CN201808259U - Anti-UV multi-layer co-extruded functional polystyrene (PS) foamed profile - Google Patents

Anti-UV multi-layer co-extruded functional polystyrene (PS) foamed profile Download PDF

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Publication number
CN201808259U
CN201808259U CN2010205509104U CN201020550910U CN201808259U CN 201808259 U CN201808259 U CN 201808259U CN 2010205509104 U CN2010205509104 U CN 2010205509104U CN 201020550910 U CN201020550910 U CN 201020550910U CN 201808259 U CN201808259 U CN 201808259U
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China
Prior art keywords
layer
acrylic acid
functional
styrene
acrylonitrile
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Expired - Fee Related
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CN2010205509104U
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Chinese (zh)
Inventor
李志杰
张文杰
李晓强
罗京科
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong Intco Recycling Resources Co., Ltd.
Shanghai Intco Industrial Co., Ltd.
Original Assignee
SHANGHAI INTCO INDUSTRIAL Co Ltd
ZIBO INTCO FRAMING PRODUCTS CO Ltd
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Priority to CN2010205509104U priority Critical patent/CN201808259U/en
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Publication of CN201808259U publication Critical patent/CN201808259U/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

The utility model relates to an anti-UV multi-layer co-extruded functional polystyrene (PS) foamed profile which is of a layered structure. The PS foamed profile is characterized by sequentially comprising the following layers from inside to outside: a PS foaming layer, a high impact polystyrene (HIPS) covering layer, an ethylene-vinyl acetate copolymer (EVA) bonding layer, an acrylic-styrene-acrylonitrile (ASA) functional layer and an ASA anti-radiation layer. By adding the ASA functional layer, the surface of the PS foamed profile has crystal-clear effect; and the outermost layer is an ASA resin, wherein, acrylic rubber without unsaturated double bonds in the ASA resin structure is adopted to resist degradation, ageing and fading caused by ultraviolet irradiation and can resist decomposition or discoloration caused by high temperature during the oxidation process in air. Therefore, the anti-UV multi-layer co-extruded functional PS foamed profile has the advantages of excellent ageing resistance and weather resistance and layered product appearance.

Description

The multi-layer co-extruded functional polystyrene foaming section of uvioresistant
Technical field
The utility model relates to the multi-layer co-extruded functional polystyrene foaming section of a kind of uvioresistant.
Background technology
Series of advantages such as polystyrene low-foaming material has that light weight, price are low, insect protected, mothproof, moisture-proof, asepsis environment-protecting.Be widely used in places such as photo frame, picture frame, home decoration material.Along with the raising of people's living standard, also more and more diversified to the performance demands of product, can adapt to outdoor high UV-irradiation environment, surface and have transparent effect as the crystal, durable in use, the non-discoloring product of scratch-resistant more and more is subjected to client's favor.
At present, the polystyrene imitating wood section product major part on the market is the double-layer coextrusion product, and its skin-material mostly is the high impact polystyrene material, stamps various patterns from the teeth outwards by technologies such as ink jet printing, hot rolling seals then.Because the high impact polystyrene material is originally as opaque material, typography can't be copied out the transparent effect as the crystal.And the printing ink ultraviolet-resistant capacity of printing is relatively poor, and easy variable color comes off when using out of doors for a long time, so existing manufacturing technique can't be made the product that the surface has transparent effect as the crystal and is fit to outdoor long-time use.Therefore develop the production technology that makes new advances, make the product that meets the requirements of the customers,, have crucial economic worth to satisfy the growing market demand.
Summary of the invention
According to the deficiencies in the prior art, the technical problems to be solved in the utility model is: provide a kind of uvioresistant multi-layer co-extruded functional polystyrene foaming section, its surface has transparent effect as the crystal, and anti-uv-ray is strong, and product appearance has stereovision.
The technical scheme that its technical problem that solves the utility model adopts is: provide a kind of uvioresistant multi-layer co-extruded functional polystyrene foaming section, have layer structure, it is characterized in that: be followed successively by foamed polystyrene layer, high impact polystyrene cover layer, ethylene-vinyl acetate copolymer tack coat, acrylic acid-styrene-acrylonitrile functional layer, acrylic acid-styrene-acrylonitrile radiation protective layer from inside to outside.
Be provided with ornament in described acrylic acid-styrene-acrylonitrile functional layer.
Use transparent acrylic acid-SAN in described acrylic acid-styrene-acrylonitrile radiation protective layer.
Also can adopt transparent plexiglass to replace acrylic acid-SAN in described acrylic acid-styrene-acrylonitrile functional layer and acrylic acid-styrene-acrylonitrile radiation protective layer.
Wherein ground floor (sandwich layer) polystyrene (PS) foaming layer is the main part that constitutes product; Second layer high impact polystyrene cover layer (HIPS), main effect is to cover various pores and the other defect that the core layer foaming layer produces, and can stamp background color, determines the dominant hue of product; The three-layer ethylene-acetate ethylene copolymer (EVA) tack coat prevents that bonding is not firm between each layer, produces the generation of the phenomenon of layering; The 4th layer of acrylic acid-styrene-acrylonitrile (ASA) functional layer, this layer adopts transparent ASA resin to add the relatively poor colouring agent of thin shade covering power therein and mixes colours, and add the decoration particle (as circle, rhombus, various petal-shaped particle) of the various different shapes of making by high-melting-point ASA or resin and the good other materials of ASA compatibility, this decoration particle is dispersed in the ASA functional layer in the process of extruding, to produce versicolor Aero Glass; Layer 5 acrylic acid-styrene-acrylonitrile radiation protective layer, this layer adopt transparent ASA resin and add the antioxidant of 0.01%-1% and the UV resistant agent of 0.01%-2% with its oxidation resistance of further raising.
The PS expanded material of ground floor through screw diameter be that the single screw extrusion machine of Φ 90 is extruded, second layer HIPS resin adds that screw diameter is that the single screw extrusion machine of Φ 45 is extruded, the 3rd layer of EVA resin adds that screw diameter is that the single screw extrusion machine of Φ 30 is extruded, the 4th layer of ASA resin adds that screw diameter is that the single screw extrusion machine of Φ 45 is extruded, to add screw diameter be that the single screw extrusion machine of Φ 45 is extruded to layer 5 ASA resin.The material that five extruders are extruded imports in the co-extruding mould, and extrusion molding obtains described multi-layer co-extruded functional polystyrene foaming section.
Wherein also can adopt transparent plexiglass (PMMA) to replace acrylic acid-SAN (ASA) in acrylic acid-styrene-acrylonitrile functional layer and acrylic acid-styrene-acrylonitrile radiation protective layer.
The beneficial effects of the utility model are: by the interpolation of ASA functional layer, the surface has transparent effect as the crystal; Outermost layer adopts ASA (acrylic acid-styrene-acrylonitrile) resin, the degraded of using the acrylic rubber do not contain unsaturated double-bond can resist the ultraviolet ray irradiation in the ASA resin structure to cause, wear out, fade, simultaneously can resist decomposition or the variable color that the high temperature in the aerial oxidation process causes, have fabulous anti-aging and weather resistance; Product appearance has stereovision.
Description of drawings
Fig. 1 is a structural representation of the present utility model;
Among the figure: 1 is the foamed polystyrene layer; 2 is the high impact polystyrene cover layer; 3 is the ethylene-vinyl acetate copolymer tack coat; 4 is acrylic acid-styrene-acrylonitrile functional layer; 5 is acrylic acid-styrene-acrylonitrile radiation protective layer; 6 is ornament;
The specific embodiment
Below in conjunction with accompanying drawing embodiment of the present utility model is described further:
As shown in Figure 1, the multi-layer co-extruded functional polystyrene foaming section of uvioresistant comprises: foamed polystyrene layer 1, high impact polystyrene cover layer 2, ethylene-vinyl acetate copolymer tack coat 3, acrylic acid-styrene-acrylonitrile functional layer 4, acrylic acid-styrene-acrylonitrile radiation protective layer 5 are followed successively by foamed polystyrene layer 1, high impact polystyrene cover layer 2, ethylene-vinyl acetate copolymer tack coat 3, acrylic acid-styrene-acrylonitrile functional layer 4, acrylic acid-styrene-acrylonitrile radiation protective layer 5 from inside to outside.
Wherein be provided with ornament 6 in acrylic acid-styrene-acrylonitrile functional layer 4.
Wherein the PS expanded material of ground floor through screw diameter be that the single screw extrusion machine of Φ 90 is extruded, the HIPS resin of the second layer adds that screw diameter is that the single screw extrusion machine of Φ 45 is extruded, the 3rd layer EVA resin adds that screw diameter is that the single screw extrusion machine of Φ 30 is extruded, the 4th layer ASA resin adds that screw diameter is that the single screw extrusion machine of Φ 45 is extruded, to add screw diameter be that the single screw extrusion machine of Φ 45 is extruded to the ASA resin of layer 5.The material that five extruders are extruded imports in the co-extruding mould, and extrusion molding obtains described multi-layer co-extruded functional polystyrene foaming section.
The utility model is not limited to present embodiment, wherein also can adopt transparent plexiglass (PMMA) to replace acrylic acid-SAN (ASA) in acrylic acid-styrene-acrylonitrile functional layer 4 and acrylic acid-styrene-acrylonitrile radiation protective layer 5.

Claims (4)

1. multi-layer co-extruded functional polystyrene foaming section of uvioresistant, have layer structure, it is characterized in that: be followed successively by foamed polystyrene layer (1), high impact polystyrene cover layer (2), ethylene-vinyl acetate copolymer tack coat (3), acrylic acid-styrene-acrylonitrile functional layer (4), acrylic acid-styrene-acrylonitrile radiation protective layer (5) from inside to outside.
2. the multi-layer co-extruded functional polystyrene foaming section of uvioresistant according to claim 1 is characterized in that being provided with ornament (6) in described acrylic acid-styrene-acrylonitrile functional layer (4).
3. the multi-layer co-extruded functional polystyrene foaming section of uvioresistant according to claim 2 is characterized in that the middle acrylic acid-SAN that uses saturated pair of transparent key of described acrylic acid-styrene-acrylonitrile radiation protective layer (5).
4. the multi-layer co-extruded functional polystyrene foaming section of uvioresistant according to claim 1 is characterized in that also can adopting in described acrylic acid-styrene-acrylonitrile functional layer (4) and acrylic acid-styrene-acrylonitrile radiation protective layer (5) transparent plexiglass to replace acrylic acid-SAN.
CN2010205509104U 2010-09-30 2010-09-30 Anti-UV multi-layer co-extruded functional polystyrene (PS) foamed profile Expired - Fee Related CN201808259U (en)

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CN2010205509104U CN201808259U (en) 2010-09-30 2010-09-30 Anti-UV multi-layer co-extruded functional polystyrene (PS) foamed profile

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101992574A (en) * 2010-09-30 2011-03-30 淄博英科框业有限公司 Uvioresistant multi-layer polystyrene foaming section bar with co-extrusion function

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101992574A (en) * 2010-09-30 2011-03-30 淄博英科框业有限公司 Uvioresistant multi-layer polystyrene foaming section bar with co-extrusion function
CN101992574B (en) * 2010-09-30 2013-06-12 山东英科环保再生资源股份有限公司 Uvioresistant multi-layer polystyrene foaming section bar with co-extrusion function

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Legal Events

Date Code Title Description
C14 Grant of patent or utility model
GR01 Patent grant
C56 Change in the name or address of the patentee

Owner name: SHANDONG YINGKE ENVIRONMENTAL PROTECTING RENEWABLE

Free format text: FORMER NAME: ZIBO INTCO FRAMING PRODUCTS CO., LTD.

CP01 Change in the name or title of a patent holder

Address after: Qilu Industrial Park Linzi District 255400 in Shandong province Zibo City Road No. 18

Co-patentee after: Shanghai Intco Industrial Co., Ltd.

Patentee after: Shandong Intco Recycling Resources Co., Ltd.

Address before: Qilu Industrial Park Linzi District 255400 in Shandong province Zibo City Road No. 18

Co-patentee before: Shanghai Intco Industrial Co., Ltd.

Patentee before: Zibo Intco Framing Products Co., Ltd.

C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20110427

Termination date: 20130930