CN206666608U - The equipment of secondary zinc oxide removal of impurities concentration of valuable metals zinc - Google Patents

The equipment of secondary zinc oxide removal of impurities concentration of valuable metals zinc Download PDF

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Publication number
CN206666608U
CN206666608U CN201720475374.8U CN201720475374U CN206666608U CN 206666608 U CN206666608 U CN 206666608U CN 201720475374 U CN201720475374 U CN 201720475374U CN 206666608 U CN206666608 U CN 206666608U
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CN
China
Prior art keywords
blast cap
zinc
zinc oxide
equipment
fluidized bed
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Expired - Fee Related
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CN201720475374.8U
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Chinese (zh)
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伍卫民
肖泉
蒙翔
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German Guangshen Xinye Pioneer Metals Corp
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German Guangshen Xinye Pioneer Metals Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

Abstract

The utility model discloses a kind of equipment of secondary zinc oxide removal of impurities concentration of valuable metals zinc, it is characterized in that, it includes fluidized bed furnace, whirlwind tower and flue gas purifying equipment, and whirlwind tower is connected with fluidized bed furnace, and fluidized bed furnace is provided with material inlet, fuel inlet and zinc oxide delivery outlet;The air blast chamber that fluidized bed furnace includes the firing chamber of accommodating raw material and is arranged on below firing chamber, the top of firing chamber are provided with exhaust gases passes, the external air blower of air blast chamber, and air blast chamber is connected with blast cap;Blast cap includes blast cap bar and blast cap head, and blast cap bar is provided with upward through hole, and blast cap head-shield coordinates located at one end of blast cap bar and with the activity of blast cap bar.The utility model can reduce the waste of zinc resource, and cost advantage is obvious, energy-conserving and environment-protective.

Description

The equipment of secondary zinc oxide removal of impurities concentration of valuable metals zinc
Technical field
It the utility model is related to by removing high-fluorine chlorine secondary zinc oxide flue dust impurity recycling technical field, more particularly It is related to the equipment of a kind of de- high-fluorine chlorine secondary zinc oxide flue dust and the concentration of valuable metals zinc that cleans.
Background technology
Most of Pb-Zn deposits raw material is all Pb-Zn deposits symbiosis, and being extremely difficult to lead zinc by diffeential floatation is kept completely separate.Lead It is that zinc is enriched in slag that zinc ore, which is smelted, then handles clinker, output zinc oxide or secondary zinc oxide with fuming furnace.It is in addition, wet The leached mud and poor zinc oxide ore of method zine-smelting plant output obtain zinc oxide or secondary zinc oxide by rotary kiln fuming.Secondary oxidation The main component of zinc is ZnO, and simply grade is 45%~65%.So-called " secondary " refers to grade time, in China Guangxi, expensive The local yield in state, Yunnan, Hunan etc. is larger, mainly utilizes caused Water Quenching Slag and hydrometallurgy during pyrometallurgical smelting zinc Caused zinc leaching residue and other solid waste containing zinc carry out recovery secondary zinc oxide by rotary kiln baking during zinc, Secondary zinc oxide purposes is mainly processed further electrolytic zinc or zinc oxide.
About 4/5ths produced at present in the total output of world's essence zinc by wet process smelting technique, i.e. roasting-leaching-net Change-electrodeposition.With industrial rapid development, the shortage increasingly of mineral resources, it is miscellaneous that zinc concentrate is produced in current domestic mining industry circle Matter content more and more higher, higher requirement is proposed to the adaptability of zinc abstraction system.In recent years, due in raw material fluorine, chlorine contain The rising of amount, comprehensive utilization of resources, which maximizes, progressively implements more strict with environmental requirement, many large-scale systems of zinc hydrometallurgy factory Fluorine, level of chlorine are in rising trend in system.And harm of the presence of fluorine chlorine to wet method system equipment is quite big.
First, the presence of fluorine, chlorine can produce serious harm to equipment, and the influence to mixer is mainly reflected in paddle On, for wet zinc-making system mixer using extensively, most of paddle material is stainless steel, the rise of fluorine chlorine ion concentration, makes stirring The service life of machine paddle shortens.Pump is the power that solution conveys in system, and stainless steel pump has good corrosion resistance because of it And it is used widely.The rise of fluorine chlorine ion concentration in solution, to parts such as the impeller of pump, pump case, pump cover, axle, sealings Corrosion aggravation, add the consumption of pump.Intercrystalline corrosion, pitting corrosion, stress corrosion, corrosion caused by the medium of fluorine-containing chlorine The parts that fatigue, cavitation damage, turbulent flow corrosion cause impeller, impeller nut, axle sleeve of pump etc. to be in contact with medium are corroded Dissolving, it is especially the most prominent with the corrosion of impeller.The leakage of pump can be also caused simultaneously, make the burn into of pump bearing damage and screw rod The damage of pedestal, the damage of valve.
Secondly, the presence of fluorine, chlorine can also produce serious harm to electrolytic process, and the fluorine chlorine in solution is as harmful member Element, it is basic no scattered in traditional zinc powder purification technique, and the open circuit of fluorine, chlorine was not carried out, cause fluorine, chlorine in the solution It is cumulative.In solution of zinc sulfate, fluorine, chlorion belong to the anionic impurity of corrosion anode and cathode, and fluorine ion can destroy negative electrode The pellumina of surface of aluminum plate, cause cathode aluminum plate consumption increase;Meanwhile fluorine can make zinc produce bonding on minus plate (aluminium sheet) Phenomenon, it is difficult often to there is cathode zinc stripping plate so that follow-up electrolytic process can not be normally carried out.Shown according to related data, work as fluorine Concentration continues in 50mg/L, and cathode surface begins with obvious corrosion pit, when concentration reaches 100~150mg/L, negative electrode Edges of boards edge starts more serious corrosion occur, and speed, which is thinned, in thickness accelerates, and stripping plate is difficult.When fluorinion concentration reach 150mg/L with After upper, stripping plate is highly difficult, and about 30% plank is all difficult disposably to peel, the minus plate well damage thereby resulted in;Simultaneously Fluorine is high toxic material, can influence the activity of enzyme in a variety of organs of human body and tissue, influence workers ' health.Therefore both at home and abroad to sulphur Oil repellent requirement in sour zinc electrolyte is less than 50mg/L.Chlorine mainly causes positive plate to corrode and influences electricity in electrolytic process Zinc percentage of product, when chlorine ion concentration is in 300mg/L, certain influence is produced on separating out zinc percentage of product, passes through and adjusts electrolysis addition Agent can be eased, and after chlorine ion concentration is more than 500mg/L, separates out zinc quality and be severely impacted, and be difficult control System, while positive plate corrosion rate is substantially accelerated, and when chlorine ion concentration is after 800mg/L, substantially there is chlorine precipitation on anode, Cause operating environment severe exacerbation.Meanwhile chlorion reacts in anodic oxidation into after chlorate with anode lead, increase solution contains Lead, the rank for separating out zinc is reduced, shorten anode life.Therefore the chlorine in zinc sulphate electrolyte is contained both at home and abroad and requires to be less than 200mg/L。
Therefore, secondary zinc oxide is used for zinc hydrometallurgy, and the wherein removal of fluorine chlorine just turns into current urgent problem to be solved.
On the other hand, the office's of tune statistics display according to the U.S., the explored zinc resource reserves in the world in 2009 are 900,000,000 tons, main It is distributed in the ground such as Australia, the U.S., Canada, Peru, reserves in China about 20% or so.The zinc grade in China is distributed substantially Between 1-7.5%, average grade 3.3%, zinc ore of the grade more than 6% only accounts for three point one, low grade zinc development of resources profit With process high energy consumption, high grade exploitation totally after will unavoidably cause China's zinc resource shortage.Worldwide, metallic zinc Belong to the metal recycled, secondary resource containing zinc has turned into the important component of zinc raw materials for production.According to U.S.'s zinc trade Easy corporate statistics shows, about 10,000,000 tons of the annual total quantity consumed of metallic zinc, wherein the self-contained secondary money of zinc of about 30% metallic zinc Source, the species of secondary resource containing zinc is various, and mainly smeltery and chemical plant are smelted, are zinc-plated, forged, when reclaiming waste material process It is caused.China have every year 50% zinc be used in it is zinc-plated industrial, it is per ton to produce when zinc-plated iron-steel waste material regenerates through electric arc furnaces 15-20 kilograms of soot containing zinc.Global annual big appointment produces 3,700,000 tons of such cigarette ashes, contains zinc caused by scrap iron and steel regeneration Cigarette ash is the main secondary resource of regenerated zinc.But by institute's iron content, carbon, chloride and minimal amount of fluoride etc. are miscellaneous in such ash Matter is more, it is impossible to be directly used in smelting enterprise, and in high-fluorine chlorine secondary zinc oxide flue dust the fluorine-containing chlorion of institute to process in zinc electrolyzing There is very detrimental effect, very big technical barrier is brought to recovery process.Such cigarette ash is being entered by rotary kiln technology always Row processing and enrichment, the product chloride ion content produced between 0.9-1%, content of fluoride ion between 0.1-0.8%, And it is carbon containing, iron content is higher, zinc abstraction enterprise still can not use.Some are directly taken as toxic waste to treat, any useless Abandon and stack, bring very big intractability to carrying out steel regeneration smelting enterprise using electric arc furnaces, and cause the wave of resource Take, but also environment is polluted.For this reason, it is necessary to develop can high efficiente callback using such zinc cigarette ash technological process and Equipment, industrial volume production is realized, reduce the waste of zinc resource, the pollution reduced to environment is imperative, very urgent.
The content of the invention
The purpose of this utility model be exactly in order to solve the deficiency of prior art and provide it is a kind of it is reasonable in design, structure is simple The equipment of single, efficient energy-saving secondary zinc oxide removal of impurities concentration of valuable metals zinc.
The utility model is to realize above-mentioned purpose using following technical solution:A kind of secondary zinc oxide removal of impurities is enriched with The equipment of valency metallic zinc, it is characterised in that it includes fluidized bed furnace, whirlwind tower and flue gas purifying equipment, and whirlwind tower connects with fluidized bed furnace Connect, fluidized bed furnace is provided with material inlet, fuel inlet and zinc-oxide calcine delivery outlet;
The air blast chamber that fluidized bed furnace includes the firing chamber of accommodating raw material and is arranged on below firing chamber, the top of firing chamber is set Exhaust gases passes, the external air blower of air blast chamber are equipped with, air blast chamber is connected with blast cap;Blast cap includes blast cap bar and blast cap head, wind Cap bar is provided with upward through hole, and blast cap head-shield coordinates located at one end of blast cap bar and with the activity of blast cap bar.
Further, blast cap bar includes the blast cap body of rod and is arranged on the chimb of blast cap body of rod side, is provided with chimb more It is individual stand to passage;Blast cap head-shield is located at one end of the blast cap body of rod, is connected threadably with chimb so that blast cap The through hole of bar and passage mobile communication.
Further, the whirlwind tower includes tower body and the cyclone channel set along tower body sidepiece spiral, the bottom of tower body Discharging opening is provided with, top is provided with exhaust passage, centrifugal action of the gas Jing Guo cyclone channel so that side of the dust through tower body Wall falls into discharging opening and discharged, and flue gas then rises to exhaust passage, is discharged to flue gas purifying equipment and/or fluidized bed furnace.
Further, the bottom of the whirlwind tower body is cone cylinder structure wide at the top and narrow at the bottom, and discharging opening is arranged on the bottom of cone cylinder End.
Further, the output end of the discharging opening is provided with conveying device, and the conveying device guides fluidized bed furnace into so that from The material of discharging opening output can return to fluidized bed furnace and further be calcined.
Further, the inwall of the tower body is provided with scraper component, will be adsorbed by scraper component in tower body inwall Material scraper falls on discharging opening.
Further, the exhaust passage is to found the centre pipe to tower body top is arranged on, and centre pipe is from the inside to the outside It is disposed with heatproof material tube layer, heatproof material skeletal framework and lining fire clay.
The beneficial effect that the utility model can be reached using above-mentioned technical solution is:
1st, the utility model carries out being calcined decarburization removal of impurities using fluidized bed furnace to high-fluorine chlorine secondary zinc oxide smoke raw material, and enrichment is again Zinc oxide is reclaimed, can be separated except the objectionable impurities such as the super high-fluorine chlorine in rotary kiln institute parity zinc oxide, dust removal rate are high;And match somebody with somebody Gas cleaning collecting device is covered, whole system is tight-closed, and tail gas only has a small amount of carbon dioxide and water vapour body, is inhaled by tail gas The direct qualified discharge of tower is received, very totally.
2nd, disposal ability of the present utility model is very big, can continue uninterruptedly to carry out volume production, production capacity is traditional rotary kiln 5-10 times, output efficiency is high, and energy consumption is low, low-carbon environment-friendly;
3rd, cost advantage is obvious;With 3900 yuan current of zinc sulfide ore processing charges per ton, electrolytic zinc plant processing steel mill cigarette ash The production model that production zinc-oxide calcine cost is up to 6500 yuan per ton is compared, and is using fluidized bed furnace decarburization dechlorination of the present utility model Maximally effective processing mode, particularly the chlorine containing 3-5% can be removed to less than 0.05%, this is to process high fluorine using rotary kiln Chlorine secondary zinc oxide flue dust is too far behind to catch up, it is also not possible to reaches this quality index;
Such a technique, which dramatically removes, has separated fluorine contained in secondary zinc oxide, chloride, effectively reduces electrolysis The corrosion of fluorine ion, chlorion (50mg/L) to cathode plate surface oxide-film in zinc solution, extend the service life of positive plate.
4th, energy-conserving and environment-protective.The source of raw material mainly comes from carrying out the cigarette of steel regeneration smelting enterprise using electric arc furnaces Dirt, this flue dust are usually to be discharged as solid waste, and the pollution to environment is very big;Using skill of the present utility model Art scheme can just be made full use of these solid waste, and the zinc-oxide calcine product for processing to obtain is deep by zinc abstraction The welcome and favor of enterprise, product are in seller's market all the time, and supply falls short of demand, and byproduct zinc chloride fumes and liquor zinci chloridi can It is sold to down-stream enterprise to be processed further refining, there is the advantages of sustainable development.
Brief description of the drawings
Fig. 1 is structural representation of the present utility model;
Fig. 2 is whirlwind tower structural representation of the present utility model;
Fig. 3 is fluidized bed furnace structural representation of the present utility model;
Fig. 4 is flow sheet of the present utility model;
Fig. 5 is cap structure schematic diagram of the present utility model;
Fig. 6 is blast cap bar structural representation of the present utility model;
Fig. 7 is Fig. 6 top view.
Description of reference numerals:1st, fluidized bed furnace 1-1, firing chamber 1-2, air blast chamber 2, whirlwind tower 2-1, tower body 2-2, Cyclone channel 2-3, discharging opening 2-4, exhaust passage 3, flue gas purifying equipment 3-1, Venturi tube 3-2, catch box 3-3, wash Wash tower 3-4, electric demister 3-5, tail gas absorber 3-6, circulating slot 3-7, venturi pump 4, blast cap 4-1, blast cap bar 4- 11st, through hole 4-12, blast cap body of rod 4-13, chimb 4-2, blast cap head.
Embodiment
The technical program is explained in detail below in conjunction with specific embodiment.
As shown in Fig. 1-Fig. 7, the utility model is a kind of equipment of secondary zinc oxide removal of impurities concentration of valuable metals zinc, and it includes Fluidized bed furnace 1, whirlwind tower 2 and flue gas purifying equipment 3, whirlwind tower 2 are connected with fluidized bed furnace 1, and the quantity of whirlwind tower is two, is connected successively Setting is connect, fluidized bed furnace is provided with material inlet, fuel inlet and zinc oxide delivery outlet;Fluidized bed furnace 1 includes the roasting of accommodating raw material The room 1-1 and air blast chamber 1-2 being arranged on below firing chamber, the top of firing chamber are provided with exhaust gases passes, and air blast chamber is external Air blower, air blast chamber are connected with blast cap 4;Blast cap includes blast cap bar 4-1 and blast cap head 4-2, and blast cap bar is provided with upward lead to Hole 4-11, blast cap head-shield coordinate located at one end of blast cap bar and with the activity of blast cap bar.Blast cap bar includes blast cap body of rod 4-12 and set Put the chimb 4-13 in blast cap body of rod side, be provided with chimb it is multiple stand to passage;Blast cap head-shield is located at the blast cap body of rod One end, be connected threadably with chimb so that the through hole of blast cap bar and passage mobile communication.
Further, the whirlwind tower 2 includes tower body 2-1 and the cyclone channel 2-2 set along tower body sidepiece spiral, tower body Bottom be provided with discharging opening 2-3, top is provided with exhaust passage 2-4, centrifugal action of the gas Jing Guo cyclone channel so that powder Side wall of the dirt through tower body falls into discharging opening and discharged, and flue gas then rises to exhaust passage, to flue gas purifying equipment and fluidized bed furnace Discharge.Tower body 2-1 bottom is cone cylinder structure wide at the top and narrow at the bottom, and discharging opening is arranged on the bottom of cone cylinder.The discharging opening it is defeated Go out end and be provided with conveying device, the conveying device guides fluidized bed furnace into so that can return to boiling from the material of discharging opening output Stove is further calcined.The inwall of tower body is provided with scraper component, is scraped the material adsorbed in tower body inwall by scraper component To discharging opening.Exhaust passage 2-4 is to found the centre pipe to tower body top is arranged on, and centre pipe is disposed with from the inside to the outside Heatproof material tube layer, heatproof material skeletal framework and lining fire clay.
Flue gas purifying equipment 3 includes Venturi tube 3-1, the catch box 3-2 being connected with Venturi tube, scrubbing tower 3-3, electric demisting dress 3-4, tail gas absorber 3-5 are put, Venturi tube is connected by furnace gas pipe with whirlwind tower, and the output end of catch box is connected with circulating slot 3-6, venturi pump 3-7, the output end connection Venturi tube of venturi pump are installed on the circulating slot;Scrubbing tower is connected with alkali groove so that Flue gas, by washing, forms sodium carbonate and solder(ing)acid after the cyclone centrifugal dust collection of whirlwind tower, and tail gas is up to standard directly Emptying.
It is process corresponding with the equipment below:It includes roasting workshop section and purification section, roasting workshop section be by The smoke raw material of secondary zinc oxide containing high-fluorine chlorine is sent into fluidized bed furnace and carries out being calcined decarburization removal of impurities enriching and recovering zinc oxide.It is calcined the boiling of workshop section Rise in stove roasting process, by air blower supplemental oxygen, the carbon, the metallic zinc microparticle that allow in raw material fully burn with oxygen, pass through Quality oxide zinc calcine after oversintering, removal of impurities, enrichment is discharged from fluidized bed furnace slag discharge drum, caused titanium dioxide in roasting Carbon, water vapour, chloride and small amounts zinc powder dirt are extracted into whirlwind tower, are acted on through centrifugal dust-removing, isolate byproduct zinc chloride With small amounts Zn dust, other smoke enter purification section.
The purification section is the flue gas after being calcined the cyclone centrifugal dust collection of workshop section, by Venturi tube, scrubbing tower text Family name's pipe carries out spray washing dedusting, and Containing Zinc Chloride, the aqueous solution of zinc oxide are collected Xun rings through hydrops case and used, hydrops case precipitation Zinc oxide and zinc chloride mud, push back and continue to be calcined in stove.A small amount of zinc chloride acid mist is cleared through electric demisting, and tail gas is by absorption tower Caustic soda (NaOH) groove neutralizes absorption again, and zinc chloride generates zinc hydroxide precipitation and sodium-chloride water solution after being neutralized with caustic soda, After recovery for further processing;Part water vapour and very small amount carbon dioxide is up to standard is directly emptied by tail gas absorber.
Further, in the technical program, the raw material composition of use includes simple substance zinc, simple substance carbon, iron compound, chlorination conjunction Thing;Raw material sources:The high-fluorine chlorine secondary zinc oxide flue dust that steel mill's electric arc furnaces comes out;
The element of high-fluorine chlorine secondary zinc oxide flue dust is formed to be included by weight percentage:Zinc 35-60%;Carbon 25-35%, chlorine 3- 5%, iron 5-8%, fluorine 0.3-0.8%.
Chemical equation in roasting process:
2Zn+O2===2ZnO;
C+O2===CO2
Chemical equation in purification process:
ZnCl2+ 2NaOH===2Zn (OH)2↓+2NaCl
The fluorine-containing zinc chloride of institute can not be aoxidized and decomposed by roasting in raw material, and flue gas and oxidation can only be sublimed into by high temperature Zinc is separated, by being collected in whirlwind tower and purification section flue gas cooling procedure.
High-fluorine chlorine secondary zinc oxide flue dust after roasting workshop section and purification section processing, obtained finished product include zinc oxide, Iron compound, chloride, fluoride;Element is formed includes zinc 50-69%, chlorine 0.01-0.05%, iron 5- by weight percentage 8%, fluorine 0.01-0.03%.
The utility model carries out being calcined decarburization removal of impurities compared with prior art, using fluidized bed furnace to soot containing zinc raw material, returns Zinc oxide is received, rotary kiln can be handled and produce the high chlorine objectionable impurities of zinc oxide, dust removal rate is high;And supporting flue gas purifying equipment, it is System is more closed, and gas discharge is cleaner;Production capacity is bigger, is 5-10 times of traditional rotary kiln, personnel's efficiency is high, energy consumption It is low;Cost advantage is obvious, extends the service life of minus plate during electrolytic zinc;Energy-conserving and environment-protective, the source of raw material are mainly Come from the cigarette ash that steel mill's electric arc furnaces comes out, this cigarette ash is usually to be discharged as discarded object, and the pollution to environment is very Greatly, these discarded objects can just be made full use of using the technical solution of the utility model, obtained zinc oxide product Relevant enterprise can be sold to, byproduct zinc chloride fumes and liquor zinci chloridi can be sold to down-stream enterprise and be processed further carrying Refining, has the advantages of sustainable development.
Above-described is only preferred embodiment of the present utility model, it is noted that for the ordinary skill of this area For personnel, on the premise of not departing from the utility model and creating design, various modifications and improvements can be made, these all belong to In the scope of protection of the utility model.

Claims (7)

1. a kind of equipment of secondary zinc oxide removal of impurities concentration of valuable metals zinc, it is characterised in that it includes fluidized bed furnace, whirlwind tower and cigarette Gas cleaning equipment, whirlwind tower are connected with fluidized bed furnace, and fluidized bed furnace is provided with material inlet, fuel inlet and zinc oxide delivery outlet;
The air blast chamber that fluidized bed furnace includes the firing chamber of accommodating raw material and is arranged on below firing chamber, the top of firing chamber is provided with Exhaust gases passes, the external air blower of air blast chamber, air blast chamber are connected with blast cap;Blast cap includes blast cap bar and blast cap head, blast cap bar Upward through hole is provided with, blast cap head-shield coordinates located at one end of blast cap bar and with the activity of blast cap bar.
2. the equipment of secondary zinc oxide removal of impurities concentration of valuable metals zinc according to claim 1, it is characterised in that blast cap bar bag Include and the blast cap body of rod and be arranged on the chimb of blast cap body of rod side, be provided with chimb it is multiple stand to passage;Blast cap head-shield is set In one end of the blast cap body of rod, it is connected threadably with chimb so that the through hole of blast cap bar and passage mobile communication.
3. the equipment of secondary zinc oxide removal of impurities concentration of valuable metals zinc according to claim 1, it is characterised in that the whirlwind Tower includes tower body and the cyclone channel set along tower body sidepiece spiral, and the bottom of tower body is provided with discharging opening, and top is provided with row Gas passage.
4. the equipment of secondary zinc oxide removal of impurities concentration of valuable metals zinc according to claim 3, it is characterised in that the tower body Bottom be cone cylinder structure wide at the top and narrow at the bottom, discharging opening is arranged on the bottom of cone cylinder.
5. the equipment of secondary zinc oxide removal of impurities concentration of valuable metals zinc according to claim 3, it is characterised in that the discharging The output end of mouth is provided with conveying device, and the conveying device guides fluidized bed furnace into.
6. the equipment of secondary zinc oxide removal of impurities concentration of valuable metals zinc according to claim 3, it is characterised in that the tower body Inwall be provided with scraper component.
7. the equipment of secondary zinc oxide removal of impurities concentration of valuable metals zinc according to claim 3, it is characterised in that the exhaust Passage is to found the centre pipe to tower body top is arranged on, and centre pipe is disposed with heatproof material tube layer, resistance to from the inside to the outside Warm material skeletal framework and lining fire clay.
CN201720475374.8U 2017-05-02 2017-05-02 The equipment of secondary zinc oxide removal of impurities concentration of valuable metals zinc Expired - Fee Related CN206666608U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107217150A (en) * 2017-05-02 2017-09-29 英德广申鑫业金属有限公司 The method and apparatus of secondary zinc oxide removal of impurities concentration of valuable metals zinc
CN111363931A (en) * 2020-03-24 2020-07-03 鑫联环保科技股份有限公司 System for high temperature separation cooperates with ammonium complex entrapment zinc-containing solid waste in semi-volatile heavy metal

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107217150A (en) * 2017-05-02 2017-09-29 英德广申鑫业金属有限公司 The method and apparatus of secondary zinc oxide removal of impurities concentration of valuable metals zinc
CN111363931A (en) * 2020-03-24 2020-07-03 鑫联环保科技股份有限公司 System for high temperature separation cooperates with ammonium complex entrapment zinc-containing solid waste in semi-volatile heavy metal

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Granted publication date: 20171124

Termination date: 20190502