that higher recovery rate is realized, and the influence of the glass materials on the subsequent recovery process is avoided.
Example 2
As shown in fig. 3, the recycling apparatus for complete glass photovoltaic module of the present embodiment mainly comprises a mechanical separation chamber 1, a crushing mechanism 2, a heating chamber 3, a screening mechanism 4, a glass separation mechanism 5 and a conveying mechanism 6, the conveying mechanism 6 is used as a conveying part of the whole device and is used for conveying materials among the mechanical separation chamber 1, the glass separation mechanism 5, the crushing mechanism 2, the heating chamber 3 and the screening mechanism 4 in sequence, the mechanical separation chamber 1 is used for removing a junction box, a metal frame and a back plate by adopting a mechanical separation method, the glass separation mechanism 5 is used for separating complete glass on the surface of the photovoltaic module after the junction box, the metal frame and the back plate are removed, and the glass separation mechanism comprises a preheating chamber 50, a vacuum sucker component 51 and a heating block 52 which are arranged in the preheating chamber 50, the heating block 52 is used for heating the photovoltaic module, and the vacuum sucker component 51 is used for separating the complete glass after an EVA material is heated and softened; the crushing mechanism 2 is used for crushing the photovoltaic module after the complete glass is separated into a granular mixture; the heating chamber 3 is used for heating and gasifying EVA materials, and the screening mechanism 4 is used for separating silicon wafers and metal welding strips.
The glass separating mechanism 5 comprises a stripping knife 53 besides the vacuum chuck assembly 51 and the heating block 52, wherein the stripping knife 53 is used for being inserted between the glass and the EVA material after being heated so as to separate the EVA material from the glass, and the vacuum chuck assembly 51 is convenient to take away the complete glass. The heating of the peeling blade 53 can also be performed by the heating block 52.
Specifically, the mechanical separation chamber 1 includes a workbench for placing and fixing the complete glass photovoltaic assembly P and a jig for removing the junction box, the metal frame and the back plate, for example, the jig for removing the junction box may be a box removing tool including an image sensor for capturing the position of the junction box, a micro control chip, a clamp for clamping and fixing the complete glass photovoltaic assembly and a manipulator for clamping and removing the junction box, and when the image sensor detects the relative position coordinate of the junction box with respect to the clamp platform, the micro control chip controls the manipulator to move to a specified position and remove the junction box. The jig for removing the metal frame can comprise a clamp body, and when the back plate of the complete glass photovoltaic assembly P is fixed on the workbench by the clamp, the metal frame can be clamped and removed by the clamp body. The jig for removing the back plate can be a grinding mechanism suspended above the workbench, the back plate of the photovoltaic module after the junction box and the metal frame are removed faces upwards, and the back plate layer is contacted and ground by the grinding mechanism, so that the back plate can be removed. Can also be provided with in the mechanical separation room 1 and wash the pond, around demolising terminal box, metal frame, backplate, all can utilize this washing pond to wash photovoltaic module, can get rid of debris such as silt, weeds of subassembly surface adhesion before the machinery is demolishd, also can wash impurity such as the adnexed dust piece in subassembly surface after the machinery is demolishd.
The conveying mechanism 6 can adopt a roller type conveying structure for physical conveying, and the crushing mechanism 2 can crush the photovoltaic module stripped with the complete glass into a granular mixture. Specifically, the crushing mechanism 2 mainly comprises a lower crushing roller 211 and an upper crushing roller 212, the lower crushing roller 211 and the upper crushing roller 212 are oppositely arranged at intervals, the surfaces of the lower crushing roller 211 and the upper crushing roller 212 are both provided with crushing teeth in a protruding mode, and when a photovoltaic module transmitted by the transmission mechanism 6 enters the lower crushing roller 211 and the upper crushing roller 212Between the upper crushing rollers 212, the lower crushing roller 211 and the upper crushing roller 212 crush the photovoltaic module into fine particles in a pressing manner during rotation. Preferably, a plurality of pairs of lower crushing rollers 211 and upper crushing rollers 212 are arranged on the transmission path of the photovoltaic module at intervals, and the interval between the lower crushing roller 211 and the upper crushing roller 212 positioned at the downstream of the transmission path is smaller than the interval between the lower crushing roller 211 and the upper crushing roller 212 positioned at the upstream of the transmission path, so that the photovoltaic module is crushed for a plurality of times and the particle size becomes smaller in sequence, and the better crushing effect is achieved. It will be appreciated that the crushing assembly may also be other types of crushing structures, such as a pulse crusher, an impact crusher, etc. The upstream part of the lower crushing roller 211 and the upper crushing roller 212 are matched to realize the coarse crushing pretreatment of the complete glass photovoltaic module to form coarse crushed particles, and the particle size range d of the coarse crushed particles3Satisfy d3Less than 50mm, and a part of the lower crushing roller 211 and the upper crushing roller 212 at the downstream are matched to realize the fine crushing treatment of the complete glass photovoltaic module, and the particle size range d of the fine particles after the fine crushing treatment4Satisfy d4<15mm。
And then, a heating chamber 3 is arranged at the downstream of the crushing mechanism 2, the mixture formed by crushing and consisting of the silicon wafer, the metal welding strip and the EVA material is heated at a high temperature, the heating temperature in the heating chamber 3 is 500-520 ℃, after heating for 20-25 minutes, the EVA material is decomposed and gasified by heat, and the separated silicon wafer and copper-tin welding strip monomer are left.
The utility model discloses an adopt machinery, the joint separation mode that thermal decomposition combined together retrieves complete glass photovoltaic module, and adopt to use mechanical separation mode as leading, the recovery mode is disassembled for assisting to the thermal treatment mode, isolate terminal box in proper order, the metal frame, the backplate, the EVA material, metal solder strip and silicon chip and glass, the abundant separation of single component among the photovoltaic module has been realized, and can not produce the waste gas that influences the environment, because peel off glass in advance, consequently, the monomer separation degree of difficulty in the follow-up recovery process has been reduced, and the rate of recovery is high, each free rate of recovery all can reach more than 90%.
The foregoing is directed to embodiments of the present application and it is noted that numerous modifications and adaptations may be made by those skilled in the art without departing from the principles of the present application and are intended to be within the scope of the present application.

Claims (9)

1. The recovery device for the complete glass photovoltaic module is characterized by comprising a mechanical separation chamber (1), a crushing mechanism (2), a heating chamber (3), a screening mechanism (4), a glass separation mechanism (5) and a conveying mechanism (6), wherein the conveying mechanism (6) is used for conveying materials among the mechanical separation chamber (1), the glass separation mechanism (5), the crushing mechanism (2), the heating chamber (3) and the screening mechanism (4) in sequence; the mechanical separation chamber (1) is used for dismantling the junction box, the metal frame and the back plate by adopting a mechanical separation method; the glass separation mechanism (5) is used for separating complete glass on the surface of the photovoltaic module after the junction box, the metal frame and the back plate are detached, and comprises a preheating chamber (50), a vacuum sucker assembly (51) and a heating block (52) which are arranged in the preheating chamber (50), wherein the heating block (52) is used for heating the photovoltaic module, and the vacuum sucker assembly (51) is used for separating the complete glass after an EVA material is heated and softened; the crushing mechanism (2) is used for crushing the photovoltaic module after the complete glass is separated into a granular mixture; the heating chamber (3) is used for heating and gasifying EVA materials, and the screening mechanism (4) is used for separating silicon wafers from metal welding strips.
2. The recycling device of a complete glass photovoltaic module according to claim 1, characterized in that said glass separation means (5) further comprises a peeling knife (53), said peeling knife (53) being intended to be inserted between the glass and the EVA material after heating, in order to detach the EVA material from the glass.
3. The recycling device of the whole glass photovoltaic module according to claim 1, wherein the crushing mechanism (2) comprises a crushing assembly (21), the crushing assembly (21) is composed of a lower crushing roller (211) and an upper crushing roller (212), the lower crushing roller (211) and the upper crushing roller (212) are oppositely arranged at intervals, and the surfaces of the lower crushing roller and the upper crushing roller are convexly provided with crushing teeth.
4. The recycling apparatus of a complete glass photovoltaic module according to claim 3, characterized in that a plurality of pairs of said lower crushing roller (211) and said upper crushing roller (212) are arranged at intervals on the transport path of the photovoltaic module, and the interval between said lower crushing roller (211) and said upper crushing roller (212) located downstream of the transport path is smaller than the interval between said lower crushing roller (211) and said upper crushing roller (212) located upstream of the transport path.
5. The recovery device of the complete glass photovoltaic module according to claim 1, wherein a cleaning tank is arranged in the mechanical separation chamber (1), and the cleaning tank is used for removing sundries adhered to the surface of the module before the junction box, the metal frame and the back plate are disassembled.
6. The recycling apparatus of the complete glass photovoltaic module according to claim 1, wherein the preheating chamber (50) is hermetically disposed, and the preheating temperature of the heating block (52) is 200-225 ℃.
7. The recycling apparatus of the complete glass photovoltaic module according to claim 6, characterized in that the heating temperature of the heating chamber (3) is 500-520 ℃.
8. The recycling device of the complete glass photovoltaic assembly according to any one of claims 1 to 7, wherein an image sensor for capturing the position of the junction box, a micro control chip, a clamp for clamping and fixing the complete glass photovoltaic assembly and a manipulator for clamping and removing the junction box are arranged in the mechanical separation chamber (1).
9. A complete glass photovoltaic module recovery device according to any of claims 1 to 7, characterized by the mechanical separation chamber (1) inside of which is located a grinding mechanism for contacting and grinding away the backsheet layer.
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111790723A (en) * 2020-06-24 2020-10-20 青海黄河上游水电开发有限责任公司光伏产业技术分公司 Recovery method and device of complete glass photovoltaic module
CN115041501A (en) * 2022-06-14 2022-09-13 河北省凤凰谷零碳发展研究院 Treatment and recovery system and method for glass-free photovoltaic laminated part
CN115318796A (en) * 2022-09-02 2022-11-11 重庆远达烟气治理特许经营有限公司科技分公司 Separation method of photovoltaic module after irradiation treatment
CN116651888A (en) * 2023-08-01 2023-08-29 国能龙源环保有限公司 Method for recycling waste photovoltaic modules
CN117046864A (en) * 2023-08-28 2023-11-14 国能龙源环保有限公司 Photovoltaic module recycling method and device
CN111790723B (en) * 2020-06-24 2024-05-10 青海黄河上游水电开发有限责任公司光伏产业技术分公司 Recovery method and device for complete glass photovoltaic module

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111790723A (en) * 2020-06-24 2020-10-20 青海黄河上游水电开发有限责任公司光伏产业技术分公司 Recovery method and device of complete glass photovoltaic module
CN111790723B (en) * 2020-06-24 2024-05-10 青海黄河上游水电开发有限责任公司光伏产业技术分公司 Recovery method and device for complete glass photovoltaic module
CN115041501A (en) * 2022-06-14 2022-09-13 河北省凤凰谷零碳发展研究院 Treatment and recovery system and method for glass-free photovoltaic laminated part
CN115318796A (en) * 2022-09-02 2022-11-11 重庆远达烟气治理特许经营有限公司科技分公司 Separation method of photovoltaic module after irradiation treatment
CN115318796B (en) * 2022-09-02 2024-02-20 重庆远达烟气治理特许经营有限公司科技分公司 Separation method of photovoltaic module after irradiation treatment
CN116651888A (en) * 2023-08-01 2023-08-29 国能龙源环保有限公司 Method for recycling waste photovoltaic modules
CN117046864A (en) * 2023-08-28 2023-11-14 国能龙源环保有限公司 Photovoltaic module recycling method and device

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