CN202332579U - Metallic film capacitor - Google Patents

Metallic film capacitor Download PDF

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Publication number
CN202332579U
CN202332579U CN2011202838918U CN201120283891U CN202332579U CN 202332579 U CN202332579 U CN 202332579U CN 2011202838918 U CN2011202838918 U CN 2011202838918U CN 201120283891 U CN201120283891 U CN 201120283891U CN 202332579 U CN202332579 U CN 202332579U
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Prior art keywords
metallic film
electrode
film
metal film
exit
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CN2011202838918U
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Chinese (zh)
Inventor
邓朝勇
马亚林
石健
崔瑞瑞
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Guizhou University
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Guizhou University
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Abstract

The utility model discloses a metallic film capacitor. The metallic film capacitor comprises an insulating substrate, wherein a metallic film electrode with a lead-out end is arranged on the top of the insulating substrate, a dielectric film is arranged on the surface of the metallic film electrode outside an lead-out end interface, and a metallic film electrode with a lead-out end is arranged on the top of the dielectric film. According to the utility model, two metallic film layers with small thickness are deposited by using a mask process and are utilized as an upper electrode and a lower electrode, thereby greatly reducing the use amount of metal, lowering the production cost and simplifying the fabrication process. The dielectric film has the advantages of small thickness, high mechanical strength and high stability, and is suitable for various complex environments. The metallic film capacitor provided by the utility model can be manufactured through industrial production to realize important practical significance, and has the advantages of low manufacture cost, high physical performance and chemical stability, long service life, lower manufacture cost and high application value.

Description

Metallic film electric capacity
Technical field
The utility model relates to a kind of electric capacity and reaches especially a kind of metallic film electric capacity.
Background technology
The thin-film capacitor range of capacity is wide, and operating voltage range is extremely wide, good temp characteristic, and stability is high, can realize metallization, has self-healing property, is widely used in a plurality of industries such as electronics, space flight, communication, military affairs.Along with China's digitlization, informationization, networked construction process are constantly accelerated; And the development of very lagre scale integrated circuit (VLSIC); Require electronic component miniaturization, filmization and multifunction, this makes conventional plastic film and silicon dioxide reach certain limit as main capacitor dielectric material.Problems such as present electric capacity exists the dielectric constant of medium low, and heat-resisting poor, film forming is poor, and mechanical strength is low.
Summary of the invention
The purpose of the utility model is: a kind of metallic film electric capacity is provided, and its each item performance is outstanding, with low cost, is easy to industrialization, to overcome the deficiency of prior art.
The utility model is achieved in that metallic film electric capacity; Comprise insulated substrate; Be provided with the metal film electrode
Figure 735176DEST_PATH_IMAGE001
of band exit
Figure 818035DEST_PATH_IMAGE001
at the top of insulated substrate; Be provided with dielectric film on metal film electrode
Figure 441281DEST_PATH_IMAGE001
surface outside exit interface, be provided with the metal film electrode
Figure 484640DEST_PATH_IMAGE002
of band exit
Figure 662178DEST_PATH_IMAGE002
at the top of dielectric film.
On exit
Figure 751673DEST_PATH_IMAGE001
and exit
Figure 481732DEST_PATH_IMAGE002
surface in addition, all be provided with the passivation protection film, its material is silicon dioxide or silicon nitride.Material requirements as the passivation protection film has good insulation performance and temperature stability.
The thickness of metal film electrode
Figure 150611DEST_PATH_IMAGE001
and metal film electrode
Figure 143974DEST_PATH_IMAGE002
is respectively 0.1~0.3 μ m, and their material is one or more the alloy in tantalum, niobium, aluminium, copper, the silver.It is very low that these metals and their alloy have resistivity, but high temperature high voltage resistant has high stability, can adapt to characteristics such as various complicated.
The thickness of dielectric film is 0.04~0.06 μ m, and its material is tantalum pentoxide or aluminium oxide.Their dielectric constant is high, good heat resistance, and good film-forming property, mechanical strength is high, and the insulating properties energy consumption of the dielectric film for preparing can prevent capacitance short-circuit, reduces leakage current.
Tantalum pentoxide and aluminium oxide have very high dielectric constant (tantalum pentoxide is 27, and aluminium oxide is 39.9, and plastic film is about 3), fusing point high (tantalum pentoxide is about 1800 ℃), stable chemical performance, corrosion-resistant and Heat stability is good.Be dielectric film capacitor CV density big (be under the same voltage conditions, the capacitance of unit volume is big) with tantalum pentoxide or aluminium oxide etc., (ESR) is little for equivalent series resistance, and leakage current is little.The metal film electrode of deposition has the self-recovery performance, and the reliability of opposing insulation breakdown is higher, can under extraordinary conditions such as high temperature or low temperature, use, and has long-term stability.This thin-film capacitor can be applied in numerous high-tech areas such as electronics, space flight, military affairs.
Owing to adopted above-mentioned technical scheme, compared with prior art, the utility model deposits the less metal film of two layers of thickness as upper/lower electrode through masking process, has greatly reduced metal consumption, has reduced production cost, and manufacture craft is simple.The thickness of dielectric film is little, and mechanical strength is high, has advantages of higher stability, can adapt to various complicated.The utility model can carry out vegetation through the production of industrialization, have important practical significance, and the cost of making is comparatively cheap; And resulting product has better physical performance and chemical stability; Long service life, cost of manufacture is lower, is with a wide range of applications.
Description of drawings
Fig. 1 is the structural representation of the utility model;
Fig. 2 is the vertical view of Fig. 1;
Description of reference numerals:
1-metal film electrode
Figure 304828DEST_PATH_IMAGE001
; The 2-dielectric film; 3-metal film electrode
Figure 41840DEST_PATH_IMAGE002
; The 4-insulated substrate; 5-passivation protection film; 6-exit
Figure 96384DEST_PATH_IMAGE001
; 7-exit .
Embodiment
The embodiment 1 of the utility model: the structure of metallic film electric capacity is as shown in Figure 1, comprises aluminium oxide (Al 2O 3) insulated substrate 4 processed, be provided with the band exit at the top of insulated substrate 4 7 metal film electrode 1, metal film electrode
Figure 92973DEST_PATH_IMAGE001
1 thickness is 0.2 μ m, and material is a tantalum, at exit
Figure 959298DEST_PATH_IMAGE001
The metal film electrode that 6 interfaces are outer
Figure 688219DEST_PATH_IMAGE001
1 surface is provided with the dielectric film 2 that thickness is 0.05 μ m, and its material is a tantalum pentoxide; Be provided with the band exit at the top of dielectric film 2
Figure 767034DEST_PATH_IMAGE002
7 metal film electrode 3, metal film electrode
Figure 941718DEST_PATH_IMAGE002
3 thickness is 0.2 μ m, and material is a niobium; At exit
Figure 423515DEST_PATH_IMAGE001
6 and exit All being provided with the silicon nitride on the surface beyond 7 is the passivation protection film 5 of material.
The preparation method of metallic film electric capacity is at the aluminium oxide (Al of cleaning 2O 3) lay one deck mask on the insulated substrate, adopt magnetron sputtering method, be material with the tantalum, deposit the thick metal film electrode of more than one 0.20 μ m
Figure 65029DEST_PATH_IMAGE001
, obtain semi-finished product A; A heat-treats with semi-finished product, and heat treated temperature is 750 ℃, and the processing time is 30 minutes; Laying mask handling on the semi-finished product A, and adopted magnetron sputtering method, is material with the tantalum pentoxide, and depositing thickness is the matter film of 0.05 μ m, obtains semi-finished product B; B heat-treats with semi-finished product, and heat treated temperature is 750 ℃, and the processing time is 30 minutes; On the semi-finished product B that handled, laying mask, adopt magnetron sputtering method, is material with the niobium, and depositing thickness is 0.20 μ m metal film electrode
Figure 7577DEST_PATH_IMAGE002
, and at metal film electrode ,
Figure 397287DEST_PATH_IMAGE002
On reserve exit respectively And exit
Figure 983306DEST_PATH_IMAGE002
, obtain semi-finished product C; C heat-treats with semi-finished product, and heat treated temperature is 750 ℃, and the processing time is 30 minutes; Adopt magnetron sputtering method; With the silicon nitride is material; Deposit the passivation protection film on the semi-finished product C surface beyond the exit, after the semi-finished product C that will deposit the passivation protection film again cuts, obtain the single metal thin-film capacitor; And with coated with graphite back spray silver slurry extraction electrode on exit, packing obtains finished product after handling again.
The utility model Example 2: Metal film capacitors, including aluminum nitride insulating substrate 4, the top of the insulating substrate 4 has a leading end with
Figure 315062DEST_PATH_IMAGE001
6 metal film electrodes
Figure 539370DEST_PATH_IMAGE001
1, the metal film electrodes
Figure 132025DEST_PATH_IMAGE001
1 has a thickness of 0.1μm , material is aluminum, the terminals
Figure 416376DEST_PATH_IMAGE001
6 interfaces of the metal film electrodes
Figure 828903DEST_PATH_IMAGE001
1 has a thickness of 0.04μm on the surface of the dielectric film 2, the material is tantalum pentoxide; the top of the dielectric film 2 has a leading end with
Figure 263426DEST_PATH_IMAGE002
7 of metal film electrodes
Figure 445009DEST_PATH_IMAGE002
3, the metal film electrodes
Figure 634682DEST_PATH_IMAGE002
3 has a thickness of 0.1μm, material for the silver; at terminals
Figure 65663DEST_PATH_IMAGE001
6 and terminations
Figure 631773DEST_PATH_IMAGE002
7 outside surface has a silica-based material passivation film 9.
The preparation method of metallic film electric capacity; On the aluminium nitride insulated substrate of cleaning, lay one deck mask; Adopt magnetron sputtering method; With aluminium is material, deposits the thick metal film electrode of more than one 0.10 μ m
Figure 838502DEST_PATH_IMAGE001
, obtains semi-finished product A; A heat-treats with semi-finished product, and heat treated temperature is 700 ℃, and the processing time is 35 minutes; Laying mask handling on the semi-finished product A, and adopted magnetron sputtering method, is material with the tantalum pentoxide, and depositing thickness is the matter film of 0.04 μ m, obtains semi-finished product B; B heat-treats with semi-finished product, and heat treated temperature is 700 ℃, and the processing time is 35 minutes; On the semi-finished product B that handled, lay mask; Adopt magnetron sputtering method; With silver is material; Depositing thickness is 0.10 μ m metal film electrode
Figure 199076DEST_PATH_IMAGE002
; And on metal film electrode
Figure 586195DEST_PATH_IMAGE001
,
Figure 487155DEST_PATH_IMAGE002
, reserve exit
Figure 377750DEST_PATH_IMAGE001
and exit
Figure 174805DEST_PATH_IMAGE002
respectively, obtain semi-finished product C; C heat-treats with semi-finished product, and heat treated temperature is 700 ℃, and the processing time is 35 minutes; Adopt the PECVD method; On the semi-finished product C surface beyond the exit, deposit silicon dioxide passivation protection film; After the semi-finished product C that will deposit the passivation protection film again cuts, obtain the single metal thin-film capacitor, and to the exit metal spraying; Through the wave-soldering extraction electrode, packing obtains finished product after handling again on gilding layer.
The utility model Example 3: metal film capacitors, including a ceramic substrate made of an insulating substrate 4, the top of the insulating substrate 4 has a leading end with
Figure 190166DEST_PATH_IMAGE001
7 metal film electrodes
Figure 363658DEST_PATH_IMAGE001
1, the metal film electrodes
Figure 905498DEST_PATH_IMAGE001
1 has a thickness of 0.3μm , the material is copper alloy, at terminals
Figure 873454DEST_PATH_IMAGE001
6 interfaces of the metal film electrodes
Figure 969586DEST_PATH_IMAGE001
1 on the surface of a dielectric film thickness of 0.06μm 2, the material is alumina; dielectric film 2 in the top of a bathroom with terminals
Figure 87714DEST_PATH_IMAGE002
7 of metal film electrodes 3, the metal film electrodes
Figure 91760DEST_PATH_IMAGE002
3 has a thickness of 0.3μm, material is copper niobium alloys; at terminals
Figure 206346DEST_PATH_IMAGE001
6 and terminations
Figure 456062DEST_PATH_IMAGE002
7 on a surface other than have a silicon nitride passivation film as the material 5.
The preparation method of metallic film electric capacity; On the ceramic substrate insulated substrate of cleaning, lay one deck mask; Adopt magnetron sputtering method; With the albronze is material, deposits the thick metal film electrode of more than one 0.30 μ m
Figure 847860DEST_PATH_IMAGE001
, obtains semi-finished product A; A heat-treats with semi-finished product, and heat treated temperature is 800 ℃, and the processing time is 25 minutes; Laying mask handling on the semi-finished product A, and adopted magnetron sputtering method, is material with the aluminium oxide, and depositing thickness is the matter film of 0.06 μ m, obtains semi-finished product B; B heat-treats with semi-finished product, and heat treated temperature is 800 ℃, and the processing time is 25 minutes; On the semi-finished product B that handled, lay mask; Adopt magnetron sputtering; With the copper niobium alloy is material; Depositing thickness is 0.30 μ m metal film electrode
Figure 157619DEST_PATH_IMAGE002
; And on metal film electrode
Figure 228343DEST_PATH_IMAGE001
,
Figure 812908DEST_PATH_IMAGE002
, reserve exit
Figure 652688DEST_PATH_IMAGE001
and exit
Figure 133348DEST_PATH_IMAGE002
respectively, obtain semi-finished product C; C heat-treats with semi-finished product, and heat treated temperature is 800 ℃, and the processing time is 25 minutes; Adopt the PECVD method; With the silicon nitride is material; Deposit the passivation protection film on the semi-finished product C surface beyond the exit, after the semi-finished product C that will deposit the passivation protection film again cuts, obtain the single metal thin-film capacitor; And with coated with graphite back spray silver slurry extraction electrode on exit, packing obtains finished product after handling again.

Claims (4)

1. metallic film electric capacity; Comprise insulated substrate (4); It is characterized in that: the metal film electrode I (1) that is provided with band exit I (6) at the top of insulated substrate (4); Be provided with dielectric film (2) on metal film electrode I (1) surface outside exit I (6) interface, be provided with the metal film electrode II (3) of band exit II (7) at the top of dielectric film (2).
2. metallic film electric capacity according to claim 1 is characterized in that: on exit I (6) and exit II (7) surface in addition, all be provided with passivation protection film (5).
3. metallic film electric capacity according to claim 1 is characterized in that: the thickness of metal film electrode I (1) and metal film electrode II (3) is respectively 0.1~0.3 μ m.
4. metallic film electric capacity according to claim 1 is characterized in that: the thickness of dielectric film (2) is 0.04~0.06 μ m.
CN2011202838918U 2011-08-05 2011-08-05 Metallic film capacitor Expired - Fee Related CN202332579U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102385985A (en) * 2011-08-05 2012-03-21 贵州大学 Metal thin film capacitor and preparation method thereof
CN102394177A (en) * 2011-11-29 2012-03-28 贵州大学 Laminated metallic film capacitor and preparing method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102385985A (en) * 2011-08-05 2012-03-21 贵州大学 Metal thin film capacitor and preparation method thereof
CN102394177A (en) * 2011-11-29 2012-03-28 贵州大学 Laminated metallic film capacitor and preparing method thereof
CN102394177B (en) * 2011-11-29 2013-07-03 贵州大学 Laminated metallic film capacitor and preparing method thereof

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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120711

Termination date: 20150805

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