CN1813106A - Coated base paper and a method for manufacturing coated base paper - Google Patents

Coated base paper and a method for manufacturing coated base paper Download PDF

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Publication number
CN1813106A
CN1813106A CNA2004800184230A CN200480018423A CN1813106A CN 1813106 A CN1813106 A CN 1813106A CN A2004800184230 A CNA2004800184230 A CN A2004800184230A CN 200480018423 A CN200480018423 A CN 200480018423A CN 1813106 A CN1813106 A CN 1813106A
Authority
CN
China
Prior art keywords
paper
coating
body paper
overcoat
protection against
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA2004800184230A
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Chinese (zh)
Inventor
O·梅基宁
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
M- Ray & Co Ltd
Original Assignee
M- Ray & Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by M- Ray & Co Ltd filed Critical M- Ray & Co Ltd
Publication of CN1813106A publication Critical patent/CN1813106A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/36Polyalkenyalcohols; Polyalkenylethers; Polyalkenylesters
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • D21H19/10Coatings without pigments
    • D21H19/12Coatings without pigments applied as a solution using water as the only solvent, e.g. in the presence of acid or alkaline compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/14Layer or component removable to expose adhesive
    • Y10T428/1476Release layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/28Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2839Web or sheet containing structurally defined element or component and having an adhesive outermost layer with release or antistick coating

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paper (AREA)

Abstract

The object of the invention is coated base paper. According to the invention, it comprises cellulose fibres based pigment-coated paper having 1 to 5 barrier layers. The barrier layer comprises a barrier chemical selected from the group comprising polyvinyl alcohol, acrylate-based barrier latexes and their mixtures. The object of the invention is also a method for the manufacture of coated base paper. In the method, onto a pigment-coated paper based on cellulose fibres 1-5 barrier layers are applicated by using a method not contacting the web.

Description

The method of the body paper of the body paper of coating and manufacturing coating
The field of the invention
The purpose of this invention is to provide body paper and a kind of method of making the body paper of this coating of the coating that especially is suitable as the body paper that is used for label or barrier paper, wherein overcoat (being protective layer) is applied on the coated paper of cellulosic fibrous substrates.
Prior art
Body paper also is called barrier paper or lining paper, use in the process of making label laminate and self-adhesive label, and it is little by little also as the packaging material that are used for adhesive material.The most normally, body paper or barrier paper are that the glass paper mold is transparent, the paper of supercalendering and top sizing, or usually with the paper that comprises kaolinic pigment scraper coating, for example impervious as far as possible fine paper of supercalendering.The laminar structure of the pressure-sensitive label of common known prior art shows with schematic diagram in accompanying Fig. 1.
In Fig. 1, with release coating 20 coatings, this coating comprises siloxanes to body paper 10 the most commonly.Pressure-sensitive adhesive layer 30 is applied on the release coating 20 that comprises siloxanes, and the surperficial paper 40 of formation label adheres on the glue-line 30.
Because the surperficial paper of label subsequently will be with smooth mode as required from the surface isolation of this body paper, therefore the siloxane layer that is applied on the body paper must be level and smooth and not have the hole.In order to obtain not have the level and smooth siloxane layer in hole, this body paper can not have hole, gauffer, dust or inhomogeneities.The surface of this body paper should fully seal to prevent that siloxanes from infiltrating this body paper.This body paper can not the chemical affect siloxanes the catalysis sclerosis.If the hole is present in the body paper, the adhesive of adhesive-layer can penetrate siloxane layer in this body paper, crack and the fracture of the paper web that causes waste passage (litter path) and label laminate during operation subsequently.
Generally, this siloxanes is with 1-1.25g/m 2Thickness be applied on the body paper and solidify down at about 140 ℃.Siloxanes is expensive, therefore as far as possible hardy with the silicone coating straticulation, but on the other hand, because good stalling characteristic, still the siloxane layer of adequate thickness must be made so that possible problem and the fracture that prevents from advance to occur owing to the hole, porosity and the surface heterogeneity that usually are present among the fine paper.In order to reduce the use of siloxanes, this body paper should be impervious and level and smooth as far as possible.
Publication Wochenb1.Papierfabr., 122, No11, p.468-472 (1994) provide a kind of method, wherein, has 67g/m with the top sizing composition coating that comprises polyvinyl alcohol and carboxymethyl cellulose or polyvinyl alcohol and starch in order to have reduced the consumption of siloxanes 2The bleached paper of grammes per square metre.
In patent JP171600/93, the two sides with the polyvinyl alcohol coated paper has been described, handle and press polish with steam under pressure subsequently.
In paper-making process, polyvinyl alcohol usually the coating paste in as protecting colloid.Especially, have low-molecular-weight polyvinyl alcohol grade and be suitable for comprising the coating paste that contains Kaolin pigments mixture class.Polyvinyl alcohol also can be used as main or auxiliary adhesive and be used as excipient such as fluorescent whitening agent in coating and top sizing composition carrier.
Many known, on paper web as the drying of the polyvinyl alcohol of overcoat be difficulty with catabiotic because on polyvinyl alcohol, occur easily, thereby be difficult to the water that it comprises from this surface removal like the surface of leather, cause the surface to keep inhomogeneous.
From the above mentioned, can find out the method for the impermeable and level and smooth body paper and the described body paper of manufacturing of bigger bulk of remarkable needs and lower grammes per square metre, described body paper is based on the coated paper of being made by chemical pulp, can save material by this body paper, and body paper only needs the thin layer of siloxanes as adherent layer when making label laminate.
Purpose of the present invention
An object of the present invention is to provide impervious body paper of the coating of chemical pulp base.
Another object of the present invention provides a kind of manufacture method of impermeable body paper of coating of chemical pulp base.
In addition, an object of the present invention is the impermeable body paper of coating of chemical pulp base as the purposes that is used for the body paper and the barrier paper of label.
Feature according to body paper of the present invention, the method for making it and its purposes is illustrated in the claims.
The general introduction of invention
Have realized that, can avoid or significantly reduce the problem that is present in the body paper of producing according to prior art by using according to solution of the present invention, wherein the body paper of pigment application cellulosic fibrous substrates, preferred chemical pulp base is with the overcoat coating that preferably includes polyvinyl alcohol.
The detailed description of invention
According to solution of the present invention, one or more layers thin overcoat is applied on the pigment coated paper, wherein this pigment coated paper is made by cellulose fibre, and preferably it mainly is, especially preferably makes above 50% chemical pulp.The thickness of this layer is by measuring the grammes per square metre (g/m of this layer 2) limit, wherein the grammes per square metre of this layer obtains by weigh this body paper and coated paper, or by calculating the flow (g/s/m of used square metre and protection against chemical product 2/ s) obtain.Preferably, this paper is the fine paper of pigment application well known in the art, wherein its coating is used the pigment paste that comprises kaolin or carbonate, preferred kaolin paste, and described paste contains the adhesive that is selected from the common adhesive of using in styrene-butadiene latex, polyvinyl alcohol and other this area.
On the coated paper of making according to the method for prior art, the known method that does not contact paper web of use itself is coated with the 1-5 layer, preferably one deck comprises the aqueous solution of protection against chemical product, the spraying process that this method is selected from the curtain coating method and implements by injection.The protection against chemical product are selected from polyvinyl alcohol, the RaisioChemicals Oy Rebarco of company as mentioning as an example The protection latex of the acrylate base of series and their mixture.The preferred polyvinyl alcohol that uses has short chain, viscosity (mPas) and degree of hydrolysis (mol%) excursion and is 3-98 to 15-99.Use and contain protection against chemical product content, so that the solution of coating has 100cP, the preferred viscosity of 50cP at the most at the most as 3-50 weight %, preferred 3-25 weight %, especially preferably the aqueous solution of 3-5 weight % is coated with as the protection against chemical product.When using the acrylate emulsion as the protection against chemical product, they also can comprise filler, pigment, styrene-butadiene latex and other conventional adhesive.Be coated with these protection against chemical product so that it has preferred 0.5-3g/m in body paper 2Amount.Preferably, the coating of overcoat is carried out in the mode of online coating.
After the coating overcoat, utilize the noncontact dry technology to use method well known in the art such as IR or fluidized bed drying method to carry out drying.After drying, choose wantonly and can carry out supercalendering.As mentioned above, according to the present invention, this overcoat is that impervious so that unnecessary needs carry out supercalendering.In spraying and curtain coating method, choose wantonly pigment, surface tension modifier, drier, defoamer and other excipient well known in the art are added in this overcoat.
The non-contact method that is used to be coated with this overcoat for purposes of the invention is absolutely necessary as spraying or curtain coating method, provides impervious uniform surface by non-contact method.Because do not have to use the equipment of the parts with contact paper web in these methods, they can not produce fracture.
According to the present invention, by this method, can make have impervious unusually, uniformly and do not have a body paper of the smooth surface in hole.Also can not permeate this body paper because siloxanes can not absorb in this body paper, this causes the consumption of the siloxanes that adherent layer can be used to reduce to about 0.7g/m 2Can use any siloxanes or silicone emulsion that is used for label and barrier paper well known in the art to carry out the siliconization processing by the known any method of prior art.
In addition, can reduce the consumption and the amount of binder of coating in the paste of the fibrous material in this body paper, and compare, reality can be coated with the paste amount and reduce at the most 20% with conventional method.Therefore, might make the body paper of light grammes per square metre, but it has at least with the same good properties of the known body paper of prior art and has similar to the known body paper of prior art or even higher bulk.Press polish can make the paper of light grammes per square metre lighter and can realize standard thickness.According to solution of the present invention, also can obviously reduce the consumption of material.
Illustrate in greater detail the present invention by the following example; Yet they are not limitations of the present invention.
Embodiment
Embodiment 1
Preparation utilizes spraying process to be coated with the bodystock paper of polyvinyl alcohol
Use Helicoater equipment, have 85g/m by being sprayed on 2Grammes per square metre and 12.5g/m 2The non-calendered paper Simkraft MF Special of blade coating amount The thin layer of last pva coating.Sample 1 is the reference sample that is not coated with.Use in sample 2 that to have 10-98 degree of hydrolysis, 5% solid content, 64cP viscosity and coating weight be 1g/m 2Polyvinyl alcohol Mowiol Used in sample 3 that to have 15-99 degree of hydrolysis, 5% solid content, 27cP viscosity and coating weight be 1g/m 2Polyvinyl alcohol Mowiol , in sample 4, used the polyvinyl alcohol of same grade, but solids content is 3%, viscosity is that 18cP and coating weight are 0.5g/m 2Use blade coating to carry out the pigment application of body paper, carry out drying subsequently, then or use spraying process or use curtain coating method coating overcoat, drying and optionally become page with production-scale supercalender press polish.The result of the sample of non-press polish is as shown in following table 1, and the result of the sample of press polish is as shown in table 2 below.
Table 1: the sample of non-press polish
Simkraft MF reference sample 1 Simkraft MF+ 1g/m 2The PVA sample 2 Simkraft MF+ 1g/m 2PVA sample 3 Simkraft MF+ 0.5g/m 2PVA sample 4
BW(g/m 2) 90.4 90.2 90.9 90.3
Thickness (μ m) 112 116 113 112
Bulk (cm 3/g) 1.24 1.29 1.24 1.24
Glossiness 75 (%) 13 22 23 21
Ink absorption value (%) NP mk abs. 42 30 30 33
Oil absorption value (g/m 2) Unger oil absorption value 2.08 0.76 0.73 0.54
Table 2: the sample of press polish
2 nip Simkraft MF+ tamb 272 2 nip Simkraft MF+ 1g/m 2 PVA 2 nip Simkraft MF+ 1g/m 2 PVA 2 nip Simkraft MF+ 0.5g/m 2 PVA 8 nip Simkraft MF+ tamb 272
BW(g/m 2) 89.4 90.6 91.3 90.5 91.2
Thickness (μ m) 83 82 81 83 82
Bulk (cm 3/g) 0.93 0.91 0.89 0.92 0.91
Glossiness 75 (%) 48 69 68 66 52
Ink absorption value (%) 33 22 21 20 30
Oil absorption value (g/m 2) 0.71 0.06 0.19 0.13 1.1
PVA measures (g/m 2) 0 0.4 0.4 0.2 0
When comparing, use the ink absorption value of the sample of polyvinyl alcohol significantly to reduce with the sample that does not contain polyvinyl alcohol; When comparing, use the oily absorption value of the sample of polyvinyl alcohol significantly to reduce with the sample that does not contain polyvinyl alcohol.Even without press polish, also can be used for siliconization from the grade of these tests.

Claims (14)

1. Tu Bu body paper, it is characterized in that: it comprises having 1-5 layer pigment coated paper overcoat, cellulosic fibrous substrates, wherein overcoat comprises the protection latex that is selected from polyvinyl alcohol, acrylate base and the protection against chemical product of their mixture.
2. according to the body paper of claim 1, it is characterized in that: the number of overcoat is one deck.
3. according to the body paper of claim 1 or 2, it is characterized in that: the consumption of protection against chemical product is 0.5-3 weight % in the body paper.
4. according to each body paper of claim 1 to 3, it is characterized in that: the protection against chemical product are the polyvinyl alcohol with short chain.
5. according to each body paper of claim 1 to 4, it is characterized in that: pigment coated paper mainly is the pigment application fine paper of chemical pulp base.
6. method of making the body paper of coating, it is characterized in that: on the pigment coated paper of cellulosic fibrous substrates by not contacting the method coating 1-5 layer overcoat of paper web, wherein overcoat comprise aqueous solution form, be selected from the protection latex of polyvinyl alcohol, acrylate base or the protection against chemical product of their mixture.
7. according to the method for claim 6, it is characterized in that: coating one deck overcoat.
8. according to the method for claim 6 or 7, it is characterized in that: the method that does not contact paper web is curtain coating method or spraying process.
9. according to each method of claim 6 to 8, it is characterized in that: the protection against chemical product are to have the aqueous solution form coating of 3-50 weight % concentration.
10. according to the method for claim 9, it is characterized in that: the protection against chemical product are coated with the aqueous solution form with 3-25 weight % concentration, and the solution of coating has the viscosity of 100cP at the most.
11. the method according to claim 10 is characterized in that: the protection against chemical product are coated with the aqueous solution form with 3-5 weight % concentration, and the solution of coating has the viscosity of 50cP at the most.
12. according to each method of claim 6 to 11, it is characterized in that: the coating of overcoat is carried out with online coating method.
13., it is characterized in that: after the coating overcoat, use the noncontact dry technology to carry out drying according to each method of claim 6 to 12.
14. according to claim 1 to 5 each body paper or by the body paper produced according to each method of claim 6 to 13 as the purposes that is used for the body paper of label and barrier paper.
CNA2004800184230A 2003-06-30 2004-05-25 Coated base paper and a method for manufacturing coated base paper Pending CN1813106A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI20030976 2003-06-30
FI20030976A FI20030976A (en) 2003-06-30 2003-06-30 Coated base paper and process for making coated base paper

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CN1813106A true CN1813106A (en) 2006-08-02

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US (1) US20060231226A1 (en)
EP (1) EP1639200A1 (en)
JP (1) JP2007514868A (en)
CN (1) CN1813106A (en)
CA (1) CA2531153A1 (en)
FI (1) FI20030976A (en)
WO (1) WO2005001201A1 (en)

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CN114645487A (en) * 2020-12-18 2022-06-21 芬欧汇川集团 Dispersion coated impervious paper

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Publication number Priority date Publication date Assignee Title
CN103422396A (en) * 2012-05-24 2013-12-04 金东纸业(江苏)股份有限公司 Coated paper and non-setting adhesive bottom paper using the coated paper
CN103422396B (en) * 2012-05-24 2015-09-30 金东纸业(江苏)股份有限公司 Coated paper and apply the adhesive sticker base stock of this coated paper
CN114645487A (en) * 2020-12-18 2022-06-21 芬欧汇川集团 Dispersion coated impervious paper

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Publication number Publication date
FI20030976A (en) 2004-12-31
US20060231226A1 (en) 2006-10-19
EP1639200A1 (en) 2006-03-29
FI20030976A0 (en) 2003-06-30
JP2007514868A (en) 2007-06-07
WO2005001201A1 (en) 2005-01-06
CA2531153A1 (en) 2005-01-06

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