CN207673375U - Heat chemistry heat accumulation hot electron power generation device - Google Patents

Heat chemistry heat accumulation hot electron power generation device Download PDF

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Publication number
CN207673375U
CN207673375U CN201721827297.4U CN201721827297U CN207673375U CN 207673375 U CN207673375 U CN 207673375U CN 201721827297 U CN201721827297 U CN 201721827297U CN 207673375 U CN207673375 U CN 207673375U
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China
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heat
power generation
hot electron
electron power
heat accumulation
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CN201721827297.4U
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肖刚
郑光华
倪明江
骆仲泱
岑可法
程乐鸣
高翔
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Zhejiang University ZJU
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Zhejiang University ZJU
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/40Solar thermal energy, e.g. solar towers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/14Combined heat and power generation [CHP]

Abstract

The utility model belongs to photo-thermal power generation technical field, specifically provides a kind of heat chemistry heat accumulation hot electron power generation device.The utility model aims to solve the problem that the generating efficiency of existing hot electron power generation device is highly susceptible to the problem of intensity of solar radiation influences.The hot electron power generation device of the utility model includes hot electron power generation component and the heat accumulation component being connected with hot electron power generation component;Wherein, hot electron power generation component can be converted solar energy into electrical energy and be exported, heat accumulation component includes the heat chemistry heat accumulation element of shell and receiving in the shell, heat chemistry heat accumulation element can absorb solar radiation, and convert solar energy into chemical energy storage, when the intensity of solar radiation changes, heat accumulation component can carry out heat exchange with hot electron power generation component, to stablize the operating temperature of hot electron power generation component, electric energy can be steadily exported so that heat chemistry heat accumulation hot electron power generation device is effectively ensured, and then effectively stablize the generating efficiency of heat chemistry heat accumulation hot electron power generation device.

Description

Heat chemistry heat accumulation hot electron power generation device
Technical field
The utility model belongs to photo-thermal power generation technical field, specifically provides a kind of heat chemistry heat accumulation hot electron power generation device.
Background technology
With science and technology be constantly progressive and the continuous consumption of earth resource, people start to be keen to study it is various can The utilization method of regenerated resources;Wherein, solar energy is all the time as neutral carbon regenerative resource most abundant on the earth The research emphasis of renewable energy utilization technology.Normally, existing solar light-heat power-generation technology is all to first pass through optical collector to connect Solar radiation is received, then thermo-electric converting device is recycled to convert solar energy into electrical energy.Meanwhile not according to heat to electricity conversion mode Together, existing solar light-heat power-generation technology is broadly divided into conventional heat power generation technology, thermoelectric generation and thermoelectron Three kinds of generation technology.
Further, conventional heat power generation technology is turned by converting solar energy into mechanical energy, then by mechanical energy Electric energy is turned to realize power generation, includes mainly Stirling cycle generation technology, Rankine cycle generation technology and Brayton cycle Three kinds of generation modes of generation technology.And hot electron power generation technology is mainly used as energy transmission by the electronics that solar energy inspires Medium converts solar energy into electrical energy, hot electron power generation technology not only have it is good continue generating capacity, and it is sending out Static exercise only need to be carried out in electric process, therefore, power generation can be realized without moving component in hot electron power generation technology.In thermoelectron In generation technology, electronics producing method, which includes mainly thermal induction thermionic emission technology and photon, enhances thermionic emission technology Two kinds.
Specifically, thermal induction thermionic emission technology can directly absorb the solar radiation of focusing and be translated into heat It can so that the free electron in cathode is concurrently incident upon in vacuum through thermalization effusion cathode surface, finally overcomes space charge barrier It is received by the anode of neighbour, to convert solar energy into electrical energy.Compared with thermal induction electron emitting technology, photon enhances thermoelectricity Sub- lift-off technology can then carry out solar radiation more efficient utilize;Further, photon enhances thermionic emission technology The super bandgap photonic in solar radiation can be absorbed to generate light induced electron with semiconductor, meanwhile, in solar radiation Excess energy and sub-bandgap photon can also be thermal energy by sorption enhanced, so as to thermalized electron and it be made to escape throwing from cathode surface It is incident upon anode.But the utilization of existing photon enhancing thermionic emission technology still has having disadvantages that;For example, existing power generation Device is highly susceptible to the influence of intensity of solar radiation when being generated electricity with photon enhancing thermionic emission technology;Change speech It, the temperature of cathode and anode is highly susceptible to the influence of intensity of solar radiation in existing photon enhancing hot electron power generation device, To the generation of electronics, transport and reception impacts, and then seriously affect electric energy stablizes output.
Correspondingly, this field needs a kind of new heat chemistry heat accumulation hot electron power generation device to solve the above problems.
Utility model content
In order to solve the above problem in the prior art, in order to solve the generating efficiency of existing hot electron power generation device very The problem of being easy to be influenced by intensity of solar radiation, the utility model provides a kind of heat chemistry heat accumulation hot electron power generation device, The heat chemistry heat accumulation hot electron power generation device includes hot electron power generation component and is connected with the hot electron power generation component Heat chemistry heat accumulation element;The hot electron power generation component can convert heat into electric energy;The heat chemistry heat accumulation element is used for Thermal energy is stored, and heat exchange is carried out with the hot electron power generation component, in order to stabilize the work of the hot electron power generation component Temperature.
In the optimal technical scheme of above-mentioned heat chemistry heat accumulation hot electron power generation device, set on the heat chemistry heat accumulation element It is equipped with multiple through-holes in array distribution;And the hot electron power generation component is embedded in the through-hole.
In the optimal technical scheme of above-mentioned heat chemistry heat accumulation hot electron power generation device, the heat chemistry heat accumulation element is by resistance to High-temperature metal and heat chemistry heat accumulating are made.
In the optimal technical scheme of above-mentioned heat chemistry heat accumulation hot electron power generation device, the hot electron power generation component includes Cathode and anode;The cathode is connected with the through-hole, and the cathode can be by absorbing the heat chemistry heat accumulation element In heat to the anode discharge thermoelectron.
In the optimal technical scheme of above-mentioned heat chemistry heat accumulation hot electron power generation device, the cathode is sleeve structure, and And the size of the cathode and the size of the through-hole match.
In the optimal technical scheme of above-mentioned heat chemistry heat accumulation hot electron power generation device, the hot electron power generation component also wraps Include sealing element;The sealing element, the cathode and the anode are formed with confined space, and the confined space is vacuum, And store caesium steam and/or barium steam.
In the optimal technical scheme of above-mentioned heat chemistry heat accumulation hot electron power generation device, the heat chemistry heat accumulation thermoelectron hair Electric installation further includes heat producing element;The heat producing element is connected with the heat chemistry heat accumulation element, for being stored up to the heat chemistry Thermal element provides heat.
In the optimal technical scheme of above-mentioned heat chemistry heat accumulation hot electron power generation device, the heat producing element is nuclear reactor Fuel rod;Or the heat producing element includes combustion chamber, the combustion chamber is used for combustion of fossil fuels.
In the optimal technical scheme of above-mentioned heat chemistry heat accumulation hot electron power generation device, the heat chemistry heat accumulation thermoelectron hair Electric installation further includes concentrating component;The concentrating component can assemble solar radiation to the heat chemistry heat accumulation element;It is described Concentrating component is at least one of Fresnel optical collector, slot-type optical collector, dish-style concentrator and tower concentrator.
In the optimal technical scheme of above-mentioned heat chemistry heat accumulation hot electron power generation device, the heat chemistry heat accumulation thermoelectron hair Electric installation further includes thermodynamic cycle electrification component;The thermodynamic cycle electrification component and the hot electron power generation component and the heat Chemical heat storage element is connected, and the thermodynamic cycle electrification component can convert heat into electric energy;The thermodynamic cycle hair Electrical component is Stirling cycle generator and/or Brayton cycle generator.
It will be appreciated to those of skill in the art that in the optimal technical scheme of the utility model, the utility model Heat chemistry heat accumulation hot electron power generation device includes hot electron power generation component and the thermalization that is connected with the hot electron power generation component Learn heat accumulation element;Wherein, the hot electron power generation component can convert heat into electric energy and export, the heat chemistry heat accumulation member Part can convert solar energy into chemical energy storage, when the intensity of solar radiation changes, the heat chemistry heat accumulation element Heat exchange can be carried out with the hot electron power generation component, to effectively stablize the operating temperature of the hot electron power generation component, And then dramatically ensure that the hot electron power generation component can steadily export electric energy;Meanwhile the heat chemistry heat accumulation heat Electronics power generator further includes thermodynamic cycle electrification component, the thermodynamic cycle electrification component and the hot electron power generation component phase Even, so that the heat generated when the hot electron power generation component generates electricity is again converted to electric energy, to realize the step of the energy It utilizes, and then farthest improves the generating efficiency of the heat chemistry heat accumulation hot electron power generation device.
Description of the drawings
Fig. 1 is the first signal of the first preferred embodiment of the heat chemistry heat accumulation hot electron power generation device of the utility model Figure;
Fig. 2 is the second signal of the first preferred embodiment of the heat chemistry heat accumulation hot electron power generation device of the utility model Figure;
Fig. 3 is the structural representation of the second preferred embodiment of the heat chemistry heat accumulation hot electron power generation device of the utility model Figure;
Fig. 4 is the structural representation of the third preferred embodiment of the heat chemistry heat accumulation hot electron power generation device of the utility model Figure;
Fig. 5 is that the thermodynamic cycle electrification component of the heat chemistry heat accumulation hot electron power generation device of the utility model joins for Bretton Close structural schematic diagram when circulation electric generating apparatus;
Fig. 6 is that the thermodynamic cycle electrification component of the heat chemistry heat accumulation hot electron power generation device of the utility model joins for Stirling Close structural schematic diagram when circulation electric generating apparatus.
Description of the drawings:1, shell;2, heat chemistry heat accumulation element;3, cathode;4, anode;5, turbine;6, generator;7, it compresses Machine;8, reheater;9, expansion chamber;10, compression chamber;11, cooler;12, regenerator;13, nuclear reactor fuel rod;14, it burns Room.
Specific implementation mode
Two kinds of preferred embodiments of the utility model are described with reference to the accompanying drawings.It should be understood by those skilled in the art that , these embodiments be used only for explain the utility model technical principle, it is not intended that limit the guarantor of the utility model Protect range.Those skilled in the art can as needed make adjustment to it, to adapt to specific application scenario.For example, to the greatest extent The each element for managing heat chemistry heat accumulation hot electron power generation device described in the specification all has scheduled shape and structure, but It is that these elements are obviously also configured to other shapes and structure, as long as the element can complete predetermined function.This The change of kind of component shape and structure therefore falls within the guarantor of the utility model without departing from the basic principle of the utility model Within the scope of shield.
It should be noted that in the description of the present invention, term "upper", "lower", "left", "right", "front", "rear", The term in direction or position relationship that "inner", "outside" etc. are used to indicate is direction based on ... shown in the drawings or position relationship, this is only It is merely for convenience of describing, rather than indicates or imply that described device or element must have a particular orientation, with specific side Position construction and operation, therefore should not be understood as limiting the present invention.In addition, term " first ", " second " are only used for retouching Purpose is stated, relative importance is not understood to indicate or imply.
In addition it is also necessary to explanation, in the description of the present invention, unless otherwise clearly defined and limited, art Language " connected ", " connection ", " connection " etc. indicate that the word of connection relation all shall be understood in a broad sense, for example, it may be fixedly connected, Can be detachably connected, or be integrally connected;It can be mechanical connection, can also be electrical connection;It can be direct phase It even, can also indirectly connected through an intermediary or the connection inside two elements.For those skilled in the art Speech, can understand the concrete meaning of above-mentioned term in the present invention as the case may be.
It is strong that generating efficiency based on the existing hot electron power generation device proposed in background technology is highly susceptible to solar radiation The problem of degree influences;Specifically, in existing photon enhances hot electron power generation device, the power generator can use semiconductor The super bandgap photonic in solar radiation is absorbed, to generate light induced electron;Meanwhile the excess energy in solar radiation can also be by Power generator sorption enhanced be thermal energy, and then thermalized electron and make its from cathode surface effusion be projected to anode.But existing light Son enhancing hot electron power generation device is during using or tool has disadvantages that;For example, the power generator is with photon Enhancing thermionic emission technology is highly susceptible to the influence of intensity of solar radiation when being generated electricity;Further, solar radiation Intensity can influence the temperature of cathode and anode in power generator, to the generation of light induced electron, transport and reception impacts, And then it seriously affects stablizing for electric energy and exports.In order to solve the above problem in the prior art, the utility model provides one kind New heat chemistry heat accumulation hot electron power generation device, the heat chemistry heat accumulation hot electron power generation device include hot electron power generation component with And the heat chemistry heat accumulation element being connected with the hot electron power generation component;Wherein, the hot electron power generation component can be by thermal energy It is converted into electric energy and exports, the heat chemistry heat accumulation element can convert solar energy into chemical energy storage, when solar radiation When intensity changes, the heat chemistry heat accumulation element can carry out heat exchange with the hot electron power generation component, to effectively Stablize the operating temperature of the hot electron power generation component, and then dramatically ensures the heat chemistry heat accumulation hot electron power generation dress Electric energy can steadily be exported by setting.
First preferred realities of the Fig. 1 and Fig. 2 to the heat chemistry heat accumulation hot electron power generation device of the utility model is first combined below It applies the structure of example and is illustrated using process;Wherein, Fig. 1 is the heat chemistry heat accumulation hot electron power generation device of the utility model First schematic diagram of first preferred embodiment, Fig. 2 are the first excellent of the heat chemistry heat accumulation hot electron power generation device of the utility model Select the second schematic diagram of embodiment.Specifically, the heat chemistry heat accumulation hot electron power generation device of the utility model includes thermoelectron hair Electrical component and the heat chemistry heat accumulation element 2 being connected with the hot electron power generation component.The hot electron power generation component can incite somebody to action Thermal energy is converted into electric energy, can be produced electricl energy to which the heat chemistry heat accumulation hot electron power generation device be effectively ensured;Meanwhile thermalization Chemical energy storage, when the intensity of solar radiation changes, heat chemistry heat accumulation can be converted solar energy by learning heat accumulation element 2 Element 2 can carry out heat exchange with the hot electron power generation component so that the operating temperature of the hot electron power generation component is able to Stablize, to effectively avoid the generating efficiency of existing hot electron power generation device from being highly susceptible to asking for intensity of solar radiation influence Topic, and then dramatically ensure that the heat chemistry heat accumulation hot electron power generation device can steadily export electric energy.
Further, as illustrated in fig. 1 and 2, first in the heat chemistry heat accumulation hot electron power generation device of the utility model is excellent It selects in embodiment, heat chemistry heat accumulation element 2 can absorb solar radiation so that the temperature of itself is enhanced, so as to by solar energy It is converted into chemical energy storage.Meanwhile the chemical energy that heat chemistry heat accumulation element 2 stores can generate heat by reversible reaction, and The hot electron power generation component is passed in a manner of heat transfer and thermal convection current, to effectively stablize the hot electron power generation component Operating temperature.Specifically, heat chemistry heat accumulation element 2 is using refractory metal as matrix, and compound thermal chemical heat storage material and It is made;It should be noted that different chemical reactions can occur under different temperature conditions for heat chemistry heat accumulating, to The effect for realizing neither endothermic nor exothermic, effectively to stablize the temperature of the hot electron power generation component.
Specifically, when solar radiation abundance, largely heat absorption makes own temperature constantly carry to heat chemistry heat accumulation element 2 Height, when the temperature of heat chemistry heat accumulation element 2 is increased to above the reaction equilibrium temperature of internal heat chemistry heat accumulating, thermalization The endothermic reaction will be occurred by learning heat accumulating, and then be that the chemical energy of itself stores by extra converting heat, to have Effect stablizes the temperature of heat chemistry heat accumulation element 2.In addition, when solar radiation deficiency, heat chemistry heat accumulation element 2 needs constantly to institute It states hot electron power generation component and heat is provided, constantly reduced so as to cause own temperature, when the temperature of heat chemistry heat accumulation element 2 reduces When to the reaction equilibrium temperature for being less than internal heat chemistry heat accumulating, it is anti-that with air heat release will occur for heat chemistry heat accumulating It answers, is released to convert the chemical energy of itself storage to thermal energy, further effectively to stablize heat chemistry heat accumulation element 2 Temperature, and then effectively stablize the operating temperature of the hot electron power generation component, dramatically to stablize the heat chemistry The output power of heat accumulation hot electron power generation device.
It will be appreciated to those of skill in the art that preferably, heat chemistry heat accumulation element 2 is using tungsten as matrix, combined oxidation Copper is formed through high temperature sintering;Certainly, heat chemistry heat accumulation element 2 can also be made of other materials, for example, refractory metal can be with Select tungsten, molybdenum, niobium etc.;Heat chemistry heat accumulating can select cobalt oxide, copper oxide, manganese oxide etc..With heat chemistry heat accumulation element 2 For being made of tungsten and copper oxide, in the case of solar radiation abundance, heat chemistry heat accumulation element 2 largely absorbs heat so that thermalization The temperature for learning heat accumulation element 2 constantly increases, when the temperature of the copper oxide in heat chemistry heat accumulation element 2 reaches 1100 DEG C, oxidation Copper occurs the endothermic reaction and is decomposed into cuprous oxide and oxygen, to maintain the temperature-resistant of heat chemistry heat accumulation element 2, and will be more Remaining converting heat is that the chemical energy of itself stores, to effectively stablize the operating temperature of heat chemistry heat accumulation element 2.Too In the case of sun radiation is insufficient, heat chemistry heat accumulation element 2 needs constantly to provide heat to the hot electron power generation component, to lead The temperature of cuprous oxide in pyrogenicity chemical heat storage element 2 constantly reduces, when the temperature of cuprous oxide is less than 1100 DEG C, oxidation The cuprous oxygen with air occurs exothermic reaction and recombines copper oxide, to convert the chemical energy of itself storage to heat It can release, effectively to stablize the temperature of heat chemistry heat accumulation element 2, and then effectively stablize the hot electron power generation component Operating temperature, dramatically to stablize the output power of the heat chemistry heat accumulation hot electron power generation device.
With continued reference to Fig. 1 and Fig. 2, further, the heat chemistry heat accumulation hot electron power generation device further includes shell 1, outside Shell 1 is located at the outside of heat chemistry heat accumulation element 2, and shell 1 is made of heat-resisting material, when heat chemistry heat accumulation element 2 is grown When time reaches reaction equilibrium temperature, oxidation reaction will not occur for shell 1.Meanwhile shell 1 can also generate solar radiation Heat quickly pass to heat chemistry heat accumulation element 2, so as to heat chemistry heat accumulation element 2 be capable of efficient absorption solar radiation generate Heat;In addition, shell 1 can also effectively avoid heat chemistry heat accumulation element 2 that unnecessary chemical reaction occurs with outside air, with Just the energy expenditure of the heat chemistry heat accumulation hot electron power generation device is farthest reduced.Skilled artisans appreciate that Be, it is preferable that shell 1 is made of ZG40Cr28Ni48W5Si2 alloys.
Specifically, in the first preferred embodiment of the utility model, it is in battle array to be provided on heat chemistry heat accumulation element 2 multiple The through-hole of column distribution, the hot electron power generation component are embedded in the through-hole, to farthest increase the thermoelectron The contact area of electrification component and heat chemistry heat accumulation element 2, so that the hot electron power generation component can be stored up with heat chemistry Thermal element 2 carries out sufficient heat exchange.It is understood that the quantity and distribution mode of the through-hole can be by technical staff's roots Factually border use demand sets itself.Preferably, the surface of the hot electron power generation component is coated with the nitrogen with high thermal conductivity coefficient Change boron ceramic material, so that the hot electron power generation component can be connect by boron nitride ceramics and heat chemistry heat accumulation element 2 It touches, to which the heat exchange between the hot electron power generation component and heat chemistry heat accumulation element 2 further be effectively ensured.This field skill Art personnel, it is understood that preferably, the size for the multiple through-holes being arranged on heat chemistry heat accumulation element 2 is identical, and The through-hole is evenly provided on heat chemistry heat accumulation element 2, so that identical thermoelectron can be arranged in the through-hole Electrification component, meanwhile, the multiple hot electron power generation component can also be evenly provided on heat chemistry heat accumulation element 2, to The multiple hot electron power generation component, which is effectively ensured, can generate identical output current, and then farthest reduce due to string Join resistance and caused by electric energy loss, to effectively improve electric energy output.
Referring next to Fig. 1 and Fig. 2, further, the hot electron power generation component includes cathode 3 and anode 4;Wherein, institute It states hot electron power generation component to be in contact with the through-hole by cathode 3, so that the hot electron power generation component can pass through cathode 3 Sufficient heat exchange is carried out with heat chemistry heat accumulation element 2.Preferably, cathode 3 is sleeve structure, and the size of cathode 3 and institute The size for stating through-hole matches, so that cathode 3 can come into full contact with heat chemistry heat accumulation element 2;Anode 4 is preferably entity Cylinder, and cathode 3 can be set in the outside of anode 4, so that the thermoelectron that cathode 3 generates can be quickly by anode 4 It absorbs, to dramatically improve the power generation rate of the heat chemistry heat accumulation hot electron power generation device.Meanwhile cathode 3 with sun It is provided with predetermined space between pole 4;It is understood that preferably, the predetermined gap setting between cathode 3 and anode 4 is micro- 1 Rice can rapidly move near anode 4 between 100 microns so that the electronics escaped in cathode 3 is effectively ensured;Further Preferably, it is connected and sealed by the way of crunch seal between cathode 3 and anode 4.In addition it is also necessary to which explanation, cloudy The concrete numerical value of predetermined gap between pole 3 and anode 4 also needs to technical staff according to actual product demand sets itself.Ability What field technique personnel were also understood that is, it is preferable that cathode 3 is made of barium tungsten alloy, oxide or scandate;Anode 4 is by half Conductor material or metal with low work function are made, such as molybdenum, nickel etc.;Certainly, technical staff can also be according to actually making The material of cathode 3 and anode 4 is voluntarily selected with demand.
In addition, the hot electron power generation component further includes the sealing element being arranged in 4 upper and lower ends of cathode 3 and anode, need It is noted that showing the concrete structure of other elements for convenience, sealing element is not shown in fig. 1 and 2.Due to setting It can be connected respectively with the both ends of cathode 3 and anode 4 in two sealing elements of upper and lower ends, meanwhile, and due to cathode 3 and sun Predetermined gap is provided between pole 4, therefore, the sealing element, cathode 3 and anode 4 can form an annular confined air Between.Preferably, caesium steam and/or barium steam are stored in the confined space;On the one hand, these steams can effectively reduce the moon The work function of pole 3 and anode 4 so that the electronics in cathode 3 can be more prone to escape from surface;On the other hand, these steams The space charge barrier between cathode 3 and anode 4 can also be effectively reduced, so that the electronics escaped in cathode 3 can be easier It moves in anode 4.Furthermore, it is necessary to explanation, the sealing element can be one, can also be spliced by multiple sealing elements Integral sealing element.
It is further preferred that the heat chemistry heat accumulation hot electron power generation device further includes concentrating component (not shown), The hot electron power generation component and heat chemistry heat accumulation element 2 are placed in the focal plane of the concentrating component, so as to the optically focused Component can assemble solar radiation to shell 1 so that heat chemistry heat accumulation element 2 can absorb more heats by shell 1. Meanwhile it will be appreciated to those of skill in the art that preferably, the concentrating component be Fresnel optical collector, slot-type optical collector, At least one of dish-style concentrator and tower concentrator;It should be noted that when the concentrating component be tower concentrator or When dish-style concentrator, technical staff may be used the mode foucusing solar radiation of an optically focused and be assembled to shell 1;This Outside, technical staff can also use the spot mode of secondary reflection.Certainly, technical staff can also be according to actual use situation certainly The selected concentrating component of row.
Then Fig. 1 is combined to carry out specifically the power generation process of the heat chemistry heat accumulation hot electron power generation device of the utility model Bright, when solar radiation exposes to shell 1, shell 1 transfers heat to heat chemistry heat accumulation element 2 so that heat chemistry heat accumulation member The temperature of part 2 constantly increases, meanwhile, heat chemistry heat accumulation element 2 can transfer heat to the moon of the hot electron power generation component Pole 3, at this point, the temperature of cathode 3 is also continuously improved so that the electronics in the conduction band of cathode 3 is by continuous thermalization, when electron institute has Energy be more than cathode work function number when, electronics from the surface of cathode 3 escape, meanwhile, under the action of faint built in field, from The electronics of the surface effusion of cathode 3 can be projected near anode 4, absorbed by anode 4, then come back to the expense of anode 4 On rice energy level, to produce electricl energy.In addition, when the intensity deficiency of solar radiation, heat chemistry heat accumulation element 2 can also be put Thermal response, to effectively stablize the operating temperature of cathode 3 so that cathode 3 can continuously generate electronics, and then effectively protect Demonstrate,prove the lasting generation of electric energy.
Still further preferably, the heat chemistry heat accumulation hot electron power generation device further includes thermodynamic cycle electrification component;Institute It states thermodynamic cycle electrification component with the hot electron power generation component and heat chemistry heat accumulation element 2 to be connected, and the thermodynamic cycle Electrification component can convert heat into electric energy.Specifically, the part energy in cathode 3 conducted by way of heat radiation to Anode 4;Meanwhile another part energy in cathode 3 is then by way of electronics condensation by energy conduction to anode 4, and then promote Make the temperature rise of anode 4.In addition, heat chemistry heat accumulation element 2 also can constantly absorb heat by solar radiation;Therefore, will The thermodynamic cycle electrification component is connected with the hot electron power generation component and heat chemistry heat accumulation element 2, and in the heating power Heat-exchange working medium is stored in circulating generation component so that the thermodynamic cycle electrification component can pass through heat-exchange working medium and the thermoelectricity Sub- electrification component and heat chemistry heat accumulation element 2 exchange heat.On the one hand, these heat-exchange working mediums can take heat out of, to effectively The temperature of anode 4 is reduced, and then effectively improves the generating efficiency of the hot electron power generation component;On the other hand, the heat chemistry These converting heats can also be electric energy by thermodynamic cycle electrification component by heat accumulation hot electron power generation device, to utmostly Improve the generating efficiency of the heat chemistry heat accumulation hot electron power generation device in ground.Preferably, the thermodynamic cycle electrification component is this Special woods circulating generator and/or Brayton cycle generator, certainly, technical staff can also voluntarily be selected according to actual use situation Determine thermodynamic cycle electrification component.
Referring next to Fig. 3, which is the second preferred implementation of the heat chemistry heat accumulation hot electron power generation device of the utility model The structural schematic diagram of example;As shown in figure 3, heat chemistry heat accumulation hot electron power generation device described in the second preferred embodiment has the All elements in one preferred embodiment are still filled with the heat chemistry heat accumulation hot electron power generation described in first preferred embodiment Unlike setting, in second preferred embodiment of the utility model, the heat chemistry heat accumulation hot electron power generation device further includes Nuclear reactor fuel rod 13 in heat chemistry heat accumulation element 2 is set.Further, when storing in heat chemistry heat accumulation element 2 When shortage of heat, heat can be generated by nuclear reaction occurs by being stored in the nuclear fuel inside nuclear reactor fuel rod 13, from And heat chemistry heat accumulation element 2 is heated so that the temperature of heat chemistry heat accumulation element 2 is effectively ensured, so as to further The temperature of cathode 3 is effectively ensured, so that the hot electron power generation component can continue to generate electricity.Those skilled in the art can Understand, technical staff can be according to the installation position of actual use demand sets itself nuclear reactor fuel rod 13.
Referring next to Fig. 4, which is that the third of the heat chemistry heat accumulation hot electron power generation device of the utility model is preferably implemented The structural schematic diagram of example;As shown in figure 4, heat chemistry heat accumulation hot electron power generation device described in third preferred embodiment has the All elements in one preferred embodiment are still filled with the heat chemistry heat accumulation hot electron power generation described in first preferred embodiment Unlike setting, in the third preferred embodiment of the utility model, the heat chemistry heat accumulation hot electron power generation device further includes The toroidal combustion chamber 14 being set in outside shell 1.Further, when the shortage of heat stored in heat chemistry heat accumulation element 2, combustion Heat can be generated with combustion of fossil fuels by burning in room 14, to heat to heat chemistry heat accumulation element 2 so that heat chemistry is stored up The temperature of thermal element 2 is effectively ensured, so that the temperature of cathode 3 is further effectively ensured, so that the thermoelectron is sent out Electrical component can continue to generate electricity.It is understood that technical staff can be according to actual use demand sets itself combustion chamber 14 Shape and installation position.
Referring next to Fig. 5, which is the thermodynamic cycle power generation of the heat chemistry heat accumulation hot electron power generation device of the utility model Structural schematic diagram when component is Bretton combined cycle generating unit;It below will be using the thermodynamic cycle electrification component as mine-laying Cogeneration process is illustrated for when combined cycle generating unit.As shown in figure 5, specifically, the Bretton Combined cycle generating unit includes turbine 5, generator 6, compressor 7 and reheater 8.Preferably, changing in the power generator Hot working fluid is air, can absorb heat when air flows through the hot electron power generation component and heat chemistry heat accumulation element 2, make it Own temperature is improved to 900-1100 DEG C, and the air after heating flows through turbine 5, is then constantly done work by turbine 5 so that power generation Machine 6 constantly produces electricl energy;Finally, air enters in compressor 7 and is compressed, then so that air passes through reheater 8 and room temperature Air carries out heat exchange, and later, air carries out hot friendship again by the hot electron power generation component and heat chemistry heat accumulation element 2 It changes, to complete entire cyclic process, realizes lasting power generation.
Referring next to Fig. 6, which is the thermodynamic cycle power generation of the heat chemistry heat accumulation hot electron power generation device of the utility model Structural schematic diagram when component is Stirling combined cycle generating unit;To be below that this is special with the thermodynamic cycle electrification component Cogeneration process is illustrated for when woods combined cycle generating unit.As shown in fig. 6, specifically, the Stirling Combined cycle generating unit includes expansion chamber 9, compression chamber 10, cooler 11 and regenerator 12, wherein the hot electron power generation group The left end of part and heat chemistry heat accumulation element 2 is connected with regenerator 12, the hot electron power generation component and heat chemistry heat accumulation element 2 Right end be connected with expansion chamber 9.Preferably, the heat-exchange working medium in the Stirling cycle power generator is air, air energy Enough constantly to carry out heat exchange with the hot electron power generation component and heat chemistry heat accumulation element 2, then air is in expansion chamber 9, institute It states and is vibrated back and forth in hot electron power generation component and heat chemistry heat accumulation element 2, regenerator 12, cooler 11 and compression chamber 10, together When constantly inhale heat release, and then piston is pushed to move back and forth so that external generator constantly produces electricl energy.Further, work as sky Through the hot electron power generation component and when heat chemistry heat accumulation element 2, the temperature of the anode 4 of the hot electron power generation component obtains air-flow Lower to effective, to dramatically improve thermionic generation efficiency, meanwhile, the temperature of air is also promoted, so Air flows through regenerator 12 and enters back into cooler 11 and compression chamber 10 afterwards, to push piston to do work;Preferably, cooler 11 Wall surface temperature be 50-100 DEG C, the air after heat release again flows through the hot electron power generation component and heat after regenerator 12 Chemical heat storage element, meanwhile, it pushes the acting of the piston in expansion chamber 9 and produces electricl energy.Skilled artisans appreciate that It is, it is preferable that the frequency of oscillation of entire Stirling cycle is maintained at 25-50Hz.
So far, it has been combined attached drawing and describes the technical solution of the utility model, still, those skilled in the art are easy reason Solution, the scope of protection of the utility model are expressly not limited to these specific implementation modes.Without departing from the utility model Under the premise of principle, those skilled in the art can make the relevant technologies feature equivalent change or replacement, these change or Technical solution after replacement is fallen within the scope of protection of the utility model.

Claims (10)

1. a kind of heat chemistry heat accumulation hot electron power generation device, which is characterized in that the heat chemistry heat accumulation hot electron power generation device packet The heat chemistry heat accumulation element for including hot electron power generation component and being connected with the hot electron power generation component;
The hot electron power generation component can convert heat into electric energy;
The heat chemistry heat accumulation element carries out heat exchange for storing thermal energy, and with the hot electron power generation component, so as to steady The operating temperature of the fixed hot electron power generation component.
2. heat chemistry heat accumulation hot electron power generation device according to claim 1, which is characterized in that the heat chemistry heat accumulation member Multiple through-holes in array distribution are provided on part;And
The hot electron power generation component is embedded in the through-hole.
3. heat chemistry heat accumulation hot electron power generation device according to claim 2, which is characterized in that the heat chemistry heat accumulation member Part is made of refractory metal and heat chemistry heat accumulating.
4. heat chemistry heat accumulation hot electron power generation device according to claim 2, which is characterized in that the hot electron power generation group Part includes cathode and anode;
The cathode is connected with the through-hole, and the cathode can be by absorbing the heat in the heat chemistry heat accumulation element Thermoelectron is discharged to the anode.
5. heat chemistry heat accumulation hot electron power generation device according to claim 4, which is characterized in that the cathode is casing knot Structure, and
The size of the cathode and the size of the through-hole match.
6. heat chemistry heat accumulation hot electron power generation device according to claim 4, which is characterized in that the hot electron power generation group Part further includes sealing element;
The sealing element, the cathode and the anode are formed with confined space, and the confined space is vacuum, and is stored There are caesium steam and/or barium steam.
7. the heat chemistry heat accumulation hot electron power generation device according to any one of claim 1-6, which is characterized in that the heat Chemical heat storage hot electron power generation device further includes heat producing element;
The heat producing element is connected with the heat chemistry heat accumulation element, for providing heat to the heat chemistry heat accumulation element.
8. heat chemistry heat accumulation hot electron power generation device according to claim 7, which is characterized in that the heat producing element is core Reactor fuel rod;Or
The heat producing element includes combustion chamber, and the combustion chamber is used for combustion of fossil fuels.
9. the heat chemistry heat accumulation hot electron power generation device according to any one of claim 1-6, which is characterized in that the heat Chemical heat storage hot electron power generation device further includes concentrating component;
The concentrating component can assemble solar radiation to the heat chemistry heat accumulation element;
The concentrating component is at least one of Fresnel optical collector, slot-type optical collector, dish-style concentrator and tower concentrator.
10. the heat chemistry heat accumulation hot electron power generation device according to any one of claim 1-6, which is characterized in that described Heat chemistry heat accumulation hot electron power generation device further includes thermodynamic cycle electrification component;
The thermodynamic cycle electrification component is connected with the hot electron power generation component and the heat chemistry heat accumulation element, and described Thermodynamic cycle electrification component can convert heat into electric energy;
The thermodynamic cycle electrification component is Stirling cycle generator and/or Brayton cycle generator.
CN201721827297.4U 2017-12-22 2017-12-22 Heat chemistry heat accumulation hot electron power generation device Active CN207673375U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109958479A (en) * 2017-12-22 2019-07-02 浙江大学 Heat chemistry heat accumulation hot electron power generation device
CN111457770A (en) * 2020-04-14 2020-07-28 浙江大学 Hot electron enhanced heat exchange device, heat exchange system and heat exchange method

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109958479A (en) * 2017-12-22 2019-07-02 浙江大学 Heat chemistry heat accumulation hot electron power generation device
CN109958479B (en) * 2017-12-22 2024-01-09 浙江大学 Thermochemical heat storage hot electron power generation device
CN111457770A (en) * 2020-04-14 2020-07-28 浙江大学 Hot electron enhanced heat exchange device, heat exchange system and heat exchange method
CN111457770B (en) * 2020-04-14 2021-07-23 浙江大学 Hot electron enhanced heat exchange device, heat exchange system and heat exchange method

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