CN203651231U - Transfer printing foil and decoration molding product - Google Patents

Transfer printing foil and decoration molding product Download PDF

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Publication number
CN203651231U
CN203651231U CN201320123070.7U CN201320123070U CN203651231U CN 203651231 U CN203651231 U CN 203651231U CN 201320123070 U CN201320123070 U CN 201320123070U CN 203651231 U CN203651231 U CN 203651231U
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China
Prior art keywords
transfer foil
layer
convex
concave
glossiness
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Expired - Lifetime
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CN201320123070.7U
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Chinese (zh)
Inventor
樋爪友美
渡边学
渡边恵
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Toppan Inc
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Toppan Printing Co Ltd
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  • Laminated Bodies (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

The utility model provides a transfer printing foil and a decoration molding product. The transfer printing foil can be used for enabling the decoration molding product to have a pearlescent appearance with third dimension. According to the transfer printing foil, a pearly luster layer containing a gloss material is directly formed on a concave-convex forming layer with a concave-convex shape. Therefore, the gloss material settled in the pearly luster layer is configured into a three-dimensional shape according to the concave-convex shape of the concave-convex forming layer. The gloss material is configured into a three-dimensional shape, so that the decoration molding product using the transfer printing foil has the pearlescent appearance with the three-dimensional surface.

Description

Transfer foil and decorated molded article
Technical field
The utility model relates to the decorated molded article after decorating for the transfer foil on decorative article surface and by this transfer foil.
Background technology
Used transfer foil to carry out incrustation to article in the past.Use the incrustation of transfer foil to be used to require in the various uses of the appearance design that vision attractability is high.For example, can enumerate the appliance body of (1) commodity or daily necessities etc.; (2) container class of food or various article; (3) framework class of electronic equipment or office appliance etc. etc.
For example, moulding decorative method below proposing time ((in mold) moulding in mould): transfer foil is put into die injection moulding, then closing molding, in this mould, penetrate molten resin, carry out injection mo(u)lding, manufacture and make the integrated decorated molded article of transfer foil (referring to patent documentation 1) thus.
On the other hand, as incrustation, known have a pearlescent appearance.In addition, as the method that pearlescent appearance is provided, the known method that has use transfer foil, described transfer foil is to obtain after using the ink that contains glossiness material to form stratiform.Generally, the real density of glossiness material is greater than ink, and sedimentation easily occurs in the time of coating ink in layer.Therefore, cause glossiness material to be arranged with two dimensional surface shape, and the face side of decorated molded article from incrustation is while observing, its outward appearance lacks third dimension.So, need to provide and there is relief pearlescent appearance.
For example, there is in order to provide the decorated molded article that presents relief pearlescent appearance, following organization plan is proposed: form two layers of pearl layer, be top layer side pearl layer and lower layer side pearl layer, and the particle diameter of the glossiness material using in top layer side pearl layer and lower layer side pearl layer differ from one another (referring to patent documentation 2).In addition, according to disclosed method in patent documentation 2, need to can see lower layer side pearl layer by top layer side pearl layer.Therefore, be necessary to make top layer side pearl layer to there is the transparency, and glossiness material used and attainable design are all restricted.
Prior art document
Patent documentation
Patent documentation 1: Japanese kokai publication hei 10-71680 communique
Patent documentation 2: Japanese Patent Publication 5-80793 communique
utility model content
Therefore, the utility model completes in order to address the above problem, and its objective is a kind of transfer foil that can give decorated molded article and have relief pearlescent appearance is provided.
An embodiment of the present utility model is a kind of transfer foil; it is characterized in that; comprise base material film, be laminated in release layer on described base material film, be laminated in sealer on described release layer, be laminated in concave-convex stratification on described sealer, be laminated in glossiness ink layer in described concave-convex stratification, be laminated in the adhesive layer in described glossiness ink layer, described glossiness ink layer is the pearl layer that contains glossiness ink material.
In addition, described glossiness pigment can be that apparent density is the more than 0.7 glossiness material below 1.8.
In addition, described concave-convex stratification can form by printing.
In addition, described concave-convex stratification can be by being used the different galley of version line number repeatedly to print and form.
In addition, described concavo-convex cambial concavo-convex can formation by hot pressing line processing method.
An embodiment of the present utility model is a kind of decorated molded article that utilizes above-mentioned transfer foil to carry out incrustation and to obtain.
Transfer foil of the present utility model has the structure that directly forms the pearl layer that contains glossiness material in the concave-convex stratification with concaveconvex shape.Therefore, in pearl layer, the glossiness material of sedimentation is configured to 3 D stereo shape according to concavo-convex cambial concaveconvex shape.Because glossiness material is with 3 D stereo shape configuration, so, use the decorated molded article of transfer foil of the present utility model can there is surface and present relief pearlescent appearance.
brief description of the drawings
Fig. 1 is the diagrammatic sectional view that represents one of transfer foil of the present utility model example.
Symbol description
1 ... base material film
2 ... release layer
3 ... transfer printing layer
4 ... sealer
6 ... adhesive layer
7 ... transfer foil
8 ... concave-convex stratification
9 ... pearl layer
Detailed description of the invention
Below transfer foil of the present utility model is described.
(base material film)
Base material film is the position as the matrix of transfer foil.
As base material film, can from there is flexible material, select suitable material to be used.For example can use the mylar such as (1) PET, polybutylene terephthalate, PEN; (2) vistanex such as polyethylene, polypropylene, polybutene, polymethylpentene, ethylene-propylene-butylene copolymer; (3) polyamide such as nylon 6, nylon 66; (4) polyvinyl chloride etc.Particularly single shaft or twin shaft extend polyester film, its excellent heat resistance, and when in-molded, can prevent that the resin temperature because penetrating from damage transfer foil, so preferably as the base material film using in transfer foil of the present utility model.In addition, base material film can also be the composite membrane of the multilayer that obtains of two or more film of laminating.
In addition, the thickness of base material film preferably more than 5 μ m below 200 μ m left and right scope in, more preferably more than 25 μ m below 100 μ m left and right scope in.The base material film of thickness in above-mentioned scope can such as, suitably be processed in various print processes (intaglio printing, hectographic printing, serigraphy, flexographic printing (flexography) etc.), and can efficiency produce well transfer foil.But in transfer foil of the present utility model, the thickness of base material film is not limited to above-mentioned scope.
(release layer)
Release layer is formed on described base material film.After making transfer foil and object article integrated, peel off base material film and release layer at the position of release layer, can make thus the outmost surface of obtained decorated molded thing become sealer described later.
In addition, as the material of release layer, can suitably select the known material as release property resin to be used.For example can use melmac, acrylic resin, mylar, polyurethane resin, fluororesin, organic siliconresin, epoxy resin etc.In addition, the material of release layer can be the resin compound that is mixed with various kinds of resin.Particularly melmac or by the isocyanates acrylic resin obtaining that hardens, excellent heat resistance, and when in-molded, can prevent that the resin temperature because penetrating from damage transfer foil, so, preferably as the material of the release layer using in transfer foil of the present utility model.
Can be formed release layer: make the dispersion of materials of release layer and be dissolved in solvent, preparing release layer coating fluid, being suitably coated with this release layer coating fluid by known coating formation method, and making it dry.Now, as coating formation method, for example, can use roller coat, reverse roller coat (reverse roll coat), intaglio plate coating, oppositely intaglio plate coating (reverse gravure coat), line rod to be coated with the coating processes such as (bar coating), bar type coating (rod coat), rubberizing (kiss coat), blade coating (knife coat), mould coating (die coat), comma shape scraper for coating (comma coat), flow coat (flow coat), spraying.
In addition, the thickness of release layer preferably more than 0.01 μ m below 5.0 μ m left and right scope in.The release layer of thickness in above-mentioned scope can utilize common various coating formation method to form the film of homogeneous.But in transfer foil of the present utility model, the thickness of release layer is not limited to above-mentioned scope.
(sealer)
Sealer is formed on above-mentioned release layer.After making transfer foil and object article integrated, sealer becomes the outmost surface of obtained decoration formation.
As the material of sealer, consider each physical property such as against weather, abrasion resistance, scratch resistance, chemical resistance, can be from known material choice for use suitably.For example, can use polyurethane resin, acrylic resin, mylar etc.
Can form by the following method sealer: make the dispersion of materials of sealer and be dissolved in solvent, preparing surperficial protective layer coating solution, suitably using known coating formation method, being coated with this sealer coating fluid, making it dry.Now, as coating formation method, for example, can use the coating processes such as roller coat, reverse roller coat, intaglio plate coating, oppositely intaglio plate coating, rod coating, bar type coating, rubberizing, blade coating, mould coating, comma shape scraper for coating, flow coat, spraying.
The thickness of sealer preferably more than 3 μ m below 15 μ m left and right scope in.But in transfer foil of the present utility model, the thickness of sealer is not limited to above-mentioned scope.
In addition, as the material of sealer, preferably use curable with actinic energy ray resin.Curable with actinic energy ray resin is by irradiating active energy ray, makes the resin that between the functional group in resin, generation is cross-linked and hardens.As curable with actinic energy ray resin, for example, can enumerate resin at least containing acryloyl group or methacryl etc.While using curable with actinic energy ray resin as the material of sealer, after making transfer foil and object article integrated, by irradiating active energy ray, can bring into play following effect: (1) is maintaining under thermoplastic state sealer, the surface configuration of tracing object article on one side, carries out transfer printing on one side; (2), after moulding transfer foil, by being cross-linked sclerosis, improve the surface strength at the outmost surface position of decorated molded article.Therefore,, by using the material of curable with actinic energy ray resin as sealer, can realize mouldability and sufficient hardness (painting property firmly) simultaneously.
While using curable with actinic energy ray resin as the material of sealer; form after sealer in coating; can (1) irradiate active energy ray, (2) heating etc. with not exclusively crosslinked degree, make sealer become not exclusively (part) crosslinked state.Be incomplete (part) crosslinked state by making sealer, can bring into play following effect: (1), compared with uncrosslinked state, can be dried more completely, and improve the treatability of transfer foil; (2) suppress the mobile etc. of sealer that heat when being transferred to object article or stress causes.
(concave-convex stratification)
Concave-convex stratification is formed on above-mentioned sealer.Concave-convex stratification has concaveconvex shape on bed boundary.
As concavo-convex cambial material, can be in the processability of considering (1) concaveconvex shape; (2) for after making transfer foil and object article integrated, can be observed pearl layer by concave-convex stratification, the in the situation that of need to thering is light transmission etc. in visible region, choice for use suitably from known material.For example can use transparent ink, bonding agent, thermosetting resin (two liquid reaction type polyurethane resins, vinyl chloride, acetate ethylene copolymer resin etc.), cellulose derivative etc.
In addition, can form described concave-convex stratification by printing.Can be by printed layers have or not to form concaveconvex shape.
Being used for printing concavo-convex cambial formation method can suitably select from known method.For example can use intaglio printing, hectographic printing, intaglio printing, serigraphy, flexographic printing, electrostatic printing, ink jet printing etc.
Concavo-convex cambial thickness preferably more than 1 μ m below 10 μ m left and right scope in.But in transfer foil of the present utility model, concavo-convex cambial thickness is not limited to above-mentioned scope.
In addition, described concave-convex stratification can be by being used the different galley of version line number repeatedly to print and form.By using the different galley of version line number repeatedly to print, can form the concaveconvex shape of the ink film version line based on printed.For example, in intaglio printing, by using version line number different galley repeatedly to print, can form the concaveconvex shape due to oblique line shape/netted version line.
In addition, also can form by hot pressing line (emboss) processing method described concavo-convex cambial concavo-convex.Hot pressing line processing method is on one side thermosetting resin to be heated on one side and pushes embossing plate, thus the mould transfer printing of the concaveconvex shape of transfer printing embossing plate.
(pearl layer)
Pearl layer is formed at described concavo-convex cambial positive upper strata.In addition, pearl layer contains glossiness material, so given pearlescent appearance.
Pearl layer is by coating, the pearl layer coating fluid that glossiness dispersion of materials obtains in ink to be formed.Now, because the real density of glossiness material is greater than ink, so easily sedimentation in coated surface in the time of coating ink is deposited in pearl layer and concavo-convex cambial interface.Owing to being provided with concaveconvex shape at the interface of concave-convex stratification and pearl layer, present third dimension so pile up the face of glossy property material along concaveconvex shape.Therefore,, in the decorated molded article after making transfer foil and object article integrated, in the time observing from outer surface, glossiness material with the configuration of 3 D stereo shape, has relief pearlescent appearance so can be observed according to concavo-convex cambial concaveconvex shape.In addition, in the time observing from the outer surface of decorated molded article, owing to observing pearl layer by concave-convex stratification, so must there is the transparency without pearl layer.Therefore, be not limited to there is transparent glossiness material, can select glossiness material.Thereby can make the range of choice of glossiness material used broaden, so can realize various appearances design.
As glossiness material, can from can make the material of light generation scattering, dispersion, suitably select and use.For example can use: (1) pulverizes the material that shell inner side partly obtains; (2) by the material obtaining after crushing pearl; (3) mica (mica); (4) utilize TiO 2the material that covers mica particulate and obtain; (5) utilize metal oxide to cover mica particulate and the material that obtains; (6) metal particle powder such as aluminium powder etc.
Make the ink of glossiness dispersion of materials, can from known ink, select and use according to selected glossiness material.In addition, can, according to desirable appearance design, in the ink that makes glossiness dispersion of materials, add the colouring agent such as dyestuff or pigment, extender pigment.
For the coating formation method for being coated with pearl layer, can, according to selected glossiness material and ink, from known method, suitably select.For example can use intaglio printing, hectographic printing, intaglio printing, serigraphy, flexographic printing, electrostatic printing, ink jet printing etc.
In addition, preferably apparent density glossiness material in the scope of left and right below 1.8 more than 0.7 of glossiness material.If the apparent density of glossiness pigment is too small with respect to above-mentioned scope, the dispersiveness of glossiness material in ink improves, and glossiness material is difficult to be deposited in pearl layer and concavo-convex cambial interface, so be difficult to present concavo-convex cambial effect, third dimension declines.In addition, if the density of glossiness material is excessive with respect to above-mentioned scope, the dispersed excessive descent of glossiness material in ink, so, the sedimentation in ink of glossiness material, and significantly variation of coating.But in transfer foil of the present utility model, the apparent density of glossiness material used is not limited to above-mentioned scope.
In addition, about the addition of glossiness material, with respect to 100 mass parts by glossiness dispersion of materials in ink and the pearl layer coating fluid obtaining, glossiness pigment is preferably more than 1 mass parts below 30 mass parts in the scope of left and right.But in transfer foil of the present utility model, the addition of the glossiness material using is not limited to above-mentioned scope.
In addition, the particle diameter of glossiness material preferably more than 1 μ m below 60 μ m left and right scope in.Glossiness material in above-mentioned scope can such as, be coated with well in various print processes (intaglio printing, hectographic printing, serigraphy, flexographic printing etc.).But in transfer foil of the present utility model, the particle diameter of the glossiness material using is not limited to above-mentioned scope.
(adhesive layer)
Adhesive layer is formed on described pearl layer.Adhesive layer is to contact with object article in the time making transfer foil and object article integrated, and makes transfer foil and the bonding position of object article.
Can suitably select from having when normal temperature, the heating with tack, the fusible material of the surfacing of object article for the material of adhesive layer.Particularly, can from the known material such as bonding agent, adhesive, heat-fusible materials, suitably select.For example can use separately the resins such as acrylic resin, epoxy resin, vinyl acetate resinoid, vinyl chloride resin, isocyanates resinoid, silicone based resin, styrene-butadiene resinoid, vinyl chloride-vinyl acetate resinoid, ethene-vinyl acetate resinoid, polyester resin, chlorinated rubber class, chlorinated polypropylene resinoid, polyurethanes resin, or use latex resin taking the mixture of above-mentioned resin as principal component, organic solvent type resin, water-soluble resin etc.
In addition, as the formation method of adhesive layer, can be according to the material for adhesive layer, suitably use known coating formation method, be coated with and make it dry, form thus adhesive layer.As coating formation method, for example, can use the printing processes such as (1) intaglio printing, hectographic printing, serigraphy; (2) roller coat, reverse the coating processes such as the coating of roller coat, intaglio plate, oppositely intaglio plate coating, rod coating, bar type coating, rubberizing, blade coating, mould coating, comma shape scraper for coating, flow coat, spraying, extrusion coated etc.
In addition, the thickness of adhesive layer preferably more than 0.5 μ m below 10 μ m left and right scope in.But in transfer foil of the present utility model, the thickness of adhesive layer is not limited to above-mentioned scope.
In addition, transfer foil of the present utility model, as long as directly form the structure of the pearl layer that contains glossiness material in the concave-convex stratification with concaveconvex shape, can be brought into play desired effect.Therefore, transfer foil of the present utility model can also be following structure: further additionally increase functional layer in other bed boundarys except the bed boundary of concave-convex stratification/pearl layer.
Fig. 1 represents the diagrammatic sectional view of one of transfer foil 7 of the present utility model example.
Transfer foil 7 shown in Fig. 1 closes release layer 2 and transfer printing layer 3 at a surface layer of base material film 1.Transfer printing layer 3 is the sequential laminatings with sealer 4/ concave-convex stratification 8/ pearl layer 9/ adhesive layer 6.In the concave-convex stratification 8 with concaveconvex shape, directly form the pearl layer 9 that contains glossiness pigment, so the glossiness material in pearl layer 9 configures in three-dimensional mode.In addition, the concaveconvex shape of concave-convex stratification 8 is removed by pearl layer 9, so the surface of the adhesive layer 6 contacting with decorated molded article is level and smooth.
Below decorated molded article of the present utility model is described.
Decorated molded article of the present utility model is the decorated molded article that uses above-mentioned transfer foil.By transfer foil of the present utility model is transferred to object article, and peel off base material film and peel ply, can obtain thus sealer is the decorated molded thing of outmost surface.
In addition, about the material of the object article of transfer printing transfer foil, as long as can with the material of the material adhesive selected in the adhesive layer of transfer foil, be not particularly limited.For example, the material of object article can be the vistanex such as polyethylene, polypropylene; Acrylic resin; Vinyl chloride resin; Acrylonitrile-butadiene-styrene copolymer (ABS resin); Polycarbonate resin; Phenolic resins etc.In addition, as long as suitably select printing transferring method according to shape, so the shape of object article is not particularly limited.For example, the shape of object article can be thin slice (film), flat board, curved slab, clava, stereoscopic article etc.
In addition, can use moulding decorative method (in-molded) simultaneously,, after transfer foil is put into die injection moulding, mould is closed, and carry out injection mo(u)lding to penetrating molten resin in this mould, make thus transfer foil and article shaped integrated, thereby manufacture decorated molded article.In-molded by using, can give preferably appearance design to the article with 3D shape (curve form, concaveconvex shape, have hole shape etc.).
[embodiment]
< embodiment 1 >
Lower mask body is enumerated an embodiment transfer foil of the present utility model and decorated molded article is described.
(manufacture of transfer foil)
First, on base material film, form release layer.
Now, form release layer by be coated with release layer coating fluid on base material film.Release layer coating fluid uses melmac class coating fluid.Utilize intaglio plate rubbing method coating release layer coating fluid.In addition, base material film uses twin shaft to extend polyethylene terephthalate film (thickness: 50 μ m).The dry thickness of the release layer forming in addition, is 0.5 μ m.
Next, on release layer, form sealer.
Now, form sealer by coating surface protective layer coating solution on release layer.Sealer coating fluid uses UV cured type acrylic resin.Utilize reverse intaglio plate rubbing method coating surface protective layer coating solution.The dry thickness of the sealer forming in addition, is 10.0 μ m.
Next, on sealer, form concave-convex stratification.
Now, concave-convex stratification is to form by using the different galley of version line number to carry out secondary intaglio printing.Thus, can on coated face, form concavo-convex by version line.In intaglio printing for the first time, use line number is that the intaglio plate of 175 lines prints, and making dried thickness is 1.0 μ m.In intaglio printing for the second time, use line number is that the intaglio plate of 150 lines prints, and making dried thickness is 1.2 μ m.In addition, the ink using in intaglio printing is thermmohardening type ink.
Next, in concave-convex stratification, form pearl layer.
Now, form pearl layer by coating pearl layer coating fluid.Pearl layer coating fluid is to be added with 5 mass parts glossiness materials (average grain diameter: 30 μ intaglio plate ink m).Utilize intaglio printing coating pearl layer coating fluid.The dry thickness of the pearl layer forming in addition, is 0.5 μ m.
Next, on pearl layer, form adhesive layer.
Now, adhesive layer uses acrylic resin.The dry thickness of the adhesive layer forming in addition, is 2.0 μ m.
Can manufacture thus sequential laminating, transfer foil of the present utility model with film base material/release layer/sealer/concave-convex stratification/pearl layer/adhesive layer.
(using the manufacture of the decorated molded article of transfer foil)
The transfer foil of the present utility model of above-mentioned manufacture is configured in mould, adhesive layer one side to transfer foil penetrates resin, takes out resin formed product, at the release layer position of transfer foil from mould, peel off base material film and release layer from resin formed product, thereby obtain decorated molded article (in-molded).
Next, the decorated molded article that effects on surface protective layer is outmost surface carries out ultraviolet ray and irradiates, and makes the crosslinked sclerosis of sealer.Now, use high-pressure sodium lamp with 120W/cm irradiation ultraviolet radiation, accumulated light reaches 1000mJ/cm 2.
Obtain thus decorated molded article of the present utility model.The outmost surface of the decorated molded article obtaining is sealer, and outmost surface is level and smooth.In addition, while observing the decorated molded article obtaining, can observe and there is relief pearlescent appearance.
Industry utilizability
Transfer foil of the present utility model is expected at the article that field need to be decorated for surface widely.For example can be for fields such as portable data assistance framework, PC framework, air-conditioning framework, TV framework, camera framework, household appliances guidance panel, acoustic product panel, various instrument touch panel, sheet for interior material, automobile exterior material, bicycle assembly parts, Container for cosmetics, food exterior material, tableware, toiletry, toys.

Claims (5)

1. a transfer foil, is characterized in that, comprising:
Base material film,
Be laminated in release layer on described base material film,
Be laminated in sealer on described release layer,
Be laminated in concave-convex stratification on described sealer,
Be laminated in glossiness ink layer in described concave-convex stratification and
Be laminated in the adhesive layer in described glossiness ink layer.
2. transfer foil according to claim 1, is characterized in that, described concave-convex stratification forms by printing.
3. transfer foil according to claim 1, is characterized in that, described concave-convex stratification is by being used the different galley of version line number repeatedly to print and form.
4. transfer foil according to claim 1, is characterized in that, described concavo-convex cambial concavo-convex be to form by hot pressing line processing method.
5. a decorated molded article is to utilize the transfer foil described in any one in claim 1 to 4 carry out incrustation and obtain.
CN201320123070.7U 2012-03-19 2013-03-18 Transfer printing foil and decoration molding product Expired - Lifetime CN203651231U (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2012-061864 2012-03-19
JP2012061864A JP2013193298A (en) 2012-03-19 2012-03-19 Transfer foil and decorative molded object

Publications (1)

Publication Number Publication Date
CN203651231U true CN203651231U (en) 2014-06-18

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