CN204630955U - Plunderring into formula X-fluorescence measurement mechanism of a kind of quick detection Heavy Metals in Cosmetics content - Google Patents
Plunderring into formula X-fluorescence measurement mechanism of a kind of quick detection Heavy Metals in Cosmetics content Download PDFInfo
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- CN204630955U CN204630955U CN201520245739.9U CN201520245739U CN204630955U CN 204630955 U CN204630955 U CN 204630955U CN 201520245739 U CN201520245739 U CN 201520245739U CN 204630955 U CN204630955 U CN 204630955U
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 44
- 229910001385 heavy metal Inorganic materials 0.000 title claims abstract description 31
- 238000001514 detection method Methods 0.000 title claims abstract description 19
- 238000005259 measurement Methods 0.000 title claims abstract description 17
- 230000005284 excitation Effects 0.000 claims abstract description 20
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 19
- 239000010703 silicon Substances 0.000 claims abstract description 19
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000007493 shaping process Methods 0.000 claims abstract description 14
- 238000006073 displacement reaction Methods 0.000 claims abstract description 11
- 238000001228 spectrum Methods 0.000 claims abstract description 6
- 238000012545 processing Methods 0.000 claims abstract description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 16
- 229910052742 iron Inorganic materials 0.000 claims description 9
- 238000007405 data analysis Methods 0.000 claims description 5
- 229910001220 stainless steel Inorganic materials 0.000 claims description 4
- 239000010935 stainless steel Substances 0.000 claims description 4
- 230000003321 amplification Effects 0.000 claims description 3
- 238000003199 nucleic acid amplification method Methods 0.000 claims description 3
- 238000005286 illumination Methods 0.000 claims description 2
- 238000004458 analytical method Methods 0.000 description 14
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 4
- 229910052753 mercury Inorganic materials 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 230000002087 whitening effect Effects 0.000 description 3
- 238000004876 x-ray fluorescence Methods 0.000 description 3
- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 description 2
- 229910052785 arsenic Inorganic materials 0.000 description 2
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000001095 inductively coupled plasma mass spectrometry Methods 0.000 description 2
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000003321 atomic absorption spectrophotometry Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000002795 fluorescence method Methods 0.000 description 1
- 238000002189 fluorescence spectrum Methods 0.000 description 1
- 238000009616 inductively coupled plasma Methods 0.000 description 1
- 238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229940100892 mercury compound Drugs 0.000 description 1
- 150000002731 mercury compounds Chemical class 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000009304 pastoral farming Methods 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000012113 quantitative test Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 239000011573 trace mineral Substances 0.000 description 1
- 235000013619 trace mineral Nutrition 0.000 description 1
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- Analysing Materials By The Use Of Radiation (AREA)
Abstract
What the utility model disclosed a kind of quick detection Heavy Metals in Cosmetics content plunders into formula X-fluorescence measurement mechanism, comprise excitation source, sniffer, sample stage, analyzer and circuit output device, excitation source comprises X-ray tube, X-ray tube high pressure and be arranged at the collimating apparatus in X-ray tube exit; Sniffer comprises silicon drifting detector, detector high pressure, charge-sensitive preamplifier and pulse-shaping amplifier; Sample stage comprises manual rotation displacement platform, position, angle platform and sample box; Analyzer is digital multichannel spectrometer; Circuit output device comprises computing machine, printer and display; Regulate position and the angle of sample stage, the X ray that X-ray tube is sent is radiated on cosmetic sample with low-angle, excite the feature X-fluorescence information of heavy metal element in cosmetic sample, fluorescence information is received by silicon drifting detector, through pulse-shaping amplifier be shaped amplify after by digital multichannel spectrometer be converted into can be used for analyze power spectrum and carry out data processing and control by computing machine.
Description
Technical field:
What the utility model related to a kind of quick detection Heavy Metals in Cosmetics content plunders into formula X-fluorescence measurement mechanism, and adopt and plunder into formula xrf analysis principle, especially can detect Heavy Metals in Cosmetics content fast, it belongs to element express-analysis field.
Background technology:
The metal contained in cosmetics and nonmetally have a variety of, some deliberately adds to reach some given efficacy.Often can play whitening effect as added mercury, because the ferment that mercury compound can destroy epidermal area is movable, melanin cannot be formed; Plumbous oxide has certain covering effect; Also can be used for whitening; Arsenic all has very strong affinity to protein and each seed amino acid, due to its specific physical character, shows easily by the feature that biosome absorbs, is often used to all kinds of whitening spot-removing product.Also some metal is that the metal ingredient that should not have remains in cosmetics because raw materials for production composition is impure.And as with the addition of the heavy metals such as arsenic, mercury, lead in fruit cosmetic, the infringement that Long-Time Service causes human body is very large.The security of cosmetics has become the problem of consumers in general's concern day by day.
The existing method of inspection mostly is atomic absorption spectrophotometry and atomic fluorescence spectrum, but these method complicated operations, time-consuming, once can only measure a kind of element.Inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma spectrometry method (ICP-AES) are applicable to the feature such as multielement analysis and trace element analysis due to it, are applied in cosmetics Analysis of Heavy Metal.
X-fluorescence method, as a kind of method of material element constituent analysis, becomes the conventional analysis means of ultimate analysis in experiment and industrial and mining enterprises already, has obvious advantage: do not have destructiveness, be not directly infected with sample, can not change sample structure; Be physical method, the chemistry affect of element to be measured can not be subject to; Can carry out multielement quantitative test, analyzable element kind is many simultaneously; Highly sensitive, the element of trace can accurately be detected; Can be used as on-the site analysis and analysis speed is fast, is a kind of cheap analytical approach.
The utility model adopts plunders into formula x-ray fluorescence analysis (Grazing Incidence X-ray Fluorescence, GI-XRF) technology, quick, the sample not only with conventional energy dispersion xrf analysis technology can't harm, carry out simultaneously the feature of multielement detection, and there is low detection limit, complete and once test that required minimal sample amount is few, the feature of the detection that is more suitable for fluid sample, be considered to one of the most accurate instrument for the test of film thickness, density and component.Current GI-XRF technology is not only successfully applied to semi-conductor industry, and its application is also in continuous expansion.
Utility model content:
The utility model provide a kind of without chemical contamination, the plunderring into formula X-fluorescence measurement mechanism of Measuring Time is short, precision is high, structure is simple, safe and reliable quick detection Heavy Metals in Cosmetics content.
The utility model adopts following technical scheme: a kind of quick detection Heavy Metals in Cosmetics content plunder into formula X-fluorescence measurement mechanism, it comprises excitation source, sniffer, sample stage, analyzer and circuit output device, described excitation source comprises X-ray tube, X-ray tube high pressure and be arranged at the collimating apparatus in X-ray tube exit; The pulse-shaping amplifier that described sniffer comprises silicon drifting detector, detector high pressure, the charge-sensitive preamplifier be connected with silicon drifting detector and is connected with charge-sensitive preamplifier; The sample box that described sample stage comprises manual rotation displacement platform, is positioned at position, the angle platform on manual rotation displacement platform and is positioned on the platform of position, angle, is placed with cosmetic sample in sample box; Described analyzer is the digital multichannel spectrometer be connected with pulse-shaping amplifier; Described circuit output device comprises the computing machine carrying out data analysis that is connected with digital multichannel spectrometer and the printer of the data gone out for output display Computer Analysis be connected with computing machine and display; Regulate position and the angle of sample stage, the X ray that X-ray tube is sent is radiated on cosmetic sample that sample stage is placed with low-angle, excite the feature X-fluorescence information of heavy metal element in cosmetic sample, fluorescence information is received by silicon drifting detector, is converted into the power spectrum for analyzing and carries out data processing and control by computing machine after pulse-shaping amplifier is shaped amplification by digital multichannel spectrometer.
Further, described manual rotation displacement platform can move up and down 10mm respectively, moves left and right 10mm, movable 10mm, rotating 360 degrees.
Further, position, described angle platform precision is 0.35 degree, and regulate position, angle corner of table degree, the X ray that excitation source is sent is to be less than the angular illumination of 0.5 degree on cosmetic sample.
Further, described X-ray tube high pressure is 15000 volts.
Further, the diameter of described collimating apparatus is 2mm, length 40mm.
Further, the spacing of the X ray that the X-ray tube of described excitation source sends and sample box is 50 millimeters, and angle is less than 0.5 degree.
Further, the spacing of described silicon drifting detector and sample box is 15mm, and angle is 90 degree.
Further, described excitation source, sniffer, sample stage and analyzer are all arranged in iron case, and described iron case thickness is the stainless steel of 1mm.
The utility model has following beneficial effect:
(1). adopt and plunder into formula x-ray fluorescence analysis principle, the content of Heavy Metals in Cosmetics can be detected fast, simple and fast and low cost;
(2). because X-ray tube high pressure is 15000 volts, the X-ray energy sent is up to 15keV, through stainless steel shielding without any leakage, therefore does not have radiation damage to user of service;
(3). owing to adopting silicon drifting detector comparatively advanced now and multichannel analyzer, so precision is high, Measuring Time is short, and personal error is little, and operator's labour intensity is low;
(4). the utility model X-fluorescence check weighing metal instrument without chemical contamination, no radioactivity pollute, Measuring Time is short, precision is high, structure is simple, safe and reliable, easy to use.
Accompanying drawing illustrates:
Fig. 1 is the structural drawing of plunderring into formula X-fluorescence measurement mechanism that the utility model detects Heavy Metals in Cosmetics content fast.
Fig. 2 is the detection energy spectrogram of Pb in Cosmetics (Pb) element in embodiment 1.
Fig. 3 is the detection energy spectrogram of Mercury In Cosmetics (Hg) element in embodiment 1.
Wherein:
1-X light pipe; 2-collimating apparatus; 3-silicon drifting detector; 4-sample box; 5-iron case; 6-X light pipe high pressure; 7-detector high pressure; 8-charge-sensitive preamplifier; 9-pulse-shaping amplifier; 10-digital multichannel spectrometer; 11-computing machine; 12-manual rotation displacement platform; Position, 13-angle platform.
Embodiment:
Please refer to shown in Fig. 1, a kind of quick detection Heavy Metals in Cosmetics content of the utility model plunder into formula X-fluorescence measurement mechanism, it comprises excitation source, sniffer, sample stage, analyzer and circuit output device; Excitation source comprises X-ray tube 1, X-ray tube high pressure 6 and be arranged at the collimating apparatus 2 in X-ray tube 1 exit; The pulse-shaping amplifier 9 that sniffer comprises silicon drifting detector 3, detector high pressure 7, the charge-sensitive preamplifier 8 be connected with silicon drifting detector 3 and is connected with charge-sensitive preamplifier 8; The sample box 4 that sample stage comprises manual rotation displacement platform 12, is positioned at position, the angle platform 13 on manual rotation displacement platform 12 and is positioned on position, angle platform 13, wherein cosmetic sample is positioned in sample box 4; Analyzer is the digital multichannel spectrometer 10 be connected with pulse-shaping amplifier 9; Circuit output device comprises the computing machine 11 carrying out data analysis that is connected with digital multichannel spectrometer 10 and the printer of the data analyzed for output display computing machine 11 be connected with computing machine 11 and display.Regulate position and the angle of sample stage, the X ray that X-ray tube is sent is radiated on cosmetic sample that sample stage is placed with low-angle, after exciting the feature X-fluorescence information of heavy metal element in cosmetic sample, received by silicon drifting detector, through digital multichannel spectrometer, pulse-shaping amplifier signal is converted into the power spectrum that can be used for analyzing, finally carries out data processing and control by computing machine.
Wherein manual rotation displacement platform 12 can move up and down 10mm respectively, moves left and right 10mm, movable 10mm, rotating 360 degrees.Wherein position, angle platform 13 precision is 0.35 degree, and by regulating position, angle platform 13 angle, the X ray that excitation source is sent is radiated on cosmetic sample with low-angle (being less than 0.5 degree), is formed to plunder to excite form into formula X-fluorescence.X-ray tube 1 high pressure is 15000 volts.The diameter of collimating apparatus 2 is 2mm, length 40mm.The spacing of the X ray that the X-ray tube 1 of excitation source sends and sample box 4 is 50 millimeters, and angle is less than 0.5 degree.Silicon drifting detector 3 is 15mm with the spacing of sample box 4, and angle is 90 degree.Wherein excitation source, sniffer, sample stage and analyzer are all arranged in iron case 5, and the thickness of iron case 5 is the stainless steel of 1mm, fix for the radiation protection of X ray and inner body.
The principle of work of plunderring into formula X-fluorescence measurement mechanism that the utility model detects Heavy Metals in Cosmetics content is fast: by regulating position and the angle of sample stage, the X ray that excitation source is sent is radiated on cosmetic sample with low-angle, excite the feature X-fluorescence information of heavy metal element in cosmetic sample, this fluorescence information is accepted by silicon drifting detector 3 and is converted into electric signal, be converted into by digital multichannel spectrometer 10 power spectrum that can be used for analyzing again after pulse-shaping amplifier 9 is shaped amplification, data analysis is carried out again by computing machine 11, because spy's XRF seized with terror of the heavy metal that the concentration of heavy metal and device obtain is counted as direct ratio in sample, so the content of heavy metal in sample can be drawn as calculated after machine 11 data analysis, finally by printer and display, data are exported.
Embodiment 1:
1. adopt Dandong Dongfang Electronics pipe factory silver target X-ray tube 1, X-ray tube high pressure 6 is set to 15000 volts, can spy's XRF seized with terror of heavy metal in excited sample effectively; Adopt position, the angle platform 13 of Japanese Sigma, the X ray that excitation source is launched and the angle of sample surfaces are 0.35 degree, and the distance of X-ray tube l and sample surfaces is 50 millimeters, and the diameter of collimating apparatus 2 is 2 millimeters, ensure that check weighing metal instrument obtains best resolution.
2. adopt angle between U.S. amptek company SDD-123 silicon drifting detector 3 and sample surfaces to be 90 degree, distance is 15 millimeters, and these are to ensure that analyser obtains good resolution equally.
3. excitation source, sniffer and digital multichannel spectrometer 10 is fixed in the iron case 5 of 1 millimeter, this iron case 5 not only plays the effect of electric shield, and play the effect of radiation shield, it make highest energy be 15keV the complete conductively-closed of X ray and without any leakage.
4. configure the cosmetic sample of different content of beary metal, often kind of sample measures 100s respectively.
5. the signal that silicon drifting detector 3 is collected utilizes pulse-shaping amplifier 9 to amplify, the power spectrum that can be used for analyzing is converted into afterwards through digital multichannel spectrometer 10, obtain plumbous energy spectrogram (as Fig. 2) and energy spectrogram (as Fig. 3) of mercury respectively, carry out data processing by computing machine again, obtain Heavy Metals in Cosmetics constituent content.
The above is only preferred implementation of the present utility model; should be understood that; for those skilled in the art, can also make some improvement under the prerequisite not departing from the utility model principle, these improvement also should be considered as protection domain of the present utility model.
Claims (8)
1. one kind detect fast Heavy Metals in Cosmetics content plunder into formula X-fluorescence measurement mechanism, it comprises excitation source, sniffer, sample stage, analyzer and circuit output device, it is characterized in that: described excitation source comprises X-ray tube (1), X-ray tube high pressure (6) and be arranged at the collimating apparatus (2) in X-ray tube (1) exit; The pulse-shaping amplifier (9) that described sniffer comprises silicon drifting detector (3), detector high pressure (7), the charge-sensitive preamplifier (8) be connected with silicon drifting detector (3) and is connected with charge-sensitive preamplifier (8); The sample box (4) that described sample stage comprises manual rotation displacement platform (12), is positioned at the position, angle platform (13) on manual rotation displacement platform (12) and is positioned on position, angle platform (13), sample box is placed with cosmetic sample in (4); Described analyzer is the digital multichannel spectrometer (10) be connected with pulse-shaping amplifier (9); Described circuit output device comprises the computing machine (11) carrying out data analysis that is connected with digital multichannel spectrometer (10) and the printer of the data analyzed for output display computing machine (11) be connected with computing machine (11) and display; Regulate position and the angle of sample stage, the X ray that X-ray tube (1) is sent is radiated on cosmetic sample that sample stage is placed with low-angle, excite the feature X-fluorescence information of heavy metal element in cosmetic sample, fluorescence information is received by silicon drifting detector, is converted into the power spectrum for analyzing and carries out data processing and control by computing machine (11) after pulse-shaping amplifier (9) is shaped amplification by digital multichannel spectrometer (10).
2. a kind of quick detection Heavy Metals in Cosmetics content as claimed in claim 1 plunder into formula X-fluorescence measurement mechanism, it is characterized in that: described manual rotation displacement platform (12) can move up and down 10mm respectively, move left and right 10mm, movable 10mm, rotating 360 degrees.
3. a kind of quick detection Heavy Metals in Cosmetics content as claimed in claim 1 plunder into formula X-fluorescence measurement mechanism, it is characterized in that: position, described angle platform (13) precision is 0.35 degree, regulate position, angle platform (13) angle, the X ray that excitation source is sent is to be less than the angular illumination of 0.5 degree on cosmetic sample.
4. the plunderring into formula X-fluorescence measurement mechanism of a kind of quick detection Heavy Metals in Cosmetics content as claimed in claim 1, is characterized in that: described X-ray tube high pressure (6) is 15000 volts.
5. the plunderring into formula X-fluorescence measurement mechanism of a kind of quick detection Heavy Metals in Cosmetics content as claimed in claim 1, is characterized in that: the diameter of described collimating apparatus (2) is 2mm, length 40mm.
6. a kind of quick detection Heavy Metals in Cosmetics content as claimed in claim 1 plunder into formula X-fluorescence measurement mechanism, it is characterized in that: the spacing of the X ray that the X-ray tube (1) of described excitation source sends and sample box (4) is 50 millimeters, and angle is less than 0.5 degree.
7. the plunderring into formula X-fluorescence measurement mechanism of a kind of quick detection Heavy Metals in Cosmetics content as claimed in claim 1, is characterized in that: described silicon drifting detector (3) is 15mm with the spacing of sample box (4), and angle is 90 degree.
8. a kind of quick detection Heavy Metals in Cosmetics content as claimed in claim 1 plunder into formula X-fluorescence measurement mechanism, it is characterized in that: described excitation source, sniffer, sample stage and analyzer are all arranged in iron case (5), described iron case (5) thickness is the stainless steel of 1mm.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520245739.9U CN204630955U (en) | 2015-04-21 | 2015-04-21 | Plunderring into formula X-fluorescence measurement mechanism of a kind of quick detection Heavy Metals in Cosmetics content |
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| CN201520245739.9U CN204630955U (en) | 2015-04-21 | 2015-04-21 | Plunderring into formula X-fluorescence measurement mechanism of a kind of quick detection Heavy Metals in Cosmetics content |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104807845A (en) * | 2015-04-21 | 2015-07-29 | 南京航空航天大学 | Grazing incidence X-ray fluorescence measuring device for quickly detecting heavy metal content in cosmetics |
| CN109827982A (en) * | 2017-11-23 | 2019-05-31 | 核工业西南物理研究院 | A kind of fast detector of heavy metal-polluted soil detection |
-
2015
- 2015-04-21 CN CN201520245739.9U patent/CN204630955U/en not_active Withdrawn - After Issue
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104807845A (en) * | 2015-04-21 | 2015-07-29 | 南京航空航天大学 | Grazing incidence X-ray fluorescence measuring device for quickly detecting heavy metal content in cosmetics |
| CN104807845B (en) * | 2015-04-21 | 2018-05-08 | 南京航空航天大学 | A kind of quick detection Heavy Metals in Cosmetics content is plunderred into Formula X fluorescence measuring device |
| CN109827982A (en) * | 2017-11-23 | 2019-05-31 | 核工业西南物理研究院 | A kind of fast detector of heavy metal-polluted soil detection |
| CN109827982B (en) * | 2017-11-23 | 2024-04-26 | 核工业西南物理研究院 | Quick detector for detecting heavy metals in soil |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| AV01 | Patent right actively abandoned |
Granted publication date: 20150909 Effective date of abandoning: 20180508 |
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| AV01 | Patent right actively abandoned |