CN1912152A - 一种从铜钴铁合金中浸出有价金属的方法 - Google Patents
一种从铜钴铁合金中浸出有价金属的方法 Download PDFInfo
- Publication number
- CN1912152A CN1912152A CNA2006100320518A CN200610032051A CN1912152A CN 1912152 A CN1912152 A CN 1912152A CN A2006100320518 A CNA2006100320518 A CN A2006100320518A CN 200610032051 A CN200610032051 A CN 200610032051A CN 1912152 A CN1912152 A CN 1912152A
- Authority
- CN
- China
- Prior art keywords
- alloy
- copper
- cobalt
- valuable metal
- leaching valuable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 66
- 239000010949 copper Substances 0.000 title claims abstract description 66
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 61
- 239000000956 alloy Substances 0.000 title claims abstract description 61
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 51
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 19
- 239000002184 metal Substances 0.000 title claims abstract description 19
- 238000000034 method Methods 0.000 title claims abstract description 19
- RIVZIMVWRDTIOQ-UHFFFAOYSA-N cobalt iron Chemical compound [Fe].[Co].[Co].[Co] RIVZIMVWRDTIOQ-UHFFFAOYSA-N 0.000 title claims description 48
- 238000002386 leaching Methods 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000002253 acid Substances 0.000 claims abstract description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 6
- 239000011707 mineral Substances 0.000 claims abstract description 6
- OBLMUVZPDITTKB-UHFFFAOYSA-N [Fe].[Co].[Cu] Chemical compound [Fe].[Co].[Cu] OBLMUVZPDITTKB-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000010438 heat treatment Methods 0.000 claims abstract description 3
- 239000007800 oxidant agent Substances 0.000 claims abstract description 3
- 239000002893 slag Substances 0.000 claims description 27
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 20
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 10
- 235000017550 sodium carbonate Nutrition 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 8
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 8
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 claims description 8
- 239000003595 mist Substances 0.000 claims description 7
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 6
- 239000007789 gas Substances 0.000 claims description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 6
- 235000011152 sodium sulphate Nutrition 0.000 claims description 6
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 5
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 4
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 4
- 235000010755 mineral Nutrition 0.000 claims description 4
- 150000007522 mineralic acids Chemical class 0.000 claims description 4
- 229940001516 sodium nitrate Drugs 0.000 claims description 4
- 235000010344 sodium nitrate Nutrition 0.000 claims description 4
- 239000004317 sodium nitrate Substances 0.000 claims description 4
- 229910000640 Fe alloy Inorganic materials 0.000 claims description 3
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000292 calcium oxide Substances 0.000 claims description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 3
- 238000013467 fragmentation Methods 0.000 claims description 3
- 238000006062 fragmentation reaction Methods 0.000 claims description 3
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 239000000460 chlorine Substances 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 238000001816 cooling Methods 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000012286 potassium permanganate Substances 0.000 claims description 2
- 238000002791 soaking Methods 0.000 claims description 2
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 2
- 239000001117 sulphuric acid Substances 0.000 claims description 2
- 235000011149 sulphuric acid Nutrition 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 abstract description 37
- 229910017052 cobalt Inorganic materials 0.000 abstract description 37
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract description 37
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 34
- 229910052742 iron Inorganic materials 0.000 abstract description 17
- 239000000843 powder Substances 0.000 abstract description 16
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 229910001313 Cobalt-iron alloy Inorganic materials 0.000 abstract description 2
- 230000004907 flux Effects 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 238000004458 analytical method Methods 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000000706 filtrate Substances 0.000 description 7
- 238000001914 filtration Methods 0.000 description 7
- 239000004615 ingredient Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- 230000006698 induction Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910001361 White metal Inorganic materials 0.000 description 3
- 238000000889 atomisation Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 238000010792 warming Methods 0.000 description 3
- 239000010969 white metal Substances 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- RYTYSMSQNNBZDP-UHFFFAOYSA-N cobalt copper Chemical compound [Co].[Cu] RYTYSMSQNNBZDP-UHFFFAOYSA-N 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000008204 material by function Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011858 nanopowder Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Abstract
Description
Claims (10)
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CNB2006100320518A CN100345986C (zh) | 2006-08-04 | 2006-08-04 | 一种从铜钴铁合金中浸出铜钴铁的方法 |
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CN100345986C CN100345986C (zh) | 2007-10-31 |
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Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101463427A (zh) * | 2008-11-27 | 2009-06-24 | 佛山市邦普镍钴技术有限公司 | 一种从钴白合金中回收有价金属的方法 |
CN101818246A (zh) * | 2010-05-11 | 2010-09-01 | 南通新玮镍钴科技发展有限公司 | 一种钴铜白合金的浸出处理工艺 |
CN101524761B (zh) * | 2009-04-17 | 2010-10-13 | 戴煜 | 一种制取钴矿物原料粉末的方法 |
CN101608258B (zh) * | 2008-11-20 | 2011-02-16 | 厦门钨业股份有限公司 | 采用钴铜合金作原料工业提取钴、铜、铁的方法 |
CN102021326A (zh) * | 2009-09-09 | 2011-04-20 | 彭国伟 | 铜钴合金浸出方法 |
CN102321824A (zh) * | 2011-10-13 | 2012-01-18 | 北京矿冶研究总院 | 一种钴白合金脱硅的方法 |
CN102560100A (zh) * | 2012-02-21 | 2012-07-11 | 海南金亿新材料股份有限公司 | 一种利用铜钴铁合金制备高纯超细钴粉的工艺方法 |
CN101818250B (zh) * | 2009-02-27 | 2012-10-24 | 浙江华友钴业股份有限公司 | 一种处理钴铜铁合金的方法 |
CN102925695A (zh) * | 2012-10-20 | 2013-02-13 | 贵研铂业股份有限公司 | 一种废旧高温合金物料的镍和钴浸出方法 |
CN102978406A (zh) * | 2012-12-14 | 2013-03-20 | 西北有色金属研究院 | 一种含铼的高温合金废料的再生方法 |
CN104611565A (zh) * | 2014-12-24 | 2015-05-13 | 金川集团股份有限公司 | 一种从钴铜锌锰生产废液中选择性回收钴铜的方法 |
CN105063349A (zh) * | 2015-08-17 | 2015-11-18 | 长沙矿冶研究院有限责任公司 | 从熔炼合金中浸出铜钴镍的方法 |
CN107640961A (zh) * | 2017-09-28 | 2018-01-30 | 江西理工大学 | 一种高导热氧化铝陶瓷覆铜板的制备方法 |
CN108977662A (zh) * | 2018-07-13 | 2018-12-11 | 兰州金川新材料科技股份有限公司 | 一种利用钴铁合金制备氯化钴溶液和硫酸铜溶液的方法 |
CN112410538A (zh) * | 2020-11-17 | 2021-02-26 | 湖南仁发材料科技有限公司 | 一种铜钴铁合金综合回收有价金属的生产工艺 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101717862B (zh) * | 2009-11-20 | 2011-06-08 | 湖南铠通金属有限公司 | 一种铜钴铁合金综合回收有价金属的生产工艺 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU4906800A (en) * | 1999-05-27 | 2000-12-18 | Hatch Associates Ltd. | Recovery of cobalt and nickel from iron-rich mattes and alloys by leaching |
CA2273067A1 (en) * | 1999-05-27 | 2000-11-27 | Grenvil Marquis Dunn | Process for recovering value metals from iron-containing alloys |
CN1510151A (zh) * | 2002-12-26 | 2004-07-07 | 中国科学院过程工程研究所 | 含钴渣的处理方法 |
CN1333089C (zh) * | 2005-12-13 | 2007-08-22 | 浙江盈联科技有限公司 | 一种处理钴铜合金的方法 |
-
2006
- 2006-08-04 CN CNB2006100320518A patent/CN100345986C/zh not_active Expired - Fee Related
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101608258B (zh) * | 2008-11-20 | 2011-02-16 | 厦门钨业股份有限公司 | 采用钴铜合金作原料工业提取钴、铜、铁的方法 |
CN101463427B (zh) * | 2008-11-27 | 2012-09-05 | 佛山市邦普循环科技有限公司 | 一种从钴白合金中回收有价金属的方法 |
CN101463427A (zh) * | 2008-11-27 | 2009-06-24 | 佛山市邦普镍钴技术有限公司 | 一种从钴白合金中回收有价金属的方法 |
CN101818250B (zh) * | 2009-02-27 | 2012-10-24 | 浙江华友钴业股份有限公司 | 一种处理钴铜铁合金的方法 |
CN101524761B (zh) * | 2009-04-17 | 2010-10-13 | 戴煜 | 一种制取钴矿物原料粉末的方法 |
CN102021326B (zh) * | 2009-09-09 | 2013-04-17 | 彭国伟 | 铜钴合金浸出方法 |
CN102021326A (zh) * | 2009-09-09 | 2011-04-20 | 彭国伟 | 铜钴合金浸出方法 |
CN101818246A (zh) * | 2010-05-11 | 2010-09-01 | 南通新玮镍钴科技发展有限公司 | 一种钴铜白合金的浸出处理工艺 |
CN101818246B (zh) * | 2010-05-11 | 2012-05-23 | 南通新玮镍钴科技发展有限公司 | 一种钴铜白合金的浸出处理工艺 |
CN102321824A (zh) * | 2011-10-13 | 2012-01-18 | 北京矿冶研究总院 | 一种钴白合金脱硅的方法 |
CN102321824B (zh) * | 2011-10-13 | 2013-06-05 | 北京矿冶研究总院 | 一种钴白合金脱硅的方法 |
CN102560100A (zh) * | 2012-02-21 | 2012-07-11 | 海南金亿新材料股份有限公司 | 一种利用铜钴铁合金制备高纯超细钴粉的工艺方法 |
CN102925695A (zh) * | 2012-10-20 | 2013-02-13 | 贵研铂业股份有限公司 | 一种废旧高温合金物料的镍和钴浸出方法 |
CN102978406A (zh) * | 2012-12-14 | 2013-03-20 | 西北有色金属研究院 | 一种含铼的高温合金废料的再生方法 |
CN104611565A (zh) * | 2014-12-24 | 2015-05-13 | 金川集团股份有限公司 | 一种从钴铜锌锰生产废液中选择性回收钴铜的方法 |
CN105063349A (zh) * | 2015-08-17 | 2015-11-18 | 长沙矿冶研究院有限责任公司 | 从熔炼合金中浸出铜钴镍的方法 |
CN105063349B (zh) * | 2015-08-17 | 2017-07-07 | 长沙矿冶研究院有限责任公司 | 从熔炼合金中浸出铜钴镍的方法 |
CN107640961A (zh) * | 2017-09-28 | 2018-01-30 | 江西理工大学 | 一种高导热氧化铝陶瓷覆铜板的制备方法 |
CN107640961B (zh) * | 2017-09-28 | 2020-06-23 | 江西理工大学 | 一种高导热氧化铝陶瓷覆铜板的制备方法 |
CN108977662A (zh) * | 2018-07-13 | 2018-12-11 | 兰州金川新材料科技股份有限公司 | 一种利用钴铁合金制备氯化钴溶液和硫酸铜溶液的方法 |
CN112410538A (zh) * | 2020-11-17 | 2021-02-26 | 湖南仁发材料科技有限公司 | 一种铜钴铁合金综合回收有价金属的生产工艺 |
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Denomination of invention: Method for extracting valence metal from copper ferrocobalt alloy Effective date of registration: 20150909 Granted publication date: 20071031 Pledgee: CITIC Bank Changsha branch Pledgor: HUNAN RESHINE NEW MATERIAL Co.,Ltd. Registration number: 2015430000023 |
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