CN205556329U - Swimming pool circulating water electrolysis type purifier - Google Patents

Swimming pool circulating water electrolysis type purifier Download PDF

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Publication number
CN205556329U
CN205556329U CN201620247379.0U CN201620247379U CN205556329U CN 205556329 U CN205556329 U CN 205556329U CN 201620247379 U CN201620247379 U CN 201620247379U CN 205556329 U CN205556329 U CN 205556329U
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water
swimming pool
plate
pond
water fender
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CN201620247379.0U
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Chinese (zh)
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史方度
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Jiangyin Sifang swimming rehabilitation industry Limited by Share Ltd
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Jiangyin Quartet Swim Equipment Co Ltd
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Abstract

The utility model discloses a swimming pool circulating water electrolysis type purifier, the drain pipe that includes the inlet tube that is linked together with the export of the return water of swimming pool, be linked together with the water inlet of swimming pool, set gradually in the inlet tube with electrolytic reaction ware between the drain pipe, air floatation precipitation pond, electrolysis reactor is provided with a set of anode plate and the negative plate of being made by metal material at least, the anode plate and the negative plate is linked together with power supply respectively, the air floatation precipitation pond includes the pond body, set up in this internal skimming device of pond, the electrolytic reaction ware is controlled by control system, be provided with the water quality testing meter that is used for detecting the interior aquatic of swimming pool oxidant content in the control system, need not to add adding medicament, carry out the swimming pool water treatment through electrolytic mode, practice thrift swimming pool use cost environmental protection safety.

Description

Swimming pool circulating water electrolytic formula purifier
Technical field
This utility model relates to a kind of swimming pool circulating water electrolytic formula purifier.
Background technology
Swimming pool engineering has the feature of self, and it need to be with the special technology of swimming pool, special equipment, and these are made With regard to the strongest professional swimming pool industry, it is in particular in:
(1) the circulating filtration sterilization of swimming pool water is exactly the utilization of recycled water, and water circulates repeatedly and makes profits With, namely the water (no matter how high filtering accuracy and purity) after filtering and processing is sent constantly into unfiltered In water containing pollutant, making the water of pure and impure mixing reach sanitary standard, the water then constantly polluted is the most successive Be circulated, filter, clarify and sterilize;Simultaneously because swimmer and ambient outside bring pollutant into swimming pool, in pond certainly Raw antibacterial and algae, therefore water is also constantly polluting;Circulate, filter, sterilize, clarify, pollute to be in and put down dynamically Weighing apparatus state.Change that this dynamic representation adds at the swimming instability of number, the fluctuation of pond water temperature, chemistry, circular flow Variation etc..
(2) feature that swimming pool water (physics) processes is circulating filtration, and in other the less consideration of engineering of water treatment Circulation and the relevant issues such as cycle period, also admission port, water return outlet distribution so that water distribution uniformity problem, slough and short stream Problem.
(3) persistence of polluter and unstability, it is desirable to carry out filters and continuous disinfection.At the physics of water quality Reason and chemical treatment are carried out simultaneously.Cell body structure to be paid attention to and endless form and swimming pool special equipment and pipe fitting reasonable Select and layout.
(4) safety, health, economy, science, reliable, low-carbon environment-friendly and sustainable development that swimming-pool water processes are ensured, It is also contemplated that the difference of other pool side equipment, luminaire etc. wants summation function.
In swimming pool engineering, remove beyond professional theory, technology, equipment and the practice of its own, general Water treatment theory and technology are also widely used in the practice of swimming pool engineering.Such as: break point chlorination, Lan Shi is saturated Coefficient, the even partial velocities of suspense granule motion characteristic value, etc..
Owing to the number of swimming-pool water contact is more, water can be polluted by swimmer self institute band antibacterial;Therefore, in swimming The water in pond can comprise each bacterioid.When swimming in pond, water accidentally enters the oral cavity of swimmer and the most accidentally drinks into swimming During water, it is assumed that water is unhygienic, then will result in discomfort, it is also possible to cause disease;Situation severe patient can cause typhoid fever, The infection that syphilis, bloody dysentery etc. are sick.In order to ensure swimming pool water quality safety, protection swimmer's is healthy, is equipped with necessity to swimming pool Water disinfecting device and take necessity pool water treatment medicament put into be requisite.But, some medicament itself Being poisonous, accidentally drink and may bring immesurable consequence into swimming water, electrochemical process can release this kind of trouble and worry.
Summary of the invention
The purpose of this utility model is to overcome defect present in prior art, it is provided that a kind of swimming pool circulating water electrolytic formula Purifier, it is not necessary to add medicament, carries out sewage disposal by the way of electrolysis, saves swimming pool use cost.
For achieving the above object, the technical solution of the utility model there is provided a kind of swimming pool circulating water electrolytic formula and purifies dress Put, including exporting drain pipe that the water inlet pipe being connected is connected with the water inlet of swimming pool with the backwater of swimming pool, being set in turn in Electrolysis reactor between described water inlet pipe and described drain pipe, air supporting sedimentation tank, be provided with at least in described electrolysis reactor One group of positive plate being made up of metal material and minus plate, described positive plate and described minus plate respectively with power supply phase Connection, described air supporting sedimentation tank includes pond body, is arranged at the intrinsic skimmer device in described pond, and described electrolysis reactor is by controlling System processed controls, and is provided with by detecting in swimming pool based on the water quality detection of water oxygen agent content in described control system.
Improving further: be provided with flow-monitoring device on described water inlet pipe, described flow-monitoring device includes stream Amount detection meter.
Improve further: described pond is the most internal is disposed with the first water fender, the second dash along water (flow) direction Plate and third gear water plate, described skimmer device between described first water fender and described second water fender, described first Water fender is crisscross arranged with described second water fender, and described third gear water plate be arranged in parallel with described second water fender, and described The upper end of two water fenders is connected with the top of described pond body, the bottom of described first water fender and described pond body Bottom is connected.
Improve further: described skimmer device includes the master that conveyer belt ringwise matches with described conveyer belt Dynamic cylinder and follower rollers, described drive roll is by motor-driven rotation, and on described conveyer belt, there are some skimmings equidistant connection Plate, described third gear water plate be disposed with slag charge collecting box.
Improve further: described drain pipe is provided with L-shaped water fender with the junction of described pond body.
Improve further: some groups of pole plates in described electrolysis reactor use bipolar type to connect.
Advantage of the present utility model and having the beneficial effects that:
Use split-type design, will be respectively placed in two independent devices with air supporting sedimentation tank in electrolysis reactor OK, make device structure rationalize, thus improve processing procedure efficiency;
In electrolysis reactor, pole plate uses bipolar type to connect, and can effectively reduce polar plate spacing, reduces tank voltage and energy consumption, ton Water consumption reduces by 75%~90% than Conventional electrochemical process unit, simplifies power connection equipment and pole plate replacement operation simultaneously;
In air supporting sedimentation tank, current general direction is bottom-up, reduces bubble and blocks up and block;
The metal hydroxides flco that produces after electrolysis by arranging skimmer device effectively to remove and aoxidize organic dirt Dye thing.
Accompanying drawing explanation
Fig. 1 is this utility model schematic diagram.
Wherein: 1, flow-monitoring device;2, electrolysis reactor;3, pond body;4, power supply;5, control system;6, One water fender;7, the second water fender;8, conveyer belt;9, skimming plate;10, slag charge collecting box;11, third gear water plate;12, L-shaped gear Water plate.
Detailed description of the invention
Below in conjunction with the accompanying drawings and embodiment, detailed description of the invention of the present utility model is further described.Hereinafter implement Example is only used for clearly illustrating the technical solution of the utility model, and can not limit protection model of the present utility model with this Enclose.
As it is shown in figure 1, a kind of swimming pool circulating water electrolytic formula purifier, including exporting entering of being connected with the backwater of swimming pool Drain pipe that water pipe is connected with the water inlet of swimming pool, the electrolysis being set in turn between described water inlet pipe and described drain pipe Reactor 2, air supporting sedimentation tank, be provided with in described electrolysis reactor 2 positive plate that least one set is made up of metal material and Minus plate, described positive plate and described minus plate are connected with power supply 4 respectively, and described air supporting sedimentation tank includes pond body 3, being arranged at the skimmer device in described pond body 3, described electrolysis reactor 2 is controlled by control system 5, described control system 5 Inside it is provided with by detecting in swimming pool based on the water quality detection of water oxygen agent content.
By the oxygenate content in water quality detection meter detection swimming pool inner water, when oxygenate content is too high, then control electricity Solve reactor 2 to quit work, or control the part metals pole plate work in electrolysis reactor 2, when oxygenate content is too low, Then control electrolysis reactor 2 continuous firing.
Electrolysis principle:
Electrolysis produces the principle of hypochlorite
Use diaphragm-free electrolysis, generate hypochlorite by homogeneous secondary chemical reaction.As: sodium chloride electrolyte concentration Low, during about 3 %~5 %, electrode process is, the chlorine that anode reaction separates out generates hydrogen chloride and time chlorine after being dissolved in electrolyte Acid, owing to electrolysis bath is without barrier film, negative electrode generates hydroxide ion, the hydrion that will produce with following dissociation equilibrium after separating out hydrogen In conjunction with, make balance move right, generate hydrone and sodium hypochlorite.
HClO + H2O = H3O+ + ClO—
HClO + Na+ + OH — = NaClO+H2O
NaClO can be generated and be expressed as following net reaction:
NaCl + H2O = NaClO+ H2
NaClO is the intermediate product of a kind of instability, and it reacts after generation it is possible to below Can Jiaing, it is impossible to obtain The NaClO solution of high concentration, and high current efficiency.
(1) cathodic reduction:
ClO-+ H2O+2e → Cl+OH
(2) anodic oxidation:
6ClO-+ 3H2O → 2ClO3-+4Cl+6 H++ 1.5O2+6e
After in electrolysis bath, ClO-concentration and temperature improve, the speed of above-mentioned reaction will improve, and the ClO3-of generation becomes many, Current efficiency substantially reduces.
(3) chemical oxidation in solution;
ClO-+2HClO → ClO3-+2Cl+2H+
(4) in electrolyte, NaCl concentration is low, and anode analysis O2 side reaction probability increases, and makes current efficiency reduce.
(5) decomposition reaction of ClO-itself is greatly influenced by temperature, and when temperature improves, decomposes and aggravates:
ClO-→ Cl+0.5O2
3NaClO → NaClO3 + 2 NaCl
In sewage disposal, produce hypochlorite (ClO) and oxidation product chlorate (ClO3-) be all strong oxidizer, Wherein: under acidity and neutrallty condition, the standard electrode potential of ClO/Cl is 1.49V, under acidity and neutrallty condition, The standard electrode potential of ClO3-is 1.45V.Electrochemical process water processes possesses Strong oxdiative-self-produced oxidant;Strong reduction-self-produced is also Former dose;Flocculation-self-produced flocculant;Air supporting-ultra-fine bubble of self-produced air supporting and sterilizing, decolouring and the big function of deodorize seven.Electrochemistry Antibacterial, virus, capsule spore can all be gone out in by Strong oxdiative and highfield by method direct purification swimming pool recycling technology completely Kill.
Electrolysis produces peroxydisulfate and is hydrolyzed into the principle of hydrogen peroxide
In electrolytic process certain under conditions of, produce peroxydisulfate.As: containing sulphuric acid and peroxydisulfate in stock solution , at higher current densities, there is following anodic oxidation reactions:
Anode reaction: 2HSO4-→ S2O82-+2H ++ 2e, 2SO42-→ S2O82-+2e
Cathode reaction: 2H ++ 2e → H2
Total cell reaction: SO4=+ H2SO4 → S2O8=+ H2
The peroxydisulfate of gained is hydrolyzed, and i.e. can get hydrogen peroxide:
S2O8 =+ 2H2O →2H ++ 2SO4= + H2O2
Reaction is carried out in aqueous, it may happen that analyse the side reaction of O2 on anode:
H2O → O2 +4H + + 4e
The side reaction that analysis O2 occurs will make current reduction.In order to improve current efficiency, overpotential for oxygen evolution should be selected high Electrode material, if with iron plate, its overpotential is according to Tafel equation, and its values of intercept a is about between 0.6~0.8 V, for moderate Value, improves electric current density, adds a small amount of depolarizing agent (e.g., F-, CI-, urea etc.), and the addition of depolarizing agent can change electric current Apparent condition, can suppress the precipitation of oxygen consumingly, and the generation on S2O82-affects little.
In sewage disposal, produce peroxydisulfate (S2O82-) and hydrolyzate hydrogen peroxide (H2O2) is all Strong oxdiative Agent, wherein: the standard electrode potential of S2O82-is 2.01V, under acidity and neutrallty condition, the standard electrode potential of H2O2 is 1.77V, in the basic conditions, the electrode potential of H2O2 is 0.88V.Use soluble anode iron plate electrode reaction, generation The synthesis Fenton reagent of Fe2+ and H2O2, its electrode potential is 2.87V.Almost the Organic substance of difficult degradation can be broken into Machine fragment even resolves into CO2's and H2O.
Play equally direct purification swimming pool recycling technology completely can by antibacterial, virus, capsule spore all by Strong oxdiative and Highfield is killed.
Control flow rate of water flow for convenience, improve effect and the efficiency of electrolysis, described water inlet pipe is provided with flow prison Control device 1, described flow-monitoring device 1 includes flow control valve and flow detection meter, and described flow-monitoring device 1 is with described Control system 5 is connected.
So that water fluid stable in swimming pool, uniformly, effluent weir load is low, effluent quality good, in described pond body 3 It is disposed with the first water fender the 6, second water fender 7 and third gear water plate 11, described skimmer device position along water (flow) direction Between described first water fender 6 and described second water fender 7, described first water fender 6 is staggered with described second water fender 7 to be set Putting, described third gear water plate 11 be arranged in parallel with described second water fender 7, the upper end of described second water fender 7 and described pond The top of body 3 is connected, and the bottom of described first water fender 6 is connected with the bottom of described pond body 3.
Removing metal hydroxides flco and oxidation organic pollution for convenience, described skimmer device includes ringwise Drive roll that conveyer belt 8 matches with described conveyer belt 8 and follower rollers, described drive roll by motor-driven rotation, On described conveyer belt 8, there are some skimming plates 9 equidistant connection, described third gear water plate 11 be disposed with slag charge collecting box 10.
Blocking up to reduce bubble and block, described drain pipe is provided with L-shaped water fender with the junction of described pond body 3 12。
Some groups of pole plates in described electrolysis reactor 2 use bipolar type to connect, and can effectively reduce polar plate spacing, reduce groove Voltage and energy consumption, ton water consumption reduces by 75%~90% than Conventional electrochemical process unit, simplifies power connection equipment and pole plate simultaneously Replacement operation.
The above is only preferred implementation of the present utility model, it is noted that for the common skill of the art For art personnel, on the premise of without departing from this utility model know-why, it is also possible to make some improvements and modifications, these change Enter and retouch and also should be regarded as protection domain of the present utility model.

Claims (6)

1. a swimming pool circulating water electrolytic formula purifier, it is characterised in that: include with swimming pool backwater outlet be connected enter Drain pipe that water pipe is connected with the water inlet of swimming pool, the electrolysis being set in turn between described water inlet pipe and described drain pipe Reactor, air supporting sedimentation tank, be provided with positive plate and the moon that least one set is made up of metal material in described electrolysis reactor Pole plate, described positive plate and described minus plate are connected with power supply respectively, and described air supporting sedimentation tank includes pond body, sets Being placed in the intrinsic skimmer device in described pond, described electrolysis reactor, by control system control, is provided with in described control system By detecting in swimming pool based on the water quality detection of water oxygen agent content.
2. swimming pool circulating water electrolytic formula purifier as claimed in claim 1, it is characterised in that: it is provided with on described water inlet pipe Flow-monitoring device, described flow-monitoring device includes flow detection meter.
3. swimming pool circulating water electrolytic formula purifier as claimed in claim 1, it is characterised in that: described pond is the most internal along water Flow path direction is disposed with the first water fender, the second water fender and third gear water plate, and described skimmer device is positioned at described first Between water fender and described second water fender, described first water fender is crisscross arranged with described second water fender, described third gear Water plate be arranged in parallel with described second water fender, and the upper end of described second water fender is connected with the top of described pond body, The bottom of described first water fender is connected with the bottom of described pond body.
4. swimming pool circulating water electrolytic formula purifier as claimed in claim 3, it is characterised in that: described skimmer device include in The drive roll that matches with described conveyer belt of conveyer belt of annular and follower rollers, described drive roll is driven by motor Rotating, on described conveyer belt, there are some skimming plates equidistant connection, described third gear water plate be disposed with slag charge collecting box.
5. swimming pool circulating water electrolytic formula purifier as claimed in claim 3, it is characterised in that: described drain pipe and described pond The junction of body is provided with L-shaped water fender.
6. swimming pool circulating water electrolytic formula purifier as claimed in claim 1, it is characterised in that: in described electrolysis reactor Some groups of pole plates use bipolar type to connect.
CN201620247379.0U 2016-03-29 2016-03-29 Swimming pool circulating water electrolysis type purifier Active CN205556329U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106587278A (en) * 2016-12-28 2017-04-26 西安交通大学 Electrochemical descaling equipment model selection method for circulating cooling water system
CN112811676A (en) * 2020-12-30 2021-05-18 黑晶科技(嘉兴)有限公司 Method for degrading antibiotic-containing wastewater by using geopolymer particle three-dimensional electrode

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106587278A (en) * 2016-12-28 2017-04-26 西安交通大学 Electrochemical descaling equipment model selection method for circulating cooling water system
CN106587278B (en) * 2016-12-28 2019-06-11 西安交通大学 The electrochemical descaling Equipments Choosing Method of recirculating cooling water system
CN112811676A (en) * 2020-12-30 2021-05-18 黑晶科技(嘉兴)有限公司 Method for degrading antibiotic-containing wastewater by using geopolymer particle three-dimensional electrode
CN112811676B (en) * 2020-12-30 2023-08-15 黑晶科技(嘉兴)有限公司 Method for degrading antibiotic-containing wastewater by using geopolymer particle three-dimensional electrode

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Address after: 214400 Jiangsu city of Wuxi province Jiangyin City East Ring Road No. 267

Patentee after: Jiangyin Sifang swimming rehabilitation industry Limited by Share Ltd

Address before: 214400 Jiangyin, Jiangsu, Chengjiang Street Industrial Park (Xinhua Village)

Patentee before: Jiangyin Quartet Swim Equipment Co., Ltd.