CN209374566U - A kind of cold boot of fuel cell system with storage heater - Google Patents

A kind of cold boot of fuel cell system with storage heater Download PDF

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Publication number
CN209374566U
CN209374566U CN201920146192.5U CN201920146192U CN209374566U CN 209374566 U CN209374566 U CN 209374566U CN 201920146192 U CN201920146192 U CN 201920146192U CN 209374566 U CN209374566 U CN 209374566U
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CN
China
Prior art keywords
pile
micropump
storage heater
fuel cell
temperature
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Active
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CN201920146192.5U
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Chinese (zh)
Inventor
张峰鸣
陈婕
徐晨
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SHANGHAI FUEL CELL VEHICLE POWERTRAIN CO Ltd
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SHANGHAI FUEL CELL VEHICLE POWERTRAIN CO Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B90/00Enabling technologies or technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02B90/10Applications of fuel cells in buildings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

The utility model relates to field of fuel cell technology, provide a kind of cold boot of fuel cell system with storage heater, including pile, the pile refers to a kind of energy conversion device, and the main cooling system for cooling down the pile, for protecting the Micropump circulatory system of mild heat to the pile, the Micropump circulatory system includes Micropump, backup power source and storage heater, the Micropump is for controlling coolant liquid circulation, the backup power source is when the pile is closed, for providing electric power to the Micropump, the storage heater is for absorbing storage heat and release heat, the pile, the Micropump and the storage heater connect to form the first circuit.The utility model can be improved cold boot of fuel cell efficiency, protects fuel cell, improves performance and the service life of battery.

Description

A kind of cold boot of fuel cell system with storage heater
Technical field
The utility model relates to field of fuel cell technology, refer in particular to provide a kind of fuel electricity with storage heater Pond cold starting system.
Background technique
Fuel cell is the electrochemistry dress that a kind of chemical energy that will be present in fuel and oxidant is converted into electric energy It sets, is the 4th kind of generation mode after thermoelectricity, water power and nuclear power.Wherein, Proton Exchange Membrane Fuel Cells (PEMFC) is combustion Expect one kind of battery, monocell is made of anode, cathode and proton exchange membrane, and anode is the place that hydrogen fuel aoxidizes, Cathode is the place of oxidant reduction.Its power generation process is not related to oxyhydrogen combustion, and energy conversion rate is high, and when power generation does not generate dirt Dye, power generating modules, high reliablity, assembling and maintenance are all very convenient, also without noise when work.Therefore, proton exchange Membrane cell power supply is a kind of cleaning, efficiently environmentally protective power supply.But due to the electrification of Proton Exchange Membrane Fuel Cells It learns reaction to carry out on water-gas-proton (electronics) three phase boundary, temperature starts when being lower than zero degree, the water that inside battery generates Icing phenomenon can be generated, while blocking the gas passage of reaction zone, causes the rupture of proton exchange membrane to influence battery performance. Thus it is guaranteed that the cold start-up safety of Proton Exchange Membrane Fuel Cells is to improve a critical issue of battery performance and service life.
Summary of the invention
In order to solve the above technical problems, the main purpose of the utility model is to provide a kind of combustions with storage heater Expect battery cold starting system, can be improved cold boot of fuel cell efficiency, protects fuel cell, improve performance and the longevity of battery Life.
To reach above-mentioned purpose, the technical solution of the utility model application is: providing a kind of combustion with storage heater Expect that battery cold starting system, including pile, the pile refer to a kind of energy conversion device, and the master for cooling down the pile Cooling system, for protecting the Micropump circulatory system of mild heat to the pile, the Micropump circulatory system includes Micropump, spare Power supply and storage heater, the Micropump are used for for controlling coolant liquid circulation, the backup power source when the pile is closed Electric power is provided to the Micropump, the storage heater is for absorbing storage heat and release heat, the pile, the Micropump And the storage heater connects to form the first circuit.
In the technical program, when pile operates normally, main cooling system is opened, and is carried out by coolant liquid to pile cold But, meanwhile, it also added the Micropump circulatory system, when stack temperature is excessively high, storage heater absorbs heat and stores, together When can also cool down to pile, by stack temperature stablize be suitble to range in;When stack temperature is too low, storage heater can be The heat of storage releases, and for heating up to pile, the stability of stack temperature is increased, at this point, the work of storage heater Make to save the energy without being additionally provided power.When pile is out of service, in the case where executing holding mode, the Micropump circulatory system It can be kept the temperature to pile, stack temperature is made to maintain zero degrees celsius or more a period of time, prevent from damaging pile because of freezing and expansion, together Shi Shixian is quickly cold-started.
In the present embodiment preferably, the storage heater is separated structure, including first end, heating sheet and second end Portion, the first end and the second end clamp the heating sheet between, the first end with it is described micro- Pump connection, the second end are connect with the main cooling system.
In the technical program, using isolated phase change heat storage material, intermediate course is PTC heating sheet, since this is special Separated structure there are two heat exchange pipelines, to realize the operation of different mode.
In the present embodiment preferably, the first split cavity to be formed, institute is isolated equipped with metal conducting strip in the first end State the first phase-change material that the first split cavity is 70-80 DEG C filled with phase transition temperature;
The second end is equipped with metal conducting strip and the second split cavity to be formed, the second split cavity filling is isolated Having phase transition temperature is 40-50 DEG C of the second phase-change material.
In the technical program, when pile operates normally, the temperature by main cooling system coolant liquid after cooling is lower, Therefore storage heater uses the lower 40-50 DEG C of phase change heat storage material of phase transition temperature close to one end of main cooling system, can be with Lower phase-transition heat-storage temperature is preferentially provided.One end temperature close to pile is relatively high, then uses 70-80 DEG C of phase transformation material Material.Micropump looped cycle can be opened when pile power increases suddenly, it is steady to absorb amount of heat using the material of the high phase transition temperature Determine temperature.In the optimized copper metal conducting strip of disengagement chamber indoor deployment, may be implemented efficiently to store heat release function.
In the present embodiment preferably, the first end is equipped with several metal conducting strips, and first separation chamber is isolated Form several regions;
The second end is equipped with several metal conducting strips, is isolated second separation chamber to form several regions.
In the present embodiment preferably, the main cooling system includes deionizater and intercooler, the deionizater, described The first end of storage heater and the intercooler are sequentially connected and are formed second branch, and the second branch is attempted by described The both ends of pile.
In the present embodiment preferably, the main cooling system further includes water pump, thermostat and radiator, the pile, institute It states water pump, the thermostat and the radiator and is sequentially connected and is formed third branch, water pump is far from institute in the third branch The one end for stating thermostat is connected to the one end of the deionizater far from the pile, and radiator is connected in the third branch The one end of the pile far from the deionizater.
In the present embodiment preferably, the main cooling system further includes water supply tank, the water supply tank, the radiator, institute It states thermostat and the water pump is sequentially connected and forms series loop.
In the present embodiment preferably, be serially connected with Micropump switch in the control terminal of the Micropump, Micropump switch also with institute State pile connection.
The utility model provides a kind of cold boot of fuel cell system with storage heater, can bring following at least one Kind the utility model has the advantages that
1. in the utility model, by the Micropump circulatory system, can be realized by low-temperature insulation function and improve fuel cell It is cold-started efficiency, fuel cell is protected, improves performance and the service life of battery.
2. in the utility model, absorbing storage heat and release heat by storage heater, stack temperature can be improved Stability, while by pile operation generate heat absorption store recycle, reduce energy consumption.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the present embodiment fuel battery cooling system.
Fig. 2 is the structural schematic diagram of the present embodiment storage heater.
Fig. 3 is the schematic diagram of the section structure of the first end of the present embodiment storage heater.
Fig. 4 is the time diagram that the present embodiment Micropump circulatory system keeps the temperature pile in varying environment temperature.
Drawing reference numeral explanation:
1. pile, 2. Micropumps switch, 3. Micropumps, 4. heat storage devices, 5. intercoolers, 6. deionizaters, 7. water pumps, 8. sections Warm device, 9. radiators, 10. water supply tanks, 11. first ends, 12. heating sheets, 13. the second ends, 14. metal conducting strips, 15. One split cavity.
Specific embodiment
Although the utility model can easily show as various forms of embodiments, it is shown in the accompanying drawings and at this What be will be explained in specification is only some of specific embodiments, while being understandable that this specification is construed as The utility model principle it is exemplary illustrated, and be not intended to for the utility model being restricted to it is illustrated herein as.
As a result, a feature pointed in this specification by one embodiment to illustrate the utility model wherein One feature, rather than imply that each embodiment of the utility model must have illustrated feature.Further it is to be noted that It is that present specification describes many features.Although certain features can be combined to show possible system design, These features can also be used for other combinations that explanation is not known.As a result, unless otherwise indicated, illustrated combination is not intended to Limitation.
In the embodiment shown in the figures, the instruction (such as upper, lower, left, right, front and rear) in direction is practical to explain The structure of novel various assemblies and movement are not absolute but opposite.When these components are in position shown in the drawings When, these explanations are suitable.If the explanation of the position of these components changes, the instruction in these directions is also corresponding Ground changes.
Below in conjunction with the attached drawing of this specification, the preferred embodiment of the utility model is further described in detail.
In example 1, as shown in Figure 1 to Figure 3, a kind of fuel cell with storage heater is present embodiments provided Cold starting system, including pile 1, pile 1 refer to a kind of energy conversion device, refer generally to fuel cell;For cooling down the electricity The main cooling system (not marking) of heap;For protecting the Micropump circulatory system (not marking) of mild heat, Micropump cyclic system to pile 1 System includes Micropump 3, Micropump switch 2 and storage heater 4, and Micropump 3 is for controlling coolant liquid circulation, and Micropump 2 is for controlling Micropump 3 Switch, it further includes backup power source (not shown) that Micropump, which follows bad system, and backup power source is when pile 1 is closed, for mentioning to Micropump 3 For electric power, it is preferable that backup power source is lithium battery, and it is excellent that lithium battery has that specific energy is big, has extended cycle life, has a safety feature etc. Point;Storage heater 4 forms circulation for absorbing storage heat and release heat, pile 1, Micropump 3 and the connection of storage heater 4 Circuit.Storage heater 4 is separated structure, including first end 11, heating sheet 12 and the second end 13, first end 11 and the Two ends 13 clamp heating sheet 12 between, and first end 11 is connect with Micropump 3, the second end 13 and main cooling system Connection.First end 11 is equipped with the first split cavity 15 that the isolation of metal conducting strip 14 is formed, and the first split cavity 15 is filled with First phase-change material (not shown);The second split cavity that the second end 13 is formed equipped with the isolation of metal conducting strip 14, second point The second phase-change material is filled with from chamber.Preferably, the phase-change material that the first phase-change material is 70-80 DEG C of phase transition temperature;Second The phase-change material that phase-change material is 40-50 DEG C of phase transition temperature;Metal conducting strip material is copper;Heating sheet is PTC heating sheet.It is preferred that Ground, first end 11 are equipped with several metal conducting strips 14, and the isolation of the first separation chamber 15 is formed several regions;The second end 13 is set There are several metal conducting strips 14, the second separation chamber is isolated to form several regions.Phase-change material refer to it is temperature-resistant in the case where And change state of matter and the substance of latent heat can be provided, the process for changing physical property is known as phase transition process, at this moment phase-change material It will absorb or discharge a large amount of latent heat.
Main cooling system includes deionizater 6, intercooler 5, water pump 7, thermostat 8, radiator 9 and water supply tank 10, in it is cold Device 5 prevents high temperature coolant its role is to reduce the temperature of coolant liquid in main cooling system, the thermic load to reduce pile 1 Into pile 1, pile 1 is damaged;Deionizater 6 prevents ion from damaging pile 1 for removing deionization;It is cold based on water pump 7 But system circulation provides power, and coolant liquid is made to circulate through pile 1, cools down to pile 1;Thermostat 8 is according to coolant temperature Height automatic adjustment enter 9 radiators cooling liquid measure, change the range of DO of coolant liquid, with adjust main cooling system dissipate Thermal energy power guarantees that pile 1 works within the scope of suitable temperature;Radiator 9 is for giving coolant liquid radiating and cooling;When coolant liquid When temperature is lower, pile 1 and deionizater 6 and the foundation of intercooler 5 connect and compose circulation loop, pile 1 and deionizater 6, water Pump 7 and the foundation of thermostat 8 connect and compose circulation loop;When the temperature of coolant liquid is higher, pile 1 and deionizater 6, water pump 7, Thermostat 8 and the foundation of radiator 9 connect and compose circulation loop, are cooled down by radiator 9 to coolant liquid;When coolant liquid deficiency When, coolant liquid is supplemented by water supply tank 10, pile 1 and deionizater 6, water supply tank 10 and the foundation of radiator 9 connect and compose circulation Circuit.
In the present embodiment, the local circulation that the isolation of storage heater 4 that Micropump 4 and PTC are combined is formed, is operating normally In, system coolant liquid is recycled by water pump 7, due to lower, the first end of storage heater 4 by the temperature of intercooler 5 Portion 13 uses the lower 40-50 DEG C of phase change heat storage material of phase transition temperature, therefore can preferentially provide lower phase-transition heat-storage temperature; The second end 13 then uses 70-80 DEG C of phase-change material by Micropump 3;Micropump loop can be opened when 1 power of pile increases suddenly Circulation absorbs amount of heat equilibrium temperature using the material of the high phase transition temperature.After stack system is closed, if desired starting is protected Warm mode is then opened Micropump circulation according to Micropump switch 2 and is kept the temperature.Wherein heat storage device structure is as shown in Fig. 2, use Isolated phase change heat storage material, intermediate course are PTC heating sheet.Since the special separated structure is there are two heat exchange pipelines, To realize the operation of different mode.In the optimized copper metal conducting strip of disengagement chamber indoor deployment, may be implemented efficiently Heat release function is stored, section is as shown in figure 3, phase-change material is filled in gap.
In example 2, as shown in Figure 1, on the basis of example 1, Micropump cooling system further include controller (not Display), controller can intermittently starting Micropump 3;When battery SOC is lower than threshold power, controller closes Micropump 3.It is closed in pile 1 After closing, water pump is to close at this time, and when temperature is reduced to 5 degrees Celsius, 3 interval of Micropump that Micropump switch 2 opens low-power consumption is followed Ring, power source is standby lithium pond at this time.During pile operates normally, water pump 7 is open state, and power demand increases, can produce Heat amount, when 1 running temperature of pile is higher than 80 degrees Celsius, Micropump switch 2 opens Micropump 3, utilizes the phase transformation of heat storage device 4 Heat-storing material absorbs a large amount of heat equilibrium temperature, reduces pile damage.Controller is often electricity configuration, has time-wise separation From arousal function.When outdoor temperature is lower than 0 DEG C, system, which will be prompted to whether to start holding mode, starts the system, to be supplied to User selects to use.Controller intermittently starting Micropump when pile is lower than 5 DEG C operates, while considering A-battery SOC, if mistake Low, then preferential close guarantees other equipment operation, under holding mode, when stack temperature is no longer stable lower than 0 DEG C or increases When then system determine holding mode failure, close circulation Micropump guarantee electricity.In cold start-up, when stack temperature is higher than 0 degree, Water pump and Micropump circulating-heating pile are opened simultaneously, when stack temperature is lower than 0 degree, then opens PTC heating simultaneously.
In the present embodiment three, as shown in Figures 1 to 4, on the basis of embodiment one, two, when pile 1 is opened, detection The temperature of pile 1;Compare the temperature of pile 1 and the size of multiple threshold temperatures, multiple threshold temperatures include first threshold temperature, Second threshold temperature, first threshold temperature are greater than second threshold temperature;It is micro- when the temperature of pile 1 is higher than first threshold temperature Pump circulation system opens refrigerating mode, cools down to pile 1, while absorbing storage heat;When the temperature of pile 1 is lower than first threshold Temperature and be higher than second threshold temperature when, the Micropump circulatory system opens the temperature for stablizing pile 1;When the temperature of pile 1 is low In second threshold temperature and when no longer increasing, the Micropump circulatory system opens heating mode.When pile 1 is closed, detection pile 1 Temperature;Compare the temperature of pile 1 and the size of multiple threshold temperatures, multiple threshold temperatures include first threshold temperature, the second threshold It is worth temperature and third threshold temperature, first threshold temperature is greater than third threshold temperature, and third threshold temperature is greater than second threshold temperature Degree;When the temperature of pile 1 is higher than first threshold, the Micropump circulatory system opens refrigerating mode, cools down to pile 1, absorbs simultaneously Store heat;When the temperature of pile 1 is lower than first threshold temperature and is higher than third threshold temperature, the Micropump circulatory system is for steady Determine the temperature of pile 1;When the temperature of pile 1 is lower than third threshold temperature and is higher than second threshold temperature, the Micropump circulatory system Intermittently starting is used to stablize the temperature of pile 1;When the temperature of pile 1 is lower than second threshold temperature and no longer increases, Micropump is followed Loop system is closed.Preferably, first threshold temperature is 80 DEG C;Second threshold temperature is 0 DEG C;Third threshold temperature is 5 DEG C.Such as figure Shown in 4, the Micropump circulatory system is able to achieve heat preservation to pile 1 in varying environment temperature, and electricity can be kept under -10 DEG C of temperature Heap 1 maintained 5 DEG C more than 24 hours, and pile 1 can be kept to maintain 5 DEG C more than 8 hours, in -30 DEG C of gas under -20 DEG C of temperature 5 DEG C of the maintenance of pile 1 can be kept more than 5.5 hours under temperature.
It should be noted that above-described embodiment can be freely combined as needed.The above is only of the invention preferred Embodiment, it is noted that for those skilled in the art, in the premise for not departing from the principle of the invention Under, several improvements and modifications can also be made, these modifications and embellishments should also be considered as the scope of protection of the present invention.

Claims (8)

1. a kind of cold boot of fuel cell system with storage heater, including pile, the pile refers to a kind of energy conversion Device, and the main cooling system for cooling down the pile, it is characterised in that:
It further include the Micropump circulatory system for protecting mild heat to the pile, the Micropump circulatory system includes Micropump, standby With power supply and storage heater, the Micropump for controlling coolant liquid circulation, use when the pile is closed by the backup power source In providing electric power to the Micropump, the storage heater is the pile, described micro- for absorbing storage heat and release heat Pump and the storage heater connect to form the first circuit.
2. the cold boot of fuel cell system according to claim 1 with storage heater, it is characterised in that:
The storage heater is separated structure, including first end, heating sheet and the second end, the first end with it is described The second end by the heating sheet clamp between, the first end is connect with the Micropump, the second end and The main cooling system connection.
3. the cold boot of fuel cell system according to claim 2 with storage heater, it is characterised in that:
The first end is equipped with metal conducting strip and the first split cavity to be formed is isolated, and first split cavity is filled with phase The first phase-change material that temperature is 70-80 DEG C;
The second end is equipped with metal conducting strip and the second split cavity to be formed is isolated, and second split cavity is filled with phase The second phase-change material that temperature is 40-50 DEG C.
4. the cold boot of fuel cell system according to claim 3 with storage heater, it is characterised in that:
The first end is equipped with several metal conducting strips, is isolated first separation chamber to form several regions;
The second end is equipped with several metal conducting strips, is isolated second separation chamber to form several regions.
5. the cold boot of fuel cell system described according to claim 1~any one of 4 with storage heater, feature It is:
The main cooling system includes deionizater and intercooler, the first end of the deionizater, the storage heater And the intercooler is sequentially connected and is formed second branch, the second branch is attempted by the both ends of the pile.
6. the cold boot of fuel cell system according to claim 5 with storage heater, it is characterised in that:
The main cooling system further includes water pump, thermostat and radiator, the water pump, the thermostat and the radiator according to Secondary connection simultaneously forms third branch, and water pump is connected to the deionizater far from one end of the thermostat in the third branch One end far from the pile, radiator is connected to the one end of the pile far from the deionizater in the third branch.
7. the cold boot of fuel cell system according to claim 6 with storage heater, it is characterised in that:
The main cooling system further includes water supply tank, and the water supply tank, the radiator, the thermostat and the water pump are successively It connects and forms series loop.
8. the cold boot of fuel cell system described according to claim 1~any one of 4 with storage heater, feature It is:
Micropump switch is serially connected in the control terminal of the Micropump, the Micropump switch is also connect with the pile.
CN201920146192.5U 2019-01-28 2019-01-28 A kind of cold boot of fuel cell system with storage heater Active CN209374566U (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110931829A (en) * 2019-12-06 2020-03-27 吉林大学 Fuel cell cold start system with purging device and control method
CN111799485A (en) * 2020-06-15 2020-10-20 武汉格罗夫氢能汽车有限公司 Hydrogen fuel cell low-temperature starting system and heating method thereof
CN113506891A (en) * 2021-08-06 2021-10-15 大连海事大学 Modularized solid oxide fuel cell system
CN115000461A (en) * 2022-06-10 2022-09-02 中国第一汽车股份有限公司 Hydrogen fuel cell stack cold start system and low-temperature cold start control method
CN111799485B (en) * 2020-06-15 2024-05-10 武汉格罗夫氢能汽车有限公司 Hydrogen fuel cell low-temperature starting system and heating method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110931829A (en) * 2019-12-06 2020-03-27 吉林大学 Fuel cell cold start system with purging device and control method
CN111799485A (en) * 2020-06-15 2020-10-20 武汉格罗夫氢能汽车有限公司 Hydrogen fuel cell low-temperature starting system and heating method thereof
CN111799485B (en) * 2020-06-15 2024-05-10 武汉格罗夫氢能汽车有限公司 Hydrogen fuel cell low-temperature starting system and heating method thereof
CN113506891A (en) * 2021-08-06 2021-10-15 大连海事大学 Modularized solid oxide fuel cell system
CN115000461A (en) * 2022-06-10 2022-09-02 中国第一汽车股份有限公司 Hydrogen fuel cell stack cold start system and low-temperature cold start control method

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