CN1974666A - 增强的聚酰胺模塑材料 - Google Patents
增强的聚酰胺模塑材料 Download PDFInfo
- Publication number
- CN1974666A CN1974666A CNA2006101452105A CN200610145210A CN1974666A CN 1974666 A CN1974666 A CN 1974666A CN A2006101452105 A CNA2006101452105 A CN A2006101452105A CN 200610145210 A CN200610145210 A CN 200610145210A CN 1974666 A CN1974666 A CN 1974666A
- Authority
- CN
- China
- Prior art keywords
- weight
- component
- polyamide molding
- molding material
- polyamide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/10—Polyamides derived from aromatically bound amino and carboxyl groups of amino-carboxylic acids or of polyamines and polycarboxylic acids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
- C08L2666/20—Macromolecular compounds having nitrogen in the main chain according to C08L75/00 - C08L79/00; Derivatives thereof
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Reinforced Plastic Materials (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
Description
材料 | 商品名 | 相对粘度20℃间甲酚,0.5% | 组分按重量计% | 制造商 |
PA66 | Radipol A45 | 在1%的H2SO4中为2.7 | --- | Radici Chimica,Italy |
PA6T/6I | XE 3733NK | 1.56 | 70/30 | EMS-CHEMIEAG,Switzerland |
GF | VetrotexEC10-4.5MM 99B | --- | --- | Saint-GobainVetrotex,France |
CF | Tenax HTA5N51 6MM | --- | --- | Toho TenaxEurope GmbH,Germany |
PA6I/6T | GRIVORYG21 | 1.52 | 2/1 | EMS-CHEMIEAG,Switzerland |
PA6 | GRILONA23 | 在1%H2SO4中为2.47 | --- | EMS-CHEMIEAG,Switzerland |
实施例 | No. | |||||||||
性能 | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 |
PA66按重量计%PA6T/6I按重量计%玻璃纤维按重量计%碳纤维按重量计% | 255428 | 337428 | 25543.56.5 | 33743.56.5 | 1845810 | 22.73628 | 182628 | 24646 | 164646 | 200646 |
拉伸弹性模量MPa | 20500 | 20000 | 19100 | 19400 | 28800 | 28600 | 28800 | 28300 | 28200 | 28300 |
最大拉伸强度MPa断裂伸度% | 2502.5 | 2502.5 | 2502.5 | 2502.5 | 2401.8 | 2601.8 | 2501.8 | 2451.7 | 2451.8 | 2451.7 |
Charpy New冲击23℃kJ/m2 | 80 | 90 | 90 | 95 | 65 | 70 | 70 | 60 | 60 | 65 |
HDT A℃HDT C℃ | 245185 | 255190 | 245185 | 245200 | 245215 | 245215 | 245215 | 245195 | 245200 | 245195 |
对比实施例 | No. | |||||
性能 | 11 | 12 | 13 | 14 | 15 | 16 |
PA66按重量计%PA6T/6I按重量计%PA6I/6T按重量计%PA6按重量计%.玻璃纤维按重量计% | 501040 | 371250 | 5050 | 281060 | 3565 | 23770 |
拉伸弹性模量MPa | 14000 | 17000 | 17600 | 20000 | 22600 | 25000 |
最大拉伸强度MPa断裂伸度% | 2152.8 | 2502.5 | 2502.0 | 2502.2 | 2101.6 | 2401.5 |
Charpy New冲击23℃kJ/m2Charpy New切口冲击23℃kJ/m2 | 6511 | 9012 | 8010 | 7014 | 4512 | 6010 |
HDT A ℃HDT C ℃ | 240150 | 235165 | 285210 | 235175 | 210180 | 240190 |
实施例 | No. | ||||
性能 | 17 | 18 | 19 | 20 | 21 |
PA66按重量计%PA6T/6I按重量计%玻璃纤维按重量计%碳纤维按重量计% | 37.512.5437 | 3010528 | 26.258.75569 | 22.57.56010 | 26.258.75569 |
拉伸弹性模量MPa | 20400 | 25200 | 30700 | 33400 | 29500 |
最大拉伸强度MPa断裂伸度% | 3101.9 | 3201.7 | 2901.8 | 2601.5 | 3201.6 |
Charpy New冲击23℃kJ/m2Charpy New切口冲击23℃kJ/m2 | 8530 | 9045 | 8550 | 9045 | 12060 |
温度设置挤压机和注入室 | ℃ | 280-370 |
翻转团粒 | kg/h | 100-180 |
输出速度 | m/min | 5-11 |
纤维预热 | ℃ | 无 |
团粒长度 | mm | 11 |
Claims (18)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP20050025216 EP1788027B1 (de) | 2005-11-18 | 2005-11-18 | Verstärkte Polyamidformmassen |
EP05025216.2 | 2005-11-18 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1974666A true CN1974666A (zh) | 2007-06-06 |
CN1974666B CN1974666B (zh) | 2011-12-21 |
Family
ID=35448231
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2006101452105A Active CN1974666B (zh) | 2005-11-18 | 2006-11-17 | 增强的聚酰胺模塑材料 |
Country Status (10)
Country | Link |
---|---|
US (1) | US9221974B2 (zh) |
EP (2) | EP1788027B1 (zh) |
JP (1) | JP5296974B2 (zh) |
KR (1) | KR101279648B1 (zh) |
CN (1) | CN1974666B (zh) |
AT (1) | ATE387475T1 (zh) |
BR (1) | BRPI0604752A (zh) |
DE (2) | DE502005001079D1 (zh) |
ES (1) | ES2301128T3 (zh) |
TW (1) | TWI428392B (zh) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102719092A (zh) * | 2012-07-06 | 2012-10-10 | 上海日之升新技术发展有限公司 | 一种复合增强尼龙组合物及其制备方法 |
CN102803364A (zh) * | 2009-06-19 | 2012-11-28 | 沙伯基础创新塑料知识产权有限公司 | 长玻璃纤维增强的热塑性树脂的单种导电性粒料及其制备方法 |
CN103804897A (zh) * | 2014-02-14 | 2014-05-21 | 张家港大塚化学有限公司 | 工程塑料 |
CN103898627A (zh) * | 2014-04-01 | 2014-07-02 | 浙江裕鑫聚磐实业有限公司 | 一种抗黄变锦纶弹力丝的生产方法 |
CN104559164A (zh) * | 2013-10-15 | 2015-04-29 | 通贝国际有限公司 | 采用尼龙和碳纳米管的复合物的电缆扎带 |
CN105829431A (zh) * | 2013-12-20 | 2016-08-03 | Ems专利股份公司 | 经长纤维增强的聚酰胺 |
CN106589927A (zh) * | 2016-11-04 | 2017-04-26 | 上海普利特复合材料股份有限公司 | 一种纤维共混增强尼龙复合材料及其制备方法 |
CN116790116A (zh) * | 2023-04-27 | 2023-09-22 | 珠海万通特种工程塑料有限公司 | 半芳香族聚酰胺组合物及其制备方法与应用 |
Families Citing this family (41)
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DE502005001079D1 (de) | 2005-11-18 | 2007-08-30 | Ems Chemie Ag | Verstärkte Polyamidformmassen |
US20070276081A1 (en) * | 2006-05-23 | 2007-11-29 | Shengmei Yuan | High modulus thermoplastic compositions |
US20100036382A1 (en) * | 2006-12-26 | 2010-02-11 | Solvay Advanced Polymers, L.L.C. | Orthopedic tool made of a plastic material |
EP1942147B1 (de) * | 2006-12-28 | 2009-04-01 | Ems-Chemie Ag | Mit flachen Glasfasern verstärkte Polyamidformmassen sowie daraus hergestellte Spritzgussteile |
US9567462B2 (en) | 2006-12-28 | 2017-02-14 | Ems-Chemie Ag | Polyamide molding materials reinforced with glass fibers and injection molded parts thereof |
DE502007006117D1 (de) * | 2007-08-24 | 2011-02-10 | Ems Patent Ag | Mit flachen Glasfasern verstärkte Hochtemperatur-Polyamidformmassen |
EP2055743B2 (de) | 2007-10-30 | 2019-03-20 | Ems-Patent Ag | Formmassen zur Herstellung von Formteilen im Trinkwasserbereich |
EP2060607B2 (de) * | 2007-11-16 | 2019-11-27 | Ems-Patent Ag | Gefüllte Polyamidformmassen |
EP2060596B1 (de) * | 2007-11-16 | 2012-06-13 | Ems-Patent Ag | Gefüllte Polyamidformmassen |
JP5600381B2 (ja) * | 2008-05-01 | 2014-10-01 | 三菱エンジニアリングプラスチックス株式会社 | ねじ部材用ポリアミド樹脂組成物 |
DE102008057240A1 (de) * | 2008-11-10 | 2010-05-12 | Brose Fahrzeugteile Gmbh & Co. Kommanditgesellschaft, Hallstadt | Zusammensetzung zur Herstellung einer Verstellvorrichtung eines Kraftfahrzeugs |
PL2365033T3 (pl) * | 2010-03-12 | 2013-12-31 | Ems Patent Ag | Poliamidowa masa do formowania o modyfikowanej udarności oraz wytworzony z niej zbiornik |
WO2011134930A1 (de) | 2010-04-30 | 2011-11-03 | Basf Se | Langfaserverstärkte polyamide mit polyolefinen |
EP2412757B1 (de) | 2010-07-30 | 2013-11-13 | Ems-Patent Ag | Polyamidformmasse zur Herstellung von Formkörpern mit einer Weichgriffoberfläche sowie entsprechende Formkörper |
EP2601265A1 (de) | 2010-08-02 | 2013-06-12 | Basf Se | Langfaserverstärkte polyester |
BR112013010469A2 (pt) * | 2010-10-29 | 2017-09-12 | Du Pont | Estrutura composta e processo de elaboração da estrutura composta |
SI2535365T1 (sl) | 2011-06-17 | 2014-02-28 | Ems-Patent Ag | Delno aromatične oblikovalne mase in njihova uporaba |
EP2666803B1 (de) | 2012-05-23 | 2018-09-05 | Ems-Patent Ag | Kratzfeste, transparente und zähe Copolyamidformmassen, hieraus hergestellte Formkörper und deren Verwendung |
WO2014029641A1 (de) | 2012-08-20 | 2014-02-27 | Basf Se | Langfaserverstärkte flammgeschützte polyester |
US8962717B2 (en) | 2012-08-20 | 2015-02-24 | Basf Se | Long-fiber-reinforced flame-retardant polyesters |
EP2716716B1 (de) | 2012-10-02 | 2018-04-18 | Ems-Patent Ag | Polyamid-Formmassen und deren Verwendung bei der Herstellung von Formkörpern |
SI2746339T1 (sl) | 2012-12-18 | 2015-05-29 | Ems-Patent Ag | Poliamidna oblikovalna masa in oblikovalni deli proizvedeni iz enakega |
EP2949704B1 (de) * | 2012-12-21 | 2019-04-24 | Ems-Patent Ag | Anfärberesistente artikel und ihre verwendung |
EP2778190B1 (de) | 2013-03-15 | 2015-07-15 | Ems-Patent Ag | Polyamidformmasse sowie hieraus hergestellter Formkörper |
DE102014215370A1 (de) | 2013-09-05 | 2015-03-05 | Basf Se | Langfaserverstärkte flammgeschützte Polyamide |
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US10442365B2 (en) * | 2014-06-13 | 2019-10-15 | Ford Global Technologies, Llc | Apparatus and methods for vehicle structural or semi-structural component assembly enabling tunable deceleration characteristics |
KR102436751B1 (ko) * | 2014-06-20 | 2022-08-26 | 바스프 에스이 | 폴리아마이드 성형 조성물, 이로부터 수득되는 성형 부품, 및 이들의 용도 |
CN104262955B (zh) * | 2014-09-17 | 2017-04-12 | 上海日之升新技术发展有限公司 | 高gwit碳纤增强无卤阻燃pa46复合材料及其制备 |
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US10465060B2 (en) * | 2014-10-27 | 2019-11-05 | Ube Industries, Ltd. | Polyamide composition and molded article produced from the composition |
JP6497823B2 (ja) * | 2015-02-13 | 2019-04-10 | エーエムエス−パテント アクチェンゲゼルシャフト | ポリアミド成形材料及びこの成形材料から製造された成形品 |
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US11813818B2 (en) | 2016-02-23 | 2023-11-14 | Andersen Corporation | Fiber-reinforced composite extrusion with enhanced properties |
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JP7082605B2 (ja) | 2016-07-13 | 2022-06-08 | エーエムエス-パテント アクチェンゲゼルシャフト | 伝導性熱可塑性ポリアミド成形コンパウンド |
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ATE367420T1 (de) | 2005-11-18 | 2007-08-15 | Ems Chemie Ag | Verstärkte polyamidformmassen |
DE502005001079D1 (de) | 2005-11-18 | 2007-08-30 | Ems Chemie Ag | Verstärkte Polyamidformmassen |
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-
2005
- 2005-11-18 DE DE200550001079 patent/DE502005001079D1/de active Active
- 2005-11-18 EP EP20050025216 patent/EP1788027B1/de not_active Not-in-force
-
2006
- 2006-11-08 TW TW95141412A patent/TWI428392B/zh not_active IP Right Cessation
- 2006-11-08 US US11/594,249 patent/US9221974B2/en not_active Expired - Fee Related
- 2006-11-14 KR KR20060112460A patent/KR101279648B1/ko active IP Right Grant
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- 2006-11-15 EP EP20060023732 patent/EP1788028B1/de not_active Not-in-force
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- 2006-11-15 DE DE200650000398 patent/DE502006000398D1/de active Active
- 2006-11-15 ES ES06023732T patent/ES2301128T3/es active Active
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Cited By (12)
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CN102803364A (zh) * | 2009-06-19 | 2012-11-28 | 沙伯基础创新塑料知识产权有限公司 | 长玻璃纤维增强的热塑性树脂的单种导电性粒料及其制备方法 |
CN102803364B (zh) * | 2009-06-19 | 2015-01-14 | 沙伯基础创新塑料知识产权有限公司 | 长玻璃纤维增强的热塑性树脂的单种导电性粒料及其制备方法 |
CN102719092A (zh) * | 2012-07-06 | 2012-10-10 | 上海日之升新技术发展有限公司 | 一种复合增强尼龙组合物及其制备方法 |
CN102719092B (zh) * | 2012-07-06 | 2015-06-03 | 上海日之升新技术发展有限公司 | 一种复合增强尼龙组合物及其制备方法 |
CN104559164A (zh) * | 2013-10-15 | 2015-04-29 | 通贝国际有限公司 | 采用尼龙和碳纳米管的复合物的电缆扎带 |
US10029834B2 (en) | 2013-10-15 | 2018-07-24 | Thomas & Betts International Llc | Cable tie employing composite of nylon and carbon nanotubes |
CN105829431A (zh) * | 2013-12-20 | 2016-08-03 | Ems专利股份公司 | 经长纤维增强的聚酰胺 |
CN103804897A (zh) * | 2014-02-14 | 2014-05-21 | 张家港大塚化学有限公司 | 工程塑料 |
CN103898627A (zh) * | 2014-04-01 | 2014-07-02 | 浙江裕鑫聚磐实业有限公司 | 一种抗黄变锦纶弹力丝的生产方法 |
CN106589927A (zh) * | 2016-11-04 | 2017-04-26 | 上海普利特复合材料股份有限公司 | 一种纤维共混增强尼龙复合材料及其制备方法 |
CN116790116A (zh) * | 2023-04-27 | 2023-09-22 | 珠海万通特种工程塑料有限公司 | 半芳香族聚酰胺组合物及其制备方法与应用 |
CN116790116B (zh) * | 2023-04-27 | 2024-05-07 | 珠海万通特种工程塑料有限公司 | 半芳香族聚酰胺组合物及其制备方法与应用 |
Also Published As
Publication number | Publication date |
---|---|
BRPI0604752A (pt) | 2007-08-28 |
CN1974666B (zh) | 2011-12-21 |
KR20070053115A (ko) | 2007-05-23 |
JP2007138177A (ja) | 2007-06-07 |
ES2301128T3 (es) | 2008-06-16 |
TWI428392B (zh) | 2014-03-01 |
US9221974B2 (en) | 2015-12-29 |
TW200724604A (en) | 2007-07-01 |
EP1788027B1 (de) | 2007-07-18 |
KR101279648B1 (ko) | 2013-06-26 |
ATE387475T1 (de) | 2008-03-15 |
EP1788027A1 (de) | 2007-05-23 |
JP5296974B2 (ja) | 2013-09-25 |
EP1788028B1 (de) | 2008-02-27 |
DE502006000398D1 (de) | 2008-04-10 |
EP1788028A1 (de) | 2007-05-23 |
US20070123632A1 (en) | 2007-05-31 |
DE502005001079D1 (de) | 2007-08-30 |
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