CN1665917A - 溶剂组合物 - Google Patents
溶剂组合物 Download PDFInfo
- Publication number
- CN1665917A CN1665917A CN03815725XA CN03815725A CN1665917A CN 1665917 A CN1665917 A CN 1665917A CN 03815725X A CN03815725X A CN 03815725XA CN 03815725 A CN03815725 A CN 03815725A CN 1665917 A CN1665917 A CN 1665917A
- Authority
- CN
- China
- Prior art keywords
- tdce
- content
- quality
- composition
- solvent compositions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 113
- 239000002904 solvent Substances 0.000 title claims abstract description 65
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 65
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 87
- 125000004432 carbon atom Chemical group C* 0.000 claims description 21
- 229950000929 flurotyl Drugs 0.000 claims description 20
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 6
- 125000003158 alcohol group Chemical group 0.000 claims 4
- 230000004907 flux Effects 0.000 abstract description 13
- ZDCRNXMZSKCKRF-UHFFFAOYSA-N tert-butyl 4-(4-bromoanilino)piperidine-1-carboxylate Chemical compound C1CN(C(=O)OC(C)(C)C)CCC1NC1=CC=C(Br)C=C1 ZDCRNXMZSKCKRF-UHFFFAOYSA-N 0.000 abstract 2
- KFUSEUYYWQURPO-OWOJBTEDSA-N trans-1,2-dichloroethene Chemical group Cl\C=C\Cl KFUSEUYYWQURPO-OWOJBTEDSA-N 0.000 abstract 2
- 238000011086 high cleaning Methods 0.000 abstract 1
- 239000002689 soil Substances 0.000 abstract 1
- -1 2,2,3-trimethylpentane alkane Chemical class 0.000 description 15
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 15
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 13
- 150000001875 compounds Chemical class 0.000 description 11
- 239000007789 gas Substances 0.000 description 9
- 239000007791 liquid phase Substances 0.000 description 9
- 239000012071 phase Substances 0.000 description 9
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
- 238000009835 boiling Methods 0.000 description 7
- 239000012530 fluid Substances 0.000 description 7
- 150000002632 lipids Chemical class 0.000 description 7
- 238000005555 metalworking Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 150000002430 hydrocarbons Chemical class 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 4
- JVSWJIKNEAIKJW-UHFFFAOYSA-N 2-Methylheptane Chemical compound CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 4
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 4
- 239000000428 dust Substances 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 150000002170 ethers Chemical class 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 230000003287 optical effect Effects 0.000 description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- POLCUAVZOMRGSN-UHFFFAOYSA-N dipropyl ether Chemical compound CCCOCCC POLCUAVZOMRGSN-UHFFFAOYSA-N 0.000 description 3
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 238000004817 gas chromatography Methods 0.000 description 3
- 150000002576 ketones Chemical class 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- ZWRUINPWMLAQRD-UHFFFAOYSA-N n-Nonyl alcohol Natural products CCCCCCCCCO ZWRUINPWMLAQRD-UHFFFAOYSA-N 0.000 description 3
- QWVGKYWNOKOFNN-UHFFFAOYSA-N o-cresol Chemical compound CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 description 3
- UBOXGVDOUJQMTN-UHFFFAOYSA-N 1,1,2-trichloroethane Chemical compound ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 2
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 2
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 2
- RQUBQBFVDOLUKC-UHFFFAOYSA-N 1-ethoxy-2-methylpropane Chemical compound CCOCC(C)C RQUBQBFVDOLUKC-UHFFFAOYSA-N 0.000 description 2
- VQKFNUFAXTZWDK-UHFFFAOYSA-N 2-Methylfuran Chemical compound CC1=CC=CO1 VQKFNUFAXTZWDK-UHFFFAOYSA-N 0.000 description 2
- AFABGHUZZDYHJO-UHFFFAOYSA-N 2-Methylpentane Chemical compound CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 2
- RXGUIWHIADMCFC-UHFFFAOYSA-N 2-Methylpropyl 2-methylpropionate Chemical compound CC(C)COC(=O)C(C)C RXGUIWHIADMCFC-UHFFFAOYSA-N 0.000 description 2
- QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 description 2
- WWUVJRULCWHUSA-UHFFFAOYSA-N 2-methyl-1-pentene Chemical compound CCCC(C)=C WWUVJRULCWHUSA-UHFFFAOYSA-N 0.000 description 2
- GXDHCNNESPLIKD-UHFFFAOYSA-N 2-methylhexane Chemical compound CCCCC(C)C GXDHCNNESPLIKD-UHFFFAOYSA-N 0.000 description 2
- COAUHYBSXMIJDK-UHFFFAOYSA-N 3,3-dichloro-1,1,1,2,2-pentafluoropropane Chemical compound FC(F)(F)C(F)(F)C(Cl)Cl COAUHYBSXMIJDK-UHFFFAOYSA-N 0.000 description 2
- LAIUFBWHERIJIH-UHFFFAOYSA-N 3-Methylheptane Chemical compound CCCCC(C)CC LAIUFBWHERIJIH-UHFFFAOYSA-N 0.000 description 2
- DUPUVYJQZSLSJB-UHFFFAOYSA-N 3-ethyl-2-methylpentane Chemical compound CCC(CC)C(C)C DUPUVYJQZSLSJB-UHFFFAOYSA-N 0.000 description 2
- HTSABYAWKQAHBT-UHFFFAOYSA-N 3-methylcyclohexanol Chemical compound CC1CCCC(O)C1 HTSABYAWKQAHBT-UHFFFAOYSA-N 0.000 description 2
- VLJXXKKOSFGPHI-UHFFFAOYSA-N 3-methylhexane Chemical compound CCCC(C)CC VLJXXKKOSFGPHI-UHFFFAOYSA-N 0.000 description 2
- HCFAJYNVAYBARA-UHFFFAOYSA-N 4-heptanone Chemical compound CCCC(=O)CCC HCFAJYNVAYBARA-UHFFFAOYSA-N 0.000 description 2
- MQWCXKGKQLNYQG-UHFFFAOYSA-N 4-methylcyclohexan-1-ol Chemical compound CC1CCC(O)CC1 MQWCXKGKQLNYQG-UHFFFAOYSA-N 0.000 description 2
- CHBAWFGIXDBEBT-UHFFFAOYSA-N 4-methylheptane Chemical compound CCCC(C)CCC CHBAWFGIXDBEBT-UHFFFAOYSA-N 0.000 description 2
- ZCTQGTTXIYCGGC-UHFFFAOYSA-N Benzyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OCC1=CC=CC=C1 ZCTQGTTXIYCGGC-UHFFFAOYSA-N 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 2
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 2
- JKRZOJADNVOXPM-UHFFFAOYSA-N Oxalic acid dibutyl ester Chemical compound CCCCOC(=O)C(=O)OCCCC JKRZOJADNVOXPM-UHFFFAOYSA-N 0.000 description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- XSIFPSYPOVKYCO-UHFFFAOYSA-N butyl benzoate Chemical compound CCCCOC(=O)C1=CC=CC=C1 XSIFPSYPOVKYCO-UHFFFAOYSA-N 0.000 description 2
- XUPYJHCZDLZNFP-UHFFFAOYSA-N butyl butanoate Chemical compound CCCCOC(=O)CCC XUPYJHCZDLZNFP-UHFFFAOYSA-N 0.000 description 2
- NMJJFJNHVMGPGM-UHFFFAOYSA-N butyl formate Chemical compound CCCCOC=O NMJJFJNHVMGPGM-UHFFFAOYSA-N 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 description 2
- IIEWJVIFRVWJOD-UHFFFAOYSA-N ethylcyclohexane Chemical compound CCC1CCCCC1 IIEWJVIFRVWJOD-UHFFFAOYSA-N 0.000 description 2
- 150000008282 halocarbons Chemical class 0.000 description 2
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 2
- NGAZZOYFWWSOGK-UHFFFAOYSA-N heptan-3-one Chemical compound CCCCC(=O)CC NGAZZOYFWWSOGK-UHFFFAOYSA-N 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- JUMYIBMBTDDLNG-OJERSXHUSA-N hydron;methyl (2r)-2-phenyl-2-[(2r)-piperidin-2-yl]acetate;chloride Chemical compound Cl.C([C@@H]1[C@H](C(=O)OC)C=2C=CC=CC=2)CCCN1 JUMYIBMBTDDLNG-OJERSXHUSA-N 0.000 description 2
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 description 2
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 description 2
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 description 2
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 2
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- GDOPTJXRTPNYNR-UHFFFAOYSA-N methylcyclopentane Chemical compound CC1CCCC1 GDOPTJXRTPNYNR-UHFFFAOYSA-N 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- KPSSIOMAKSHJJG-UHFFFAOYSA-N neopentyl alcohol Chemical compound CC(C)(C)CO KPSSIOMAKSHJJG-UHFFFAOYSA-N 0.000 description 2
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- 125000004817 pentamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 2
- XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 229940099204 ritalin Drugs 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 2
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 2
- MGSRCZKZVOBKFT-UHFFFAOYSA-N thymol Chemical compound CC(C)C1=CC=C(C)C=C1O MGSRCZKZVOBKFT-UHFFFAOYSA-N 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- NMRPBPVERJPACX-UHFFFAOYSA-N (3S)-octan-3-ol Natural products CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 description 1
- WUOACPNHFRMFPN-VIFPVBQESA-N (R)-(+)-alpha-terpineol Chemical compound CC1=CC[C@H](C(C)(C)O)CC1 WUOACPNHFRMFPN-VIFPVBQESA-N 0.000 description 1
- RIQRGMUSBYGDBL-UHFFFAOYSA-N 1,1,1,2,2,3,4,5,5,5-decafluoropentane Chemical compound FC(F)(F)C(F)C(F)C(F)(F)C(F)(F)F RIQRGMUSBYGDBL-UHFFFAOYSA-N 0.000 description 1
- QVLAWKAXOMEXPM-UHFFFAOYSA-N 1,1,1,2-tetrachloroethane Chemical compound ClCC(Cl)(Cl)Cl QVLAWKAXOMEXPM-UHFFFAOYSA-N 0.000 description 1
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical group FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- KFUSEUYYWQURPO-UHFFFAOYSA-N 1,2-dichloroethene Chemical compound ClC=CCl KFUSEUYYWQURPO-UHFFFAOYSA-N 0.000 description 1
- OZXIZRZFGJZWBF-UHFFFAOYSA-N 1,3,5-trimethyl-2-(2,4,6-trimethylphenoxy)benzene Chemical compound CC1=CC(C)=CC(C)=C1OC1=C(C)C=C(C)C=C1C OZXIZRZFGJZWBF-UHFFFAOYSA-N 0.000 description 1
- 239000005968 1-Decanol Substances 0.000 description 1
- VTBOTOBFGSVRMA-UHFFFAOYSA-N 1-Methylcyclohexanol Chemical compound CC1(O)CCCCC1 VTBOTOBFGSVRMA-UHFFFAOYSA-N 0.000 description 1
- HNAGHMKIPMKKBB-UHFFFAOYSA-N 1-benzylpyrrolidine-3-carboxamide Chemical compound C1C(C(=O)N)CCN1CC1=CC=CC=C1 HNAGHMKIPMKKBB-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- YACLCMMBHTUQON-UHFFFAOYSA-N 1-chloro-1-fluoroethane Chemical compound CC(F)Cl YACLCMMBHTUQON-UHFFFAOYSA-N 0.000 description 1
- RRQYJINTUHWNHW-UHFFFAOYSA-N 1-ethoxy-2-(2-ethoxyethoxy)ethane Chemical compound CCOCCOCCOCC RRQYJINTUHWNHW-UHFFFAOYSA-N 0.000 description 1
- JSZOAYXJRCEYSX-UHFFFAOYSA-N 1-nitropropane Chemical compound CCC[N+]([O-])=O JSZOAYXJRCEYSX-UHFFFAOYSA-N 0.000 description 1
- FDHDUXOBMHHFFJ-UHFFFAOYSA-N 1-pentylnaphthalene Chemical compound C1=CC=C2C(CCCCC)=CC=CC2=C1 FDHDUXOBMHHFFJ-UHFFFAOYSA-N 0.000 description 1
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 description 1
- HFZLSTDPRQSZCQ-UHFFFAOYSA-N 1-pyrrolidin-3-ylpyrrolidine Chemical compound C1CCCN1C1CNCC1 HFZLSTDPRQSZCQ-UHFFFAOYSA-N 0.000 description 1
- LTMRRSWNXVJMBA-UHFFFAOYSA-L 2,2-diethylpropanedioate Chemical compound CCC(CC)(C([O-])=O)C([O-])=O LTMRRSWNXVJMBA-UHFFFAOYSA-L 0.000 description 1
- SKDGWNHUETZZCS-UHFFFAOYSA-N 2,3-ditert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(O)=C1C(C)(C)C SKDGWNHUETZZCS-UHFFFAOYSA-N 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- WMDZKDKPYCNCDZ-UHFFFAOYSA-N 2-(2-butoxypropoxy)propan-1-ol Chemical compound CCCCOC(C)COC(C)CO WMDZKDKPYCNCDZ-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- WOFPPJOZXUTRAU-UHFFFAOYSA-N 2-Ethyl-1-hexanol Natural products CCCCC(O)CCC WOFPPJOZXUTRAU-UHFFFAOYSA-N 0.000 description 1
- HQLKZWRSOHTERR-UHFFFAOYSA-N 2-Ethylbutyl acetate Chemical compound CCC(CC)COC(C)=O HQLKZWRSOHTERR-UHFFFAOYSA-N 0.000 description 1
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 1
- AVMSWPWPYJVYKY-UHFFFAOYSA-N 2-Methylpropyl formate Chemical compound CC(C)COC=O AVMSWPWPYJVYKY-UHFFFAOYSA-N 0.000 description 1
- TZYRSLHNPKPEFV-UHFFFAOYSA-N 2-ethyl-1-butanol Chemical class CCC(CC)CO TZYRSLHNPKPEFV-UHFFFAOYSA-N 0.000 description 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 1
- WOYWLLHHWAMFCB-UHFFFAOYSA-N 2-ethylhexyl acetate Chemical group CCCCC(CC)COC(C)=O WOYWLLHHWAMFCB-UHFFFAOYSA-N 0.000 description 1
- MHNNAWXXUZQSNM-UHFFFAOYSA-N 2-methylbut-1-ene Chemical compound CCC(C)=C MHNNAWXXUZQSNM-UHFFFAOYSA-N 0.000 description 1
- NDVWOBYBJYUSMF-UHFFFAOYSA-N 2-methylcyclohexan-1-ol Chemical compound CC1CCCCC1O NDVWOBYBJYUSMF-UHFFFAOYSA-N 0.000 description 1
- ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 2-octanone Chemical compound CCCCCCC(C)=O ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 0.000 description 1
- QCAHUFWKIQLBNB-UHFFFAOYSA-N 3-(3-methoxypropoxy)propan-1-ol Chemical compound COCCCOCCCO QCAHUFWKIQLBNB-UHFFFAOYSA-N 0.000 description 1
- GIEZWIDCIFCQPS-UHFFFAOYSA-N 3-ethyl-3-methylpentane Chemical compound CCC(C)(CC)CC GIEZWIDCIFCQPS-UHFFFAOYSA-N 0.000 description 1
- MXLMTQWGSQIYOW-UHFFFAOYSA-N 3-methyl-2-butanol Chemical class CC(C)C(C)O MXLMTQWGSQIYOW-UHFFFAOYSA-N 0.000 description 1
- JIGUICYYOYEXFS-UHFFFAOYSA-N 3-tert-butylbenzene-1,2-diol Chemical compound CC(C)(C)C1=CC=CC(O)=C1O JIGUICYYOYEXFS-UHFFFAOYSA-N 0.000 description 1
- RYAIMSPHUVXLQI-UHFFFAOYSA-N 4-(aminomethyl)-2-(benzotriazol-2-yl)phenol Chemical compound NCC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 RYAIMSPHUVXLQI-UHFFFAOYSA-N 0.000 description 1
- WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 description 1
- VGVHNLRUAMRIEW-UHFFFAOYSA-N 4-methylcyclohexan-1-one Chemical compound CC1CCC(=O)CC1 VGVHNLRUAMRIEW-UHFFFAOYSA-N 0.000 description 1
- QHPQWRBYOIRBIT-UHFFFAOYSA-N 4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C=C1 QHPQWRBYOIRBIT-UHFFFAOYSA-N 0.000 description 1
- PZBQVZFITSVHAW-UHFFFAOYSA-N 5-chloro-2h-benzotriazole Chemical compound C1=C(Cl)C=CC2=NNN=C21 PZBQVZFITSVHAW-UHFFFAOYSA-N 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
- KDPMIBMNNGCWTF-UHFFFAOYSA-N C(CCC)O.CC1(CC(C(=O)O)=CC=C1)C(=O)O Chemical class C(CCC)O.CC1(CC(C(=O)O)=CC=C1)C(=O)O KDPMIBMNNGCWTF-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- YYLLIJHXUHJATK-UHFFFAOYSA-N Cyclohexyl acetate Chemical compound CC(=O)OC1CCCCC1 YYLLIJHXUHJATK-UHFFFAOYSA-N 0.000 description 1
- IEPRKVQEAMIZSS-UHFFFAOYSA-N Di-Et ester-Fumaric acid Natural products CCOC(=O)C=CC(=O)OCC IEPRKVQEAMIZSS-UHFFFAOYSA-N 0.000 description 1
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 description 1
- IEPRKVQEAMIZSS-WAYWQWQTSA-N Diethyl maleate Chemical compound CCOC(=O)\C=C/C(=O)OCC IEPRKVQEAMIZSS-WAYWQWQTSA-N 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- BJIOGJUNALELMI-ONEGZZNKSA-N Isoeugenol Natural products COC1=CC(\C=C\C)=CC=C1O BJIOGJUNALELMI-ONEGZZNKSA-N 0.000 description 1
- JGFBQFKZKSSODQ-UHFFFAOYSA-N Isothiocyanatocyclopropane Chemical compound S=C=NC1CC1 JGFBQFKZKSSODQ-UHFFFAOYSA-N 0.000 description 1
- RJUFJBKOKNCXHH-UHFFFAOYSA-N Methyl propionate Chemical compound CCC(=O)OC RJUFJBKOKNCXHH-UHFFFAOYSA-N 0.000 description 1
- RSJKGSCJYJTIGS-UHFFFAOYSA-N N-undecane Natural products CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 1
- 239000005844 Thymol Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000004202 aminomethyl group Chemical group [H]N([H])C([H])([H])* 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- UDEWPOVQBGFNGE-UHFFFAOYSA-N benzoic acid n-propyl ester Natural products CCCOC(=O)C1=CC=CC=C1 UDEWPOVQBGFNGE-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 229940007550 benzyl acetate Drugs 0.000 description 1
- SESFRYSPDFLNCH-UHFFFAOYSA-N benzyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCC1=CC=CC=C1 SESFRYSPDFLNCH-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 1
- OBNCKNCVKJNDBV-UHFFFAOYSA-N butanoic acid ethyl ester Natural products CCCC(=O)OCC OBNCKNCVKJNDBV-UHFFFAOYSA-N 0.000 description 1
- PWLNAUNEAKQYLH-UHFFFAOYSA-N butyric acid octyl ester Natural products CCCCCCCCOC(=O)CCC PWLNAUNEAKQYLH-UHFFFAOYSA-N 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- BJIOGJUNALELMI-ARJAWSKDSA-N cis-isoeugenol Chemical compound COC1=CC(\C=C/C)=CC=C1O BJIOGJUNALELMI-ARJAWSKDSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 150000003997 cyclic ketones Chemical class 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 1
- WVIIMZNLDWSIRH-UHFFFAOYSA-N cyclohexylcyclohexane Chemical compound C1CCCCC1C1CCCCC1 WVIIMZNLDWSIRH-UHFFFAOYSA-N 0.000 description 1
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 1
- FUGIIBWTNARRSF-UHFFFAOYSA-N decane-5,6-diol Chemical compound CCCCC(O)C(O)CCCC FUGIIBWTNARRSF-UHFFFAOYSA-N 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- PCYQQSKDZQTOQG-NXEZZACHSA-N dibutyl (2r,3r)-2,3-dihydroxybutanedioate Chemical compound CCCCOC(=O)[C@H](O)[C@@H](O)C(=O)OCCCC PCYQQSKDZQTOQG-NXEZZACHSA-N 0.000 description 1
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- WYACBZDAHNBPPB-UHFFFAOYSA-N diethyl oxalate Chemical compound CCOC(=O)C(=O)OCC WYACBZDAHNBPPB-UHFFFAOYSA-N 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 229940019778 diethylene glycol diethyl ether Drugs 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
- 125000005594 diketone group Chemical group 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- LDCRTTXIJACKKU-ARJAWSKDSA-N dimethyl maleate Chemical compound COC(=O)\C=C/C(=O)OC LDCRTTXIJACKKU-ARJAWSKDSA-N 0.000 description 1
- XAHVPYNDLCTDTE-UHFFFAOYSA-N dipentyl oxalate Chemical compound CCCCCOC(=O)C(=O)OCCCCC XAHVPYNDLCTDTE-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 description 1
- 150000002240 furans Chemical class 0.000 description 1
- YEJRWHAVMIAJKC-UHFFFAOYSA-N gamma-butyrolactone Natural products O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- LHGVFZTZFXWLCP-UHFFFAOYSA-N guaiacol Chemical compound COC1=CC=CC=C1O LHGVFZTZFXWLCP-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- SHOJXDKTYKFBRD-UHFFFAOYSA-N mesityl oxide Natural products CC(C)=CC(C)=O SHOJXDKTYKFBRD-UHFFFAOYSA-N 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229940095102 methyl benzoate Drugs 0.000 description 1
- 229940017219 methyl propionate Drugs 0.000 description 1
- OLXYLDUSSBULGU-UHFFFAOYSA-N methyl pyridine-4-carboxylate Chemical compound COC(=O)C1=CC=NC=C1 OLXYLDUSSBULGU-UHFFFAOYSA-N 0.000 description 1
- OSWPMRLSEDHDFF-UHFFFAOYSA-N methyl salicylate Chemical compound COC(=O)C1=CC=CC=C1O OSWPMRLSEDHDFF-UHFFFAOYSA-N 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 239000002480 mineral oil Chemical class 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- DIOQZVSQGTUSAI-UHFFFAOYSA-N n-butylhexane Natural products CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 1
- UUIQMZJEGPQKFD-UHFFFAOYSA-N n-butyric acid methyl ester Natural products CCCC(=O)OC UUIQMZJEGPQKFD-UHFFFAOYSA-N 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 150000002828 nitro derivatives Chemical class 0.000 description 1
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 1
- MCSAJNNLRCFZED-UHFFFAOYSA-N nitroethane Chemical compound CC[N+]([O-])=O MCSAJNNLRCFZED-UHFFFAOYSA-N 0.000 description 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- BKIMMITUMNQMOS-UHFFFAOYSA-N normal nonane Natural products CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- BNIXVQGCZULYKV-UHFFFAOYSA-N pentachloroethane Chemical compound ClC(Cl)C(Cl)(Cl)Cl BNIXVQGCZULYKV-UHFFFAOYSA-N 0.000 description 1
- AQIXEPGDORPWBJ-UHFFFAOYSA-N pentan-3-ol Chemical compound CCC(O)CC AQIXEPGDORPWBJ-UHFFFAOYSA-N 0.000 description 1
- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 1
- DLRJIFUOBPOJNS-UHFFFAOYSA-N phenetole Chemical compound CCOC1=CC=CC=C1 DLRJIFUOBPOJNS-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- 229960001860 salicylate Drugs 0.000 description 1
- 229930195734 saturated hydrocarbon Natural products 0.000 description 1
- GQKZRWSUJHVIPE-UHFFFAOYSA-N sec-amyl acetate Natural products CCCC(C)OC(C)=O GQKZRWSUJHVIPE-UHFFFAOYSA-N 0.000 description 1
- 229910000679 solder Inorganic materials 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229960000790 thymol Drugs 0.000 description 1
- BJIOGJUNALELMI-UHFFFAOYSA-N trans-isoeugenol Natural products COC1=CC(C=CC)=CC=C1O BJIOGJUNALELMI-UHFFFAOYSA-N 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000009637 wintergreen oil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
- C11D7/5018—Halogenated solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/261—Alcohols; Phenols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
- C11D7/5022—Organic solvents containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/28—Organic compounds containing halogen
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
本发明是如下的溶剂组合物:相对于1,1,2,2-四氟乙基-2,2,2-三氟***、反-1,2-二氯乙烯(tDCE)和碳原子数为1-3的醇的总量,1,1,2,2-四氟乙基-2,2,2-三氟***为25.0~75.0%(是质量标准,以下相同),反-1,2-乙氯乙烯是15.0~74.9%、碳原子数1~3的醇是0.1~10.0%。本发明的溶剂组合物能除去熔剂等污物,去污力高。
Description
技术领域
本发明涉及用于除去附着于集成电路等电子部件、精密机械部件、玻璃基板等物品的油脂类、印刷基板等的熔剂、尘埃等污物的溶剂组合物。
背景技术
过去,在精密机械工业、光学机械工业、电气电子工业以及塑料加工业等,为除去在制造加工工序等时附着的油、熔剂、尘埃、蜡等的精密洗净,广泛使用着不燃性和化学及热稳定性优良、对油脂类具有溶解力的含氟溶剂二氯五氟丙烷(以下简称R-225)等氯氟化烃(以下简称HCFC)。
然而,由于HCFC存在臭氧破坏系数,在先进国家有2020年完全停止生产的问题。与此不同,1,1,2,2-四氟乙基-2,2,2-三氟***(CHF2CF2OCH2CF3)不存在臭氧破坏系数,是对地球环境影响小的含氟溶剂,但有对油脂类的溶解力低的问题。另一方面,反-1,2-二氯乙烯,对油脂类溶解力高,但存在闪点低至4℃的问题。
已知1,1,2,2-四氟乙基-2,2,2-三氟***与反-1,2-二氯乙烯存在共沸混合物(参照日本特许公开公报平10-324652号中的权利要求3)。然而上述混合物虽具不燃性,且去污力高,但对熔剂等洗时对离子性的污物除去不充分,有时会产生白色残渣等,存在问题。
发明内容
本发明提供含1,1,2,2-四氟乙基-2,2,2-三氟***(R347)、反-1,2-二氯乙烯(tDCE)与碳原子数1~3的醇(ROH)的溶剂组合物(以下称组合物A),其特征在于,对于(R347)、(tDCE)和(ROH)的总量,(R347)的含量是25.0~75.0%(是质量标准,以下无特别说明时,含量均是质量标准),(tDCE)的含量是15.0~74.9%,(ROH)的含量是0.1~10.0%。
本发明提供含1,1,2,2-四氟乙基-2,2,2-三氟***(R347)、反-1,2-二氯乙烯(tDCE)和甲醇(MeOH)的溶剂组合物(以下称组合物B),其特征在于,对于(R347)、(tDCE)和(MeOH)的总量,(R347)的含量是35.0~55.0%,(tDCE)的含量是39.0~61.0%,(MeOH)的含量是4.0~6.0%。
本发明提供含1,1,2,2-四氟乙基-2,2,2-三氟***(R347)、反-1,2-二氯乙烯(tDCE)和乙醇(EtOH)的溶剂组合物(以下称组合物C),其特征在于,对于(R347)、(tDCE)和(EtOH)的总量,(R347)的含量是39.0~59.0%,(tDCE)的含量是37.5~59.5%,(EtOH)的含量是1.5~3.5%。
本发明提供含1,1,2,2-四氟乙基-2,2,2-三氟***(R347)、反-1,2-二氯乙烯(tDCE)和2-丙醇(IPA)的溶剂组合物(以下称组合物D),其特征在于,对于(R347)、(tDCE)和(IPA)的总量,(R347)的含量是40.0~60.0%,(tDCE)的含量是39.0~59.9%,(IPA)的含量是0.1~1.0%。
本发明提供由1,1,2,2-四氟乙基-2,2,2-三氟***(R347)、反-1,2-二氯乙烯(tDCE)和甲醇(MeOH)组成的溶剂组合物(以下称组合物E),其特征在于,对于(R347)、(tDCE)和(MeOH)的总量,(R347)的含量是44.9%,(tDCE)的含量是50.0%,(MeOH)的含量是5.1%。
本发明提供由1,1,2,2-四氟乙基-2,2,2-三氟***(R347)、反-1,2-二氯乙烯(tDCE)和乙醇(EtOH)组成的溶剂组合物(以下称组合物F),其特征在于,对于(R347)、(tDCE)和(EtOH)的总量,(R347)的含量是49.0%,(tDCE)的含量是48.5%,(EtOH)的含量是2.5%。
本发明提供由1,1,2,2-四氟乙基-2,2,2-三氟***(R347)、反-1,2-二氯乙烯(tDCE)和2-丙醇(IPA)组成的溶剂组合物(以下称组合物G),其特征在于,对于(R347)、(tDCE)和(IPA)的总量,(R347)的含量是49.7%,(tDCE)的含量是50.0%,(IPA)的含量是0.3%。
本发明的溶剂组合物通过含有规定量的碳原子数1~3的醇,对熔剂的洗净等,特别是离子性污物的除去,具有优良的去污力。
具体实施方式
组合物A,闪点高于室温(25℃),或其组成在沸腾状态不着火,具有不燃性。而且对于油脂类和熔剂类去污力高。
作为组合物A的碳原子数1~3的醇,例如可列举甲醇、乙醇、1-丙醇、2-丙醇。
组合物A特好是对于1,1,2,2-四氟乙基-2,2,2-三氟***(R347)、反-1,2-二氯乙烯和碳原子数1~3的醇的总量,1,1,2,2-四氟乙基-2,2,2-三氟***为30.0~65.0%(以质量计),反-1,2-二氯乙烯为25.0~69.9%(以质量计),碳原子数1~3的醇为0.1~10.0%(以质量计)的溶剂组合物。
组合物E、F、G都为共沸溶剂组合物。共沸溶剂组合物是指反复蒸发、冷凝该组合物,组成也不变化的组合物。
而组合物B、C、D由于反复蒸发、冷凝该组合物组成变化小,是实际上可和共沸溶剂组合物同样方法使用的组合物。这样的组合物,一般称为共沸样溶剂组合物。
在使用组合物B、C、D、E、F、G洗净物品等时,由于该组合物的组成变化小或无变化,使用时可维持稳定的洗净性能。而且由于可使用与以前用的R225同样的装置洗净。而且由于可使用与以前用的R225同样的装置洗净,优点是以前的技术不需要大幅度改变。
组合物A~G,仅由1,1,2,2-四氟乙基-2,2,2-三氟***、反-1,2-二氯乙烯和碳原子数1~3的醇(组合物B~G内特定的醇)组成较好,但也可以再含其他化合物。这里,组合物B、C、D的场合,在实际上保持共沸样溶剂组合物的范围内,组合物E、F、G的场合,在实际上保持共沸溶剂组合物的性质的范围内,可以分别含有其他化合物。
作为其他化合物可列举选自烃类、醇类(碳原子数1~3的醇除外)、酮类、卤代烃类(反-1,2-二氯乙烯除外)、醚类、酯类及乙二醇醚类中的至少1种。这些化合物在溶剂组合物中的含量比,较好小于等于20质量%,更好小于等于10质量%。其他化合物含量的下限,是能达到添加该化合物的目的的是低限度的量。通常,该最低限度的量对于溶剂组合物总量是大于等于0.1质量%。含其他化合物的溶剂组合物中存在共沸组成的场合,最好使用其共沸组成。
作为烃类,较好是碳原子数5~15的链状或环状的饱和或不饱和烃类,可列举正戊烷、2-甲基丁烷、正己烷、2-甲基戊烷、2,2-二甲基丁烷、2,3-二甲基丁烷、正庚烷、2-甲基己烷、3-甲基己烷、2,4-二甲基戊烷、正辛烷、2-甲基庚烷、3-甲基庚烷、4-甲基庚烷、2,2-二甲基己烷、2,5-二甲基己烷、3,3-二甲基己烷、2-甲基-3-乙基戊烷、3-甲基-3-乙基戊烷、2,3,3-三甲基戊烷、2,3,4-三甲基戊烷、2,2,3-三甲基戊烷烷、2-甲基庚烷烷、2,2,4-三甲基戊烷烷、正壬烷烷、2,2,5-三甲基己烷烷、正癸烷烷、正十一碳烷烷、环戊烷、甲基环戊烷、环己烷、甲基环己烷、乙基环己烷、二环己烷、十氢化萘、四氢化萘、戊基萘等。更好是正戊烷、环戊烷、正己烷、环己烷、正庚烷等碳原子数5~7的烃。
作为醇类,较好是碳原子数4~16的链状或环状的饱和或不饱和醇类,可列举正丁醇、仲丁醇、异丁醇、叔丁醇、1-戊醇、2-戊醇、1-乙基-1-丙醇、2-甲基-1-丁醇、3-甲基-1-丁醇、3-甲基-2-丁醇、新戊醇、1-己醇、2-甲基-1-戊醇、4-甲基-2-戊醇、2-乙基-1-丁醇、1-庚醇、2-庚醇、3-庚醇、1-辛醇、2-辛醇、2-乙基-1-己醇、1-壬醇、3,5,5-三甲基-1-己醇、1-癸醇、1-十-烷醇、1-十二烷醇、环己醇、1-甲基环己醇、2-甲基环己醇、3-甲基环己醇醇、4-甲基环己醇、α-萜品醇、2,6-二甲基-4-庚醇、壬醇、十四烷醇等。更好是正丁醇等碳原子数4~5的烷醇。
作为酮类,较好是碳原子数3~9的链状或环状的酮类,具体可列举丙酮、甲基·乙基酮、2-戊酮、3-戊酮、2-己酮、甲基·异丁基酮、2-庚酮、3-庚酮、4-庚酮、二异丁基酮、异亚丙基丙酮、佛尔酮、2-辛酮、环己酮、甲基环己酮、异佛尔酮、2,4-戊二酮酮、2,5-乙二酮等。更好是丙酮、甲基·乙基酮等碳原子数3~4的酮。
作为卤代烃类,较好是碳原子数1~6的氟代或氯氟代烃类,可例举二氯甲烷、1,1-二氯乙烷、1,2-二氯乙烷、1,1,2-三氯乙烷、1,1,1,2-四氯乙烷、1,1,2,2-四氯乙烷、五氯乙烷、1,1-二氯乙烷、顺-1,2-二氯乙烷、三氯乙烷、四氯乙烷、1,2-三氯丙烷、二氯五氟丙烷、二氯氟乙烷、十氟戊烷等。更好是二氯甲烷、三氟乙烯、四氯乙烯等碳原子数1~2的氯代烃。
作为醚类,较好是碳原子数2~8的链状或环状的醚类,可列举二***、二丙醚、二异丙醚、二丁醚、苯甲醚、苯***、甲基苯甲醚、二噁烷、呋喃、甲基呋喃、四氢呋喃等。更好是二***、二异丙醚、二噁烷、四氢呋喃等碳原子数4~6的醚。
作为酯类,较好是碳原子数2~19的链状或环状的酯类,具体可列举甲酸甲酯、甲酸乙酯、甲酸丙酯、甲酸丁酯、甲酸异丁酯、甲酸戊酯、醋酸甲酯、醋酸乙酯、醋酸丙酯、醋酸异丙酯、醋酸丁酯、醋酸异丁酯、醋酸仲丁酯、醋酸戊酯、醋酸甲氧基丁酯、醋酸仲己酯、醋酸2-乙基丁酯、醋酸2-乙基己酯、醋酸环己酯、醋酸苄酯、丙酸甲酯、丙酸乙酯、丙酸丁酯、丁酸甲酯、丁酸乙酯、丁酸丁酯、异丁酸异丁酯、2-羟基-2-甲基丙酸乙酯、苯甲酸甲酯、苯甲酸乙酯、苯甲酸丙酯、苯甲酸丁酯、苯甲酸苄酯、γ-丁内酯酯、草酸二乙酯、草酸二丁酯、草酸二戊酯、丙二酸二乙酯、马来酸二甲酯、马来酸二乙酯、马来酸二丁酯、酒石酸二丁酯、柠檬酸三丁酯、癸二酸二丁酯、邻苯二酸二甲酯、邻苯二酸二乙酯、邻苯二酸二丁酯等。更好是醋酸甲酯、醋酸乙酯等碳原子数3~4的酯。
作为乙二醇醚类,是碳原子数2~4的二元醇的2~4聚体中的1个或2个羟基的氢原子被碳原子数1~6的烷基取代的化合物,较好是二乙二醇的烷基醚类或二丙二醇的烷基醚类。具体可列举二乙二醇单甲醚、二乙二醇单***、二乙二醇单正丙醚、二乙二醇单异丙醚、二乙二醇单正丁醚、二乙二醇单异丁醚、二乙二醇二甲醚、二乙二醇二***、二乙二醇二丁醚等二乙二醇的醚类、二丙二醇单甲醚、二丙二醇单***、二丙二醇单正丙醚、二丙二醇单异丙醚、二丙二醇单正丁醚、二丙二醇单异丁醚等的二丙二醇的醚类等。
而且主要为提高稳定性,在组合物A~G中可在0.001~5质量%的范围内配合例如以下列举的化合物的1种或2种以上。但是组合物B、C、D的场合,在实际上保持共沸样溶剂组合物的性质的范围内,组合物E、F、G的场合是在实际上保持共沸溶剂组合物的性质的范围内,配合该化合物。
硝基甲烷、硝基乙烷、硝基丙烷、硝基苯等硝基化合物类。二乙胺、三乙胺、异丙胺、正丁胺等胺类;苯酚、邻甲苯酚、间甲苯酚、对甲苯酚、百里香酚、对叔丁基苯酚、叔丁基邻苯二酚、邻苯二酚、异丁子香酚、邻甲氧基苯酚、双酚A、水杨酸异戊酯、水杨酸苄酯、水杨酸甲酯、2,6-二叔丁基对甲苯酚等酚类;2-(2′-羟基-5′-甲基苯基)苯并***、2-(2′-羟基-3′-叔丁基-5′-甲基苯基)-5-氯苯并***,1,2,3-苯并***、1-[(N,N-双-2-乙基己基)氨基甲基]苯并***等***类。
组合物A~G适用于与以前R-225类组合物同样的各种用途。具体的用途有除去附着于物品的污物的洗净剂、在物品上涂布各种化合物时用的该化合物的稀释溶剂或抽提剂。上述物品的材质可列举玻璃、陶瓷、塑料、弹性体、金属等。而作为物品的具体例子,可列举电子、电气机器、精密机械、器具、光学机械等,以及作为其部件的集成电路、微型发动机、断电器、轴承、光学透镜、印刷基板、玻璃基板等。
附着于物品的污物,可列举物品或构成物品的部件制造时所使用而最后必须除去的污物,或物品使用时附着的污物。形成污物的物质可列举润滑脂类、矿物油类、蜡类、油性墨水类等油脂类、熔剂类和尘埃。
上述污物的具体除去方法,可列举例如手揩洗净、浸渍洗净、喷雾洗净、振摇洗净、超声波洗净、蒸气洗净等。并且可采用组合上述方法的方法等。
组合物A、B、C、D,通过改变组成比,可调整对污物等的溶解力。
实施例
以下说明本发明的实施例和比较例。
例1-5、7-11、13-17、19-23、25-29、31-35、37-41、43-47、49-53、55-67、69-72为实施例,例6、12、18、24、30、36、42、48、54、68为比较例。
汇总试验结果的各表中的简称表示下述意义:
R347:1,1,2,2-四氟乙基-2,2,2-三氟***
TDCE:反-1,2-二氯乙烯
MeOH:甲醇
EtOH:乙醇
IPA:2-丙醇
〔例1-6〕
用表1所述组成形成的溶剂组合物,采用克利夫兰开放式闪点测定器依据ASTM D92-90记载的方法测定25℃、40℃、溶剂组合物沸腾状态时闪点的有无。结果示于表1。
表1
例 | R347 | tDCE | MeOH | 25℃时的闪点 | 40℃时的闪点 | 沸腾状态时的闪点 |
1 | 25.0 | 74.9 | 0.1 | 无 | 有 | - |
2 | 35.0 | 61.0 | 4.0 | 无 | 无 | 无 |
3 | 44.9 | 50.0 | 5.1 | 无 | 无 | 无 |
4 | 55.0 | 39.0 | 6.0 | 无 | 无 | 无 |
5 | 75.0 | 15.0 | 10.0 | 无 | 无 | 无 |
6 | 20.0 | 79.9 | 0.1 | 有 | - | - |
〔例7-12〕
用表2所述组成形成的溶剂组合物,采用克利夫兰开放式闪点测定器依据ASTM D 92-90记载的方法测定25℃、40℃、溶剂组合物沸腾状态时闪点的有无。结果示于表2。
表2
例 | R347 | tDCE | EtOH | 25℃时的闪点 | 40℃时的闪点 | 沸腾状态时的闪点 |
7 | 25.0 | 74.9 | 0.1 | 无 | 有 | - |
8 | 39.0 | 59.5 | 1.5 | 无 | 无 | 无 |
9 | 49.0 | 48.5 | 2.5 | 无 | 无 | 无 |
10 | 59.0 | 37.5 | 3.5 | 无 | 无 | 无 |
11 | 75.0 | 15.0 | 10.0 | 无 | 无 | 无 |
12 | 20.0 | 79.9 | 0.1 | 有 | - | - |
〔例13-18〕
用表3所述组成形成的溶剂组合物,采用克利夫兰开放式闪点测定器依据ASTM D 92-90记载的方法测定25℃、40℃、溶剂组合物沸腾状态时闪点的有无。结果示于表3。
表3
例 | R347 | tDCE | IPA | 25℃时的闪点 | 40℃时的闪点 | 沸腾状态时的闪点 |
13 | 25.0 | 74.9 | 0.1 | 无 | 有 | |
14 | 40.0 | 59.9 | 0.1 | 无 | 无 | 无 |
15 | 49.7 | 50.0 | 0.3 | 无 | 无 | 无 |
16 | 60.0 | 39.0 | 1.0 | 无 | 无 | 无 |
17 | 75.0 | 15.0 | 10.0 | 无 | 无 | 无 |
18 | 20.0 | 79.9 | 0.1 | 有 | - | - |
〔例19-24〕
用表4所述组成形成的溶剂组合物,进行金属加工油的洗净试验。即将SUS-304的试验片(25mm×30mm×2mm)浸渍在金属加工油テンパ—オイル(日本グリ—ス社制)中,使金属加工油附着。从该金属加工油中取出该试验片后,将其浸渍在40℃保温的该溶剂组合物中,以超声波洗净5分钟。对洗净后的试验片目视评价金属加工油的除去程度。结果示于表4。表4中,○表示能很好除去,△表示稍有残留,×表示残留。
表4
例 | R347 | tDCE | MeOH | 油的除去情况 |
19 | 25.0 | 74.9 | 0.1 | ○ |
20 | 35.0 | 61.0 | 4.0 | ○ |
21 | 44.9 | 50.0 | 5.1 | ○ |
22 | 55.0 | 39.0 | 6.0 | ○ |
23 | 75.0 | 15.0 | 10.0 | ○ |
24 | 80.0 | 19.9 | 0.1 | △ |
[例25-30]
除使用表5所示组成形成的溶剂组合物之外,与例19~24同样,进行金属加工油的洗净试验。结果示于表5。表5中,○表示能很好除去,△表示稍有残留,×表示残留。
表5
例 | R347 | tDCE | EtOH | 油的除去情况 |
25 | 25.0 | 74.9 | 0.1 | ○ |
26 | 39.0 | 59.5 | 1.5 | ○ |
27 | 49.0 | 48.5 | 2.5 | ○ |
28 | 59.0 | 37.5 | 3.5 | ○ |
29 | 75.0 | 15.0 | 10.0 | ○ |
30 | 80.0 | 19.9 | 0.1 | △ |
[例31-36]
除使用表6所示的组成形成的溶剂组合物之外,与例19~24同样,进行金属加工油的洗净试验。结果示于表6。表6中,○表示能很好除去,△表示稍有残留,×表示残留。
表6
例 | R347 | tDCE | IPA | 油的除去情况 |
31 | 25.0 | 74.9 | 0.1 | ○ |
32 | 40.0 | 59.9 | 0.1 | ○ |
33 | 49.7 | 50.0 | 0.3 | ○ |
34 | 60.0 | 39.0 | 1.0 | ○ |
35 | 75.0 | 15.0 | 10.0 | ○ |
36 | 20.0 | 79.9 | 0.1 | △ |
[例37-42]
除使用表7所示组成形成的溶剂组合物进行熔剂洗净试验,即在IPC B-25的梳形电极基板上涂弘辉株式会社制的熔剂JS-64ND,于100℃干燥10分钟后于260℃的焊料浴中浸渍3秒钟,使焊料附着。于室温静置24小时后将该梳形电极基板浸渍在保温于40℃的表7记载的溶剂组合物中5分钟,将其洗净,目视评价熔剂的除去度。结果示于表7。表7中,○表示能很好除去,△表示有微量白色残渣残留,×表示有很多白色残渣残留。
表7
例 | R347 | tDCE | MeOH | 白色残渣的残留 |
37 | 25.0 | 74.9 | 0.1 | ○ |
38 | 35.0 | 61.0 | 4.0 | ○ |
39 | 44.9 | 50.0 | 5.1 | ○ |
40 | 55.0 | 39.0 | 6.0 | ○ |
41 | 75.0 | 15.0 | 10.0 | ○ |
42 | 80.0 | 19.9 | 0.1 | × |
[例43-48]
除使用表8所述组成形成的溶剂组合物之外,与例37-42同样进行熔剂洗净试验。结果示于表8。表8中,○表示能很好除去,△表示有微量白色残渣残留,×表示有很多白色残渣残留。
表8
例 | R347 | tDCE | EtOH | 白色残渣的残留 |
43 | 25.0 | 74.9 | 0.1 | ○ |
44 | 39.0 | 59.0 | 1.5 | ○ |
45 | 49.0 | 48.5 | 2.5 | ○ |
46 | 59.0 | 37.5 | 3.5 | ○ |
47 | 75.0 | 15.0 | 10.0 | ○ |
48 | 80.0 | 19.9 | 0.1 | △ |
[例49-54]
除使用表9所述组成形成的溶剂组合物之外,与例37-42同样进行熔剂洗净试验。结果示于表9。表9中,○表示能很好除去,△表示有微量白色残渣残留,×表示有很多白色残渣残留。
表9
例 | R347 | tDCE | IPA | 白色残渣的残留 |
49 | 25.0 | 74.9 | 0.1 | ○ |
50 | 40.0 | 59.9 | 0.1 | ○ |
51 | 49.7 | 50.0 | 0.3 | ○ |
52 | 60.0 | 39.0 | 1.0 | ○ |
53 | 75.0 | 15.0 | 10.0 | ○ |
54 | 20.0 | 79.9 | 0.1 | × |
[例55-59]
将表10所述的溶剂组合物20kg置于小型单槽式开放型洗净机中运转3日,每日6小时。运转条件,是洗净槽中仅加入溶剂组合物,将该组合物加热、蒸发、冷凝后,引入水分离器,再回到洗净槽,使每小时的循环量等于加入的组合物的量。动转18小时后从水分离器取样,以气相色谱法分析,结果示于表10。
表10
例 | 运转前的组成比(以质量计) | 运转18小时后的组成比(以质量计) |
R347/tDCE/MeOH | R347/tDCE/MeOH | |
55 | 35.0/61.0/4.0 | 35.6/60.1/4.3 |
56 | 44.9/50.0/5.1 | 44.9/50.0/5.1 |
57 | 55.0/39.0/6.0 | 54.4/40.0/5.6 |
58 | 30.0/65.0/5.0 | 36.4/62.9/0.7 |
59 | 70.0/28.0/2.0 | 63.8/35.2/1.0 |
[例60-64]
除使用表11所述的溶剂组合物以外,与例55~59同样用洗净机进行运转试验。结果示于表11。
表11
例 | 运转前的组成比(以质量计) | 运转18小时后的组成比(以质量计) |
R347/tDCE/EtOH | R347/tDCE/EtOH | |
60 | 39.0/59.5/1.5 | 39.8/58.1/2.1 |
61 | 49.0/48.5/2.5 | 49.0/48.5/2.5 |
62 | 59.0/37.5/3.5 | 58.5/38.2/3.3 |
63 | 30.0/60.0/10.0 | 34.6/59.0/6.4 |
64 | 70.0/29.0/1.0 | 61.3/37.3/1.4 |
[例65-69]
除使用表12所述的溶剂组合物以外,与例55~59同样用洗净机进行运转试验。结果示于表12。
表12
例 | 运转前的组成比(以质量计) | 运转18小时后的组成比(以质量计) |
R347/tDCE/IPA | R347/tDCE/IPA | |
65 | 40.0/59.9/0.1 | 40.4/59.4/0.2 |
66 | 49.7/50.0/0.3 | 49.7/50.0/0.3 |
67 | 60.0/39.0/1.0 | 59.4/40.0/0.6 |
68 | 20.0/70.0/10.0 | 28.3/64.5/7.2 |
69 | 65.0/33.0/2.0 | 58.7/38.0/3.3 |
[例70]
在Othmer型气液平衡装置中加入347/tDCE/MeOH=44.9质量%/50.0质量%/5.1质量%的组合物300g,在1010hPa下气相与液相的温度达到平衡状态时,从气相和液相采取该组合物的样品,用气相色谱法测定组成比。结果示于表13。
表13
时间 | 气相组成比(以质量计) | 液相组成比(以质量计) |
R5213/tDE/MeOH | R5213/tDE/MeOH | |
蒸馏前 | 44.9/50.0/5.1 | 44.9/50.0/5.1 |
平衡后 | 44.9/50.0/5.1 | 44.9/50.0/5.1 |
[例71]
在Othmer型气液平衡装置中加入347/tDCE/EtOH=49.0质量%/48.5质量%/2.5质量%的组合物300g,在1010hPa下气相与液相的温度达到平衡状态时,从气相和液相采取该组合物的样品,用气相色谱法测定组成比。结果示于表14。
表14
时间 | 气相组成比(以质量计) | 液相组成比(以质量计) |
R5213/tDE/MeOH | R5213/tDE/MeOH | |
蒸留前 | 49.0/48.5/2.5 | 49.0/48.5/2.5 |
平衡后 | 49.0/48.5/2.5 | 49.0/48.5/2.5 |
[例72]
在Othmer型气液平衡装置中加入347/tDCE/IPA=49.7质量%/50.0质量%/0.3质量%的组合物300g,在1010hPa下气相与液相的温度达到平衡状态时,从气相和液相采取该组合物的样品,用气相色谱法测定组成比。结果示于表15。
表15
时间 | 气相组成比(以质量计) | 液相组成比(以质量计) |
R5213/tDE/IPA | R5213/tDE/IPA | |
蒸留前 | 49.7/50.0/0.3 | 49.7/50.0/0.3 |
平衡后 | 49.7/50.0/0.3 | 49.7/50.0/0.3 |
本发明的溶剂组合物(组合物A~G)对各种污物去污力高,闪点高于室温。而且,组合物B、C、D是共沸样溶剂组合物,组合物E、F、G是共沸溶剂组合物,因而这些组合物即使再循环用于蒸气洗净和蒸馏等其组成不变化或者变化很小,洗净性和各种物性没有变化。所以,可以不大幅变更以前使用的洗净装置。
产业上利用的可能性
本发明的溶剂组合物,可高去污力地除去电子部件、精密机械部件、玻璃基板等物品附着的油脂类、印刷基板等的熔剂、尘埃等污物。
Claims (7)
1.溶剂组合物,它是含有1,1,2,2-四氟乙基-2,2,2-三氟***(R347)、反-1,2-二氯乙烯(tDCE)和碳原子数为1-3的醇(ROH)的溶剂组合物,其特征在于,相对于(R347)、(tDCE)和(ROH)的总量,(R347)的含量为25.0-75.0质量%;(tDCE)的含量为15.0-74.9质量%;(ROH)的含量为0.1-10.0质量%。
2.溶剂组合物,它是含有1,1,2,2-四氟乙基-2,2,2-三氟***(R347)、反-1,2-二氯乙烯(tDCE)和甲醇(MeOH)的溶剂组合物,其特征在于,相对于(R347)、(tDCE)和(MeOH)的总量,(R347)的含量为35.0-55.0质量%;(tDCE)的含量为39.0-61.0质量%;(MeOH)的含量为4.0-6.0质量%。
3.溶剂组合物,它是含有1,1,2,2-四氟乙基-2,2,2-三氟***(R347)、反-1,2-二氯乙烯(tDCE)和乙醇(EtOH)的溶剂组合物,其特征在于,相对于(R347)、(tDCE)和(EtOH)的总量,(R347)的含量为39.0-59.0质量%;(tDCE)的含量为37.5-59.5质量%;(EtOH)的含量为1.5-3.5质量%。
4.溶剂组合物,它是含有1,1,2,2-四氟乙基-2,2,2-三氟***(R347)、反-1,2-二氯乙烯(tDCE)和2-丙醇(IPA)的溶剂组合物,其特征在于,相对于(R347)、(tDCE)和(IPA)的总量,(R347)的含量为40.0-60.0质量%;(tDCE)的含量为39.0-59.9质量%;(IPA)的含量为0.1-1.0质量%。
5.溶剂组合物,它是含有1,1,2,2-四氟乙基-2,2,2-三氟***(R347)、反-1,2-二氯乙烯(tDCE)和甲醇(MeOH)的溶剂组合物,其特征在于,相对于(R347)、(tDCE)和(MeOH)的总量,(R347)的含量为44.9质量%;(tDCE)的含量为50.0质量%;(MeOH)的含量为5.1质量%。
6.溶剂组合物,它是含有1,1,2,2-四氟乙基-2,2,2-三氟***(R347)、反-1,2-二氯乙烯(tDCE)和乙醇(EtOH)的溶剂组合物,其特征在于,相对于(R347)、(tDCE)和(EtOH)的总量,(R347)的含量为49.0质量%;(tDCE)的含量为48.5质量%;(EtOH)的含量为2.5质量%。
7.溶剂组合物,它是含有1,1,2,2-四氟乙基-2,2,2-三氟***(R347)、反-1,2-二氯乙烯(tDCE)和2-丙醇(IPA)的溶剂组合物,其特征在于,相对于(R347)、(tDCE)和(IPA)的总量,(R347)的含量为49.7质量%;(tDCE)的含量为50.0质量%;(IPA)的含量为0.3质量%。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP194888/2002 | 2002-07-03 | ||
JP2002194888 | 2002-07-03 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1665917A true CN1665917A (zh) | 2005-09-07 |
CN1288231C CN1288231C (zh) | 2006-12-06 |
Family
ID=30112316
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB03815725XA Expired - Fee Related CN1288231C (zh) | 2002-07-03 | 2003-07-03 | 溶剂组合物 |
Country Status (8)
Country | Link |
---|---|
US (1) | US7163645B2 (zh) |
JP (1) | JP4556669B2 (zh) |
KR (1) | KR101002202B1 (zh) |
CN (1) | CN1288231C (zh) |
AU (1) | AU2003281307A1 (zh) |
CA (1) | CA2491467C (zh) |
TW (1) | TW200402411A (zh) |
WO (1) | WO2004005445A1 (zh) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101679922B (zh) * | 2007-06-08 | 2011-11-09 | 旭硝子株式会社 | 清洗溶剂及清洗方法 |
CN107207981A (zh) * | 2015-01-27 | 2017-09-26 | 旭硝子株式会社 | 润滑剂溶液以及具有润滑剂涂膜的物品的制造方法 |
US10662134B2 (en) | 2016-01-29 | 2020-05-26 | AGC Inc. | Solvent composition, cleaning method, coating film-forming composition, and method of forming a coating film |
US10669502B2 (en) | 2016-02-09 | 2020-06-02 | AGC Inc. | Solvent composition, cleaning method, coating film-forming composition, and method of forming a coating film |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2861390B1 (fr) * | 2003-10-24 | 2006-01-21 | Arkema | Stabilisation du trans-1,2-dichlorethylene |
US7273839B2 (en) * | 2004-10-20 | 2007-09-25 | Tarksol International L.L.C. | Method to increase flash points of flammable solvents |
US20070087951A1 (en) * | 2005-10-19 | 2007-04-19 | Hynix Semiconductor Inc. | Thinner composition for inhibiting photoresist from drying |
WO2007105724A1 (ja) * | 2006-03-14 | 2007-09-20 | Asahi Glass Company, Limited | 熱サイクル用作動媒体、ランキンサイクルシステム、ヒートポンプサイクルシステムおよび冷凍サイクルシステム |
JP2010001319A (ja) * | 2006-10-19 | 2010-01-07 | Asahi Glass Co Ltd | 共沸溶剤組成物、擬共沸溶剤組成物および混合溶剤組成物 |
US9909017B2 (en) | 2013-11-01 | 2018-03-06 | Zyp Coatings, Inc. | Miscible solvent system and method for making same |
US9434824B2 (en) | 2014-03-31 | 2016-09-06 | Zyp Coatings, Inc. | Nonflammable solvent compositions for dissolving polymers and resulting solvent systems |
US9260595B1 (en) | 2014-08-26 | 2016-02-16 | Zyp Coatings, Inc. | N-propyl bromide solvent systems |
US9816057B2 (en) | 2014-10-24 | 2017-11-14 | Edo Shellef | Nonflammable composition containing 1,2-dichloroethylene |
JPWO2018101324A1 (ja) * | 2016-11-30 | 2019-10-24 | Agc株式会社 | 溶剤組成物およびポリウレタン樹脂の除去方法 |
US10829722B2 (en) | 2016-12-28 | 2020-11-10 | Enviro Tech International, Inc. | Azeotrope-like composition |
KR101877379B1 (ko) * | 2018-01-29 | 2018-08-09 | (주)비엔에프 | 전력이 공급중인 전기 및 전자통신장비에 화재발생의 위험 없이 사용 가능한 세정제 조성물 및 이를 이용한 세정 장치 |
CN109706008B (zh) * | 2019-02-26 | 2020-11-24 | 上海锐一环保科技有限公司 | 一种含八氟戊基烯烃醚的卤代烃组合溶剂及其应用 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3539462A (en) * | 1968-10-17 | 1970-11-10 | Union Carbide Corp | Azeotropic composition |
US4877545A (en) * | 1988-12-29 | 1989-10-31 | E. I. Du Pont De Nemours And Company | Azeotropic compositions of 1,1,2-trichlorotrifluoroethane and trans-1,2-dichloroethylene with ethanol, N-propanol, isopropanol and acetone or with ethanol or acetone and nitromethane |
US4936923A (en) * | 1989-03-01 | 1990-06-26 | E. I. Du Pont De Nemours And Company | Azeotropic compositions of 1,1,2-trichlorotrifluoroethane with cis-1,2-dichloroethylene and n-propanol or isopropanol with or without nitromethane |
US4999127A (en) * | 1989-12-11 | 1991-03-12 | E. I. Du Pont De Nemours And Company | Azeotropic composition of 2-chloro-1,1,2-trifluoroethyl-2-difluoromethyl ether with trans-1,2-dichloroethylene and methnanol |
DE4013369A1 (de) * | 1990-04-26 | 1991-10-31 | Hoechst Ag | Neues azeotropes oder azeotropartiges gemisch aus 2,2,2-trifluorethyl-1,1,2,2-tetrafluorethylether und ethanol sowie dessen verwendung |
US5126067A (en) * | 1990-06-05 | 1992-06-30 | Allied-Signal Inc. | Azeotrope-like compositions of 1,1-dichloro-1-fluoroethane, 1,2-dichloroethylene and optionally an alkanol |
DE4218966A1 (de) * | 1992-06-10 | 1993-12-16 | Hoechst Ag | Isopropanolhaltige Reinigungslösungen mit erhöhtem Flammpunkt |
US6395699B1 (en) * | 1995-08-14 | 2002-05-28 | Asahi Glass Company Ltd. | Method of removing grease, oil or flux from an article |
US6030934A (en) * | 1997-02-19 | 2000-02-29 | 3M Innovative Properties Company | Azeotropic compositions of methoxy-perfluoropropane and their use |
JP3141074B2 (ja) * | 1997-05-22 | 2001-03-05 | 工業技術院長 | 含フッ素エーテルとアルコール類からなる共沸及び共沸様組成物 |
JP2879847B2 (ja) * | 1997-05-22 | 1999-04-05 | 工業技術院長 | 含フッ素エーテルと塩素系有機溶剤からなる共沸及び共沸様組成物 |
US6852684B1 (en) * | 1998-09-21 | 2005-02-08 | E. I. Du Pont De Nemours And Company | Non-flammable, high-solvency compositions comprising trans-1,2-dichloroethylene, solvent, and inerting agent |
JP3378913B2 (ja) * | 2000-06-09 | 2003-02-17 | 独立行政法人産業技術総合研究所 | 共沸又は共沸様組成物 |
US6699829B2 (en) * | 2002-06-07 | 2004-03-02 | Kyzen Corporation | Cleaning compositions containing dichloroethylene and six carbon alkoxy substituted perfluoro compounds |
-
2003
- 2003-07-03 KR KR1020047021505A patent/KR101002202B1/ko active IP Right Grant
- 2003-07-03 WO PCT/JP2003/008497 patent/WO2004005445A1/ja active Application Filing
- 2003-07-03 TW TW092118238A patent/TW200402411A/zh not_active IP Right Cessation
- 2003-07-03 CA CA2491467A patent/CA2491467C/en not_active Expired - Fee Related
- 2003-07-03 JP JP2004519261A patent/JP4556669B2/ja not_active Expired - Fee Related
- 2003-07-03 AU AU2003281307A patent/AU2003281307A1/en not_active Abandoned
- 2003-07-03 CN CNB03815725XA patent/CN1288231C/zh not_active Expired - Fee Related
-
2005
- 2005-01-03 US US11/026,092 patent/US7163645B2/en not_active Expired - Lifetime
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101679922B (zh) * | 2007-06-08 | 2011-11-09 | 旭硝子株式会社 | 清洗溶剂及清洗方法 |
CN107207981A (zh) * | 2015-01-27 | 2017-09-26 | 旭硝子株式会社 | 润滑剂溶液以及具有润滑剂涂膜的物品的制造方法 |
CN107207981B (zh) * | 2015-01-27 | 2021-01-12 | Agc株式会社 | 润滑剂溶液以及具有润滑剂涂膜的物品的制造方法 |
US10662134B2 (en) | 2016-01-29 | 2020-05-26 | AGC Inc. | Solvent composition, cleaning method, coating film-forming composition, and method of forming a coating film |
TWI716536B (zh) * | 2016-01-29 | 2021-01-21 | 日商Agc股份有限公司 | 溶劑組成物、洗淨方法、塗膜形成用組成物及塗膜之形成方法 |
US10669502B2 (en) | 2016-02-09 | 2020-06-02 | AGC Inc. | Solvent composition, cleaning method, coating film-forming composition, and method of forming a coating film |
Also Published As
Publication number | Publication date |
---|---|
US7163645B2 (en) | 2007-01-16 |
CA2491467C (en) | 2010-10-19 |
KR20050016659A (ko) | 2005-02-21 |
KR101002202B1 (ko) | 2010-12-20 |
WO2004005445A1 (ja) | 2004-01-15 |
TWI330663B (zh) | 2010-09-21 |
AU2003281307A1 (en) | 2004-01-23 |
TW200402411A (en) | 2004-02-16 |
US20050109988A1 (en) | 2005-05-26 |
CA2491467A1 (en) | 2004-01-15 |
JPWO2004005445A1 (ja) | 2005-11-04 |
CN1288231C (zh) | 2006-12-06 |
JP4556669B2 (ja) | 2010-10-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1288231C (zh) | 溶剂组合物 | |
CN1038635A (zh) | 卤代烃溶剂及其用途 | |
CN1065564C (zh) | 清洗剂、清洗方法和清洗装置 | |
CN1656207A (zh) | 含有二氯乙烯和六碳烷氧基取代的全氟化合物的清洁组合物 | |
KR960006561B1 (ko) | 혼합 용제 조성물, 이를 이용한 세정 방법 및 세정 장치 | |
CN1283773C (zh) | 溶剂组合物 | |
CN1335879A (zh) | 含有1,1,1,3,3-五氟丁烷的组合物及此种组合物的用途 | |
CN1442474A (zh) | 溶剂组合物 | |
CN1738894A (zh) | 含有氟化烃和含氧溶剂的组合物 | |
JP2013224383A (ja) | 洗浄用溶剤組成物 | |
CN100412184C (zh) | 清洗漂洗方法 | |
CN101035888A (zh) | 共沸样溶剂组合物及混合溶剂组合物 | |
CN85108457A (zh) | 三氯三氟乙烷、乙醇、硝基甲烷和2-甲基戊烷或各种己烷的混合物的类似共沸混合物的组成 | |
CN101263220A (zh) | 共沸溶剂组合物以及混合溶剂组合物 | |
JP3209450B2 (ja) | 洗浄用溶剤組成物 | |
CN1054441A (zh) | 共沸溶剂组合物 | |
CN1496288A (zh) | 使用微乳液除去有机和/或无机污垢清洗固体表面的方法 | |
JP2005281326A (ja) | 溶剤組成物 | |
JP2003327999A (ja) | 溶剤組成物 | |
CN1106614A (zh) | 脱脂组合物 | |
WO2003044148A1 (fr) | Composition de solvants | |
JP2952414B2 (ja) | 溶剤及びそれを用いる物品表面の清浄化方法 | |
JP2010001319A (ja) | 共沸溶剤組成物、擬共沸溶剤組成物および混合溶剤組成物 | |
CN1064075C (zh) | 洗净及干燥用组合物和洗净及干燥方法 | |
JP2004149658A (ja) | 溶剤組成物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CP01 | Change in the name or title of a patent holder | ||
CP01 | Change in the name or title of a patent holder |
Address after: Tokyo, Japan Patentee after: ASAHI GLASS Co.,Ltd. Address before: Tokyo, Japan Patentee before: ASAHI GLASS Co.,Ltd. |
|
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20061206 |