CN1884076A - 一种微波加热合成磷铝分子筛方法 - Google Patents
一种微波加热合成磷铝分子筛方法 Download PDFInfo
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- CN1884076A CN1884076A CN 200610011978 CN200610011978A CN1884076A CN 1884076 A CN1884076 A CN 1884076A CN 200610011978 CN200610011978 CN 200610011978 CN 200610011978 A CN200610011978 A CN 200610011978A CN 1884076 A CN1884076 A CN 1884076A
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- molecular sieve
- ionic liquid
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- 239000002808 molecular sieve Substances 0.000 title claims abstract description 77
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title claims abstract description 77
- 238000000034 method Methods 0.000 title claims abstract description 46
- 238000010438 heat treatment Methods 0.000 title claims abstract description 36
- 230000002194 synthesizing effect Effects 0.000 title claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 47
- 239000002608 ionic liquid Substances 0.000 claims abstract description 46
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 43
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 43
- 239000000047 product Substances 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 238000001035 drying Methods 0.000 claims abstract description 18
- 239000003960 organic solvent Substances 0.000 claims abstract description 17
- 239000000706 filtrate Substances 0.000 claims abstract description 16
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000004411 aluminium Substances 0.000 claims description 42
- 238000002425 crystallisation Methods 0.000 claims description 38
- 230000008025 crystallization Effects 0.000 claims description 37
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 36
- 229910019142 PO4 Inorganic materials 0.000 claims description 31
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 31
- 239000010452 phosphate Substances 0.000 claims description 31
- -1 quaternary ammonium alkyl ion Chemical class 0.000 claims description 25
- 239000011541 reaction mixture Substances 0.000 claims description 22
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 18
- 230000005855 radiation Effects 0.000 claims description 18
- 238000002156 mixing Methods 0.000 claims description 17
- 238000010792 warming Methods 0.000 claims description 15
- 238000010189 synthetic method Methods 0.000 claims description 14
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 150000002500 ions Chemical class 0.000 claims description 12
- 229910052698 phosphorus Inorganic materials 0.000 claims description 11
- 239000011574 phosphorus Substances 0.000 claims description 11
- PWZUUYSISTUNDW-VAFBSOEGSA-N quinestrol Chemical compound C([C@@H]1[C@@H](C2=CC=3)CC[C@]4([C@H]1CC[C@@]4(O)C#C)C)CC2=CC=3OC1CCCC1 PWZUUYSISTUNDW-VAFBSOEGSA-N 0.000 claims description 5
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 claims description 4
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 claims description 4
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Natural products P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims description 4
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 claims description 4
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical group [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 claims description 4
- 229910000073 phosphorus hydride Inorganic materials 0.000 claims description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 claims description 4
- 238000005406 washing Methods 0.000 abstract description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052822 amblygonite Inorganic materials 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 20
- 238000002441 X-ray diffraction Methods 0.000 description 17
- 206010013786 Dry skin Diseases 0.000 description 14
- 230000031709 bromination Effects 0.000 description 12
- 238000005893 bromination reaction Methods 0.000 description 12
- 239000002904 solvent Substances 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000003786 synthesis reaction Methods 0.000 description 6
- 238000001308 synthesis method Methods 0.000 description 4
- 239000002699 waste material Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000009415 formwork Methods 0.000 description 2
- 150000002892 organic cations Chemical class 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910016467 AlCl 4 Inorganic materials 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 150000001449 anionic compounds Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- CHXARDKIHSVFDK-UHFFFAOYSA-N hexylphosphane Chemical compound CCCCCCP CHXARDKIHSVFDK-UHFFFAOYSA-N 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 229910001412 inorganic anion Inorganic materials 0.000 description 1
- 150000008040 ionic compounds Chemical class 0.000 description 1
- 238000001570 ionothermal synthesis Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
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CNB2006100119783A CN100410172C (zh) | 2006-05-25 | 2006-05-25 | 一种微波加热合成磷铝分子筛方法 |
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CNB2006100119783A CN100410172C (zh) | 2006-05-25 | 2006-05-25 | 一种微波加热合成磷铝分子筛方法 |
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CN1884076A true CN1884076A (zh) | 2006-12-27 |
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2953508A1 (fr) * | 2009-12-08 | 2011-06-10 | Inst Francais Du Petrole | Procede de preparation d'un solide cristallise de type structural afi en presence d'un liquide ionique constitue d'un sel de 1-butyl-2methylpyridinium |
FR2953507A1 (fr) * | 2009-12-08 | 2011-06-10 | Inst Francais Du Petrole | Procede de preparation d'un solide cristallise de type structural afi en presence d'un liquide ionique constitue d'un sel de 1-hexylpyridinium |
FR2953509A1 (fr) * | 2009-12-08 | 2011-06-10 | Inst Francais Du Petrole | Procede de preparation d'un solide cristallise de type structural afi en milieu liquide ionique et en presence d'un sel d'ammonium quaternaire |
WO2011091678A1 (zh) * | 2010-01-29 | 2011-08-04 | 中国科学院大连化学物理研究所 | 一种-clo结构磷酸铝分子筛及其制备方法 |
CN102153106A (zh) * | 2010-07-29 | 2011-08-17 | 兰州理工大学 | 低共熔体中杂原子磷铝分子筛的快速制备方法 |
CN101786640B (zh) * | 2010-02-12 | 2012-09-05 | 黑龙江大学 | 一种微波加热合成sapo-31分子筛的方法 |
CN102139889B (zh) * | 2010-01-29 | 2012-11-28 | 中国科学院大连化学物理研究所 | 一种afo结构磷酸铝分子筛的合成方法 |
CN103539146A (zh) * | 2013-10-28 | 2014-01-29 | 中国海洋石油总公司 | 一种以离子热法连续式合成sapo-11分子筛的方法 |
CN108816192A (zh) * | 2018-05-08 | 2018-11-16 | 南京大学昆山创新研究院 | 一种新型粗柴油脱色剂的制备方法 |
CN109395771A (zh) * | 2018-09-26 | 2019-03-01 | 昆明理工大学 | 一种酯化-皂化反应催化剂及其制备方法和应用 |
CN110885088A (zh) * | 2019-12-19 | 2020-03-17 | 大连理工大学 | 一种多级孔AlPO-34分子筛的离子热合成方法 |
CN114160193A (zh) * | 2021-12-06 | 2022-03-11 | 厦门大学 | 一种CoAPO-11分子筛及其制备方法和应用、一种烷烃临氢异构化催化剂及应用 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1108988C (zh) * | 1999-03-17 | 2003-05-21 | 中国科学院大连化学物理研究所 | 一种大孔分子筛的微波合成方法 |
CN1169714C (zh) * | 2002-08-30 | 2004-10-06 | 清华大学 | 一种纳米级钛硅分子筛的微波合成方法 |
CN1257839C (zh) * | 2004-09-16 | 2006-05-31 | 华东师范大学 | 一种以离子液体为模板剂制备介孔分子筛的方法 |
-
2006
- 2006-05-25 CN CNB2006100119783A patent/CN100410172C/zh not_active Expired - Fee Related
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2953507A1 (fr) * | 2009-12-08 | 2011-06-10 | Inst Francais Du Petrole | Procede de preparation d'un solide cristallise de type structural afi en presence d'un liquide ionique constitue d'un sel de 1-hexylpyridinium |
FR2953509A1 (fr) * | 2009-12-08 | 2011-06-10 | Inst Francais Du Petrole | Procede de preparation d'un solide cristallise de type structural afi en milieu liquide ionique et en presence d'un sel d'ammonium quaternaire |
FR2953508A1 (fr) * | 2009-12-08 | 2011-06-10 | Inst Francais Du Petrole | Procede de preparation d'un solide cristallise de type structural afi en presence d'un liquide ionique constitue d'un sel de 1-butyl-2methylpyridinium |
CN102139889B (zh) * | 2010-01-29 | 2012-11-28 | 中国科学院大连化学物理研究所 | 一种afo结构磷酸铝分子筛的合成方法 |
WO2011091678A1 (zh) * | 2010-01-29 | 2011-08-04 | 中国科学院大连化学物理研究所 | 一种-clo结构磷酸铝分子筛及其制备方法 |
CN102139885B (zh) * | 2010-01-29 | 2012-10-03 | 中国科学院大连化学物理研究所 | 一种-clo结构磷酸铝分子筛及其制备方法 |
CN101786640B (zh) * | 2010-02-12 | 2012-09-05 | 黑龙江大学 | 一种微波加热合成sapo-31分子筛的方法 |
CN102153106B (zh) * | 2010-07-29 | 2012-12-12 | 兰州理工大学 | 低共熔体中杂原子磷铝分子筛的快速制备方法 |
CN102153106A (zh) * | 2010-07-29 | 2011-08-17 | 兰州理工大学 | 低共熔体中杂原子磷铝分子筛的快速制备方法 |
CN103539146A (zh) * | 2013-10-28 | 2014-01-29 | 中国海洋石油总公司 | 一种以离子热法连续式合成sapo-11分子筛的方法 |
CN103539146B (zh) * | 2013-10-28 | 2015-06-24 | 中国海洋石油总公司 | 一种以离子热法连续式合成sapo-11分子筛的方法 |
CN108816192A (zh) * | 2018-05-08 | 2018-11-16 | 南京大学昆山创新研究院 | 一种新型粗柴油脱色剂的制备方法 |
CN109395771A (zh) * | 2018-09-26 | 2019-03-01 | 昆明理工大学 | 一种酯化-皂化反应催化剂及其制备方法和应用 |
CN109395771B (zh) * | 2018-09-26 | 2021-07-16 | 昆明理工大学 | 一种酯化-皂化反应催化剂及其制备方法和应用 |
CN110885088A (zh) * | 2019-12-19 | 2020-03-17 | 大连理工大学 | 一种多级孔AlPO-34分子筛的离子热合成方法 |
CN114160193A (zh) * | 2021-12-06 | 2022-03-11 | 厦门大学 | 一种CoAPO-11分子筛及其制备方法和应用、一种烷烃临氢异构化催化剂及应用 |
CN114160193B (zh) * | 2021-12-06 | 2023-04-07 | 厦门大学 | 一种CoAPO-11分子筛及其制备方法和应用、一种烷烃临氢异构化催化剂及应用 |
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Inventor after: Xu Yunpeng Inventor after: Liu Baoli Inventor after: Liang Jingcheng Inventor after: Yan Lijun Inventor after: Tian Zhijian Inventor after: Wang Bingchun Inventor after: Wang Lei Inventor after: Hu Sheng Inventor after: Wei Ying Inventor after: Ma Huaijun Inventor after: Li Peng Inventor before: Xu Yunpeng Inventor before: Tian Zhijian Inventor before: Wang Bingchun Inventor before: Wang Lei Inventor before: Wei Ying Inventor before: Ma Huaijun Inventor before: Li Peng |
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