CN1968808A - Structure of preventing sticking and method of preparing the same - Google Patents
Structure of preventing sticking and method of preparing the same Download PDFInfo
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- CN1968808A CN1968808A CNA2005800201423A CN200580020142A CN1968808A CN 1968808 A CN1968808 A CN 1968808A CN A2005800201423 A CNA2005800201423 A CN A2005800201423A CN 200580020142 A CN200580020142 A CN 200580020142A CN 1968808 A CN1968808 A CN 1968808A
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- resin
- tectosome
- antiseized
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- pearl
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1681—Antifouling coatings characterised by surface structure, e.g. for roughness effect giving superhydrophobic coatings or Lotus effect
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Paints Or Removers (AREA)
- Road Signs Or Road Markings (AREA)
- Finishing Walls (AREA)
Abstract
The present invention provides an anti-adhesion mechanism and a method of producing it and more particularly, it provides an anti-adhesion mechanism comprising a structure body, a resin binder layer comprising a resin binder coated on all or part of the surface of the structure body and a bead layer comprising a plurality of beads bond to the upper side of the coated resin binder layer and being salient outside, and a method of producing an anti-adhesion mechanism comprising coating a resin binder on the surface to be coated, spraying beads on the upper portion of the resin binder before the coated resin binder is hardened and hardening them to form bead protrusions. The anti-adhesion mechanism prepared in accordance with the invention can prevent the adhesion of attachments such as stickers, posters and dusts to the coated surface and easily remove the attachments even though they are adhered, can be readily formed and can improve such properties as weather resistance, contamination resistance, scratch resistance, chemical resistance and impact resistance of the surfaces coated therewith.
Description
Technical field
The present invention relates to prevent works (antiseized tectosome (anti-adhesionmechanism)) that adheres to and preparation method thereof, more particularly, relate to and to prevent such as pasting product, placard, attachments such as dust adhere to following body surface, even and attachment or dust have adhered to also the antiseized tectosome of can be easily these attachments or dust being removed, described object comprises such as phone mast, traffic lights, street lamp, road equipment such as traffic sign and control cabinet or their supporter, guardrail, road sign, internal and external frame, the wall body of building or fabrication, electric light or lamp device, this antiseized tectosome can make dust adhere to as few as possible to be in the surface of the works in the environment of adhered a large amount of dirts and dust, and can easily they be removed, this antiseized tectosome can be formed at an easy rate, and can improve with the surface of its coating such as weatherability, anti fouling performance, resistance to marring, performance such as chemical resistance and resistance to impact the invention still further relates to the method for producing this antiseized tectosome.
Background technology
Usually, on the road various, numerous facility can be set, for example guardrail, road sign, internal and external frame, phone mast, street lamp, traffic lights, traffic sign etc., and these facilities constitute tube or concrete supporter, for the consideration to pedestrains safety, these tubes or concrete supporter all have level and smooth surface.
Such as illegal show and colour such as various stickup product and placard the outward appearance of these supporters, fabrication or building has been played destruction by what use that adhesive, glue etc. paste on the wall body of the supporter of road equipment or fabrication or building.These show and colours or attachment are destroying beautiful streetscape continuously, therefore, in order to remove these show and colours or attachment, have dropped into a large amount of material resources and manpower.
Yet, because the supporter of road equipment has straight side or circular pillar, the wall body of fabrication or building also has smooth surface, so made of paper be easy to stick to above them, therefore feasiblely monitor and prevent that these attachments from becoming very difficult such as pasting show and colour such as product and placard or attachment.In addition, in case paste, will be because of can't removing fully such as pasting product or this series advertisements material of placard or attachment with the plane close adhesion, thus pollute, streetscape and facility are played destruction.
Therefore, carried out various trials, but except for example writing brief warning poster such as " forbid advertisement " or " forbidding pasting ", proposed effectively to prevent method so far yet for preventing show and colour or attachment.
In addition, when such as the various tectosome long term exposure such as framework of road sign, internal and external frame, wall body, lamp device or its framework, the wall body of building, billboard, particularly transparent billboard outside the time, they can adsorb a large amount of dusts or pollutant.Therefore, pressing for can with these pollutants or dust be reduced to a minimum and the method that can easily remove the dust or the pollutant of adhesion.
Summary of the invention
Technical problem
In order to address the above problem, an object of the present invention is to provide a kind of can preventing and stick to following body surface such as attachments such as stickup product, placard, dusts, even and these attachments have adhered to the antiseized tectosome that also can easily it be removed, described object comprises wall body and the internal and external frame such as road equipments such as phone mast, traffic lights, street lamp, traffic sign and control cabinet or their supporter, building or fabrication, and the method for producing this antiseized tectosome.
Another object of the present invention provides a kind of dust or pollutant of can preventing and adheres to road sign, lamp device, reflecting surface, electric light and billboard, even and these dusts or pollutant adhered to the antiseized tectosome that also can easily it be removed, and the method for producing this antiseized tectosome.
Another purpose of the present invention provides and can be easy to make, and improve performances such as weatherability, anti fouling performance, resistance to marring, chemical resistance and resistance to impact with the surface of its coating, the antiseized tectosome of design attractive in appearance can also be provided, and the method for producing this antiseized tectosome.
Technical scheme
To achieve these goals, the invention provides antiseized tectosome, this antiseized tectosome comprises:
Structure;
Be coated on all or part of lip-deep binder resin layer that comprises resin binder of described structure; With
The bead layer that comprises a plurality of pearls that are combined in the binder resin layer upside that is coated with, described pearl outwards protrudes.
In addition, the present invention also provides following antiseized tectosome, and this antiseized tectosome comprises:
Structure;
Be coated on all or part of lip-deep adhesive phase that comprises adhesive of this structure;
The adhesion layer that comprises the non-weaving cloth, woven cloths, foam film or the resin molding that adhere to described adhesive phase;
Be coated on the surface of adhesion layer or comprise the lip-deep binder resin layer that comprises resin binder of the structure of adhesion layer; With
The bead layer that comprises a plurality of pearls that are combined in the binder resin layer upside that is coated with, described pearl outwards protrudes.
In addition, the present invention also provides a kind of method of producing antiseized tectosome, described method is included in coating resin adhesive on the surface that will be coated with, before the resin binder sclerosis of coating pearl is sprayed at this resin binder top, and makes their sclerosis to form the pearl projection.
Advantageous effects
Antiseized tectosome and production method thereof in according to the present invention, the projection that forms by the pearl that is positioned on the following body surface can produce irregular recess, can reduce attachment and the contact area between the surface of coating thus, described object comprises such as through the road equipment such as guardrail, phone mast, traffic lights, street lamp, traffic sign and control cabinet of coating and the wall body and the internal and external frame of their supporter, building or fabrication.Therefore, the present invention can prevent the adhesion such as the attachment of stickup product, placard, dust etc., even and attachment adhered to also and can easily it have been removed by reducing contact area.In addition, the recess that convexes to form when pearl can easily be removed these pollutants by washing (for example rain or snow) during by contamination by dust.Therefore, the present invention has excellent effect aspect anti fouling performance.
In addition, when structure is the structure that is easy to by contamination by dust, for example when road sign, lamp device, reflecting surface, electric light and billboard etc., the present invention can prevent the adhesion of dust or pollutant, even and dust or pollutant adhered to also and can easily it have been removed.
In addition, antiseized tectosome of the present invention can be formed at an easy rate, and can improve with the surface of its coating such as performances such as weatherability, anti fouling performance, resistance to marring, chemical resistance and resistances to impact.
The present invention is not subjected to the restriction of detailed description of the present invention and accompanying drawing.Can carry out other further the spirit and scope of the present invention of improving and changing and do not break away from the claims definition, this will appreciate that for those skilled in the art.
Description of drawings
Fig. 1 is the sectional view that shows the cross section of antiseized tectosome prepared in accordance with the present invention.
Fig. 2 is the figure that shows the existing road guard column.
Fig. 3 is the figure of demonstration according to the manufacture method of the outside framework of an embodiment of antiseized tectosome of the present invention.
Fig. 4 is the figure that shows the outside framework for preparing by the method shown in Figure 3 according to one embodiment of the invention.
* Reference numeral *
1: the surface that be coated with (structure)
2: binder resin layer
3: bead layer
The specific embodiment
The present invention is described in further detail below with reference to the accompanying drawings.
Antiseized tectosome according to an embodiment of the invention comprises structure 1, is coated on the binder resin layer that comprises resin binder 2 on all or part of surface of structure (outside, inner face) and comprises the bead layer 3 that is combined in binder resin layer top that is coated with and a plurality of pearls that outwards protrude.Its instantiation as shown in Figure 1.
Can constitute this structure by following method: before coating resin adhesive on the structure surface, the resin binder sclerosis that is being coated with, pearl is sprayed at resin binder top, makes their sclerosis to form the bead layer that has formed the pearl projection on it.
This structure comprises all surface that has adhered to the dust that will remove, stickup product, show and colour or pollutant, specifically, the supporter or the wall body that comprise following material, described material are road equipment, phone mast, traffic lights, street lamp, traffic sign, control cabinet, building, guardrail, road sign, internal and external frame, lamp device, lamp reflecting surface, electric light, transparent configuration and billboard.The supporter of road equipment can be the supporter of phone mast, traffic lights, street lamp, traffic sign, control cabinet etc., and control cabinet can be the control cabinet of electric supply installation, traffic lights, street lamp and so on.
For road sign, its retroreflecting effect can reduce because of the pollution of dust or pollutant, and the present invention prevents the adhesion of dust or pollutant, and utilizes wind and rain just can remove dust at an easy rate.For road sign, the structure among the present invention comprises all structures of the structure that is used as the known road sign of various forms, and can have various forms, comprising traditional cylindricality as shown in Figure 2.This structure can be made, and be comprised the structure that is used for road sign of all kinds by polyurethane, other resin, metal, concrete, PVC, FRP etc.
In addition, internal and external frame comprises all frameworks that are used as the known internal and external frame of various forms, as shown in Fig. 3 and Fig. 4.Specifically, they are internal and external frames of fabrication, electronic product, mechanical device etc., and comprise interior outer pane, inside and outside jewelry, electronic equipment outside framework, be connected the mechanical device outside framework of building, equipment, machine exterior, more specifically, can comprise various examples such as PVC/ aluminium/steel sash lattice such as fabrication, computer display outside framework, automobile external mold.
For the lamp device, because dust sticks on lamp particularly on its reflecting surface fully, thereby reduce illumination intensity, therefore suitablely use antiseized tectosome of the present invention to prevent the generation of this situation.Expectation own also can obtain this effect for lamp.In addition, for the transparent configuration thing that is configured with transparent part, for example road billboard and bus stop and other show and colour suit to use antiseized tectosome also easily it to be removed with the adhesion that prevents dust.
The resin binder that uses on the surface of structure of the present invention plays adhesive, can use the resin that is used for veneer traditionally.Specifically, preferably use one or more to be selected from resin in the group of forming by acrylic resin, ceramic-like resin, fluorine-type resin, polyurethanes resin, metallic paint and aqueous binder.For general service, can use acrylic resin, ceramic-like resin, fluorine-type resin, polyurethanes resin and their mixture, when being applied to the lamp device, then metallic paint and its are together used, thereby make the reflecting effect maximization, for simplicity, the suitable water-base resin adhesive that uses.
For acrylic resin, can use to have methacrylic acid or acrylic acid as the aqueous acrylamide acyl group hydrosol of main component, no emulsification solvent-borne type acryloyl group silane, ultraviolet curing acryloyl group polyurethane or solvent-borne type acryloyl group polyurethane.
For the polyurethanes resin, can use the conventional polyurethanes resinoid that is used for association area, for example by organic PIC with at hydroxylic moiety and the amino thermoplastic resin that is widely known by the people that partly contains the organic compound preparation of active hydrogen atom.
For the ceramic-like resin, can use estersil, its hydrolysate, water dispersible Ludox or pure dispersed Ludox.
When the resin-bonding agent content is crossed when low or too high, it can adhere to pearl, and be reduced in coating efficiency when being coated with on the surface of wall body of the supporter of road equipment or building or fabrication, in addition, also can make and worsen such as overall performances such as intensity, character, functions.
Preferably, the viscosity of resin binder is 1, and various range of viscosities in the 000cPs scope, can be adopted according to coating process (brushing, spraying, impregnating) in 000cPs～200.Particularly, if use to brush, in order to be easy to coating, preferred viscosities is 100,000cPs～200, and in the 000cPs scope, more preferably 150, about 000cPs.As the coating process of binder resin layer, can use various known methods, for example can use brushing, spraying, impregnating method.
Resin binder is applied on the surface of structure, and before the resin binder sclerosis, the top with pearl sprays and adhere to resin binder makes its sclerosis then.
Method for curing as resin binder, can use various known method for curing, particularly can be according to resin binder (coating) type selecting and use that one or more are selected from by air dry, cure, the method in quenching, catalyst sclerosis, UV cured and the group that electron-beam curing is formed, these methods can change with the type according to the resin binder of the applicability selection of application and formation method.
Employed pearl can be spherical, oval or other respective shapes arbitrarily among the present invention, because spherical bead can be by reducing attachment and the contact area between the surface of coating in formation pearl projection on the resin binder top, so preferably use spherical bead.In addition, if air or water enter the concavo-convex place between the pearl projection that forms on resin binder top, then air or water can be diffused into the top of pearl, will form air film or moisture film like this, thereby reduce object surfaces tension force.Like this, they will play the effect that prevents that attachment from pasting or adhering to.
As pearl, can use shape and granularity to satisfy those pearls of following condition: after pearl being sprayed onto resin binder top and hardening, they can be fixed on resin binder top and by resin binder by protrusion and form projection.
About the form of pearl, can use transparent, translucent or opaque, colourless or colored various known pearl, preferably use Transparent bead, to obtain good surface appearance and retroreflecting effect.About the material of pearl, can use various known pearls, for example ceramic bead, bead, resin bead and their mixture preferably use bead, PMMA (polymethyl methacrylate) pearl, zirconium oxide bead or their mixture.Can strengthen intensity and anti-adhesion characteristic by these pearls.Consider bead layer intensity, to preventing of fading and decolour and with the static characteristic of resin binder, more preferably use bead.
Described bead is particularly to handling acquisition by glass powder that abrading glass, cullet, glass fibre or cullet obtain, wherein glass ingredient is not limited in concrete kind, as long as they can be compatible with resin binder, these glass ingredients comprise that A, C, E, alkali resistance glass powder become to grade.
Can use bead, also can use from having bead that various sizes the distribute all kinds to the bead that only has certain selected size with sphere, ellipse or any other respective shapes.
Can suitably select and use the diameter of pearl according to the material on structure of the present invention surface, purposes etc., preferably the diameter of the pearl that uses is 0.1nm～3mm.For general service, preferably using diameter is the pearl of 0.2 μ m～3mm, more preferably uses the pearl of diameter as 0.3mm～1.5mm.In addition, be the minor diameter pearl of a few μ m and the major diameter pearl that diameter is several mm by combined diameter, can show various forms and performance.Yet if diameter surpasses 3mm, surface and the contact area between the attachment through being coated with will increase, and this can reduce dispersiveness.
When the present invention is used as the wall body ornament materials or is used for the transparent configuration body, consider cost and design attractive in appearance, pearl is preferably dimensioned to be 0.02 μ m～3mm; When the present invention was used for internal and external frame, for obtaining design attractive in appearance and combination reliably, pearl was preferably dimensioned to be 0.01 μ m～0.1mm; When the present invention was used for lamp device and reflecting surface or lamp itself, for improving illumination intensity and strengthening design attractive in appearance, pearl was preferably dimensioned to be 1nm～1mm.
Can be according to the amount of the material on needed anti-adhesion performance of pollutant and the plane through being coated with suitably being regulated and used pearl, specifically, relative 100 weight portion hard resin adhesives, its content is preferably 10 weight portions～150 weight portions, more preferably 50 weight portions～150 weight portions are preferably 70 weight portions～90 weight portions especially.When its content during less than 10 weight portions, content is low excessively, and is very little for the antipollution effect of pollutant, and when its content surpassed 150 weight portions, compare this content with resin binder higher, so pearl may come off after the cure process.Simultaneously, if focus in the improvement of polluting of the present invention, then its content can be better greater than 50 weight portions.
The pearl that was sprayed onto resin binder top before the resin binder sclerosis is coated on resin binder 2 sclerosis on the surface (structure) 1 and fixes the formation pearl projection 3 of protrusion on resin binder 2 tops as shown in Figure 1.
In addition, when formation on the surface at structure is coated with layer plane, can in resin binder, add glass powder in addition, then it is coated on the surface that will be coated with.
Glass powder has the thermal coefficient of expansion similar to resin binder, so can not crack because of thermal contraction or expansion, thereby improved the combination between pearl and the resin binder and pearl can not be come off or slippage, therefore can prevent effectively that pollutant or attachment from adhering on the structure surface.In addition, glass powder suppresses interfacial separation, and absorption and transmission are from the impact of outside, thereby formation can significantly reduce the coating planar structure that destruction is taken place.
Can use glass powder as glass powder used herein with variable grain shape and size, the particle of glass powder is the particle that obtains those glass powders by abrading glass, cullet, glass fibre or cullet, wherein glass ingredient is not limited in concrete kind, as long as can be compatible with resin binder, these glass ingredients comprise that A, C, E, alkali resistance glass powder become to grade.Especially, consider the adhesion with different materials, the suitable glass powder that uses the E-glass ingredient.
The diameter of glass powder is not subjected to concrete restriction, but is preferably 10 μ m～1mm, more preferably 50 μ m～1mm.When being the internal and external frame of lamp device, because they are paid attention to attractive in appearance and use thin pearl, therefore preferred use diameter is the glass powder of 0.01 μ m～1mm.When the glass powder diameter is too small, very little to pearl with the improvement that combines between the resin binder, and when the glass powder diameter is excessive, be difficult to it is evenly mixed with resin binder, therefore may reduce strength of coating, perhaps increase pucker ﹠ bloat.
Relative 100 weight portion hard resin adhesives, the content of glass powder is 20 weight portions～50 weight portions.When this content is lower than 20 weight portions, combination-protrusion (bonding-raising) effect between pearl and the resin binder is little, and when this content surpassed 50 weight portions, the amount of resin binder reduced relatively, so the adhesiveness on coating and surface may descend.
In addition, when forming coating, if desired, resin binder can also comprise glass fibre.Glass fibre can improve the crack resistance and the hot strength of the antiseized tectosome of sclerosis.
For glass fibre, can use E-composition long glass fibres or alkali resistance composition fiber, particularly, can use by being that the glass fibre of 10 μ m～20 μ m or carbon fiber cut into chopped strand that unified fibril length makes or by being ground into the milled fiber that average fiber length is made with fibre diameter.Especially, preferably chopped strand is cut into fibre length, and the average fiber length that milled fiber has is 100 μ m～300 μ m with 2mm～12mm.Consider dispersiveness and the enhancing that is coated with the hot strength of layer plane, milled fiber is especially favourable, and also can use the mixture of chopped strand and milled fiber.
Relative 100 weight portion hard resin adhesives, the content of glass fibre is preferably 1 weight portion～100 weight portions.When the content of glass fibre is in above-mentioned scope, being coated with layer plane and crackle, pucker ﹠ bloat can not occurring of sclerosis.
In addition, if desired, resin binder can also comprise additive, as common filler, conductive filler, pigment, catalysts, thickener, mobility conditioning agent, wetting agent, ultra-violet stabilizer, light reflector powder and antiprecipitant etc.Particularly, conductive filler comprises conductive powder, when they are included in the resin bed, can suppress to produce static by give electric conductivity for resin bed, and makes anti fouling performance obtain maximization.The light reflector power applications can be improved illumination intensity and design attractive in appearance is provided when the reflecting surface of lamp device.
In addition, another kind of structure as antiseized tectosome of the present invention, can be built into following form, promptly comprise: structure, all or part of lip-deep adhesive phase that comprises adhesive that is coated on structure, the adhesion layer that comprises the non-weaving cloth, woven cloths, foam film or the resin molding that stick on the adhesive phase, be coated on the adhesive layer surface or comprise that the structure of adhesive phase is lip-deep to be comprised the binder resin layer of resin binder and comprise the bead layer that is attached to binder resin layer upside that is coated with and a plurality of pearls that outwards protrude.Adhesive can be various known adhesive, and non-weaving cloth, woven cloths, foam film or resin molding are not limited only to concrete kind, as long as it can adhere to the form of film on the structure, can use various known materials (comprising wallpaper).Especially, when being road sign, can comprise the reflecting paper that is used for road sign therein.Other structure is identical with above-mentioned antiseized tectosome.
In above-mentioned two types antiseized tectosome, the general thickness that can be adjusted at the layer that forms on the structure surface according to the performance or the material on the surface of wanting coating, for the surface that makes coating keeps suitable intensity and is convenient to the formation of adherent layer, the general thickness of layer is preferably 5 μ m～3.0mm.
In addition, the invention provides a kind of structure antiseized tectosome before that is attached to, this antiseized tectosome comprises: comprise resin molding, foam film, woven cloths or non-weaving cloth adhesion layer, be coated with or be immersed in the binder resin layer that comprises resin binder on all or part of adhesion layer, and comprise a bead layer that is combined in institute's a plurality of pearls of binder resin layer upside of being coated with or flooding, described pearl outwards protrudes, by when needed this antiseized tectosome being adhered to the wall body that needs to use it, the present invention can give antiseized ability for wall body.
In addition, the present invention also provides a kind of method of producing antiseized tectosome, described method is included in coating resin adhesive on the surface that will be coated with, before the resin binder sclerosis that is coated with pearl is sprayed at this resin binder top, and makes their sclerosis to form the pearl projection.
In addition, the present invention also provides a kind of method of producing antiseized tectosome, this method is included in non-weaving cloth, woven cloths, coating resin adhesive on foam film or the resin molding, before the resin binder sclerosis that is coated with, pearl is sprayed thereon, make their sclerosis and will form the non-weaving cloth of pearl projection on it, woven cloths, foam film or resin molding adhere on the surface that will be coated with, the present invention also provides the method for the antiseized tectosome of another kind of production, this method comprises non-weaving cloth, woven cloths, foam film or resin molding adhere to the surface that will be coated with as adhesive, at non-weaving cloth, woven cloths, on the surface of foam film or resin molding or comprise coating resin adhesive on its surface of structure, before the resin binder sclerosis that is coated with, pearl is sprayed thereon, and make their sclerosis to form the pearl projection.
Used identical in used resin binder, pearl, glass powder, glass fibre and additive and the above-mentioned antiseized tectosome in producing the method for antiseized tectosome.
In addition, in the method for producing antiseized tectosome, method for curing as resin binder, can use that one or more are selected from by above-mentioned air dry, cure, the method in quenching, catalyst sclerosis, UV cured and the group that electron-beam curing is formed, and the viscosity of the resin binder that is coated with is preferably aforesaid 1,000cPs～200 are in the 000cPs scope.
Producing the method for antiseized tectosome of the present invention can implement by conventional method, and can be applicable on it to adhere to the various surfaces of following object of show and colour or attachment or the place outside the above-mentioned position, described object comprises the wall body such as road equipment such as phone mast, traffic lights, street lamp, traffic sign and control cabinet and their supporter and building or fabrication.
As specific embodiments, can form antiseized tectosome of the present invention, method one by one of following method: on the structure surface of the wall body that comprises the supporter of road equipment, building or fabrication etc. directly the mixture of coating resin adhesive and (if desired) glass powder, glass fibre or additive, spray pearl and adhere to before containing institute's coating mixture sclerosis of resin binder and be positioned at the pearl on resin binder top and make their sclerosis; Method two: on the film that comprises non-weaving cloth, woven cloths etc. directly the mixture of coating resin adhesive and (if desired) glass powder, glass fibre or additive, spray pearl before containing institute's coating mixture sclerosis of resin binder, adhere to and be positioned at the pearl on resin binder top and make their sclerosis, and the non-weaving cloth that will be coated with mentioned component then adheres in the mode of pasting product or sheet material on the surface of structure of the wall body of the holder, building or the fabrication that comprise road equipment etc.This antiseized tectosome can form on the surface of the structure that has existed, and this structure comprises the supporter of road equipment or the wall body of building or fabrication, also can form in the process of road construction facility, building, fabrication etc.
Can use used traditional coating process in the association area by selectivity according to the material on the surface that will be coated with, requirement, area etc., be coated on the mixture of resin binder and (if desired) glass powder, glass fibre or additive on the surface that will be coated with or on the non-weaving cloth.Specifically, mentioned component is easy to disperse when the non-gravity direction is coated with, uses this moment cylinder or brushing, suit and in the time can not taking place to disperse, spray for preventing that it is very favourable disperseing.Method three: will adhere on the structure by adhesive such as non-weaving cloth, woven cloths, foam film or resin molding adhesion layers such as (comprising reflecting paper).Then, with the mixture direct-coated-sticked layer of resin binder and (if desired) glass powder, glass fibre or additive and with adhesion layer contacting structure surface or total surface and before the institute's coating mixture sclerosis that contains resin binder by pearl is sprayed at resin binder top pearl is adhered to and sclerosis thereon.In method three, complete structure can be following structure, it comprises: structure, comprise the adhesive phase, the adhesion layer that comprises the non-weaving cloth, woven cloths or the resin molding that stick on the adhesive phase that are coated on the lip-deep adhesive of structure, the binder resin layer that comprises resin binder on the outer surface (partly or entirely structure outer surface) that is coated on the structure that contains adhesion layer, and comprise the bead layer that is combined in resin bed upside that is coated with and a plurality of pearls that outwards protrude.
In addition, being coated with layer plane can form on all or part surface of structure, and when only forming in the part, it can be a strip-type, and is applied to road sign etc.
In addition, being coated with layer plane can form on the surface of the structure that has existed, and also can directly it be prepared on the surface of this new construction body when building the new construction body.
Method according to the antiseized tectosome of production of the present invention, the projection that forms by the lip-deep pearl that is positioned at the said structure body can produce irregular recess, described structure comprises such as through the holder of the highway facilitieses such as phone mast, traffic lights, street lamp, traffic sign and control cabinet of coating or the wall body of building or fabrication, attachment and the contact area between the plane of coating have been reduced thus, thereby prevent the adhesion of attachment, even and pasted also and can easily it have been removed by reducing the contact area attachment as far as possible.In addition, when pearl convex to form concavo-convex during by contamination by dust, can easily remove these pollutants by washing (for example rain or snow), therefore, the present invention has shown excellent effect aspect anti fouling performance.In addition, antiseized tectosome of the present invention can form at an easy rate, and can improve with the surface of its coating such as performances such as weatherability, anti fouling performance, resistance to marring, chemical resistance and resistances to impact.
Embodiment
In order to understand the present invention better, provide following preferred embodiment.Following embodiment is intended to illustrate more fully the present invention, but not limits the scope of the invention.
Embodiment 1
Prepare at the antiseized tectosome that has adhered to the glass bead projection on the polyurethane resin surface by following method: be coated with the 1kg polyurethane resin respectively on steel, aluminium, resinous framework, transparent resin plate, glass and the concrete at 25cm * 15cm, make its thickness be 1mm, spraying average diameter before the polyurethane resin sclerosis is the 800g bead of 0.1mm, and makes their sclerosis.Specifically, the resinous framework of having used antiseized tectosome as shown in Figure 3 and Figure 4.
The adhesive tape that has adhesive on it is adhered to each above-mentioned steel that has antiseized tectosome that has prepared, aluminium, resinous framework, transparent resin plate, glass and a concrete side.As a result, adhesive tape can not adhere on any object in steel, aluminium, resinous framework, transparent resin plate, glass and the concrete.In addition, pollute steel, aluminium, resinous framework, transparent resin plate, glass and the concrete that has antiseized tectosome, wash with water then with graphite.As a result, removed the part of polluting at an easy rate.
Thus, verified that antiseized tectosome prepared in accordance with the present invention has excellent antiseized ability and anti fouling performance.
Embodiment 2
Except using average diameter is the bead of 50 μ m, uses embodiment 1 identical method to prepare antiseized tectosome.
To steel, aluminium, resinous framework, transparent resin plate, glass and the concrete that has formed antiseized tectosome thereon, use the method identical to carry out adhesive tape and adhere to and test with embodiment 1.As a result, adhesive tape does not adhere on any object in steel, aluminium, resinous framework, transparent resin plate, glass and the concrete, even and when during adhering to, having applied very big pressure, also can at an easy rate adhesive tape be taken off.
Embodiment 3
With 1kg polyurethane resin and 1kg average diameter is that 200 orders, proportion are that 2.54 glass powder evenly mixes, on steel, aluminium, resinous framework, transparent resin plate, glass and concrete, be coated with this mixture respectively, then by implement with embodiment 1 in identical method prepare antiseized tectosome.Use with embodiment 1 in identical method carry out adhesive tape and adhere to and test, its result shows that anti-adhesion effects is identical with embodiment 1.
In addition, the antiseized tectosome for preparing among embodiment 1 and the embodiment 3 has been applied external pressure, whether come off to check bead.As a result, compare with the antiseized tectosome of the embodiment 1 that does not use glass powder, the antiseized tectosome that has added the embodiment 3 of glass powder has the more excellent ability that combines with bead.
Embodiment 4
With 1kg polyurethane resin and 100g average fiber thickness is that 13.5 μ m, average fiber length are that the milled glass fiber of 300 μ m evenly mixes, on steel, aluminium, resinous framework, transparent resin plate, glass and concrete, be coated with this mixture respectively, then by implement with embodiment 1 in identical method prepare antiseized tectosome.According to embodiment 1 in identical method carry out adhesive tape and adhere to test, its result shows that anti-adhesion effects is identical with embodiment 1.
Embodiment 5
With the 1kg average diameter is that 200 orders, proportion be 2.54 glass powder with 100g average fiber thickness are that 13.5 μ m, average fiber length are that the milled glass fiber of 300 μ m evenly mixes, on steel, aluminium, resinous framework, transparent resin plate, glass and concrete, be coated with this mixture respectively, then by implement with embodiment 1 in identical method prepare antiseized tectosome.According to embodiment 1 in identical method carry out adhesive tape and adhere to test, its result shows that anti-adhesion effects is identical with embodiment 1.
Embodiment 6
Prepare antiseized tectosome by following method: coating 1kg polyurethane resin on the non-weaving cloth of 25cm * 15cm with the glass bead projection that adheres to the polyurethane resin surface, spraying the 800g average diameter before the polyurethane resin sclerosis is the bead of 1mm, and makes their sclerosis.The non-weaving cloth that has formed antiseized tectosome on it is adhered on steel, aluminium, resinous framework, transparent resin plate, glass and the concrete, use then with embodiment 1 in identical method carry out adhesive tape and adhere to and test.As a result, they have shown the anti-adhesion effects identical with embodiment 1.
Embodiment 7
Except using the PMMA pearl to replace the bead of embodiment 1 in 6, implement the method identical and prepare antiseized tectosome with embodiment 1 to 6.Adhesive tape adheres to test result and shows, anti-adhesion effects with
Embodiment 1 is identical.
Embodiment 8
Except using zirconium oxide bead to replace the bead of embodiment 1 in 6, implement the method identical and prepare antiseized tectosome with embodiment 1 to 6.Adhesive tape adheres to test result and shows, the desorption effect with
Embodiment 1 is similar.
Industrial applicibility
Antiseized tectosome and production method thereof in according to the present invention, the projection that forms by the pearl that is positioned on the following body surface can produce irregular recess, reduced attachment and the contact area between the surface of coating thus, described object is wall body and internal and external frame such as road equipment such as the guardrail that is coated with, phone mast, traffic lights, street lamp, traffic sign and control cabinet and their supporter, building or fabrication.Therefore, the present invention can prevent the adhesion such as the attachment of stickup product, placard, dust etc., even and attachment adhered to also and can easily it have been removed by contact area is minimized.In addition, the recess that convexes to form when pearl can easily be removed these pollutants by washing (for example rain or snow) during by contamination by dust.Therefore, the present invention has shown excellent effect aspect anti fouling performance.
In addition, when structure is the structure that is easy to by contamination by dust, for example when road sign, lamp device, reflecting surface, electric light and billboard etc., the present invention can prevent the adhesion of dust or pollutant, even and dust or pollutant adhered to also and can easily it have been removed.
In addition, antiseized tectosome of the present invention can be formed at an easy rate, and can improve with the surface of its coating such as performances such as weatherability, anti fouling performance, resistance to marring, chemical resistance and resistances to impact.
The present invention is not subjected to the restriction of detailed description of the present invention and accompanying drawing.Can carry out other and improve the spirit and scope of the present invention that can not break away from the claims definition with further changing, this will appreciate that for those skilled in the art.
Claims (18)
1. antiseized tectosome, this antiseized tectosome comprises:
Structure;
Be coated on all or part of lip-deep binder resin layer that comprises resin binder of described structure; With
The bead layer that comprises a plurality of pearls of the upside that is combined in the binder resin layer that is coated with, described pearl outwards protrudes.
2. antiseized tectosome, this antiseized tectosome comprises:
Structure;
Be coated on all or part of lip-deep adhesive phase that comprises adhesive of described structure;
The adhesion layer that comprises the non-weaving cloth, woven cloths, foam film or the resin molding that adhere to described adhesive phase;
Be coated on the surface of described adhesion layer or comprise the lip-deep binder resin layer that comprises resin binder of the structure of described adhesion layer; With
The bead layer that comprises a plurality of pearls of the upside that is combined in the binder resin layer that is coated with, described pearl outwards protrudes.
3. antiseized tectosome, this antiseized tectosome comprises:
The adhesion layer that comprises resin molding, foam film, woven cloths or non-weaving cloth;
Be coated with or be immersed in the binder resin layer that comprises resin binder on all or part of described adhesion layer; With
Comprise the bead layer of a plurality of pearls of the upside that is combined in institute's binder resin layer of being coated with or flooding, described pearl outwards protrudes.
4. as each described antiseized tectosome of claim 1 to 3, wherein said structure is the supporter or the wall body of following material, and described material is road equipment, phone mast, traffic lights, street lamp, traffic sign, control cabinet, building, guardrail, road sign, internal and external frame, lamp device, lamp reflecting surface, electric light, transparent configuration thing or billboard.
5. as each described antiseized tectosome of claim 1 to 3, wherein said resin binder is selected from the group of being made up of acrylic resin, ceramic-like resin, fluorine-type resin, polyurethanes resin, metallic paint, water-base resin adhesive and their combination.
6. as each described antiseized tectosome of claim 1 to 3, wherein said pearl is ceramic bead, bead, resin bead or their mixture.
7. antiseized tectosome as claimed in claim 6, wherein said pearl are bead, PMMA pearl, zirconium oxide bead or their mixture.
8. as each described antiseized tectosome of claim 1 to 3, the average diameter of wherein said pearl is 1nm～3mm.
9. as each described antiseized tectosome of claim 1 to 3, wherein relative 100 weight portion hard resin adhesives, the content of described pearl is 10 weight portions～150 weight portions.
10. as each described antiseized tectosome of claim 1 to 3, wherein said resin binder also comprises the glass powder that diameter is 0.01 μ m～1mm, relative 100 weight portion hard resin adhesives, the content of described glass powder is 20 weight portions～50 weight portions.
11. as each described antiseized tectosome of claim 1 to 3, wherein said resin binder also comprises by being that the glass fibre of 10 μ m～20 μ m or carbon fiber cut into chopped strand that unified fibril length makes or be the milled fiber that 100 μ m～300 μ m make by being ground into average fiber length with fibre diameter, relative 100 weight portion hard resin adhesives, the content of described chopped strand or milled fiber is 1 weight portion～100 weight portions.
12. as each described antiseized tectosome of claim 1 to 3, wherein said resin binder also comprises one or more and is selected from by the additive in the group of filler, conductive filler, pigment, catalysts, thickener, mobility conditioning agent, wetting agent, ultra-violet stabilizer, antiprecipitant and light reflector powder constituent.
13. as each described antiseized tectosome of claim 1 to 3, the general thickness that wherein is formed on the lip-deep layer of structure is 5 μ m～3.0mm.
14. method of producing antiseized tectosome, this method is included in coating resin adhesive on the surface that will be coated with, before the resin binder sclerosis that is coated with pearl is sprayed at the top of described resin binder, and makes their sclerosis to form the pearl projection.
15. method of producing antiseized tectosome, this method is included in coating resin adhesive on non-weaving cloth, woven cloths, foam film or the resin molding, before the resin binder sclerosis that is coated with pearl is sprayed thereon, makes their sclerosis, and non-weaving cloth, woven cloths, foam film or the resin molding that has formed the pearl projection on it adhered to the surface that will be coated with.
16. method of producing antiseized tectosome, this method comprise with non-weaving cloth, woven cloths, foam film or resin molding as adhesive adhere to the surface that will be coated with, on the surface of described non-weaving cloth, woven cloths, foam film or resin molding or comprise coating resin adhesive on its surface of structure, pearl sprayed thereon before the resin binder sclerosis that is being coated with, and make their sclerosis to form the pearl projection.
17. method as the antiseized tectosome of each described production of claim 14 to 16, wherein as the method for curing of described resin binder, can use that one or more are selected from by air dry, cure, the method in quenching, catalyst sclerosis, UV cured and the group that electron-beam curing is formed.
18. as the method for the antiseized tectosome of each described production of claim 14 to 16, wherein the range of viscosities of the resin binder that will be coated with is 1,000cPs～200,000cPs.
Applications Claiming Priority (10)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020040044846A KR100614005B1 (en) | 2004-06-17 | 2004-06-17 | Method for forming of prevention of sticking |
| KR1020040044846 | 2004-06-17 | ||
| KR1020040092292 | 2004-11-12 | ||
| KR2020050000354 | 2005-01-06 | ||
| KR2020050001170 | 2005-01-14 | ||
| KR1020050013156 | 2005-02-17 | ||
| KR2020050004273 | 2005-02-17 | ||
| KR1020050028973 | 2005-04-07 | ||
| KR2020050010051 | 2005-04-12 | ||
| KR2020050010620 | 2005-04-18 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1968808A true CN1968808A (en) | 2007-05-23 |
Family
ID=38077091
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2005800201423A Pending CN1968808A (en) | 2004-06-17 | 2005-06-17 | Structure of preventing sticking and method of preparing the same |
Country Status (2)
| Country | Link |
|---|---|
| KR (1) | KR100614005B1 (en) |
| CN (1) | CN1968808A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105517799A (en) * | 2014-09-03 | 2016-04-20 | 新道公司 | Coating sheet for preventing attachment of fliers |
| CN106470840A (en) * | 2014-06-20 | 2017-03-01 | 东洋制罐株式会社 | Structure and the liquid film forming coating fluid of liquid film are formed on surface |
| CN108986659A (en) * | 2017-06-02 | 2018-12-11 | 三星显示有限公司 | The method of the lid window of the lid window and manufacture flexible display device of flexible display device |
| CN110777543A (en) * | 2019-11-06 | 2020-02-11 | 宁波瑞凌新能源科技有限公司 | Radiation refrigeration functional layer, radiation refrigeration fabric and preparation method thereof |
| CN115703938A (en) * | 2021-08-06 | 2023-02-17 | 江苏凯伦建材股份有限公司 | Coating composition for waterproof composite material and waterproof composite material comprising same |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100725661B1 (en) * | 2005-02-17 | 2007-06-08 | 곽상운 | Method for forming of prevention of sticking |
| KR100706617B1 (en) * | 2005-06-29 | 2007-04-12 | 염영식 | Poie prevention stic sticker using and paint |
| KR100657363B1 (en) * | 2006-07-11 | 2006-12-14 | (유)백제환경 | Paint for preventing stickeng of sticker |
| KR100856868B1 (en) | 2006-12-29 | 2008-09-04 | 주식회사 신도디앤텍 | A member for preventing to adhere advertisement parers |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02168294A (en) * | 1988-12-22 | 1990-06-28 | Kyushu Shinko Rubber Kk | Manufacture of reflecting surface of marker |
| JPH083881A (en) * | 1994-06-10 | 1996-01-09 | Dainippon Printing Co Ltd | Formed product with suede-toned surface and its production |
| KR100477269B1 (en) * | 2002-04-18 | 2005-03-17 | 곽상운 | non-slip and hard synthetic resin tile |
-
2004
- 2004-06-17 KR KR1020040044846A patent/KR100614005B1/en not_active IP Right Cessation
-
2005
- 2005-06-17 CN CNA2005800201423A patent/CN1968808A/en active Pending
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106470840A (en) * | 2014-06-20 | 2017-03-01 | 东洋制罐株式会社 | Structure and the liquid film forming coating fluid of liquid film are formed on surface |
| CN106470840B (en) * | 2014-06-20 | 2018-11-16 | 东洋制罐株式会社 | The structural body and liquid film forming coating fluid of liquid film are formed on surface |
| CN105517799A (en) * | 2014-09-03 | 2016-04-20 | 新道公司 | Coating sheet for preventing attachment of fliers |
| CN108986659A (en) * | 2017-06-02 | 2018-12-11 | 三星显示有限公司 | The method of the lid window of the lid window and manufacture flexible display device of flexible display device |
| CN110777543A (en) * | 2019-11-06 | 2020-02-11 | 宁波瑞凌新能源科技有限公司 | Radiation refrigeration functional layer, radiation refrigeration fabric and preparation method thereof |
| CN110777543B (en) * | 2019-11-06 | 2021-09-14 | 宁波瑞凌新能源科技有限公司 | Radiation refrigeration functional layer, radiation refrigeration fabric and preparation method thereof |
| CN115703938A (en) * | 2021-08-06 | 2023-02-17 | 江苏凯伦建材股份有限公司 | Coating composition for waterproof composite material and waterproof composite material comprising same |
Also Published As
| Publication number | Publication date |
|---|---|
| KR100614005B1 (en) | 2006-08-21 |
| KR20050051534A (en) | 2005-06-01 |
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